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Analytical ReferenceMaterials

Detailed Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . .394-395

Environmental Mixtures by Chemical Class Index . . . . . . . . . . . .396

Custom Reference Materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .397

Neat & Single Analyte Solutions

Individual Compounds . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .399-404

Environmental Materials

500 Series Drinking Water Analyses . . . . . . . . . . . . . . . . . . . . .407-419

600 Series Wastewater Analyses . . . . . . . . . . . . . . . . . . . . . . . . .420-425

Method 418.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .426

Method 1311 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .426

Method 1664 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .426

Method 3500 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .426

8000 Series Solid Waste Analyses . . . . . . . . . . . . . . . . . . . . . . . .427-441

Contract Lab Program . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .442-451

PCBs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .451-452

Organotins . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .452

Minnesota Dept. of Agriculture Pesticides . . . . . . . . . . . . . . . . . . .453

International Environmental Mixes . . . . . . . . . . . . . . . . . . . . . .454-456

Underground Storage Tank Monitoring . . . . . . . . . . . . . . . . .457-467

Other Materials

ASTM Methods . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .469-471

Petroleum Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .472-475

Forensics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .476-478

USP OVI Solvents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .479-480

European Pharmacopoeia/ICH Solvents . . . . . . . . . . . . . . . . . . . . . .480

Organic Acids . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .481

Fatty Acid Methyl Esters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .481-483

Derivatization Reagents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .484

Food Testing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .485

Test Mixes, GC & HPLC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .486-487

Air Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .383-389

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ANALYTICAL REFERENCE MATERIALS

Detailed Table of ContentsCustom Reference Materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .397Neat & Single Analyte Solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .399-404

Environmental Reference Materials500 Series Methods – US EPA Safe Drinking Water Act (SDWA)Methods 501.1, 501.2, 501.3 – Trihalomethanes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .407Methods 502.1, 502.2 – Volatile Halogenated Organics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .408-409Method 504.1 – Ethylene Dibromide/Dibromochloropropane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .409Method 505 – Organohalide Pesticides & PCBs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .409Method 506 – Phthalate & Adipate Esters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .409Method 507 – Nitrogen & Phosphorus Pesticides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .410Methods 508, 508.1, 508A – Chlorinated Pesticides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .410-411Methods 515, 515.4 – Chlorinated Acid Herbicides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .411Method 521 – Nitrosamines . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .412Methods 524.1, 524.2 – Volatile Organics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .412-413Methods 525, 525.1, 525.2 – Semivolatile Organics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .414-415Method 526 – Semivolatile Organics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .415Method 527 – Pesticides & Flame Retardants (GC/MS) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .415Method 528 – Phenols . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .416Method 529 – Nitroaromatics & Nitramines . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .416Methods 531.1, 531.2 – Carbamates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .417Method 532 – Phenylurea Pesticides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .417Method 535 – Chloroacetanilide Herbicide Degradates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .417Method 547 – Glyphosate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .417Method 549.2 – Paraquat/Diquat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .417Method 551.1 – Chlorinated Pesticides & Herbicides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .418Methods 552, 552.1, 552.2, 552.3 – Haloacetic Acids and Dalapon . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .418-419Method 555 – Chlorinated Acids . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .419Drinking Water Odor Standard . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .419600 Series Methods – US EPA Clean Water Act (CWA)Method 601 – Purgeable Hydrocarbons . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .420Method 602 – Purgeable Aromatics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .420Method 603 – Acrolein/Acrylonitrile . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .420Method 604 – Phenols . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .420Method 605 – Benzidine/3,3’-Dichlorobenzidine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .420Method 606 – Phthalate Esters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .420Method 607 – Nitrosamines . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .421Method 608 – Organochlorine Pesticides & PCBs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .421Method 609 – Nitroaromatics & Isophorone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .421Method 610 – Polycyclic Aromatic Hydrocarbons (PAHs) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .421Method 611 – Haloethers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .421Method 612 – Chlorinated Hydrocarbons . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .421Method 615 – Chlorinated Acid Herbicides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .422Method 624 – Purgeable Halocarbons . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .422-423Method 625 – Semivolatile Organics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .424-424Tuning Mixtures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .425Technical Chlordane, Toxaphene Solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .425Aroclor Solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4258000 Series Methods – Resource Conservation and Recovery Act (RCRA) Method 418.1 – Total Recoverable Petroleum Hydrocarbons (TRPH) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .426Method 1311 – Toxicity Characteristics Leaching Procedure (TCLP) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .426Method 1664 – Oil & Grease . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .426Method 3500 – Organic Extraction Surrogates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .426Method 8010 – Halogenated Volatile Organics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .427Method 8011 – 1,2-Dibromoethane, 1,2-Dibromo-3-chloropropane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .427Method 8020 – Aromatic Volatile Organics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .427Method 8021 – Volatile Organics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .428Method 8040 – Phenols . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .428Method 8061A – Phthalate Esters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .428Methods 8080, 8081 – Chlorinated Pesticides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .428-429Methods 8082, 8082A – PCBs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .429Method 8095 – Explosives by GC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .429-430Method 8100 – Polycyclic Aromatic Hydrocarbons . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .430Methods 8140, 8141 – Organophosphorus Pesticides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .430Methods 8150, 8151, 8151A – Chlorinated Acid Herbicides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .431Method 8240 – Volatile Organic Compounds (VOC) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .432Methods 8260, 8260A, 8260B – Volatile Organic Compounds (VOC) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .433-434Methods 8270D, 8270C – Semivolatile Organic Compounds . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .435-438Method 8310 – Polycyclic Aromatic Hydrocarbons . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .439Method 8315 – Aldehydes/Ketones DNPH by HPLC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .439Method 8321 – Chlorinated Acids by HPLC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .440Method 8330 – Nitroaromatics and Nitramines by HPLC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .440-441

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Detailed Table of ContentsEPA Superfund Contract Lab Program (CLP)Volatiles – QA Mixes (SOM01.1, 04.2, 04.1, 10/92 SOW) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .442-443Volatiles – Calibration Mixes (04.2, 04.1, 3/90 SOW, OLC 03.2) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .443-444Semivolatiles – QA Mixes (SOM01.1, 04.2, 04.1, 4/89, 3/90 SOW, Low Concentration) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .444-445Semivolatiles – Calibration Mixes (SOM01.1, 04.2, 04.1, 4/89, 3/90 SOW, 03.2, Low Concentration) . . . . . . . . . . . . . . . . . . .446-448CLP GPC – Calibration Mixes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .448Pesticides – QA Mixes (SOM01.1, 04.2, 04.1, 03.2, 3/90, 4/89, 2/88 SOW) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .449CLP Pesticides Mixtures – QA Mixes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .449-450CLP Pesticides Mixtures – Calibration Mixes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .450Pesticide Calibration Mixtures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .451Technical Chlordane, Toxaphene Solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .451Aroclor Solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .451PCB Congeners . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .452Additional Environmental MixturesOrganotin Mixes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .452Minnesota Department of Agriculture Pesticides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .453International Environmental Mixes

Canada . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .454-455Europe . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .455Japan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .455Korea . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .456ISO/DIS 9377 Water Quality Testing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .456

Underground Storage Tank (UST) MonitoringRetention Time Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .457Fuel Composite Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .457Motor Oil Composite Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .457Single Source Fuel Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .458Military Fuels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .458Fuel Oil Degradation Test . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .459Mineral Spirits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .459Petroleum Volatile Organic Compounds (PVOC), Gasoline Range Organics (GRO),

Benzene-Toluene-Ethylbenzene-Xylenes (BTEX) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .459-460Gasoline & Diesel Surrogates and Internal Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .460Diesel/Biodiesel Standard . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .460State Specific Methods:

Alaska . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .461-462Arizona . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .463California; Los Angeles County CA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .463Connecticut . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .463Florida . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .463Massachusetts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .464-465Michigan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .465Mississippi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .465Northwest (Oregon/Washington) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .465Pennsylvania . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .466Tennessee/Mississippi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .466Texas . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .466Washington . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .467Wisconsin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .467

Other Reference MaterialsASTM MethodsE1387 and E1618 – Fire Debris Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .469D2887-01, D2887, D3710-95 – Simulated Distillation Petrochemical Mixtures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .469D4059-96 – PCB Standards in Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .470D5197 – Formaldehyde and Other Carbonyl Compounds in Air . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .470D5836-03 – Isocyanates in Indoor Air . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .470D6042-96 – Plastic Container Testing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .470D6352-98 – Polywax® Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .471D6584-00 – Biodiesel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .471D6730-01 – Determination of Individual Components in Spark Ignition Engine Fuels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .471Other MaterialsPetroleum Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .472-475Forensic:

Fire Debris . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .476Blood Alcohol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .476-477Bank Dye . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .477Explosives . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .477Exempted Drugs of Abuse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .478

USP OVI Solvents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .479-480European Pharmacopoeia/ICH Solvents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .480Organic Acids . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .481Fatty Acid Methyl Esters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .481-483Derivatization Reagents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .484FAPAS® Food Testing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .485Dimethyldichlorosilane Deactivating Agent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .486Test Mixes, GC, HPLC & OQ/PQ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .486-487Air Gas Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .383-389

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Index of Environmental Mixtures by Chemical ClassAAcceettaatteess30477 . . . . . . . . . . . . . . . . .43430489 . . . . . . . . . . . . . . . . .434

