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CHEMISTRY اﻟﻌﻠﻤﻲ اﻟﺴﺎدس ﻟﻠﺼﻒ اﻟﻤﺪرس ﺟﺎﺑﺮ اﻟ ﻴﻮﺳﻒ+ ٢٠٠٩ ـ٢٠١٠ ﻣﺘﻔﺎﻋﻠﺔ ﻣﻮاد ﻧﺎﺗﺠﺔ ﻣﻮاد ﻣﺘﻔﺎﻋﻠﺔ ﻣﻮادI H H I I H H I I H H I I H I H

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  • YRTSIMEHC

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    a}_h{0\h%h}.............................................. 1Z...............................................

  • f

    . .

    .

    .

    : , ,/

    :

    / :

    / ,=

    - = = (- +) - = - - / - =

    - :

    = + - = ( -) - = -

    + = + ,= = :

    . :

    , , , , ,= = = ,= = =

    , , ,

    .

    ,= , , ( )

    . = ,:

    ,= ,:

    .

  • ,= ,:

    ,= , ,= , ,= ,

    :

    : ,= ,+ ,= ,+ ,

    - = , - ,= - , - - ,

    . - - ,

    (( ))

    , : ,

    , ,

    - , , ,

    - + ,= - , + , = , ,= + ,= , -= ,=

    1.0 0.0 2.0 3.0 4.0 7.0 6.0 5.0 8.0 9.0 972 552 032 402 671 641 411 970 140 000 1

    264 744 134 514 893 083 263 243 223 103 2 195 085 865 655 445 235 915 505 194 774 3 096 186 276 366 356 446 436 326 316 206 4 177 367 657 847 047 237 427 617 807 996 5 938 338 628 028 318 608 997 297 587 877 6 898 298 788 188 578 968 368 758 158 548 7 949 549 049 539 929 429 919 419 909 309 8 699 199 789 289 879 379 969 469 959 459 9

    = : . + = : .

    : =

    = = :

    , -= ,= : = -= =

  • lCgA

    .

    .

    .

    :

    . .

    .

    2I 2H IH .

    IH IH 2 2I + 2H

    2I 2H

    ]2I [ ]2H[ ]2I[ = - ]2H[ = -

    2I 2H ]2I[ ]2H[

    ......... 2I 2H * .......... 2I 2H * % 2I 2H *

    % [ ]= ]2H[

    ] [ ]2H[

    % = [ ]

    . .( ) . - . . - . / = M \ =

    =

    ( . C ( + ) . O ( + ) . H ) = HOOC3HC . : . .

  • B A C3 B+ A2 / . ( ) A ( ) ( )

    . A , = = ] A [ = ] A [ ] A [ :

    (, - ) ] A [ - . - . ,= -= - = ] A [

    2ON , 4O2N 2ON2 :

    . 2ON % ] 2ON [= ] 2ON [:

    4O2N 2ON2 \ ,= , ] 2ON [ ,= ( , -) ] 2ON [

    , - . - . ,= -= ] 2ON [ -= ] 2ON [

    * * * ] IH [

    += ] IH [

    IH ] IH [ ..... ] IH [ C+ B2 A2 A :

    . C C , ]C [ C :

    - . - . ,= \ ,= ]C [ \ ]C [= ]C [ * * *

    ( ) IH2 2I + 2H

    IH2 2I + 2H ] IH [ - ] IH [= ] IH [ ]2H[ - ]2H[= ]2H[

    ] IH [ - ] IH [ ]2H[ - ]2H[

    + = ] IH [ - = ] 2H [

    ......... ........

    . * . *

    . S g L * . * *

    .

  • , , ]2H[ IH2 2I + 2H : IH2 2I + 2H . , , , ]2H[ - ]2H[ :

    - .- . ,= -= ] 2H [ -= ] 2H [

    , * * *

    . A C3 B2 + A

    M , A . C B , C M , B

    . M ] C [ ] B [ ] A [

    = = = C B A

    : ( )

    . :

    . * . * *

    ] C [ ] A [

    = C A [ C] [ A] [ C] [ A] + -

    += - = C A C A

    2ON , : 4O2N . 4O2N . ,

    2 4O2N 2ON 2ON ,= \ ,= ] 2ON [ \ = ] 2ON [:

    2ON ,= \ ,= ] 2ON [ ( , , ) ] 2ON [ - ] 2ON [

    - . -. , = -= ] 2ON [ -= ] 2ON [

    ] 4O2N [ , ] 4O2N [ ] 2ON [ - . -. ,= ] 4O2N [ = =

    4O2N 2ON ] 4O2N [ ] 4O2N [ - ] 4O2N [

    M ,= ] 4O2N [ = , = ] 4O2N [

  • ,= \ ,= 4O2N M= 4O2N

    IH2 2I + 2H : : ] 2H [ , IH

    ( ) . ] 2H [ % . ] 2H [ ] IH [ IH :

    , ] IH [ -. - . ,= = ] IH [ = ] IH [

    , ] 2H [ ] IH [ ] 2H [

    -. - . ,= ] 2H [ = = IH 2H =

    ,= ] 2H [ ( , ) - ] 2H [

    ] 2H [ M ,= ,= , - = , -= ] 2H [

    ] 2H [= ] 2H [ ] 2H [ \ ,=

    - = ] 2H [ ,=

    \ ( ,- ) - = , = , \,= %

    A , B A2 /

    B % .

