كيمياء
DESCRIPTION
hTRANSCRIPT
-
YRTSIMEHC
+
I
H
H
I
H I
H I
I
H
H
I
I
H
I
H
-
Xf;
%%1Zh0\/a%a}{0\......
a}_h{0\h%h}.............................................. 1Z...............................................
-
f
. .
.
.
: , ,/
:
/ :
/ ,=
- = = (- +) - = - - / - =
- :
= + - = ( -) - = -
+ = + ,= = :
. :
, , , , ,= = = ,= = =
, , ,
.
,= , , ( )
. = ,:
,= ,:
.
-
,= ,:
,= , ,= , ,= ,
:
: ,= ,+ ,= ,+ ,
- = , - ,= - , - - ,
. - - ,
(( ))
, : ,
, ,
- , , ,
- + ,= - , + , = , ,= + ,= , -= ,=
1.0 0.0 2.0 3.0 4.0 7.0 6.0 5.0 8.0 9.0 972 552 032 402 671 641 411 970 140 000 1
264 744 134 514 893 083 263 243 223 103 2 195 085 865 655 445 235 915 505 194 774 3 096 186 276 366 356 446 436 326 316 206 4 177 367 657 847 047 237 427 617 807 996 5 938 338 628 028 318 608 997 297 587 877 6 898 298 788 188 578 968 368 758 158 548 7 949 549 049 539 929 429 919 419 909 309 8 699 199 789 289 879 379 969 469 959 459 9
= : . + = : .
: =
= = :
, -= ,= : = -= =
-
lCgA
.
.
.
:
. .
.
2I 2H IH .
IH IH 2 2I + 2H
2I 2H
]2I [ ]2H[ ]2I[ = - ]2H[ = -
2I 2H ]2I[ ]2H[
......... 2I 2H * .......... 2I 2H * % 2I 2H *
% [ ]= ]2H[
] [ ]2H[
% = [ ]
. .( ) . - . . - . / = M \ =
=
( . C ( + ) . O ( + ) . H ) = HOOC3HC . : . .
-
B A C3 B+ A2 / . ( ) A ( ) ( )
. A , = = ] A [ = ] A [ ] A [ :
(, - ) ] A [ - . - . ,= -= - = ] A [
2ON , 4O2N 2ON2 :
. 2ON % ] 2ON [= ] 2ON [:
4O2N 2ON2 \ ,= , ] 2ON [ ,= ( , -) ] 2ON [
, - . - . ,= -= ] 2ON [ -= ] 2ON [
* * * ] IH [
+= ] IH [
IH ] IH [ ..... ] IH [ C+ B2 A2 A :
. C C , ]C [ C :
- . - . ,= \ ,= ]C [ \ ]C [= ]C [ * * *
( ) IH2 2I + 2H
IH2 2I + 2H ] IH [ - ] IH [= ] IH [ ]2H[ - ]2H[= ]2H[
] IH [ - ] IH [ ]2H[ - ]2H[
+ = ] IH [ - = ] 2H [
......... ........
. * . *
. S g L * . * *
.
-
, , ]2H[ IH2 2I + 2H : IH2 2I + 2H . , , , ]2H[ - ]2H[ :
- .- . ,= -= ] 2H [ -= ] 2H [
, * * *
. A C3 B2 + A
M , A . C B , C M , B
. M ] C [ ] B [ ] A [
= = = C B A
: ( )
. :
. * . * *
] C [ ] A [
= C A [ C] [ A] [ C] [ A] + -
+= - = C A C A
2ON , : 4O2N . 4O2N . ,
2 4O2N 2ON 2ON ,= \ ,= ] 2ON [ \ = ] 2ON [:
2ON ,= \ ,= ] 2ON [ ( , , ) ] 2ON [ - ] 2ON [
- . -. , = -= ] 2ON [ -= ] 2ON [
] 4O2N [ , ] 4O2N [ ] 2ON [ - . -. ,= ] 4O2N [ = =
4O2N 2ON ] 4O2N [ ] 4O2N [ - ] 4O2N [
M ,= ] 4O2N [ = , = ] 4O2N [
-
,= \ ,= 4O2N M= 4O2N
IH2 2I + 2H : : ] 2H [ , IH
( ) . ] 2H [ % . ] 2H [ ] IH [ IH :
, ] IH [ -. - . ,= = ] IH [ = ] IH [
, ] 2H [ ] IH [ ] 2H [
-. - . ,= ] 2H [ = = IH 2H =
,= ] 2H [ ( , ) - ] 2H [
] 2H [ M ,= ,= , - = , -= ] 2H [
] 2H [= ] 2H [ ] 2H [ \ ,=
- = ] 2H [ ,=
\ ( ,- ) - = , = , \,= %
A , B A2 /
B % .