AAcciiddss,, CChhlloorriinnaatteedd30498 . . . . . . . . . . . . . . . . .40132429 . . . . . . . . . . . . . .419,44032430 . . . . . . . . . . . . . . . . .41932431 . . . . . . . . . . . . . .419,440

AAcciiddss,, HHaallooaacceettiicc31644 . . . . . . . . . . . . . . . . .41831645 . . . . . . . . . . . . . . . . .41831646 . . . . . . . . . . . . . . . . .41931647 . . . . . . . . . . . . . . . . .41931896 . . . . . . . . . . . . . . . . .41831897 . . . . . . . . . . . . . . . . .418

AAcciiddss,, OOrrggaanniicc35080 . . . . . . . . . . . . . . . . .48135081 . . . . . . . . . . . . . . . . .481

AAllccoohhoollss30214 . . . . . . . . . . . . . . . . .43230466 . . . . . . . . . .401,434,46330467 . . . . . . . . . .402,434,463

AAmmpphheettaammiinneess && MMeettaabboolliitteess34020 . . . . . . . . . . . . . .399,47834021 . . . . . . . . . . . . . .402,478

BBaarrbbiittuurraatteess34028 . . . . . . . . . . . . . .399,47834029 . . . . . . . . . . . . . .399,47834030 . . . . . . . . . . . . . .399,47834031 . . . . . . . . . . . . . .399,47834032 . . . . . . . . . . . . . .399,47834033 . . . . . . . . . . . . . .402,47834034 . . . . . . . . . . . . . .402,47834035 . . . . . . . . . . . . . .402,47834036 . . . . . . . . . . . . . .403,47834037 . . . . . . . . . . . . . .403,47834038 . . . . . . . . . . . . . .404,47834039 . . . . . . . . . . . . . .404,47834040 . . . . . . . . . . . . . .404,47834041 . . . . . . . . . . . . . .404,47834058 . . . . . . . . . . . . . .402,478

BBeennzziiddiinneess31030 . . . . . . .420,436,438,44731688 . . . . . . . . . . . . . .436,44731834 . . .420,436,438,446,44731835 . . . . . . . . . .401,447,44831852 . . . . . . . . . . . . . .436,447

BBeennzzooddiiaazziippiinneess34042 . . . . . . . . . . . . . .399,47834043 . . . . . . . . . . . . . .399,47834044 . . . . . . . . . . . . . .400,47834045 . . . . . . . . . . . . . .400,47834046 . . . . . . . . . . . . . .400,47834047 . . . . . . . . . . . . . .400,47834049 . . . . . . . . . . . . . .402,47834050 . . . . . . . . . . . . . .402,47834051 . . . . . . . . . . . . . .402,47834053 . . . . . . . . . . . . . .403,47834054 . . . . . . . . . . . . . .403,47834055 . . . . . . . . . . . . . .403,47834056 . . . . . . . . . . . . . .404,47834057 . . . . . . . . . . . . . .404,478

CCaannnnaabbiinnooiidd && MMeettaabboolliitteess34010 . . . . . . . . . . . . . .400,47834011 . . . . . . . . . . . . . .400,478

CCaarrbbaammaatteess32273 . . . . . . . . . . . . . . . . .41732435 . . . . . . . . . . . . . . . . .417

CChhlloorriinnaatteedd DDiissiinnffeeccttiioonnBBiipprroodduuccttss30609 . . . . . . . . . . . . . . . . .40030615 . . . . . . . . . . . . . . . . .41830616 . . . . . . . . . . . . . . . . .418

CChhlloorriinnaatteeddPPeessttiicciiddeess//HHeerrbbiicciiddeess32438 . . . . . . . . . . . . . . . . .418

CCooccaaiinnee && MMeettaabboolliitteess34015 . . . . . . . . . . . . . .400,47834016 . . . . . . . . . . . . . .399,47834017 . . . . . . . . . . . . . .401,47834018 . . . . . . . . . . . . . .401,478

DDeeuutteerraatteedd30614 . . . . . . . . . . . . . .401,43330624 . . . . . . . . . . . . . . . . .44230625 . . . . . . . . . . . . . . . . .44231006 . . . . . . . . . .424,435,44431206 . . . . . . . . . .435,444,45331810 . . . . . . . . . . . . . . . . .44831885 . . . . . . . . . . . . . .435,44431886 . . . . . . . . . . . . . .435,44431887 . . . . . . . . . . . . . .435,44431888 . . . . . . . . . . . . . .435,44431889 . . . . . . . . . . . . . .435,44433913 . . . . . . . . . . . . . . . . .44433918 . . . . . . . . . . . . . . . . .444

EEsstteerrss,, NNiittrraattee31498 . . . . . . . . . . . . . . . . .40331600 . . . . . . . . . . . . . . . . .40331601 . . . . . . . . . . . . . . . . .401

EEsstteerrss,, PPhhtthhaallaattee31031 . . . . . . . . . . . . . . . . .42031844 . . . . . . . . . . . . . . . . .40931845 . . . . . . . . . . . . . . . . .40933227 . . . . . . . . . . . . . . . . .42833228 . . . . . . . . . . . . . . . . .42833229 . . . . . . . . . . . . . . . . .428

EEtthheerrss30617 . . . . . . . . . . . . . .399,434

EEtthheerrss,, AAllccoohhooll30626 . . . . . . . . . . . . . . . . .43430627 . . . . . . . . . . . . . .401,43430628 . . . . . . . . . . . . . .401,43430629 . . . . . . . . . . . . . .399,43430631 . . . . . . . . . . . . . .399,434

EEtthheerrss--HHaallooeetthheerrss30456 . . . . . . . . . . . . . . . . .44330475 . . . . . . . . . . . . . . . . .43331034 . . . . . . . . . . . . . . . . .421

EExxpplloossiivveess31450 . . . . . . . . . . . . . . . . .44031451 . . . . . . . . . . . . . . . . .44031607 . . . . . . . . . . . . . . . . .42931608 . . . . . . . . . . . . . . . . .42931890 . . . . . . . . . . . . . . . . .39933204 . . . . . . . . . . . . . . . . .44033205 . . . . . . . . . . . . . .401,44033900 . . . . . . . . . . . . . . . . .41633901 . . . . . . . . . . . . . .401,41633902 . . . . . . . . . . . . . .403,41633903 . . . . . . . . . . . . . .404,41633904 . . . . . . . . . . . . . .403,41633905 . . . . . . . . . . . . . . . . .440

GGllyyccoollss30471 . . . . . . . . . .432,463,465

HHeerrbbiicciiddeess,, CChhlloorriinnaatteedd AAcciiddss32054 . . . . . . . . . .411,422,43132055 . . . . . . . . . . . . . .411,42232056 400,411,419,422,431,44032057 . . .400,411,419,422,43132058 . . . . . . . . . . . . . .422,43132059 . . . . . . . . . . . . . .422,43132061 . . . . . . . . . . . . . .411,43132062 . . . . . . . . . . . . . .411,43132443 . . . . . . . . . . . . . . . . .41132444 . . . . . . . . . . . . . . . . .411

HHeerrbbiicciiddeess,, PPaarraaqquuaatt//DDiiqquuaatt32437 . . . . . . . . . . . . . . . . .417

HHeerrbbiicciiddeess,, PPhheennooxxyyaacciidd31868 . . . . . . . . . . . . . . . . .45432014 . . . . . . . . . . . . . . . . .42632054 . . . . . . . . . .411,422,43132055 . . . . . . . . . .411,422,43132058 . . . . . . . . . . . . . .422,43132059 . . . . . . . . . . . . . .422,43132429 . . . . . . . . . . . . . .419,44032430 . . . . . . . . . . . . . .419,44032431 . . . . . . . . . . . . . .419,440

HHyyddrrooccaarrbboonnss30604 . . . . . . . . . . . . . . . . .46430605 . . . . . . . . . . . . . . . . .46431064 . . . . . . . . . . . . . . . . .46731214 . . . . . . . . . .462,465,46631222 . . . . . . . . . . . . . . . . .469

HHyyddrrooccaarrbboonnss (cont'd)31266 . . . . . . . . . . . . . .462,46331459 . . . . . . . . . . . . . . . . .46431489 . . . . . . . . . . . . . . . . .46731614 . . . . . . . . . . . . . . . . .46331674 . . . . . . . . . . . . . . . . .46931675 . . . . . . . . . . . . . . . . .46931678 . . . . . . . . . . . . . . . . .45631698 . . . . . . . . . . . . . .457,46631814 . . . . . . . . . . . . . . . . .46631819 . . . . . . . . . . . . . .457,46131830 . . . . . . . . . . . . . . . . .46331832 . . . . . . . . . . . . . . . . .46331838 . . . . . . . . . . . . . .400,45831839 . . . . . . . . . . . . . .402,45831877 . . . . . . . . . . . . . .403,46331878 . . . . . . . . . . . . . . . . .46331880 . . . . . . .401,458,460,47133906 . . . . . . . . . . . . . . . . .48733908 . . . . . . . . . . . . . . . . .487

HHyyddrrooccaarrbboonnss,, AArroommaattiicc30001 . . . . . . . . . . . . . . . . .44230035 . . . . . . . . . . . . . . . . .42030051 . . . . . . . . . .427,432,45930095 . . . . . . . . . . . . . .459,46730488 . . . . . . . . . .427,432,45930496 . . . . . . . . . . . . . . . . .46330213 . . . . . . . . . .427,432,45930222 . . . . . . . . . . . . . . . . .427