    , = ] A [ \ ,= ] A [ \ = ] A [/ ] A [ = ] A [ ] A [

    \ ,= B A2 ,=

    , ] B [ - ] B [ ] A [ - ] B [ ] A [

    = = B A ] B [ ( , - )

    ,= ] B [ + = - ,= B \ ,= B M= B

    : B A2 A / ,/ . A - . -. - - C C A2 :

    \ - . -. A , B2 A :

    , \ . ,= A

  • . M , M , [ 2H] 2rB+2H BH2 / ,/ .

    , 3HN2 2H3 + 2N /

    ( ) ( ) ,/ 2H

    2rB + 2H rBH2 / ( , ) 2rB , 2H , rBH ( )

    rBH . - . -. , rBH ,/ . rBH ---------- = ]2O[ 3OS2 2O + 2OS2 /

    ( / ) 2O ---------- = 3OS ]2OS[ A C2 + B A2 /

    ,= C A % M

    , ,/ B ( A ( :

    A , : B A -. -. ,

    ,= ] A [ \ ,= ] A [ \ = ] A [ : = ] A [

    B A ] A [ - ] A [ , -= ] A [

    ,

    = -= ,

    B , A , C2 B + A :

    - . - . , C C

    A : ] A [ , ] A [ ] C [

    -. - . ,= ] A [ = = A C

    , - ] A [ \= - = , -= ] A [

  • ] C [ ] C [ - ] C [ M ,= ] C [ = , = ] C [

    \

    .

    B A -. C3 B2 + A : .

    B : \ ] A [ \ ] B [ ] A [ ]B [

    -= - = A B

    - ] A [ ] A [ - ] A [ ] B [ - ] B [ - = - - = -

    A = ] A [ + ] A [ -=

    :

    .

    B = \ C3 B + A2 A , = \ M M

    A A B , BA2 B3 + A /

    \ B . BA A

    ,= ] B [ \ ,= ] B [ \ = ] B [: ] B [ ,= ] B [

    , - ] B [ -. -. ,= ] B [ - = ] B [ - = ] B [

    BA2 B3 + A , , ] A [ ] B [ ] A [

    = =

    , , B A -. -. ,= ] A [

    = A , ] A [ - ] A [= ] A [

    ] A [ , -= ] A [ ,= ] A [ ( , - ) A[ ]

    A -. ,= -= , -= ] A [

    ] A [

  • \ ] A [ - ] A [ \ ] BA [ - ] BA [ ] A [ ]B A[

    -= = A A B

    , - - ] BA [

    BA ,= ] BA [ -=

    ,= BA \ ,= BA

    ( ) 2OC2 2O + OC2 / = OC ( ) 2O ]2OC[ ]OC[ : 2O %

    2O OC :

    = OC = =

    \ = ] OC[ ] OC[ = ] OC[ OC ,= ] OC[

    ,= ]2O[ = ]2O[ - , ]2O[ ]2O[

    -. -. ,= ]2O[ -= ]2O[ - = ]2O[

    , ]OC[ ]2O[ ]OC[ -. -. ,= ]OC[ = =

    2O OC ] OC [ = \ ,= , \ ]OC[= ]OC[

    :

    OC ]OC[ = ]2OC[ 2OC

    -. =

    : M = ]2O[= ]OC[

    + - + - ]2O[ ]2O[ ]OC[ ]OC[ OC 2O M = = - = -

    - ]2O[ ]2O[ ,= - = ,= -= ]2O[

    OC 2O ( ) 2OC2 2O + OC2 /

    ( ) , ,/ -

  • C , A + B2 C2 / . -. -. , -. -. , C

    ,/ . A , B A2 /

    B , / . A

    3HN2 2H3+ 2N / ,= ]2N[

    %

    .

    .

    . .

    .

    2N + O2H2 ON2 + 2H2 -. -. N2 H [2 ] ] ON [

    , , , , , ,

    ]ON[ ]2H[ ]ON[

    ]ON[ . ]ON[ ]2H[

    . ]2H[ : ]2H[

    ]ON[ ]2H[ ]ON[ ]2H[ = ] B [ ] A [ =

    / -: [ B] [ A]

    A A : B B :

  • . : :

    . :

    - . -

    ( ) / .

    . * : ( ) -( ) - ( = )

    ( - . - . ) ( ) ( -) ( - . . ) ( - . . )

    / . .

    /

    . ... /

    ( ) / .

    . . / /

    .

    . / /

    . . ........ /

    / .