, = ] A [ \ ,= ] A [ \ = ] A [/ ] A [ = ] A [ ] A [
\ ,= B A2 ,=
, ] B [ - ] B [ ] A [ - ] B [ ] A [
= = B A ] B [ ( , - )
,= ] B [ + = - ,= B \ ,= B M= B
: B A2 A / ,/ . A - . -. - - C C A2 :
\ - . -. A , B2 A :
, \ . ,= A
-
. M , M , [ 2H] 2rB+2H BH2 / ,/ .
, 3HN2 2H3 + 2N /
( ) ( ) ,/ 2H
2rB + 2H rBH2 / ( , ) 2rB , 2H , rBH ( )
rBH . - . -. , rBH ,/ . rBH ---------- = ]2O[ 3OS2 2O + 2OS2 /
( / ) 2O ---------- = 3OS ]2OS[ A C2 + B A2 /
,= C A % M
, ,/ B ( A ( :
A , : B A -. -. ,
,= ] A [ \ ,= ] A [ \ = ] A [ : = ] A [
B A ] A [ - ] A [ , -= ] A [
,
= -= ,
B , A , C2 B + A :
- . - . , C C
A : ] A [ , ] A [ ] C [
-. - . ,= ] A [ = = A C
, - ] A [ \= - = , -= ] A [
-
] C [ ] C [ - ] C [ M ,= ] C [ = , = ] C [
\
.
B A -. C3 B2 + A : .
B : \ ] A [ \ ] B [ ] A [ ]B [
-= - = A B
- ] A [ ] A [ - ] A [ ] B [ - ] B [ - = - - = -
A = ] A [ + ] A [ -=
:
.
B = \ C3 B + A2 A , = \ M M
A A B , BA2 B3 + A /
\ B . BA A
,= ] B [ \ ,= ] B [ \ = ] B [: ] B [ ,= ] B [
, - ] B [ -. -. ,= ] B [ - = ] B [ - = ] B [
BA2 B3 + A , , ] A [ ] B [ ] A [
= =
, , B A -. -. ,= ] A [
= A , ] A [ - ] A [= ] A [
] A [ , -= ] A [ ,= ] A [ ( , - ) A[ ]
A -. ,= -= , -= ] A [
] A [
-
\ ] A [ - ] A [ \ ] BA [ - ] BA [ ] A [ ]B A[
-= = A A B
, - - ] BA [
BA ,= ] BA [ -=
,= BA \ ,= BA
( ) 2OC2 2O + OC2 / = OC ( ) 2O ]2OC[ ]OC[ : 2O %
2O OC :
= OC = =
\ = ] OC[ ] OC[ = ] OC[ OC ,= ] OC[
,= ]2O[ = ]2O[ - , ]2O[ ]2O[
-. -. ,= ]2O[ -= ]2O[ - = ]2O[
, ]OC[ ]2O[ ]OC[ -. -. ,= ]OC[ = =
2O OC ] OC [ = \ ,= , \ ]OC[= ]OC[
:
OC ]OC[ = ]2OC[ 2OC
-. =
: M = ]2O[= ]OC[
+ - + - ]2O[ ]2O[ ]OC[ ]OC[ OC 2O M = = - = -
- ]2O[ ]2O[ ,= - = ,= -= ]2O[
OC 2O ( ) 2OC2 2O + OC2 /
( ) , ,/ -
-
C , A + B2 C2 / . -. -. , -. -. , C
,/ . A , B A2 /
B , / . A
3HN2 2H3+ 2N / ,= ]2N[
%
.
.
. .
.
2N + O2H2 ON2 + 2H2 -. -. N2 H [2 ] ] ON [
, , , , , ,
]ON[ ]2H[ ]ON[
]ON[ . ]ON[ ]2H[
. ]2H[ : ]2H[
]ON[ ]2H[ ]ON[ ]2H[ = ] B [ ] A [ =
/ -: [ B] [ A]
A A : B B :
-
. : :
. :
- . -
( ) / .
. * : ( ) -( ) - ( = )
( - . - . ) ( ) ( -) ( - . . ) ( - . . )
/ . .
/
. ... /
( ) / .
. . / /
.
. / /
. . ........ /
/ .
...... . / /
. .
.
.