HHyyddrrooccaarrbboonnss,, HHaallooggeennaatteedd30010 . . . . . . . . . . . . . .443,44430020 . . . . . . . . . . . . . . . . .42230042 408,413,427,432,433,44331035 . . . . . . . . . . . . . . . . .421

HHyyddrrooccaarrbboonnss,, HHaallooggeennaatteeddPPoollyyaarroommaattiicc31842 . . . . . . . . . . . . . .400,439

IIssooccyyaannaatteess33000 . . . . . . . . . . . . . .404,47033001 . . . . . . . . . . . . . .404,47033002 . . . . . . . . . . . . . .402,47033003 . . . . . . . . . . . . . .402,470

KKeettoonneess--AAllddeehhyyddeess30006 . . . . . . .432,434,443,44430602 . . . . . . . . . . . . . . . . .41331808 . . . . . . . . . . . . . . . . .43931833 . . . . . . . . . . . . . . . . .40031837 . . . . . . . . . . . . . .402,439

MMeetthhaaddoonnee && MMeettaabboolliitteess34005 . . . . . . . . . . . . . .402,478

NNiittrrooaarroommaattiiccss31033 . . . . . . . . . . . . . . . . .421

NNiittrroossaammiinneess31032 . . . . . . . . . . . . . . . . .42131898 . . . . . . . . . . . . . . . . .41233009 . . . . . . . . . . . . . . . . .41533910 . . . . . . . . . . . . . .403,41233911 . . . . . . . . . . . . . . . . .403

OOppiiaatteess && MMeettaabboolliitteess34000 . . . . . . . . . . . . . .400,47834002 . . . . . . . . . . . . . .402,47834006 . . . . . . . . . . . . . .403,47834007 . . . . . . . . . . . . . .403,47834063 . . . . . . . . . . . . . .402,47834065 . . . . . . . . . . . . . .403,478

OOrrggaannoommeettaalllliicc//OOrrggaannoottiinn31472 . . . . . . . . . . . . . . . . .45231473 . . . . . . . . . . . . . . . . .45231474 . . . . . . . . . . . . . .404,45231475 . . . . . . . . . . . . . .404,45231476 . . . . . . . . . . . . . .404,45231477 . . . . . . . . . . . . . .404,45231478 . . . . . . . . . . . . . .404,452

OOxxaazzoollaaddiinneess33004 . . . . . . . . . . . . . .402,470

OOxxyyggeennaatteess30619 . . . . . . . . . . . . . . . . .413

PPAAHHss ((PPoollyyaarroommaattiiccHHyyddrrooccaarrbboonnss))31011 . . . . . . . . . .430,447,44831264 . . . . . . . . . . . . . . . . .42131455 . . . . . . . . . . . . . . . . .42131458 . . . . . . . . . . . . . .462,46431469 . . . . . . . . . . . . . .462,46731622 . . . . . . . . . . . . . . . . .43831841 . . . . . . . . . . . . . . . . .43931843 . . . . . . . . . . . . . . . . .43931857 . . . . . . . . . . . . . . . . .43031869 . . . . . . . . . . . . . . . . .454

PPCCBBss,, AArroocclloorr32006 . . . . . . . . . . . . . .399,42532007 . . . . . . .399,425,438,45132008 . . . . . . .399,425,438,45132009 . . . . . . .399,425,438,45132010 . . . . . . . . . .399,425,43832011 . . . . . . .399,425,438,45132012 . . . . . . . . . .399,438,45132039 . . . . . . . . . .425,438,45132064 . . . . . . .399,425,438,45132065 . . . . . . .399,425,438,45132066 . . . . . . .399,425,438,45132067 . . . . . . .399,425,438,45132068 . . . . . . .399,425,438,45132069 . . . . . . .399,425,438,45132070 . . . . . . .399,425,438,45132299 . . . . . . . . . .425,438,45132409 . . . . . . .399,425,438,45132410 . . . . . . .399,425,438,45132456 . . . . . . . . . .425,438,451

PPCCBB CCoonnggeenneerrss32283 . . . . . . . . . . . . . .404,45232284 . . . . . . . . . . . . . .404,45232285 . . . . . . . . . . . . . .403,45232286 . . . . . . . . . . . . . .402,45232287 . . . . . . . . . . . . . .402,45232288 . . . . . . . . . . . . . .402,45232289 . . . . . . .400,410,449,45232290 . . . . . . . . . . . . . .452,45532293 . . . . . . . . . . . . . .403,45232294 . . . . . . . . . . . . . .452,45532416 . . . . . . . . . . . . . . . . .42932420 . . . . . . . . . . . . . . . . .414

PPeessttiicciiddeess,,NNiittrrooggeenn//PPhhoosspphhoorruuss32423 . . . . . . . . . . . . . .410,41433012 . . . . . . . . . . . . . .410,414

PPeessttiicciiddeess,, OOrrggaannoocchhlloorriinnee32454 . . . . . . . . . . . . . . . . .44932455 . . . . . . . . . . . . . . . . .48733011 . . . . . . . . . . . . . . . . .415

PPeessttiicciiddeess,, OOrrggaannoohhaalliiddee31012 . . . . . . . . . . . . . . . . .44732003 . . . . . . . . . . . . . . . . .45132004 . . . . . . . . . . . . . . . . .45132013 . . . . . . . . . . . . . . . . .42632022 . . . . . . . . . . . . . . . . .42132024 . . . . . . . . . . . . . . . . .40932033 . . . . . . . . . . . . . . . . .45032034 . . . . . . . . . . . . . . . . .45032040 . . . . . . . . . . . . . . . . .45032094 . . . . . . . . . . . . . . . . .41032095 . . . . . . . . . . . . . . . . .41032096 . . . . . . . . . . . . . . . . .41032291 . . . . . . . . . . . . . .428,45032292 . . . . . . . . . . . . . .429,45032297 . . . . . . . . . . . . . . . . .45032298 . . . . . . . . . . . . . . . . .45032415 . . . . . . .414,429,437,45032417 . . . . . . . . . .410,421,449

PPeessttiicciiddeess,, OOrrggaannoopphhoosspphhoorruuss31623 . . . . . . . . . . . . . . . . .43832277 . . . . . . . . . . . . . . . . .43032278 . . . . . . . . . . . . . . . . .43032418 . . . . . . . . . . . . . . . . .45532419 . . . . . . . . . . . . . . . . .43732423 . . . . . . . . . . . . . .410,41432426 . . . . . . . . . . . . . .402,41732427 . . . . . . . . . . . . . .402,41732428 . . . . . . . . . . . . . .399,41732436 . . . . . . . . . . . . . . . . .40333008 . . . . . . . . . . . . . . . . .41533013 . . . . . . . . . . . . . .410,414

PPeettrroocchheemmiiccaallss30096 . . . . . . . . . .404,458,47630097 . . . . . . . . . . . . . .404,47630098 . . . . . . . . . . . . . .404,47630099 . . . . . . . . . . . . . .404,47630436 . . . . . . . . . . . . . .404,47631222 . . . . . . . . . . . . . . . . .46931223 . . . . . . . . . . . . . . . . .46931224 . . . . . . . . . . . . . . . . .46931613 . . . . . . . . . . . . . . . . .46931674 . . . . . . . . . . . . . . . . .46931675 . . . . . . . . . . . . . . . . .46931676 . . . . . . . . . . . . . . . . .45631677 . . . . . . . . . . . . . . . . .45631678 . . . . . . . . . . . . . . . . .45631679 . . . . . . . . . . . . . . . . .45631680 . . . . . . . . . . . . . . . . .45631681 . . . . . . . . . . . . . .404,45631682 . . . . . . . . . . . . . . . . .45631683 . . . . . . . . . . . . . . . . .456

PPhheennoollss31008 . . . . . . . . . . . . . . . . .44731027 . . . . . . . . . . . . . . . . .42631029 . . . . . . . . . . . . . . . . .42031088 . . . . . . . . . . . . . . . . .42831089 . . . . . . . . . . . . . . . . .42831208 . . . . . . . . . . . . . . . . .44831209 . . . . . . . . . . . . . . . . .44831494 . . . . . . . . . . . . . . . . .44631618 . . . . . . . . . . . . . . . . .43731694 . . . . . . . . . . . . . . . . .41631695 . . . . . . . . . . . . . . . . .41631697 . . . . . . . . . . . . . . . . .416

PPhheennyylluurreeaa32433 . . . . . . . . . . . . . . . . .417

SSeemmiivvoollaattiilleess31625 . . . . . . . . . . . . . . . . .43731806 . . . . . . . . . . . . . . . . .43731829 . . . . . . . . . . . . . . . . .42431850 . . . . . . . . . . . . . . . . .43631862 . . . . . . . . . . . . . . . . .448

SSoollvveennttss,, OOVVII36274 . . . . . . . . . . . . . . . . .48036275 . . . . . . . . . . . . . . . . .480

SSoollvveennttss,, RReessiidduuaall36271 . . . . . . . . . . . . . . . . .47936272 . . . . . . . . . . . . . . . . .47936273 . . . . . . . . . . . . . . . . .479