    ...... . / /

    . .

    .

    .

  • C2 B3 + A : - . -. ] B [ ] A [

    , , , , , ,

    ] B [ ] A [ = ( ,) - ] B [ ] A [ = = = =

    ( ,) - ] B [ ] A [ A ( ,) - ] B [ ] A [

    = = = = ( ,) - ] B [ ] A [

    ] B [ ] A [ =

    . . - . -. M ]B[ M ]2A[ BA2 B2+ 2A /

    , , , , , , , , , M ,= ] B[ ,= ] 2A[

    ] B [ ] 2A [ = ( ,) , ] B [ ] 2A [

    = = = = ( ,) , ] B [ ] 2A [

    ( ,) ( ,) , ] B [ ] 2A [ = = = = ( ,) ( ,) , ] B [ ] 2A [ ] B [ ] 2A [ = = + = +

    ,

    -. - . = = = ( ,) ( ,) ] B [ ] 2A [ ] B [ ] 2A [ = ( ,) ( ,) = -. -. ,=

    :

    . ()

    .

  • ( ) ] B [ ] 2A [ ( ) = =

    ( ) ] B [ ] 2A [ ()

    .

    -. -. ]B[ ]B[ ]A[ C B3 + A /

    , , C , , ] B [ , ,

    ] B [ . / :

    ]A[ ] B [ A

    A ] B [ = ( ,) ] B [

    = = = = ( ,) ] B [

    ] B [ =

    ] C [ ] C [ ] B [

    -. -. = C [ ] = = C B

    ( \ ,) - ] B [ ,= - = - - = ] B [

    ] B [ = - ,= , =

    -. -. , = , ,=

    , ] B [

    = = = , ] B [

    =

  • -. -. M ]C[ M ]B[ M ]A[ P C + B2 + A /

    , , , , , , , ,

    , , , , , , , ,

    ,/ -. - . OlC[2] M F[2] F2 OlC2 + 2 OlCF22 /

    - , , , - , , , 2OlCF ( ,)

    - , , , / ]B[ . ]B[ ]A[ C2 B3+ A /

    . - . , , , ( ) -

    - . - . ------- , , ,= C . - . , , , ,/

    - ]B[ ]A[ D2 +C3 B3 +A2 /

    ]A[ -. - . , , , :

    = = , , , C - = = , , , ,/ M ,= ]B[ M ,= ]A[ P B2 + A2 /

    -. -. ] B [ ] A [ , , ,

    , , , B , , , , ,/

    -. -. ]BA[ ]C[ C2+BA2 /

    , , , , , , ,/ . ]C[

    , , ------

    ( ) ( )

    ( ) ( ) ( )

    ( ) ( = )

  • B2+ A2 / :

    -. -. - M ,[ = B] M ,[ = A] / M , [ B] [ A] [ B] /

    / [B] [A] = . [ B[ ]A] ( ) [A] = = = = ( ) [A]

    ( ) ( ) [B] [A] =

    :

    ( B ) ( A = ) = =

    ( B ) ( A = ) = =

    - . - . ,= , , \ - =

    -. -. ,= , , ,= [B] [A] = \ M ,[ = B] \[ B] = , B \[ B] = =

    [ ON] O2H2+2N 2H2+ON2 / ON 2H [ 2H]

    . : [ON] [H2] = . [ ON[ ]H2]

    ( ) [2H] = = = = ( ) [2H] ( ) ( )

    [ON] [2H] = [ FH] 2O+FH4 2F2+O2H2 /

    ]2F[ [ 2O] , M,= ]FH[ M,= ]2O[

    - . - : () ]FH [ . ]FH[ O [2 ]

    = = = ( ) ]FH [

    ]FH [ ]2O [ = = = + = +

    ]FH [ ]2O [ = ( ,) , ,= ]FH [ ]2O [ = -. -. - =

    = 2F -. -. - =

  • [ ON] O2H2+2N 2H2+ON2 /

    [ 2H] [ ON] [ 2H] / /

    ]2ON[ 2OC+ ON OC + 2ON / : - . - . = ]OC[

    -. -. - 2ON , /

    ( )

    2N + O2H2 2H2 + ON2 / ( ) ]2H[ ( ) ( ) ]ON[

    ( ) ( ) 2N ( ) ] 2N [ / -. -. ,= \ = ] 2N [ = ] 2N [

    ] 2N [

    -. -. ,= \ = ] 2N [ = ] 2N [

    -. -. N2 . H [2 ] ] ON [ , , ] 2H [ ] ON [ = ( ) , ] ON [

    ] ON [ = = = ( ) , ] ON [ = = + = + , ] 2H [ ] ON [ =

    -. . - ,= = ( )

    -. -. - B2 A / M ,[ =B] A M , M ,= A

    . :

    ] B [ -. - . ,= \ ,= ] B [ = ] B [

    , ] B [ - . -. ,= = =

    B - . -. . ]A [

    , , , , ] A [ =

  • ( ,) , ] A [ = = = ( ,) , ] A [

    ] A [ =

    , - . - . = =

    ( ,)

    ]A[ -. -. ,= B3 A 2 / / -. -. , ( ) M ,= , -. -. - A2 / . A . M ,= A

    - / . A - ,= B2 A/ ,/ M ,[ = B] M ,= A -. -. - = A A3 / -. -. - M ,= A

    - / A A B C2 B + A / A , C

    / . .