-
C2 B3 + A : - . -. ] B [ ] A [
, , , , , ,
] B [ ] A [ = ( ,) - ] B [ ] A [ = = = =
( ,) - ] B [ ] A [ A ( ,) - ] B [ ] A [
= = = = ( ,) - ] B [ ] A [
] B [ ] A [ =
. . - . -. M ]B[ M ]2A[ BA2 B2+ 2A /
, , , , , , , , , M ,= ] B[ ,= ] 2A[
] B [ ] 2A [ = ( ,) , ] B [ ] 2A [
= = = = ( ,) , ] B [ ] 2A [
( ,) ( ,) , ] B [ ] 2A [ = = = = ( ,) ( ,) , ] B [ ] 2A [ ] B [ ] 2A [ = = + = +
,
-. - . = = = ( ,) ( ,) ] B [ ] 2A [ ] B [ ] 2A [ = ( ,) ( ,) = -. -. ,=
:
. ()
.
-
( ) ] B [ ] 2A [ ( ) = =
( ) ] B [ ] 2A [ ()
.
-. -. ]B[ ]B[ ]A[ C B3 + A /
, , C , , ] B [ , ,
] B [ . / :
]A[ ] B [ A
A ] B [ = ( ,) ] B [
= = = = ( ,) ] B [
] B [ =
] C [ ] C [ ] B [
-. -. = C [ ] = = C B
( \ ,) - ] B [ ,= - = - - = ] B [
] B [ = - ,= , =
-. -. , = , ,=
, ] B [
= = = , ] B [
=
-
-. -. M ]C[ M ]B[ M ]A[ P C + B2 + A /
, , , , , , , ,
, , , , , , , ,
,/ -. - . OlC[2] M F[2] F2 OlC2 + 2 OlCF22 /
- , , , - , , , 2OlCF ( ,)
- , , , / ]B[ . ]B[ ]A[ C2 B3+ A /
. - . , , , ( ) -
- . - . ------- , , ,= C . - . , , , ,/
- ]B[ ]A[ D2 +C3 B3 +A2 /
]A[ -. - . , , , :
= = , , , C - = = , , , ,/ M ,= ]B[ M ,= ]A[ P B2 + A2 /
-. -. ] B [ ] A [ , , ,
, , , B , , , , ,/
-. -. ]BA[ ]C[ C2+BA2 /
, , , , , , ,/ . ]C[
, , ------
( ) ( )
( ) ( ) ( )
( ) ( = )
-
B2+ A2 / :
-. -. - M ,[ = B] M ,[ = A] / M , [ B] [ A] [ B] /
/ [B] [A] = . [ B[ ]A] ( ) [A] = = = = ( ) [A]
( ) ( ) [B] [A] =
:
( B ) ( A = ) = =
( B ) ( A = ) = =
- . - . ,= , , \ - =
-. -. ,= , , ,= [B] [A] = \ M ,[ = B] \[ B] = , B \[ B] = =
[ ON] O2H2+2N 2H2+ON2 / ON 2H [ 2H]
. : [ON] [H2] = . [ ON[ ]H2]
( ) [2H] = = = = ( ) [2H] ( ) ( )
[ON] [2H] = [ FH] 2O+FH4 2F2+O2H2 /
]2F[ [ 2O] , M,= ]FH[ M,= ]2O[
- . - : () ]FH [ . ]FH[ O [2 ]
= = = ( ) ]FH [
]FH [ ]2O [ = = = + = +
]FH [ ]2O [ = ( ,) , ,= ]FH [ ]2O [ = -. -. - =
= 2F -. -. - =
-
[ ON] O2H2+2N 2H2+ON2 /
[ 2H] [ ON] [ 2H] / /
]2ON[ 2OC+ ON OC + 2ON / : - . - . = ]OC[
-. -. - 2ON , /
( )
2N + O2H2 2H2 + ON2 / ( ) ]2H[ ( ) ( ) ]ON[
( ) ( ) 2N ( ) ] 2N [ / -. -. ,= \ = ] 2N [ = ] 2N [
] 2N [
-. -. ,= \ = ] 2N [ = ] 2N [
-. -. N2 . H [2 ] ] ON [ , , ] 2H [ ] ON [ = ( ) , ] ON [
] ON [ = = = ( ) , ] ON [ = = + = + , ] 2H [ ] ON [ =
-. . - ,= = ( )
-. -. - B2 A / M ,[ =B] A M , M ,= A
. :
] B [ -. - . ,= \ ,= ] B [ = ] B [
, ] B [ - . -. ,= = =
B - . -. . ]A [
, , , , ] A [ =
-
( ,) , ] A [ = = = ( ,) , ] A [
] A [ =
, - . - . = =
( ,)
]A[ -. -. ,= B3 A 2 / / -. -. , ( ) M ,= , -. -. - A2 / . A . M ,= A
- / . A - ,= B2 A/ ,/ M ,[ = B] M ,= A -. -. - = A A3 / -. -. - M ,= A
- / A A B C2 B + A / A , C
/ . .