TTrriiaazziinneess32445 . . . . . . . . . . . . . .400,45532446 . . . . . . . . . . . . . .400,45532447 . . . . . . . . . . . . . .404,45532448 . . . . . . . . . . . . . .403,45532449 . . . . . . . . . . . . . .403,45533007 . . . . . . . . . . . . . . . . .415

VVoollaattiilleess30431 . . . . . . . . . . . . . . . . .40830432 . . . . . . . . . . . . . . . . .40830438 . . . . . . . . . . . . . . . . .44330456 . . . . . . . . . . . . . . . . .44330475 . . . . . . . . . . . . . . . . .43330492 . . . . . . . . . . . . . . . . .44430497 . . . . . . . . . . . . . . . . .42230601 . . . . . . . . . . . . . . . . .41330603 . . . . . . . . . . . . . .408,412

OOtthheerr EExxeemmpptteedd DDrruuggss34003 . . . . . . . . . . . . . .402,47834004 . . . . . . . . . . . . . .402,47834008 . . . . . . . . . . . . . .400,47834009 . . . . . . . . . . . . . .404,47834022 . . . . . . . . . . . . . .399,47834023 . . . . . . . . . . . . . .401,47834024 . . . . . . . . . . . . . .403,47834025 . . . . . . . . . . . . . .403,47834026 . . . . . . . . . . . . . .403,47834027 . . . . . . . . . . . . . .403,47834059 . . . . . . . . . . . . . .402,47834060 . . . . . . . . . . . . . .403,47834062 . . . . . . . . . . . . . .403,47834064 . . . . . . . . . . . . . .402,47834066 . . . . . . . . . . . . . .400,478


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ANALYTICAL

REFERENCE

MATERIALS

NEAT & SINGLEANALYTE SOLUTIONS

Individual Compounds . . . . . . . . . . . . . . . . . . . . . . . . . . . . .399-404

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*Volume is 1mL/ampul unless otherwise noted. Concentration is µg/mL unless otherwise noted.

SSoollvveenntt ccooddee::A=acetoneACN=acetonitrileC=carbon disulfideCy=cyclohexane

D=methylene chlorideDMSO=dimethyl sulfoxideEA=ethyl acetateH=hexane

I=isooctaneIp=isopropanolM=methanolMTBE=methyl tert-butyl ether

PTM=purge & trap grade methanolT=tolueneTO-transformer oilW=water (DI)

CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriicceeacenaphthene 83-32-9 M 1,000 31267acenaphthylene 208-96-8 M 1,000 31268acetaldehyde-2,4-DNPH 1019-57-4 ACN 100 33074acetochlor 34256-82-1 M 100 33208acetochlor ESA sodium salt 187022-11-3 M 100 33092acetochlor OA 184992-44-4 M 100 33094acetone 67-64-1 PTM 5,000 30245acetone-2,4-DNPH 1567-89-1 ACN 100 33075acetonitrile 75-05-8 DMSO 2.05mg/mL 36281acetonitrile 75-05-8 PTM 1,000 30495acetophenone 98-86-2 PTM 5,000 30621acifluorfen 50594-66-6 M 1,000 32255acifluorfen methyl ester 50594-67-7 M 1,000 32256acrolein 107-02-8 PTM 10,000 30499acrolein 107-02-8 W 10,000 30478acrolein-2,4-DNPH 888-54-0 ACN 100 33076acrylamide 79-06-1 M 1,000 30494acrylonitrile 107-13-1 PTM 2,000 30246alachlor 15972-60-8 M 1,000 32204alachlor 15972-60-8 M 100 33207alachlor ESA sodium salt 142363-53-9 M 100 33096alachlor OA 171262-17-2 M 100 33099aldrin 309-00-2 M 1,000 32205allyl chloride 107-05-1 PTM 2,000 30248alprazolam 28981-97-7 PTM 1,000 34042 enquire2-amino-4,6-dinitrotoluene 35572-78-2 ACN 1,000 31670 enquire4-amino-2,6-dinitrotoluene 19406-51-0 ACN 1,000 31671 enquireaminomethyl phosphonic acid

(AMPA) 1066-51-9 W 100 32428ammonium picrate 131-74-8 ACN 2,000 31890 enquireamobarbital 64-43-7 PTM 1,000 34028 enquired-amphetamine 51-63-8 PTM 1,000 34020 enquiretert-amyl alcohol 75-85-4 PTM 10,000 30631tert-amyl ethyl ether (TAEE) 919-94-8 PTM 2,000 30617tert-amyl methyl ether (TAME) 994-05-8 PTM 2,000 306295-α-androstane 438-22-2 D 2,000 31065aniline 62-53-3 M 1,000 31470anthracene 120-12-7 A 1,000 31269anthracene-d10 1719-06-08 D 2,000 31037antifoam agent for purge & trap N/A Neat 1mL 31822aprobarbital 77-02-1 PTM 1,000 34029 enquireAramite 140-57-8 H 2,000 31624Aroclor 1016 12674-11-2 H 1,000 32006Aroclor 1016 12674-11-2 I 200 32064Aroclor 1016 12674-11-2 TO 500mg/kg 32076Aroclor 1016 12674-11-2 TO 50mg/kg 32075Aroclor 1221 11104-28-2 H 1,000 32007Aroclor 1221 11104-28-2 I 200 32065Aroclor 1221 11104-28-2 TO 500mg/kg 32078Aroclor 1221 11104-28-2 TO 50mg/kg 32077Aroclor 1232 11141-16-5 H 1,000 32008Aroclor 1232 11141-16-5 I 200 32066Aroclor 1232 11141-16-5 TO 500mg/kg 32080Aroclor 1232 11141-16-5 TO 50mg/kg 32079Aroclor 1242 53469-21-9 H 1,000 32009Aroclor 1242 53469-21-9 I 200 32067Aroclor 1242 53469-21-9 TO 500mg/kg 32082Aroclor 1242 53469-21-9 TO 50mg/kg 32081Aroclor 1248 12672-29-6 H 1,000 32010Aroclor 1248 12672-29-6 I 200 32068Aroclor 1248 12672-29-6 TO 500mg/kg 32084Aroclor 1248 12672-29-6 TO 50mg/kg 32083Aroclor 1254 11097-69-1 H 1,000 32011Aroclor 1254 11097-69-1 I 200 32069Aroclor 1254 11097-69-1 TO 500mg/kg 32086Aroclor 1254 11097-69-1 TO 50mg/kg 32085Aroclor 1260 11096-82-5 H 1,000 32012Aroclor 1260 11096-82-5 I 200 32070Aroclor 1260 11096-82-5 TO 500mg/kg 32088Aroclor 1260 11096-82-5 TO 50mg/kg 32087

CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriicceeAroclor 1262 37324-23-5 H 1,000 32409Aroclor 1268 11100-14-4 H 1,000 32410atrazine 1912-24-9 A 1,000 32208aviation gas (5mL) 8006-69-1 PTM 50,000 30208aviation gas 8006-69-1 PTM 2,500 30094aviation gas 8006-69-1 PTM 50,000 30207azobenzene 103-33-3 D 1,000 31496barbital 57-44-3 PTM 1,000 34030 enquirebentazon 25057-89-0 M 1,000 32257benzaldehyde 100-52-7 D 2,000 33017benzaldehyde-2,4-DNPH 1157-84-2 ACN 100 33077benzene 71-43-2 DMSO 10mg/mL 36282benzene 71-43-2 D 250 35262benzene 71-43-2 PTM 2,000 30249benzene-d6 1076-43-3 PTM 2,000 30025benzidine 92-87-5 M 1,000 31441benzo(a)anthracene 56-55-3 M 1,000 31270benzo(a)pyrene 50-32-8 A 1,000 31271benzo(b)fluoranthene 205-99-2 A 1,000 31272benzo(ghi)perylene 191-24-2 D 1,000 31273benzo(k)fluoranthene 207-08-9 A 1,000 31274benzoic acid 65-85-0 D 2,000 31879benzoic acid 65-85-0 M 1,000 31415benzoylecgonine 519-09-5 PTM 1,000 34016 enquirebenzphetamine 5411-22-3 PTM 1,000 34022 enquirebenzyl benzoate 120-51-4 H 5,000 31847α-BHC 319-84-6 M 1,000 32206ß-BHC 319-85-7 A 1,000 32209δ-BHC 319-86-8 M 1,000 32217γ-BHC (lindane) 58-89-9 M 1,000 32226bis(2-ethylhexyl)adipate 103-23-1 M 1,000 31449bis(2-ethylhexyl)phthalate 117-81-7 D 1,000 31420bromazepam 1812-30-2 PTM 1,000 34043 enquirebromobenzene 108-86-1 PTM 2,000 302502-bromobutanoic acid 80-58-0 MTBE 2,000 318812-bromobutyrate 3196-15-4 MTBE 2,000 318822-bromochlorobenzene 694-80-4 PTM 2,000 302284-bromochlorobenzene 106-39-8 PTM 2,000 302301-bromo-2-chloroethane 107-04-0 PTM 2,000 30469bromochloromethane 74-97-5 PTM 2,000 302252-bromo-1-chloropropane 3017-95-6 PTM 2,000 30226bromodichloromethane 75-27-4 PTM 2,000 302514-bromo-3,5-dimethylphenyl-

