5.7 urban air pollution. major chemical pollutants in photochemical smog: sources and environmental...
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5.7 URBAN AIR POLLUTION
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Major Chemical Pollutants in Photochemical Smog: Sources and Environmental Effects
Toxic Chemical Sources Environmental Effects
Tropospheric Ozone (O3) (ground-level ozone)
-formed as a by-product of photochemical smog- sometimes results from stratospheric ozone moving into troposphere (intrusion)
- eye and respiratory irritation - decreased agricultural yields - slows plant growth - deteriorates plastics and rubber - “sharp” odor
Volatile Organic Compounds (VOC’s)
- evaporation of fuels and solvents - incomplete combustion of fossil fuels - naturally occurring compounds like monoterpenes and sesquiterepnes from trees
- respiratory and eye irritation - some are carcinogenic - decreased visibility due to blue-brown haze (Blue Ridge Mountains)
Nitrogen Oxides commonly called NOx as there are many possible combinations such as NO and NO2, N2O2 etc.
- combustion of fossil fuels eg. oil, coal, gas in both automobiles and industry - bacterial action in soil (see nitrogen cycle Topic 2.2.3)- forest fires - volcanic action - lightning
- decreased visibility due to yellowish color of NO2 - NO2 contributes to heart and lung problems - NO2 can suppress plant growth - decreased immune response - may increase risk of cancer
Peroxyacetyl Nitrates (PAN’s)
- formed by the reaction of NO2 with VOCs (can be formed naturally in some environments)
- eyes, nose and throat irritation - high toxicity to plants - respiratory irritation - damage to proteins
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