[ A] - ,= P A /
- . -. - M ,[ =A] / . [ A]
BA2 2B +2A / M,= 2A 2B . - . ,=
/ . A , /
,/ . [ B] , C+B A P B3+A /
A / [ B[ ]A]
- . -. - , , - . -. - , , M M BA B +A BA /
/ [ BA] A , P+C A2 /
. ,= A - ,/ M ,[ = A]
- . -. - C3 B + A2 / ,/ . ,= B A
2O + rBH4 O2H2 + 2rB2 / , ] 2O [
2rB 2rB \ / .
-
2rB + ON + O2H 2ON + rBH2 / ,= rBH 2ON -. -. , ]rBH [ ] 2ON [ ,= - . , 2ON rBH ,/ C + B2 A3 A , /
/ . A ,
: / .
:
. A A A A B B B B
-:
. A B B A A B B A
A A B B 2B . 2A
A B A B
B A
B A
. 2B 2A
: /
. .
-
-:
.
+
. / IH2 2I + 2H
+ +
+
HH
I I
H I
H I
I H I H
I
H
H
I
H I
H I
I
H
H
I
I
H
I
H
-
. : :
. :
- .
- .
( H) ( ) ( ) * =
. H . H
-= H = + H
.
.
: / ( / ) ------------ . ------- -------- : . ( . / )
. . / /
.
... H / /
H = H H
.... . / . / ... . / /
.
-
:
.
.
:
. .... . / . /
:
.
:
.
( )
( )
.
...... . / /
.
-
: .
*
. .
*
.
( . / ) . .................................... / . /
. - . - . - . - . - . -
. 2O 2H / . / ( ) / . . H/ /
.
-
( )
.
:
: .
. : -
. :
) (( ) )(
:
-: . - . - .( ) -
-: -:
+ -:
( )
-: ( ) + -: -
-: -
. ( )
[ 2H] [ON]= O2H2+2N ON2 + 2H2 /
. O2N O2H+O2N 2H+ON2 O2H+2N 2H+O2N
2H2+ON2 O2H2+2N
( )
.
-
2lC+O2H2 lCH2+2O2H /
. = = [2O2H] [lCH] = -:
[ 2O2H[ ]lCH] = lCOH+O2H lCH+2O2H
2lC+O2H lCH+ lCOH
2lC+O2H2 lCH2+2O2H
2rB + O2H + O2N rBH2 +ON2 / . rBOH ]ON[ ]rBH [ =
O 2N+ rBOH rBH+ ON2:
2rB + O2H rBH+ rBOH
2rB + O2H + O2N rBH2 + ON2 . lCK2 + 3OlCK OlCK3 /
. lCK / OlCK2 lCK + 2OlCK ] OlCK[ =
2OlCK+ OlCK lCK+ 3OlCK
lCK2 + 3OlCK OlCK3 ] ON [ ] 2O [ = 2ON2 2O + ON2 /
. 3ON 3ON 2O + ON2 ON +/
2ON2 ON + 3ON
2ON2 2O + ON2
2ON + ON 3O2N ON + 3OS 2ON + 2OS / .
3O2N :
2 + 2OS 2ON 3OS + 3O2N 2ON + ON 3O2N
ON + 3OS 2ON + 2OS
]3OS[]2ON[ =
2lC + O2H + ON 2ON + lCH2 / . ONOH
) ]2ON[]lCH[ = / (
-
2O + FH4 O2H2+ 2F2/ . 2O2H . 2OC+ ON OC + 2ON /
. . ]OC[ ]2ON[ . 3ON
. O + ON 2O+2ON 3O + ON/ .