N-methylcarbamate (BDMC) 3766-81-2 M 100 322741-bromo-4-fluorobenzene 460-00-4 A 1,000 318544-bromofluorobenzene 460-00-4 PTM 2,000 300264-bromofluorobenzene 460-00-4 PTM 2,500 300674-bromofluorobenzene 460-00-4 PTM 5,000 300034-bromofluorobenzene 460-00-4 PTM 10,000 30082bromoform 75-25-2 PTM 2,000 30252bromomethane 74-83-9 PTM 2,000 302531-bromo-2-nitrobenzene 577-19-5 A 1,000 322792-bromopropionic acid 598-72-1 MTBE 1,000 31653butabarbital 125-40-6 PTM 1,000 34031 enquirebutachlor ESA sodium salt M 100 332021,3-butadiene 106-99-0 PTM 1,000 30622butalbital 77-26-9 PTM 1,000 34032 enquire1,4-butanediol 110-63-4 M 1,000 34078 enquire(s)-(-)-1,2,4-butanetriol 42890-76-6 pyridine 1,000 33024(s)-(-)-1,2,4-butanetriol (5mL) 42890-76-6 pyridine 1,000 330321-butanol 71-36-3 D 250 352601-butanol 71-36-3 PTM 50,000 30474tert-butanol 75-65-0 PTM 50,000 30470tert-butanol-d9 25725-11-5 PTM 20,000 306182-butanone (MEK) 78-93-3 PTM 5,000 302542-butanone-2,4-DNPH 958-60-1 ACN 100 33078n-butyraldehyde-2,4-DNPH 1527-98-6 ACN 100 33079γ-butyrolactone (GBL) 96-48-0 ACN 1,000 34077 enquire


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free dataAAvvaaiillaabbllee oonn OOuurr WWeebbssiittee:: LLoott CCeerrttiiffiiccaatteess,, DDaattaa PPaacckkss,, aanndd MMSSDDSSssFor complete information detailing manufacturing and testing for Restek inventoried reference standards, visit our website at wwwwww..rreesstteekk..ccoomm//ddaattaappaacckkss.To view certificates and/or an MSDS, enter the catalog number of the product in the Search feature. For a free data pack (Adobe® PDF file), enter the catalog number and lot number of the product.


CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriicceecaffeine 74051-80-2 W 5 31804caffeine 74051-80-2 W 25 31803caffeine 74051-80-2 W 125 31802caffeine 74051-80-2 W 250 31801caffeine 74051-80-2 W 500 31800caffeine 58-08-2 M 1,000 34084 enquirecannabidiol 13956-24-1 PTM 1,000 34011 enquirecannabinol 521-35-7 PTM 1,000 34010 enquireε-caprolactam 105-60-2 D 2,000 31833carbazole 86-74-8 D 1,000 31836carbazole 86-74-8 M 1,000 31430carbon disulfide 75-15-0 PTM 2,000 30258carbon tetrachloride 56-23-5 DMSO 20mg/mL 36283carbon tetrachloride 56-23-5 PTM 2,000 30259chloral hydrate 302-17-0 ACN 1,000 30609chlordane (technical) 57-74-9 H 1,000 32021chlordane (technical) 57-74-9 I 5,000 32072chlordane (technical) 57-74-9 M 2,000 32016α-chlordane 5103-71-9 M 1,000 32207γ-chlordane 5566-34-7 M 1,000 32227chlordiazepoxide 438-41-5 PTM 1,000 34044 enquire4-chloroaniline 106-47-8 D 2,000 31211chlorobenzene 108-90-7 DMSO 1.8mg/mL 36284chlorobenzene 108-90-7 PTM 2,000 30261chlorobenzene-d5 3114-55-4 PTM 2,000 30223chlorobenzilate 510-15-6 M 1,000 32211chloroethane 75-00-3 PTM 2,000 302632-chloroethanol 107-07-3 PTM 2,000 302642-chloroethyl vinyl ether 110-75-8 PTM 2,000 302651-chloro-2-fluorobenzene 348-51-6 PTM 2,000 300401-chloro-4-fluorobenzene 352-33-0 PTM 2,500 30066chloroform 67-66-3 DMSO 0.3mg/mL 36285chloroform 67-66-3 PTM 2,000 30266chloromethane 74-87-3 PTM 2,000 302672-chloronaphthalene 91-58-7 M 1,000 312841-chloro-3-nitrobenzene 121-73-3 H 1,000 318754-chloro-3-nitrobenzotrifluoride 121-17-5 A 1,000 322821-chlorooctadecane 3386-33-2 D 10,000 310981-chlorooctane 111-85-3 PTM 10,000 30084chloroprene 126-99-8 PTM 5,000 302384-chlorotoluene 106-43-4 PTM 2,000 30269chlorpyrifos 2921-88-2 M 1,000 32212chrysene 218-01-9 A 1,000 31275clobazam 22316-47-8 PTM 1,000 34045 enquireclonazepam 1622-61-3 PTM 1,000 34046 enquirecocaethylene 529-38-4 ACN 1,000 34066 enquirecocaine 53-21-4 PTM 1,000 34015 enquirecodeine 76-57-3 PTM 1,000 34000 enquirecontinine 486-56-6 M 1,000 34086 enquirecreosote oil 8001-58-9 D 50,000 31838crotonaldehyde-2,4-DNPH 1527-96-4 ACN 100 33080cyanazine 21725-46-2 A 1,000 32215cyclohexane 110-82-7 DMSO 19.4mg/mL 36286

CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriiccee2,4-D

(2,4-dichlorophenylacetic acid) 94-75-7 M 1,000 322392,4-D methyl ester 1928-38-7 M 1,000 32240Dacthal (DCPA dimethyl ester) 1861-32-1 M 1,000 32216dalapon 75-99-0 ACN 1,000 32432dalapon 75-99-0 M 1,000 32253dalapon 75-99-0 M 2,000 32056dalapon methyl ester 17640-02-7 H 2,000 32057dalapon methyl ester 17640-02-7 M 1,000 322542,4-DB 94-82-6 M 1,000 32241DCPA diacid 2136-79-0 M 200 322612,4'-DDD 53-19-0 M 1,000 320984,4'-DDD 72-54-8 M 1,000 322012,4'-DDE 3424-82-6 M 1,000 320994,4'-DDE 72-55-9 M 1,000 322022,4'-DDT 789-02-6 M 1,000 322004,4'-DDT 50-29-3 M 1,000 32203decachlorobiphenyl

(BZ #209) (5mL) 2051-24-3 A 200 32030decachlorobiphenyl (BZ #209) 2051-24-3 A 200 32029decachlorobiphenyl (BZ #209) 2051-24-3 I 10 32289decafluorobiphenyl 434-90-2 A 1,000 31855decafluorobiphenyl 434-90-2 D 2,000 31041decafluorobiphenyl 434-90-2 ACN 1,000 31842decafluorotriphenylphosphine

(DFTPP) 5074-71-5 D 2,500 31001n-decane 124-18-5 Neat 1mL 31858desethyl-atrazine 6190-65-4 A 1,000 32445desisopropylatrazine 1007-28-9 A 1,000 32446dextromethorphan HBr

monohydrate 125-69-9 M 1,000 34081 enquiredextro-propoxyphene 1639-60-7 PTM 1,000 34008 enquirediazepam 439-14-5 PTM 1,000 34047 enquiredibenzo(a,h)anthracene 53-70-3 D 1,000 312764,4'-dibromobiphenyl 92-86-4 D 2,000 310394,4'-dibromobiphenyl 92-86-4 EA 500 32092dibromochloromethane

(chlorodibromochloromethane) 124-48-1 PTM 2,000 302711,2-dibromo-3-chloropropane

(DBCP) 96-12-8 PTM 2,000 30270dibromofluoromethane 1868-53-7 Neat 100mg 306341,2-dibromoethane 106-93-4 PTM 2,000 30272dibromomethane 74-95-3 PTM 2,000 304304,4'-dibromooctafluorobiphenyl 10386-84-2 D 2,000 310404,4'-dibromooctafluorobiphenyl 10386-84-2 H 250 320534,4'-dibromooctafluorobiphenyl 10386-84-2 MTBE 2,000 318562,3-dibromopropionic acid 600-05-5 MTBE 1,000 316552,5-dibromotoluene 615-59-8 PTM 1,000 304352,5-dibromotoluene 615-59-8 PTM 10,000 30453dibutylchlorendate 1770-80-5 A 200 32025dicamba 1918-00-9 M 1,000 32247dicamba methyl ester 6597-78-0 M 1,000 32248

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SSoollvveenntt ccooddee::

A=acetoneACN=acetonitrileC=carbon disulfideCy=cyclohexaneD=methylene chlorideDMSO=dimethyl sulfoxideEA=ethyl acetateH=hexane

I=isooctaneIp=isopropanolM=methanolMTBE=methyl tert-butyl etherPTM=purge & trap grade methanolT=tolueneTO-transformer oilW=water (DI)

CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriiccee1,2-dichlorobenzene 95-50-1 M 1,000 314421,3-dichlorobenzene 541-73-1 M 1,000 314431,4-dichlorobenzene 106-46-7 ACN 1,000 304981,4-dichlorobenzene 106-46-7 M 1,000 314441,2-dichlorobenzene-d4 2199-69-1 PTM 2,000 300493,3'-dichlorobenzidine 91-94-1 D 2,000 318353,3'-dichlorobenzidine 91-94-1 M 2,000 310263,3'-dichlorobenzidine-free base 91-94-1 Neat 100mg 318843,5-dichlorobenzoic acid 51-36-5 MTBE 1,000 316523,5-dichlorobenzoic acid

methyl ester 2905-67-1 M 1,000 322643,5-dichlorobenzoic acid

methyl ester 2905-67-1 MTBE 1,000 316491,4-dichlorobutane 110-56-5 PTM 2,000 30227trans-1,4-dichloro-2-butene 110-57-6 PTM 2,000 30274dichlorodifluoromethane