    [ A] - ,= P A /

    - . -. - M ,[ =A] / . [ A]

    BA2 2B +2A / M,= 2A 2B . - . ,=

    / . A , /

    ,/ . [ B] , C+B A P B3+A /

    A / [ B[ ]A]

    - . -. - , , - . -. - , , M M BA B +A BA /

    / [ BA] A , P+C A2 /

    . ,= A - ,/ M ,[ = A]

    - . -. - C3 B + A2 / ,/ . ,= B A

    2O + rBH4 O2H2 + 2rB2 / , ] 2O [

    2rB 2rB \ / .

  • 2rB + ON + O2H 2ON + rBH2 / ,= rBH 2ON -. -. , ]rBH [ ] 2ON [ ,= - . , 2ON rBH ,/ C + B2 A3 A , /

    / . A ,

    : / .

    :

    . A A A A B B B B

    -:

    . A B B A A B B A

    A A B B 2B . 2A

    A B A B

    B A

    B A

    . 2B 2A

    : /

    . .

  • -:

    .

    +

    . / IH2 2I + 2H

    + +

    +

    HH

    I I

    H I

    H I

    I H I H

    I

    H

    H

    I

    H I

    H I

    I

    H

    H

    I

    I

    H

    I

    H

  • . : :

    . :

    - .

    - .

    ( H) ( ) ( ) * =

    . H . H

    -= H = + H

    .

    .

    : / ( / ) ------------ . ------- -------- : . ( . / )

    . . / /

    .

    ... H / /

    H = H H

    .... . / . / ... . / /

    .

  • :

    .

    .

    :

    . .... . / . /

    :

    .

    :

    .

    ( )

    ( )

    .

    ...... . / /

    .

  • : .

    *

    . .

    *

    .

    ( . / ) . .................................... / . /

    . - . - . - . - . - . -

    . 2O 2H / . / ( ) / . . H/ /

    .

  • ( )

    .

    :

    : .

    . : -

    . :

    ) (( ) )(

    :

    -: . - . - .( ) -

    -: -:

    + -:

    ( )

    -: ( ) + -: -

    -: -

    . ( )

    [ 2H] [ON]= O2H2+2N ON2 + 2H2 /

    . O2N O2H+O2N 2H+ON2 O2H+2N 2H+O2N

    2H2+ON2 O2H2+2N

    ( )

    .

  • 2lC+O2H2 lCH2+2O2H /

    . = = [2O2H] [lCH] = -:

    [ 2O2H[ ]lCH] = lCOH+O2H lCH+2O2H

    2lC+O2H lCH+ lCOH

    2lC+O2H2 lCH2+2O2H

    2rB + O2H + O2N rBH2 +ON2 / . rBOH ]ON[ ]rBH [ =

    O 2N+ rBOH rBH+ ON2:

    2rB + O2H rBH+ rBOH

    2rB + O2H + O2N rBH2 + ON2 . lCK2 + 3OlCK OlCK3 /

    . lCK / OlCK2 lCK + 2OlCK ] OlCK[ =

    2OlCK+ OlCK lCK+ 3OlCK

    lCK2 + 3OlCK OlCK3 ] ON [ ] 2O [ = 2ON2 2O + ON2 /

    . 3ON 3ON 2O + ON2 ON +/

    2ON2 ON + 3ON

    2ON2 2O + ON2

    2ON + ON 3O2N ON + 3OS 2ON + 2OS / .

    3O2N :

    2 + 2OS 2ON 3OS + 3O2N 2ON + ON 3O2N

    ON + 3OS 2ON + 2OS

    ]3OS[]2ON[ =

    2lC + O2H + ON 2ON + lCH2 / . ONOH

    ) ]2ON[]lCH[ = / (

  • 2O + FH4 O2H2+ 2F2/ . 2O2H . 2OC+ ON OC + 2ON /

    . . ]OC[ ]2ON[ . 3ON

    . O + ON 2O+2ON 3O + ON/ .