[ 2lC] lCON2 2lC+ON2 / . ON 2lC [ ON]
. 2lCON : 2lC+O2H+ON 2ON + lCH2 /
. [ 2ON] [ lCH] - . [ lCH] [ 2ON] -
. ONOH . ]2N[ ]2H[ = 3HN2 2H3+ 2N /
. HN ]FH[ O2H2 + 2F2 2O + FH4 /
( \ ) ]2O[ . 2O2H / ]2O[ ]FH[ rBH4 + 4rBC 2rB4 + 4HC /
. . 2rB2HC 2rB . ]4HC[ ]2rB[
+H2 + =4OrC2 O2H+ =7O2rC / . 2I + O2H2 -I2 + +H2 + 2O2H / . IOH ] -I[] 2O2H [ = 2O2N C + 2ON2 2OC + ON2 /
. lC2ON 2lC + 2ON2 lC2ON2 /
. lC 2ON
O2H + 2OC2 2O 2/5 + 2H2C /
2H2C 2OC - . - . -
, , \ ( \ = O = C ) % IH2 2I + 2H / , \ . - . -. - .. / . /
-
( ) A \ ( ,) C2 A / \ ( ,)
,/ . % , ]2O [ 2 3OS 2 2O+ 2OS /
,= ]2OS[ , ,/ ]2OS[ 2A 2B 3BA2 2B3 + 2A /
2A % 2B % ( ) / . 3BA 3BA , 2H 2N /
, 2H , 3HN2 2H 3 + 2N , 2H 3HN
, ,/ . . 2ON 2 2O + ON2 /
/ -. -. . ] ON [ [ O2 ] , , , , , , [ ON] 2ON2 2O + ON2 /
- - [ 2O] / [ 2O] [ ON]
]2OlC[ ]2F[ 2OlCF2 2OlC2+ 2F / 2OlCF ,
: ,=
-. -. - M ]2F[ M ]2OlC[ , -------- , ,/ , , , . -. , 2D+B2C+B2A DC2+BA2 /
M ,= ]BA[ ,= ]DC[ - = ]BA[ . \
/ ]DC[ , - , A /
/ . A ] lCI [ ]2H [ - ,= lCH2 + 2I 2H + lCI2 /
lCI ] lCI [ ]2H[ -. -. - , , 2H 3OS /
, % 2OS + 2O 3OS2
] B [ ] A [ C B 2+ A / C
....... . /
-
A B C3 B2+ A2 / M ,= ]B[ M ,= ]A[ -. -. ,=
,/ . C M , ( ) C A /
D % B D / B D A %
/
..... . / / / .... / .... / . . / . / 2O + FH4 O2H2 + 2F2 /
]O2H [ FH2 + 2O 2F + 2O2H - ] 2F [ -
. O2H 2F - - ,= C A /
,= A A : /
. C2 B2 + A /
C -. -. ]B[ ]A[
, ,
A C2 B + A2 / M - ,= A[ ] - - =
M - ,= ]B[ ]A[ ]B[ C B2 + A3 /
]B[ ]A[ ]B[ ]A[
2N 2H / 3HN , 2N ,
3HN 2H3 + 2N
/ ....................
= BA 2A + 2B BA2 / ]BA[ - -. , -. - .
. 2A , lCaN2 + 3OlCaN OlCaN3 /
lCaN + 2OlCaN
-
/ ( )
( ) ( )
]2N[]2H[ = 3HN2 2H3+ 2N ( 2H 2N ) lCH2 2lC+ 2H /
. H ]2H[ \ ]2lC[ = 2ON + 3ON 2ON3 5O2N+ON /
. 2O+FH4 O2H2+2F2 /
. .
-. -. . [ 2F[ ]O2H] - , , -........ ,
- , , ]2O[ ]OC[ 2OC2 2O + OC2 /
]2O[. -. , , , .
- = =, , , . 3OC
= = , , , 2O + 2OS 2OS2 2O + OS2 /
.
/
O2H2 + 2N ON2+ 2H2 / -. -. M ON[] M H[2]
, , , , ,
2N + 2O2H
. 2O + 2ON 4 5O2N2 / 2O + 2ON3 3ON + 5O2N / () C2 B2+ A /
C ( ) . \ ]A[ ]B[
- , , - , ,
# #
-
-
-
: :( )
. .
O2H + 5H2COOC3HC HO5H2C + HOOC3HC :( ) .
3ONaN + lCgA lCaN + 3ONgA .
.
.
.
. .
: lCOC 2lC + OC 2
2lC OC lCOC 2lC + OC 2 , , , , OC 2lC ]2lCOC[ , , , , . , , ,
.
2lCOC 2lC OC ]2lCOC[
,= ]2lC[]OC[
:
.
3HN2 2H3+ 2N ( ) ]2H[ ]2N[ = = ( ) ]3HN[ =
]3HN[ = ]2H[ ]2N[
-
]3HN [ \ =
( ) ]2H[ ]2N[ .
. ]B[ ]A[ ]C[
B + A C2= C2 B+ A = ]C[ ]B[ ]A[
( ) =
\ ]B[ \ ]A[ ]C[
C 1/ B21+ A2 = C2 B + A = ]C [ ] B[ ]A[
( ) =
C C
]C[ ]C[ C B2/1 + A2/1 = C 2 B + A =
\]A[ \]B[ ]B[ ]A[
( ) = C C
2H + 2N3/1 3HN3/2 3HN2 2H3+ 2N /
O2H + 5H2COOC3HC HO5H2C + HOOC3HC.