(CFC-12) 75-71-8 PTM 2,000 302751,1-dichloroethane 75-34-3 PTM 2,000 302761,2-dichloroethane 107-06-2 DMSO 25mg/mL 362881,2-dichloroethane 107-06-2 PTM 2,000 302771,2-dichloroethane-d4 17060-07-0 PTM 2,000 300271,1-dichloroethene 75-35-4 DMSO 40mg/mL 362871,1-dichloroethene 75-35-4 PTM 2,000 30278cis-1,2-dichloroethene 156-59-2 PTM 2,000 30279trans-1,2-dichloroethene 156-60-5 PTM 2,000 30280cis-1,2-dichloroethylene 156-59-2 DMSO 4.67mg/mL 36289trans-1,2-dichloroethylene 156-60-5 DMSO 4.67mg/mL 362902,6-dichlorophenol 87-65-0 M 1,000 314092,4-dichlorophenylacetic acid 19719-28-9 M 200 320492,4-dichlorophenyl acetic acid

methyl ester 55954-23-9 H 200 320501,2-dichloropropane 78-87-5 PTM 2,000 302812,2-dichloropropane 594-20-7 PTM 2,000 30283cis-1,3-dichloropropene 10061-01-5 PTM 2,000 30284trans-1,3-dichloropropene 10061-02-6 PTM 2,000 302852,3-dichloropropionic acid 565-64-0 MTBE 1,000 316502,3-dichloropropionic acid

methyl ester 3674-09-7 MTBE 1,000 316511,2-dichlorotetrafluoroethane

(CFC-114) 76-14-2 PTM 2,000 30476dichlorprop 120-36-5 M 1,000 32249dichlorprop methyl ester 57153-17-0 M 1,000 32250dieldrin 60-57-1 M 1,000 32218diesel fuel #2 composite (5mL) 68334-30-5 D 50,000 31259diesel fuel #2 composite 68334-30-5 D 5,000 31093diesel fuel #2 composite 68334-30-5 D 50,000 31258diesel fuel #2: 25% weathered 68334-30-5 D 5,000 31234diesel fuel #2: 50% weathered 68334-30-5 D 5,000 31235diesel fuel #2: 75% weathered 68334-30-5 D 5,000 31236diesel fuel #2: unweathered 68334-30-5 D 5,000 31233diesel/biodiesel 80:20 67784-80-9 D 5,000 31880diethyl ether (ethyl ether) 60-29-7 PTM 2,000 302861,4-difluorobenzene 540-36-3 PTM 2,000 30032diisopropyl ether (DIPE) 108-20-3 PTM 2,000 30627dimethachlor ESA sodium salt M 100 33203

CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriiccee1,2-dimethoxyethane 173201-80-4 DMSO 0.5mg/mL 36291N,N-dimethylacetamide 127-19-5 DMSO 5.45mg/mL 362922,5-dimethylbenzaldehyde-

2,4-DNPH 152477-96-8 ACN 100 33081dimethyldichlorosilane

(DMDCS) (20mL) 75-78-5 Neat 20mL 31840N,N-dimethylformamide 68-12-2 DMSO 4.4mg/mL 362932,6-dimethylphenol 576-26-1 M 1,000 314103,5-dinitroaniline 618-87-1 ACN 1,000 31661 enquire1,2-dinitrobenzene 528-29-0 M 1,000 31453 enquire1,3-dinitrobenzene 99-65-0 ACN 1,000 31662 enquire1,4-dinitrobenzene 100-25-4 ACN 2,000 33205 enquire2,4-dinitrophenol 51-28-5 M 1,000 312912,4-dinitrotoluene 121-14-2 ACN 1,000 31663 enquire2,6-dinitrotoluene 606-20-2 ACN 1,000 31664 enquire3,4-dinitrotoluene 610-39-9 EA 2,000 33901 enquire3,4-dinitrotoluene 610-39-9 M 1,000 31452 enquiredi-n-octyl phthalate 117-84-0 M 1,000 31426dinoseb 88-85-7 M 1,000 32251dinoseb methyl ether 6099-79-2 M 1,000 32252diolein (1,3-di[cis-octadecenoyl]

glycerol) 2465-32-9 pyridine 5,000 330221,4-dioxane 123-91-1 DMSO 1.9mg/mL 362941,4-dioxane 123-91-1 D 2,000 318531,4-dioxane 123-91-1 PTM 2,000 302871,4-dioxane-d8 17647-74-4 PTM 2,000 306141,2-diphenylhydrazine 122-66-7 M 1,000 31497diuron 330-54-1 ACN 200 32450ecgonine 5796-31-6 PTM 1,000 34017 enquireecgonine methyl ester 38969-40-3 PTM 1,000 34018 enquireEDDP perchlorate 66729-78-0 M 1,000 34069 enquireEGDN 628-96-6 M 1,000 31601 enquireendosulfan I 959-98-8 M 1,000 32221endosulfan II 33213-65-9 M 1,000 32222endosulfan sulfate 1031-07-8 M 1,000 32223endrin 72-20-8 M 1,000 32219endrin aldehyde 7421-93-4 M 1,000 32224endrin ketone 53494-70-5 M 1,000 32220ethanol 64-17-5 PTM 2,000 30288ethanol 64-17-5 W 10,000 304662-ethoxyethanol 110-80-5 DMSO 0.8mg/mL 36295ethylbenzene 100-41-4 DMSO 1.84mg/mL 36296ethylbenzene 100-41-4 PTM 2,000 30290ethylbenzene-d10 25837-05-2 PTM 2,000 30029ethylbenzene-d5 20302-26-5 PTM 2,000 30028ethyl-tert-butyl ether

(ETBE) 637-92-3 PTM 2,000 30628ethylenediamine 107-15-3 M 540 35222ethylene glycol 3775-85-7 DMSO 3.1mg/mL 36297ethylene oxide 75-21-8 DMSO 500 36005ethyl methacrylate 97-63-2 PTM 2,000 30289fenfluramine 16105-77-4 PTM 1,000 34023 enquirefentanyl 437-38-7 M 1,000 34082 enquirenor-fentanyl oxalate 1609-66-1 M 1,000 34083 enquire

also availableRestek offers the ChemService product line of neat pesticides and metabolites.

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CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriicceeflunitrazepam 1622-62-4 PTM 1,000 34049 enquirefluoranthene 206-44-0 M 1,000 31277fluorene 86-73-7 M 1,000 31278fluorobenzene 462-06-6 PTM 2,000 300302-fluorobiphenyl 321-60-8 D 2,000 310912-fluorobiphenyl 321-60-8 D 10,000 310961-fluoronaphthalene 321-38-0 D 2,000 310922-fluorophenol 367-12-4 D 2,000 31047flurazepam 1172-18-5 PTM 1,000 34050 enquireformaldehyde-DNPH 1081-15-8 ACN 500 31837formaldehyde-2,4-DNPH 1081-15-8 ACN 100 33082formaldehyde oxazoladine — T 2,000 33004formamide 75-12-7 DMSO 1.1mg/mL 36298fuel oil # 4 68476-31-3 D 5,000 31216fuel oil # 4 68476-31-3 D 50,000 31244fuel oil # 5 70892-11-4 D 5,000 31217fuel oil # 5 70892-11-4 D 50,000 31246fuel oil # 6 (5mL) 68553-00-4 D 50,000 31249fuel oil # 6 68553-00-4 D 5,000 31218fuel oil # 6 68553-00-4 D 50,000 31248DL-glutethimide 18389-24-7 PTM 1,000 34058 enquireglycerin 56-81-5 pyridine 500 33020glycolaldehyde-2,4-DNPH — ACN 100 33091glyphosate (5mL) 1071-83-6 W 1,000 32427glyphosate 1071-83-6 W 1,000 324261,6-HDIP 72375-27-0 DMSO 1,000 33002heptachlor 76-44-8 M 1,000 32228heptachlor epoxide (isomer B) 1024-57-3 M 1,000 322302,2',3,4,4',5,5'-heptachlorobiphenyl

(BZ #180) 35065-29-3 I 10 32288hexachlorobenzene 118-74-1 A 1,000 322312,2',3,4,4',5'-hexachlorobiphenyl