    [ 2lC] lCON2 2lC+ON2 / . ON 2lC [ ON]

    . 2lCON : 2lC+O2H+ON 2ON + lCH2 /

    . [ 2ON] [ lCH] - . [ lCH] [ 2ON] -

    . ONOH . ]2N[ ]2H[ = 3HN2 2H3+ 2N /

    . HN ]FH[ O2H2 + 2F2 2O + FH4 /

    ( \ ) ]2O[ . 2O2H / ]2O[ ]FH[ rBH4 + 4rBC 2rB4 + 4HC /

    . . 2rB2HC 2rB . ]4HC[ ]2rB[

    +H2 + =4OrC2 O2H+ =7O2rC / . 2I + O2H2 -I2 + +H2 + 2O2H / . IOH ] -I[] 2O2H [ = 2O2N C + 2ON2 2OC + ON2 /

    . lC2ON 2lC + 2ON2 lC2ON2 /

    . lC 2ON

    O2H + 2OC2 2O 2/5 + 2H2C /

    2H2C 2OC - . - . -

    , , \ ( \ = O = C ) % IH2 2I + 2H / , \ . - . -. - .. / . /

  • ( ) A \ ( ,) C2 A / \ ( ,)

    ,/ . % , ]2O [ 2 3OS 2 2O+ 2OS /

    ,= ]2OS[ , ,/ ]2OS[ 2A 2B 3BA2 2B3 + 2A /

    2A % 2B % ( ) / . 3BA 3BA , 2H 2N /

    , 2H , 3HN2 2H 3 + 2N , 2H 3HN

    , ,/ . . 2ON 2 2O + ON2 /

    / -. -. . ] ON [ [ O2 ] , , , , , , [ ON] 2ON2 2O + ON2 /

    - - [ 2O] / [ 2O] [ ON]

    ]2OlC[ ]2F[ 2OlCF2 2OlC2+ 2F / 2OlCF ,

    : ,=

    -. -. - M ]2F[ M ]2OlC[ , -------- , ,/ , , , . -. , 2D+B2C+B2A DC2+BA2 /

    M ,= ]BA[ ,= ]DC[ - = ]BA[ . \

    / ]DC[ , - , A /

    / . A ] lCI [ ]2H [ - ,= lCH2 + 2I 2H + lCI2 /

    lCI ] lCI [ ]2H[ -. -. - , , 2H 3OS /

    , % 2OS + 2O 3OS2

    ] B [ ] A [ C B 2+ A / C

    ....... . /

  • A B C3 B2+ A2 / M ,= ]B[ M ,= ]A[ -. -. ,=

    ,/ . C M , ( ) C A /

    D % B D / B D A %

    /

    ..... . / / / .... / .... / . . / . / 2O + FH4 O2H2 + 2F2 /

    ]O2H [ FH2 + 2O 2F + 2O2H - ] 2F [ -

    . O2H 2F - - ,= C A /

    ,= A A : /

    . C2 B2 + A /

    C -. -. ]B[ ]A[

    , ,

    A C2 B + A2 / M - ,= A[ ] - - =

    M - ,= ]B[ ]A[ ]B[ C B2 + A3 /

    ]B[ ]A[ ]B[ ]A[

    2N 2H / 3HN , 2N ,

    3HN 2H3 + 2N

    / ....................

    = BA 2A + 2B BA2 / ]BA[ - -. , -. - .

    . 2A , lCaN2 + 3OlCaN OlCaN3 /

    lCaN + 2OlCaN

  • / ( )

    ( ) ( )

    ]2N[]2H[ = 3HN2 2H3+ 2N ( 2H 2N ) lCH2 2lC+ 2H /

    . H ]2H[ \ ]2lC[ = 2ON + 3ON 2ON3 5O2N+ON /

    . 2O+FH4 O2H2+2F2 /

    . .

    -. -. . [ 2F[ ]O2H] - , , -........ ,

    - , , ]2O[ ]OC[ 2OC2 2O + OC2 /

    ]2O[. -. , , , .

    - = =, , , . 3OC

    = = , , , 2O + 2OS 2OS2 2O + OS2 /

    .

    /

    O2H2 + 2N ON2+ 2H2 / -. -. M ON[] M H[2]

    , , , , ,

    2N + 2O2H

    . 2O + 2ON 4 5O2N2 / 2O + 2ON3 3ON + 5O2N / () C2 B2+ A /

    C ( ) . \ ]A[ ]B[

    - , , - , ,

    # #

  • -

  • : :( )

    . .

    O2H + 5H2COOC3HC HO5H2C + HOOC3HC :( ) .

    3ONaN + lCgA lCaN + 3ONgA .

    .

    .

    .

    . .

    : lCOC 2lC + OC 2

    2lC OC lCOC 2lC + OC 2 , , , , OC 2lC ]2lCOC[ , , , , . , , ,

    .

    2lCOC 2lC OC ]2lCOC[

    ,= ]2lC[]OC[

    :

    .

    3HN2 2H3+ 2N ( ) ]2H[ ]2N[ = = ( ) ]3HN[ =

    ]3HN[ = ]2H[ ]2N[

  • ]3HN [ \ =

    ( ) ]2H[ ]2N[ .