3HN2 2H3 + 2N
SnZ S + nZ
. .
2OC + OaC 3OCaC s s g
-
( )
:
\ =
( ) B +A C2 \ = . C3 B2 + A
- - + = -
( ) ]C[
= = ( - ) ( -) ]A[ ]B[
( ) ( )
=
) - % = (
% = [ A ]
-= ]A[
( ) .
: : . .. . [ A ] B A
. ( ) ...... . /
. / /... . /
. ... /
/ .
.
-
2I 2H , IH2 2I + 2H /
. ,= 2I , /
\ ,= = ] 2I [= ]2H [ = ] 2I [= ]2H [
IH2 2I + 2H = , , M ,= \ ,= ] 2I [
- - + M ,= ,= , , , M ,= H [2]
M ,= ]2I [ , ,= ] IH [
( ,) ] IH [ = = =
( ,) ]2I [] 2H [ /
. ,= : O2H + 5H2COOC3HC HO5H2C + HOOC3HC = = M - - + + ,=
-
, ]O2H[]5H2COOC3HC[ =
]HO5H2C[]HOOC3HC[ ( ,)
\ = = ( ,)
2H3 + 2N 3HN2 , / 3HN 2H 2/3 + 2N 2 /1 ,=
2H3 + 2N 3HN2 = M = / , = - + + , ,= - ,+ +
,= ,= ( ,) ( ,) ] 2N [ ]2H [ ,= = =
(,) ] 3HN [ 3HN 2H 2/3 + 2N 2 /1 2H3 + 2N 3HN2
= , \ = \ =
C B A2 C3 + B / B = C
= .. C A
-
A2 C3 + B = /
= ]C [ = ]B [ - - + = \ = ]C [
= = = \= ] B [
= = = ( ) ] A [ = \ = B = = = ] A [
() ( ) ] B [ ]C [ = ] B [ = = ( ) = ]C [
= \ = C
2H 2N 3HN2 2H3 + 2N / 2N \ ,
,= . 2H 2N 3HN2 2H3 + 2N = M = /
= ]2N [ = ]2H [ - - + =
- N [2] -= ]2N [ = , ( ) -
2N ,= - = ,
,= ]2N [ ,= 2N ,= ,= , ,=
( ,) ]3HN [ ,= ]2N [ = , = , = ]2H [
( , -) , ]2N [ ]2H [ ,= ]3HN [ ,= 2H ,=
, /
4O2N 2 2ON 2ON - , 4O2N 2ON 4O2N
/ 4O2N 2 2ON ,= \ ,= ] 4O2N[
, , ,= \ ,= ]2ON[ (,)
- = = ( ,)
= = = 2ON 2/1 4O2N -
-
2O + 2OS2 3OS2 3OS M ( ) / 3OS 2O M ,
% , = / /
,/ O + OC2 2OC2 2 ,= 2O OC 2H 2rB , /
, ,/ . = rBH C B+A A B /
/ B A \= = A , , /
2N 2H 3HN2 2H3 + 2N ,/ 2H3 + 2N 3HN2
A B C3 B2 + A / . % = B
.
C2 B +A () ]C[: = = =
() ]B[ ]A[
:
= . . >
<
. / /
= 3HN 2H 2N / 2N + 3 2H 2 3HN = /
\ \ \ ]2N [ ]2H [ \ 3HN[ ] = (\) \ ( \) = =
. 3HN 2H 2N 2N+ 3 2H 2 3HN / =
2N+ 3 2H 2 3HN = / / \ \ \ ]2N [ ]2H [ \ 3HN[ ] = \ \ \ (\) \ ( \) =
=
-
: ( ) :
( ) ... ( ) :
( ) ... :
( ) :
+ =
B 2 2A BA2 2B + 2A / ]BA[ M ,= ]2A[ BA = . M ,
BA2 2B + 2A = M = / , ]BA [ - - + + ,= ,=
,= , ,= , 2B 2A M,=
( ,+ ) [ ]BA BA M ,= = =
( ,) ]2B [] 2A [ C A B ( ) C3 B + A2 /
C A B A ( ) = .