(BZ #138) 35065-28-2 I 10 322862,2',4,4',5,5'-hexachlorobiphenyl

(BZ #153) 35065-27-1 I 10 32287hexachloro-1,3-butadiene 87-68-3 M 1,000 31435hexachlorocyclopentadiene 77-47-4 M 1,000 32232hexachloroethane 67-72-1 M 1,000 31436hexachlorophene 70-30-4 D 2,000 31811hexaldehyde-2,4-DNPH 1527-97-5 ACN 100 33083hexane 8031-34-3 DMSO 1.45mg/mL 36299hexobarbital 56-29-1 PTM 1,000 34033 enquirehexyl 2-ethylhexyl phthalate 75673-16-4 H:A 1,000 33228HMX 2691-41-0 ACN 1,000 31665 enquirehydraulic oil 64741-89-5 D 50,000 31839hydrocodone 34195-34-1 PTM 1,000 34002 enquirehydromorphone 71-68-1 PTM 1,000 34063 enquireindeno(1,2,3-cd)pyrene 193-39-5 D 1,000 31279iodomethane 74-88-4 PTM 2,000 30292isobutyl alcohol 78-83-1 PTM 2,000 30293isobutyraldehyde-2,4-DNPH 2057-82-1 ACN 100 33084isopropylbenzene 98-82-8 PTM 2,000 30294isovaleraldehyde-2,4-DNPH 2256-01-1 ACN 100 33085jet fuel A (5mL) 64742-47-8 D 50,000 31243jet fuel A 64742-47-8 D 5,000 31215jet fuel A 64742-47-8 D 50,000 31242JP-4 military fuel 8008-20-6 D 5,000 31219JP-4 military fuel 8008-20-6 D 50,000 31250JP-4 military fuel 8008-20-6 PTM 50,000 30472

CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriicceeJP-5 military fuel (5mL) 8008-20-6 D 50,000 31253JP-5 military fuel 8008-20-6 D 5,000 31220JP-5 military fuel 8008-20-6 D 50,000 31252JP-8 military fuel 8008-20-6 D 5,000 31262JP-8 military fuel 8008-20-6 D 50,000 31254kerosene composite (5mL) 84742-81-0 D 50,000 31257kerosene composite 84742-81-0 D 5,000 31094kerosene composite 84742-81-0 D 50,000 31256kerosene: 25% weathered 84742-81-0 D 5,000 31230kerosene: 50% weathered 84742-81-0 D 5,000 31231kerosene: 75% weathered 84742-81-0 D 5,000 31232kerosene: unweathered 84742-81-0 D 5,000 31229LAMPA 40158-98-3 ACN 1,000 34075 enquirelevorphanol 5985-38-6 PTM 1,000 34003 enquirelorazepam 846-49-1 PTM 1,000 34051 enquireLSD 50-37-3 ACN 25 34089 enquireLSD 50-37-3 ACN 100 34088 enquireMCPA 97-74-6 M 1,000 32269MCPP 93-65-2 M 1,000 322713,4-MDA HCl 4764-17-4 M 1,000 34070 enquire3,4-MDEA HCl 82801-81-8 M 1,000 34072 enquire4,4'-MDIP 72375-24-7 DMSO 1,000 330033,4-MDMA HCl 42542-10-9 M 1,000 34071 enquiremeperidine 50-13-5 PTM 1,000 34004 enquiremephobarbital 115-38-8 PTM 1,000 34034 enquiremeprobamate 57-53-4 PTM 1,000 34059 enquiremethacrolein-2,4-DNPH 5077-73-6 ACN 100 33095methacrylonitrile 126-98-7 PTM 2,000 30297methadone 1095-90-5 PTM 1,000 34005 enquire(+)methamphetamine 51-57-0 PTM 1,000 34021 enquiremethanol 67-56-1 DMSO 15mg/mL 36401methanol 67-56-1 W 10,000 30467methaqualone 340-56-7 PTM 1,000 34064 enquiremethohexital 151-83-7 PTM 1,000 34035 enquiremethoxychlor 72-43-5 M 1,000 322332-methoxyethanol 109-86-4 DMSO 0.25mg/mL 364021-(methylamino)anthraquinone 82-38-3 D 100 31823methyl arachidate 1120-28-1 Neat 35056methyl arachidonate 2566-89-4 Neat 35060methyl behenate 929-77-1 Neat 35062methyl 2-bromopropionate 5445-17-0 MTBE 1,000 31654methyl tert-butyl ether (MTBE) 1634-04-4 PTM 2,000 30402methylbutylketone 591-78-6 DMSO 0.25mg/mL 36400methyl caprate 110-42-9 Neat 35041methyl caproate 106-70-7 Neat 35037methyl caprylate 111-11-5 Neat 35039methylcyclohexane 108-87-2 DMSO 5.9mg/mL 36403 enquiremethyl-2,3-dibromopropionate 1729-67-5 MTBE 1,000 316562-methyl-4,6-dinitrophenol 534-52-1 M 1,000 31292methyl eicosadienoate 2463-02-7 Neat 35058methyl eicosatrienoate 55682-88-7 Neat 35059methyl eicosenoate 2390-09-2 Neat 35057methyl erucate 1120-34-9 Neat 35063methyl heneicosanoate 6064-90-0 Neat 35061methyl heptadecanoate 1731-92-6 Neat 35050methyl heptanoate 106-73-0 Neat 35038


also availableRestek offers the ChemService product line of neat pesticides and metabolites.

Visit wwwwww..rreesstteekk..ccoomm//ppeessttiicciiddeess for more information.


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CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriicceemethyl laurate 111-82-0 Neat 35043methyl lignocerate 2442-49-1 Neat 35064methyl linoleate 112-63-0 Neat 35053methyl linolenate 301-00-8 Neat 35054methyl methacrylate 80-62-6 PTM 2,000 30299methyl myristate 124-10-7 Neat 35045methyl myristoleate 56219-06-8 Neat 350461-methylnaphthalene 90-12-0 M 1,000 312832-methylnaphthalene 91-57-6 D 1,000 31285methyl nervonate 2733-88-2 Neat 350652-methyl-4-nitroaniline 99-55-8 M 1,000 31612 enquiremethyl nonadecanoate 1731-94-8 Neat 35055methyl nonanoate 1731-84-6 Neat 35040methyl oleate 112-62-9 Neat 35052methyl palmitate 112-39-0 Neat 35048methyl palmitoleate 1120-25-8 Neat 35049methyl pentadecanoate 7162-64-1 Neat 350474-methyl-2-pentanone (MIBK) 108-10-1 PTM 5,000 304003-methylphenol 108-39-4 M 1,000 31403N-methylpyrrolidone 872-50-4 DMSO 2.65mg/mL 36405methyl stearate 112-61-8 Neat 35051methyl tridecanoate 1731-88-0 Neat 35044methyl undecanoate 1731-86-8 Neat 35042α-methylene-γ-butyrolactone

(AMGBL) 547-65-9 ACN 1,000 34079 enquiremethylene chloride

(dichloromethane) 75-09-2 DMSO 3mg/mL 36404methylene chloride

(dichloromethane) 75-09-2 PTM 2,000 30401methyprylon 125-64-4 PTM 1,000 34060 enquiremetolachlor 51218-45-2 M 100 33209metolachlor ESA sodium salt 171118-09-5 M 100 33200metolachlor OA 152019-73-3 M 100 33201metribuzin 21087-64-9 A 1,000 32436mineral spirits: 25% weathered 8030-30-6 D 5,000 31226mineral spirits: 50% weathered 8030-30-6 D 5,000 31227mineral spirits: 75% weathered 8030-30-6 D 5,000 31228mineral spirits: unweathered

(5mL) 8030-30-6 D 50,000 31261mineral spirits: unweathered 8030-30-6 D 5,000 31225mineral spirits: unweathered 8030-30-6 D 50,000 31260monolein (1-mono[cis-9-octadecenoyl]-

rac-glycerol) 111-03-5 pyridine 5,000 33021monopalmitin 524-44-9 pyridine 5,000 33026morphine 6211-15-0 PTM 1,000 34006 enquiremotor oil composite 64742-47-8 D 50,000 31464naphthalene 91-20-3 M 1,000 31280naphthalene-d8 1146-65-2 D 2,000 31043nicotine 54-11-5 M 1,000 34085 enquirenitrazepam 146-22-5 PTM 1,000 34053 enquirenitrobenzene 99-95-3 ACN 1,000 31657 enquirenitrobenzene-d5 4165-60-0 D 2,000 31044nitrobenzene-d5 4165-60-0 D 2,000 33904nitroglycerin 55-63-0 M 1,000 31498 enquirenitroguanidine 556-88-7 M 1,000 31602 enquire2-nitromesitylene 603-71-4 M 2,000 33902nitromethane 75-52-5 DMSO 0.25mg/mL 364064-nitrophenol 100-02-7 M 1,000 312961-nitropropane 108-03-2 D 250 352632-nitropropane 79-46-9 PTM 2,000 30403N-nitrosodimethylamine 62-75-9 M 1,000 31427N-nitrosodimethylamine-d6 17829-05-9 D 1,000 33910N-nitrosodiphenylamine 86-30-6 M 1,000 31429

CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriicceeN-nitroso-di-n-propylamine 621-64-7 M 1,000 31428N-nitrosodi-n-propylamine-d14 93951-96-3 D 1,000 339112-nitrotoluene 88-72-2 ACN 1,000 31659 enquire3-nitrotoluene 99-08-1 ACN 1,000 31660 enquire4-nitrotoluene 99-99-0 ACN 1,000 31658 enquirenonatriacontane (C39) (10mL) 7194-86-7 C 3,000 31877n-nonatriacontane (C39) 7194-86-7 C 3,000 31456n-octacosane (C28) 630-02-4 D 1,000 31672oxazepam 604-75-1 PTM 1,000 34054 enquireoxycodone 124-90-3 PTM 1,000 34007 enquireoxymorphone 76-41-5 PTM 1,000 34065 enquirepentachloroanisole 1825-21-4 M 1,000 322682,2',4,5,5'-pentachlorobiphenyl