    . ]B[ ]A[ ]C[

    B + A C2= C2 B+ A = ]C[ ]B[ ]A[

    ( ) =

    \ ]B[ \ ]A[ ]C[

    C 1/ B21+ A2 = C2 B + A = ]C [ ] B[ ]A[

    ( ) =

    C C

    ]C[ ]C[ C B2/1 + A2/1 = C 2 B + A =

    \]A[ \]B[ ]B[ ]A[

    ( ) = C C

    2H + 2N3/1 3HN3/2 3HN2 2H3+ 2N /

    O2H + 5H2COOC3HC HO5H2C + HOOC3HC.

    3HN2 2H3 + 2N

    SnZ S + nZ

    . .

    2OC + OaC 3OCaC s s g

  • ( )

    :

    \ =

    ( ) B +A C2 \ = . C3 B2 + A

    - - + = -

    ( ) ]C[

    = = ( - ) ( -) ]A[ ]B[

    ( ) ( )

    =

    ) - % = (

    % = [ A ]

    -= ]A[

    ( ) .

    : : . .. . [ A ] B A

    . ( ) ...... . /

    . / /... . /

    . ... /

    / .

    .

  • 2I 2H , IH2 2I + 2H /

    . ,= 2I , /

    \ ,= = ] 2I [= ]2H [ = ] 2I [= ]2H [

    IH2 2I + 2H = , , M ,= \ ,= ] 2I [

    - - + M ,= ,= , , , M ,= H [2]

    M ,= ]2I [ , ,= ] IH [

    ( ,) ] IH [ = = =

    ( ,) ]2I [] 2H [ /

    . ,= : O2H + 5H2COOC3HC HO5H2C + HOOC3HC = = M - - + + ,=

    -

    , ]O2H[]5H2COOC3HC[ =

    ]HO5H2C[]HOOC3HC[ ( ,)

    \ = = ( ,)

    2H3 + 2N 3HN2 , / 3HN 2H 2/3 + 2N 2 /1 ,=

    2H3 + 2N 3HN2 = M = / , = - + + , ,= - ,+ +

    ,= ,= ( ,) ( ,) ] 2N [ ]2H [ ,= = =

    (,) ] 3HN [ 3HN 2H 2/3 + 2N 2 /1 2H3 + 2N 3HN2

    = , \ = \ =

    C B A2 C3 + B / B = C

    = .. C A

  • A2 C3 + B = /

    = ]C [ = ]B [ - - + = \ = ]C [

    = = = \= ] B [

    = = = ( ) ] A [ = \ = B = = = ] A [

    () ( ) ] B [ ]C [ = ] B [ = = ( ) = ]C [

    = \ = C

    2H 2N 3HN2 2H3 + 2N / 2N \ ,

    ,= . 2H 2N 3HN2 2H3 + 2N = M = /

    = ]2N [ = ]2H [ - - + =

    - N [2] -= ]2N [ = , ( ) -

    2N ,= - = ,

    ,= ]2N [ ,= 2N ,= ,= , ,=

    ( ,) ]3HN [ ,= ]2N [ = , = , = ]2H [

    ( , -) , ]2N [ ]2H [ ,= ]3HN [ ,= 2H ,=

    , /

    4O2N 2 2ON 2ON - , 4O2N 2ON 4O2N

    / 4O2N 2 2ON ,= \ ,= ] 4O2N[

    , , ,= \ ,= ]2ON[ (,)

    - = = ( ,)

    = = = 2ON 2/1 4O2N -

  • 2O + 2OS2 3OS2 3OS M ( ) / 3OS 2O M ,

    % , = / /

    ,/ O + OC2 2OC2 2 ,= 2O OC 2H 2rB , /

    , ,/ . = rBH C B+A A B /

    / B A \= = A , , /

    2N 2H 3HN2 2H3 + 2N ,/ 2H3 + 2N 3HN2

    A B C3 B2 + A / . % = B

    .

    C2 B +A () ]C[: = = =

    () ]B[ ]A[

    :

    = . . >

    <

    . / /

    = 3HN 2H 2N / 2N + 3 2H 2 3HN = /

    \ \ \ ]2N [ ]2H [ \ 3HN[ ] = (\) \ ( \) = =

    . 3HN 2H 2N 2N+ 3 2H 2 3HN / =

    2N+ 3 2H 2 3HN = / / \ \ \ ]2N [ ]2H [ \ 3HN[ ] = \ \ \ (\) \ ( \) =

    =

  • : ( ) :

    ( ) ... ( ) :

    ( ) ... :

    ( ) :

    + =

    B 2 2A BA2 2B + 2A / ]BA[ M ,= ]2A[ BA = . M ,

    BA2 2B + 2A = M = / , ]BA [ - - + + ,= ,=

    ,= , ,= , 2B 2A M,=

    ( ,+ ) [ ]BA BA M ,= = =

    ( ,) ]2B [] 2A [ C A B ( ) C3 B + A2 /

    C A B A ( ) = .