C3 B + A2 /
- - + = B - + = B = =
= - = A A = = -
( + ) [ ]C C = = =
( ) ]B [] A [ /
. ( ,) lCH 2H 2lC ( ) ( )
-
= \ = ] lCH [ \ = ] lCH [ /
2lC + 2H lCH2 ,= \ ,= ] lCH [ = - + + ,= ,= -
, ( ,) [ ]2H[]2lC \= = =
( ,) ]lCH [ ( ,) 2lC + 2H lCH2 = , \ = ]lCH [ = [ ]2H[ = ]2lC ]lCH [ \ [ ]2H[]2lC =
+ - - = ( ) \ ( ) = +
( - ) [ ]2H[]2lC
,= = = ( + ) ]lCH [
,= , ,= 2lC ,= , = [ ]2lC ,= , ,= 2H ,= , = [ ]2H
,= , ,= lCH ,= ,+ = ]lCH [ C ( ) C2 B + A /
C ( ) B A B A C ( )
C2 B + A /
( ) [ ]C ......... = =
() ]B [] A [ C2 B + A
= C + + - = C
+ + ,= = ( )
.... ............ = ( ) ( ) ( ,+ )
= ( ,+ ) ()
= ( ) =
-
D C ( ) B A ( ) /
/ = . D+C B+ A D A ( ) D+ C B+ A /
/ ]B[= ]C[ M = ]A[ B C ( ) 2OC2 2O + OC2 /
( , , , ) OC 2O 2OC / ]2OC[
( OC ,ON , 2OC , 2ON) / 2OC ON + 2OC 2ON+ OC
/ OC 2ON 2OS 2O 3OS2 2O + 2OS2 / M = ]2OS[ = 3OS ( )
\/ . ( ) ( ) C2 B + A3 / / . . C B A 5lCP /
, 5lCP , 2lC + 3lCP 5lCP , 5lCP . 2lC 3lCP
, , ,/
2ON2 2O + ON2 / - /
2H IH2 2I + 2H / = IH IH 2I
/ . 2H 2I
2OC + OaC 3OCaC . 2OC OaC 3OCaC
.
]2OC [= /
]lCH[ ]2OC [
lCH2 + lCOaL O2H + 3lCaL = 2OC 2O + C = s g s g ] O2H[ ] 2O[
-
3OCaC / ,= 2OC 2OC + OaC 3OCaC
. 3OCaC , = ]2OC [= ,= \ ,= ]2OC [ /
,= 3OCaC = 2OC :
. ( 3HN )
3HN2 2H3 + 2N = g g g ( 2N ) ( 2H )
2OC ( ) = 2OC + OaC 3OCaC s s g
2O 3OS 2OS 3OS2 2O + 2OS2 / 2OS + 2O2/1 3OS , , ,
( 3OS ) 3OS2 2O + 2OS2 =
, , , (2OS ( ) 2O ) \ = ( ,( ) ,) \ ( ,) =
2OS + 2O2/1 3OS
= = = \
2N 3HN2 2H3 + 2N / . \= 2H
( 3HN ) / 3HN2 2H3 + 2N =
( 2N ) ( 2H ) ( = 3HN ) = ( 3HN ) ( ) ( ) \ ( 3HN = ) \
, B A C 2 B3 + A / . ,=
C2 B3 + A = / , , ,= ,+ ,+ - - + ,= ,= ,
, , ,= C ,= , -,= B ,= , ,= A ( C )
= ( ,) ( ,) \ ( ,= ) = ( A) ( B )
-
:
( ) . . = . . \ = . . = . = : = :
,= lCH + 3HN lC4HN /
s g g
lCH + 3HN lC4HN /
3HN lCH ,= ( ) = ,( 3HN ( ) lCH= ) = ,= &
= -( ) =
( ) ( ) ( ) = :
. \ . ,= ( ) + = ( ) = = * * ) .
( )
. 2rBeF 2rB /
= 2rB 3rBeF 2 2rB + 2rBeF 2
\ = ] 2rB [ \ = / ( ) -( (+ ) , ) = , -( ) =
, = = + /
= /
= = ( ,) = -( ) = ,
= + =
-
5lCP ( ) / % 5lCP 2lC +3lCP
,= :
,= \ = 5lCP = 5lCP
, 2lC = 3lCP = 5lCP ,= , = 5lCP
,= ,+ ,+ ,=
=
, , , 2lC 3lCP 5lCP , , ( 3lCP ( ) 2lC )
,= = = ,( 5lCP )
3HN S2H SH4HN S2H + 3HN /
= SH4HN
SH4HN S2H + 3HN = M = /
- - = ]3HN[]S2H[
,= ( ) -( ,) = -( ) =
,= , , ,= = , = , ( ) ( )
3HN S2H = = SH4HN = S2H
S 2) 4HN ( S2H + 3HN2 /
2lC + 2H lCH2 /
g g g OC+ OiN 2OC + iN OC OiN /
s g s g = OC =
< / 2O ON , 2ON2 2O + ON2 /
,/ ,= ON
-
3OS ( ) ( ) / 2O + 2OS2 3OS2 2OS ( )
/ 2lC + 2H lCH2 /
,= ( ) ,/ ]2lC[ :
B2 A ,= / ,/ ................ ..= A 2 /1 B
.
-: : -
. .
-
- .
.
-
rBH , / = 2H + 2rB rBH2
rBH , . rBH ,
2H + 2rB rBH2 = M = / , ]2rB []2H [
- + + = , ] rBH [
-
,= ( ,) \ ( = )
,= ]2rB [ ,= ]2H [ ,= , ,= ] rBH [
rBH , ( + ,)
2H + 2rB rBH2 = , , , ( ,) ,+ ,= , , , M ,=,+ ,= ]2rB [ - + + , = ]2H [
, + , + , M ,= , ,= [ ]rBH rBH ,
( - ,) 2H + 2rB rBH2 =
, , , ( + ,) , - ,= , , , M ,=, -,= ]2rB [ + - - ,= ]2H [
+ , - , - , M,( = , +),= [ ]rBH BA2 2B + 2A /
2B 2A , BA BA , BA ,
* * *
( ) , C2 B + A /
C , B A C B A , C B A ,
C2 B + A ( ,) ] C[/ , , , = = = , - , - , - ( ,) ]B [] A[
, , , ( ,) ] C[ + + - = = =
+ , + , , (,) ]B [] A[
-
( ) C2 B + A ( ,) ] C[ , , , = = =
, + ,+ ,+ (,) ]B [] A[ , , , >
- - + ( + ,) , , + , .. .. =
( ,) C C2 B + A /
C B A ,= C B A = C = A
( = ) ( : )
C2 B + A = M = B 2/1 + A2/1 C ,= - - - \ = , \ =
= + + - ( ) ] C[
= = () ]B [] A[
( ..... ) ...... = = ]C[ C
= ]A [ = = ( ...................) + = = +
= ]C[ ( + ) =
( ....................... ) + = ( + ) ] C[
= = = ( ) ]B [] A[
B A ( ) C ( )
B A C C2 B + A / A C A
= B A = B C2 B + A /
+ + - A
+ + A = + + - ( + )
+ + + ( - ) ] C[ = =
( ................ ) + = (+) ]B [] A[
-
C2 B + A + + + - + = ]A[
- = -+ + + ( .... ....... ) + =
- - + +
+ ( + ) + ( + )
= = ( )
B A = ( ) C = ( )
(M ) C C2 B + A / ,= ]A [ C , B A
]C[ C2 B + A ( ) ] C[ ( ..... ). = =
,+ ( ) ]B [] A[ ,+ ,= ] A [
+ + - ,= ,= + + + ,+
, , ,+ ( ,+ )
( .......... ) . = ( ,)
( ,+ ) ( ) = =
( ,) ( ) - ,+ = ]C [
,= , - ,+ = ]C [ A a C2 B + A /
A B C B . . = C B C2 B + A a ()
= + + a(()) + + = = = C
a - - + = + + a -+ - + + = = +
a ( ) = =
a() a(( ) )
.. = a()
-
( ) = =
a( a ) a( a )
= a a - = a(a = ) a() = a( a ) a()
,= C BA C2 B + A /
% = C B A C
C2 B + A C / % = C
- - + +
, , , % = % = C
% = C
C < C
+ ,= =
+ + + ( ,) ( C)
= = = ( ,) ] B [ ] A [
C2 B + A
, , , ( + ,) + + =
, , , ( ,) - - + ,=
-, - , + , + ,= C
=
3HN2 2H3 + 2N / ,= =
,=
( = H = N)
-
H3 + 2N 3HN2 = M = / = ]3HN[ - + + \ = + = 3HN . =
,= = ,
]2N[]2H[ ,= = , =
, ]3HN[ ,= ,=
\ = + = \ \ ,=
,= .... . /
/ . -
: : /
( )
.( . ) /
IH2 2I + 2H: .
.
: .
( ............... ) / B A2 > : /
( ............ ) ( ) = / B A2 > /
. \ = /
/
> < = : / ... / /
( )
-
< B A2 .
:
( ) ( )
. H H H
3HN2 2H3 + 2N , = H 2ON2 4O2N ,= + H
( ) : ( )
.
. .
( ) ) .
. (
. H
> . < .
. . / /
. . 4O2N 2ON2 / :
2ON 4O 2N 2ON
4O2N
/
/
. .