    C3 B + A2 /

    - - + = B - + = B = =

    = - = A A = = -

    ( + ) [ ]C C = = =

    ( ) ]B [] A [ /

    . ( ,) lCH 2H 2lC ( ) ( )

  • = \ = ] lCH [ \ = ] lCH [ /

    2lC + 2H lCH2 ,= \ ,= ] lCH [ = - + + ,= ,= -

    , ( ,) [ ]2H[]2lC \= = =

    ( ,) ]lCH [ ( ,) 2lC + 2H lCH2 = , \ = ]lCH [ = [ ]2H[ = ]2lC ]lCH [ \ [ ]2H[]2lC =

    + - - = ( ) \ ( ) = +

    ( - ) [ ]2H[]2lC

    ,= = = ( + ) ]lCH [

    ,= , ,= 2lC ,= , = [ ]2lC ,= , ,= 2H ,= , = [ ]2H

    ,= , ,= lCH ,= ,+ = ]lCH [ C ( ) C2 B + A /

    C ( ) B A B A C ( )

    C2 B + A /

    ( ) [ ]C ......... = =

    () ]B [] A [ C2 B + A

    = C + + - = C

    + + ,= = ( )

    .... ............ = ( ) ( ) ( ,+ )

    = ( ,+ ) ()

    = ( ) =

  • D C ( ) B A ( ) /

    / = . D+C B+ A D A ( ) D+ C B+ A /

    / ]B[= ]C[ M = ]A[ B C ( ) 2OC2 2O + OC2 /

    ( , , , ) OC 2O 2OC / ]2OC[

    ( OC ,ON , 2OC , 2ON) / 2OC ON + 2OC 2ON+ OC

    / OC 2ON 2OS 2O 3OS2 2O + 2OS2 / M = ]2OS[ = 3OS ( )

    \/ . ( ) ( ) C2 B + A3 / / . . C B A 5lCP /

    , 5lCP , 2lC + 3lCP 5lCP , 5lCP . 2lC 3lCP

    , , ,/

    2ON2 2O + ON2 / - /

    2H IH2 2I + 2H / = IH IH 2I

    / . 2H 2I

    2OC + OaC 3OCaC . 2OC OaC 3OCaC

    .

    ]2OC [= /

    ]lCH[ ]2OC [

    lCH2 + lCOaL O2H + 3lCaL = 2OC 2O + C = s g s g ] O2H[ ] 2O[

  • 3OCaC / ,= 2OC 2OC + OaC 3OCaC

    . 3OCaC , = ]2OC [= ,= \ ,= ]2OC [ /

    ,= 3OCaC = 2OC :

    . ( 3HN )

    3HN2 2H3 + 2N = g g g ( 2N ) ( 2H )

    2OC ( ) = 2OC + OaC 3OCaC s s g

    2O 3OS 2OS 3OS2 2O + 2OS2 / 2OS + 2O2/1 3OS , , ,

    ( 3OS ) 3OS2 2O + 2OS2 =

    , , , (2OS ( ) 2O ) \ = ( ,( ) ,) \ ( ,) =

    2OS + 2O2/1 3OS

    = = = \

    2N 3HN2 2H3 + 2N / . \= 2H

    ( 3HN ) / 3HN2 2H3 + 2N =

    ( 2N ) ( 2H ) ( = 3HN ) = ( 3HN ) ( ) ( ) \ ( 3HN = ) \

    , B A C 2 B3 + A / . ,=

    C2 B3 + A = / , , ,= ,+ ,+ - - + ,= ,= ,

    , , ,= C ,= , -,= B ,= , ,= A ( C )

    = ( ,) ( ,) \ ( ,= ) = ( A) ( B )

  • :

    ( ) . . = . . \ = . . = . = : = :

    ,= lCH + 3HN lC4HN /

    s g g

    lCH + 3HN lC4HN /

    3HN lCH ,= ( ) = ,( 3HN ( ) lCH= ) = ,= &

    = -( ) =

    ( ) ( ) ( ) = :

    . \ . ,= ( ) + = ( ) = = * * ) .

    ( )

    . 2rBeF 2rB /

    = 2rB 3rBeF 2 2rB + 2rBeF 2

    \ = ] 2rB [ \ = / ( ) -( (+ ) , ) = , -( ) =

    , = = + /

    = /

    = = ( ,) = -( ) = ,

    = + =

  • 5lCP ( ) / % 5lCP 2lC +3lCP

    ,= :

    ,= \ = 5lCP = 5lCP

    , 2lC = 3lCP = 5lCP ,= , = 5lCP

    ,= ,+ ,+ ,=

    =

    , , , 2lC 3lCP 5lCP , , ( 3lCP ( ) 2lC )

    ,= = = ,( 5lCP )

    3HN S2H SH4HN S2H + 3HN /

    = SH4HN

    SH4HN S2H + 3HN = M = /

    - - = ]3HN[]S2H[

    ,= ( ) -( ,) = -( ) =

    ,= , , ,= = , = , ( ) ( )

    3HN S2H = = SH4HN = S2H

    S 2) 4HN ( S2H + 3HN2 /

    2lC + 2H lCH2 /

    g g g OC+ OiN 2OC + iN OC OiN /

    s g s g = OC =

    < / 2O ON , 2ON2 2O + ON2 /

    ,/ ,= ON

  • 3OS ( ) ( ) / 2O + 2OS2 3OS2 2OS ( )

    / 2lC + 2H lCH2 /

    ,= ( ) ,/ ]2lC[ :

    B2 A ,= / ,/ ................ ..= A 2 /1 B

    .

    -: : -

    . .

    -

    - .

    .

    -

    rBH , / = 2H + 2rB rBH2

    rBH , . rBH ,

    2H + 2rB rBH2 = M = / , ]2rB []2H [

    - + + = , ] rBH [

  • ,= ( ,) \ ( = )

    ,= ]2rB [ ,= ]2H [ ,= , ,= ] rBH [

    rBH , ( + ,)

    2H + 2rB rBH2 = , , , ( ,) ,+ ,= , , , M ,=,+ ,= ]2rB [ - + + , = ]2H [

    , + , + , M ,= , ,= [ ]rBH rBH ,

    ( - ,) 2H + 2rB rBH2 =

    , , , ( + ,) , - ,= , , , M ,=, -,= ]2rB [ + - - ,= ]2H [

    + , - , - , M,( = , +),= [ ]rBH BA2 2B + 2A /

    2B 2A , BA BA , BA ,

    * * *

    ( ) , C2 B + A /

    C , B A C B A , C B A ,

    C2 B + A ( ,) ] C[/ , , , = = = , - , - , - ( ,) ]B [] A[

    , , , ( ,) ] C[ + + - = = =

    + , + , , (,) ]B [] A[

  • ( ) C2 B + A ( ,) ] C[ , , , = = =

    , + ,+ ,+ (,) ]B [] A[ , , , >

    - - + ( + ,) , , + , .. .. =

    ( ,) C C2 B + A /

    C B A ,= C B A = C = A

    ( = ) ( : )

    C2 B + A = M = B 2/1 + A2/1 C ,= - - - \ = , \ =

    = + + - ( ) ] C[

    = = () ]B [] A[

    ( ..... ) ...... = = ]C[ C

    = ]A [ = = ( ...................) + = = +

    = ]C[ ( + ) =

    ( ....................... ) + = ( + ) ] C[

    = = = ( ) ]B [] A[

    B A ( ) C ( )

    B A C C2 B + A / A C A

    = B A = B C2 B + A /

    + + - A

    + + A = + + - ( + )

    + + + ( - ) ] C[ = =

    ( ................ ) + = (+) ]B [] A[

  • C2 B + A + + + - + = ]A[

    - = -+ + + ( .... ....... ) + =

    - - + +

    + ( + ) + ( + )

    = = ( )

    B A = ( ) C = ( )

    (M ) C C2 B + A / ,= ]A [ C , B A

    ]C[ C2 B + A ( ) ] C[ ( ..... ). = =

    ,+ ( ) ]B [] A[ ,+ ,= ] A [

    + + - ,= ,= + + + ,+

    , , ,+ ( ,+ )

    ( .......... ) . = ( ,)

    ( ,+ ) ( ) = =

    ( ,) ( ) - ,+ = ]C [

    ,= , - ,+ = ]C [ A a C2 B + A /

    A B C B . . = C B C2 B + A a ()

    = + + a(()) + + = = = C

    a - - + = + + a -+ - + + = = +

    a ( ) = =

    a() a(( ) )

    .. = a()

  • ( ) = =

    a( a ) a( a )

    = a a - = a(a = ) a() = a( a ) a()

    ,= C BA C2 B + A /

    % = C B A C

    C2 B + A C / % = C

    - - + +

    , , , % = % = C

    % = C

    C < C

    + ,= =

    + + + ( ,) ( C)

    = = = ( ,) ] B [ ] A [

    C2 B + A

    , , , ( + ,) + + =

    , , , ( ,) - - + ,=

    -, - , + , + ,= C

    =

    3HN2 2H3 + 2N / ,= =

    ,=

    ( = H = N)

  • H3 + 2N 3HN2 = M = / = ]3HN[ - + + \ = + = 3HN . =

    ,= = ,

    ]2N[]2H[ ,= = , =

    , ]3HN[ ,= ,=

    \ = + = \ \ ,=

    ,= .... . /

    / . -

    : : /

    ( )

    .( . ) /

    IH2 2I + 2H: .

    .

    : .

    ( ............... ) / B A2 > : /

    ( ............ ) ( ) = / B A2 > /

    . \ = /

    /

    > < = : / ... / /

    ( )

  • < B A2 .

    :

    ( ) ( )

    . H H H

    3HN2 2H3 + 2N , = H 2ON2 4O2N ,= + H

    ( ) : ( )

    .

    . .

    ( ) ) .

    . (

    . H

    > . < .

    . . / /

    . . 4O2N 2ON2 / :

    2ON 4O 2N 2ON

    4O2N

    /

    /

    . .