(BZ #101) 37680-73-2 I 10 322852,3',4,4',5-pentachlorobiphenyl

(BZ #118) 31508-00-6 I 10 32293pentachloroethane 76-01-7 PTM 2,000 30404pentachloronitrobenzene 82-68-8 EA 100 32091pentachlorophenol 87-86-5 M 1,000 31297n-pentacontane (C50) 6596-40-3 T 10 31685pentacosane (C25) 629-99-2 D 10,000 31487pentafluorobenzene 363-72-4 PTM 2,000 30031pentafluorophenol 771-61-9 D 2,000 310482-pentanone 107-87-9 D 250 35261pentazocine 64024-15-3 PTM 1,000 34062 enquirepentobarbital 76-74-4 PTM 1,000 34036 enquireperfluorotributylamine (PFTBA) 311-89-7 Neat 1mL 30482perfluorotributylamine (PFTBA) 311-89-7 Neat 1g 33027PETN

(pentaerythritol tetranitrate) 78-11-5 M 1,000 31600 enquirephenanthrene 85-01-8 M 1,000 31281phenanthrene-d10 1517-22-2 D 2,000 31045phencyclidine 956-90-1 PTM 1,000 34027 enquirephendimetrazine 50-58-8 PTM 1,000 34025 enquirephenmetrazine 1707-14-8 PTM 1,000 34026 enquirephenobarbital 50-06-6 PTM 1,000 34037 enquirephenol 108-95-2 M 1,000 31298phenol-d6 13127-88-3 D 2,000 31049phentermine 1197-21-3 PTM 1,000 34024 enquirephenylpropanolamine HCl 154-41-6 M 1,000 34073 enquirepicloram 1918-02-1 M 1,000 32265picloram methyl ester 14143-55-6 M 1,000 32266picric acid 88-89-1 M 1,000 31499 enquirePolywax 500 9002-88-4 Neat 1g 36224Polywax 655 9002-88-4 Neat 1g 36225Polywax 850 9002-88-4 Neat 1g 36226Polywax 1000 9002-88-4 Neat 1g 36227prazepam 2955-38-6 PTM 1,000 34055 enquireprometryne 7287-19-6 A 1,000 32449propachlor 1918-16-7 M 1,000 322352-propanol 67-63-0 W 50,000 30473propazine 139-40-2 A 1,000 32448propionaldehyde-2,4-DNPH 725-00-8 ACN 100 33086propionitrile 107-12-0 PTM 2,000 30407propylene glycol dinitrate

(PGDN) 6423-43-4 M 1,000 31821 enquirepyrene 129-00-0 M 1,000 31282pyridine 85404-20-2 DMSO 1mg/mL 36407pyridine 110-86-1 PTM 2,000 30409pyridine-d5 7291-22-7 D 2,000 31046


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CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriicceeRDX 121-82-4 ACN 1,000 31666 enquiresecobarbital 29071-21-4 PTM 1,000 34038 enquiresimazine 122-34-9 A 1,000 32236stearyl stearate (10mL) 2778-96-3 Cy 2,000 31636stearyl stearate (10mL) 2778-96-3 H 2,000 31681stearyl stearate 2778-96-3 Neat 100mg 31860Stoddard solvent 8052-41-3 PTM 10,000 30487styrene 100-42-5 PTM 2,000 30410sulfolane 126-33-0 DMSO 0.8mg/mL 364132,4,5-T 93-76-5 M 200 322432,4,5-T methyl ester 1928-37-6 M 1,000 32244talbutal 115-44-6 PTM 1,000 34039 enquire2,4-TDIP 72375-21-4 DMSO 1,000 330012,6-TDIP 195625-39-9 DMSO 1,000 33000temazepam 896-50-4 PTM 1,000 34056 enquireterbuthylazine 5915-41-3 A 1,000 32447o-terphenyl 84-15-1 A 2,000 31066o-terphenyl 84-15-1 D 10,000 31097p-terphenyl 92-94-4 D 10,000 31095p-terphenyl-d14 1718-51-0 D 1,000 31828α-terpineol 98-55-5 D 2,000 339122,2',5,5'-tetrachlorobiphenyl

(BZ #52) 35693-99-3 I 10 322841,1,1,2-tetrachloroethane 630-20-6 PTM 2,000 304111,1,2,2-tetrachloroethane 79-34-5 PTM 2,000 30412tetrachloroethene 127-18-4 PTM 2,000 304132,3,4,6-tetrachlorophenol 58-90-2 M 1,000 314022,4,5,6-tetrachloro-m-xylene (5mL) 877-09-8 A 200 320282,4,5,6-tetrachloro-m-xylene 877-09-8 A 200 32027n-tetracontane (C40) 4181-95-7 Neat 100mg 31859tetrahydrofuran (THF) 109-99-9 DMSO 3.6mg/mL 36408tetrahydrofuran (THF) 109-99-9 PTM 2,000 30414tetralin 119-64-2 DMSO 0.5mg/mL 36409tetrapentyltin 3765-65-9 D 2,000 31475tetra-n-propyltin 2176-98-9 D 2,000 31474tetryl 479-45-8 ACN 1,000 31667 enquireΔ9-THC 1972-08-3 M 1,000 34067 enquire(±)11-nor-9-carboxy-Δ9-THC 104874-50-2 M 100 34068 enquirethebaine 115-37-7 PTM 1,000 34009 enquirethiamylal 337-47-3 PTM 1,000 34040 enquirethiopental 71-73-8 PTM 1,000 34041 enquireTinuvin P 2440-22-4 Ip 51.8 31629m-tolualdehyde-2,4-DNPH 2880-05-9 ACN 100 33088o-tolualdehyde-2,4-DNPH 1773-44-0 ACN 100 33087p-tolualdehyde-2,4-DNPH 2571-00-8 ACN 100 33089toluene 108-88-3 DMSO 4.45mg/mL 36410toluene 108-88-3 PTM 2,000 30415toluene-d8 2037-26-5 PTM 2,000 30224toxaphene 8001-35-2 H 1,000 32005toxaphene 8001-35-2 I 5,000 32071toxaphene 8001-35-2 M 2,000 320152,4,5-TP (Silvex) 93-72-1 M 1,000 322452,4,5-TP (Silvex) methyl ester 4841-20-7 M 1,000 32246transformer oil (PCB-free) 64742-53-6 Neat 50mL 32425transformer oil (PCB-free) 64742-53-6 Neat 5mL 32424n-triacontane-d62 (C30) 638-68-6 D 500 31816triazolam 28911-01-5 PTM 1,000 34057 enquire2,4,6-tribromophenol 118-79-6 M 1,000 31401tributylphosphate 126-73-8 A 1,000 32280tributyltin chloride 1461-22-9 D 2,000 31478

CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriicceetricaprin

(1,2,3-tricaprinoylglycerol) 621-71-6 pyridine 8,000 33025tricaprin (1,2,3-tricaprinoylglycerol)

(5mL) 621-71-6 pyridine 8,000 330331,2,3-trichlorobenzene 87-61-6 PTM 2,000 304161,2,4-trichlorobenzene 120-82-1 M 1,000 314392,4,4'-trichlorobiphenyl (BZ #28) 7012-37-5 I 10 322831,1,1-trichloroethane 74552-83-3 DMSO 50mg/mL 364111,1,1-trichloroethane 71-55-6 PTM 2,000 304181,1,2-trichloroethane 79-00-5 PTM 2,000 30419trichloroethene 79-01-6 DMSO 0.4mg/mL 36412trichloroethene 79-01-6 PTM 2,000 30420trichlorofluoromethane (CFC-11) 75-69-4 PTM 2,000 304212,4,5-trichlorophenol 95-95-4 A 1,000 320172,4,5-trichlorophenol 95-95-4 M 1,000 312992,4,6-trichlorophenol 88-06-2 M 1,000 314001,2,3-trichloropropane 96-18-4 MTBE 1,000 316481,2,3-trichloropropane 96-18-4 PTM 2,000 304291,1,2-trichlorotrifluoroethane

(CFC-113) 76-13-1 PTM 2,000 30462α,α,α-trifluorotoluene 98-08-8 PTM 2,000 30048α,α,α-trifluorotoluene 98-08-8 PTM 2,500 30068α,α,α-trifluorotoluene 98-08-8 PTM 10,000 30083trifluralin 1582-09-8 M 1,000 322381,2,4-trimethylbenzene 95-63-6 PTM 2,000 304221,3,5-trimethylbenzene 108-67-8 PTM 2,000 304231,2,4-trimethyl-5-nitrobenzene 610-91-3 M 2,000 339031,3,5-trinitrobenzene 99-35-4 ACN 1,000 31668 enquire2,4,6-trinitrotoluene 118-96-7 ACN 1,000 31669 enquiretri-n-propyltin chloride 995-25-5 D 2,000 31476triolein (1,2,3-Tri[cis-octadecenoyl]

glycerol) 122-32-7 pyridine 5,000 33023tripentyltin chloride 3342-67-4 D 2,000 31477triphenylphosphate 115-86-6 A 1,000 32281unleaded gasoline composite

(5mL) 8006-61-9 PTM 50,000 30206unleaded gasoline composite 8006-61-9 PTM 2,500 30081unleaded gasoline composite 8006-61-9 PTM 50,000 30205unleaded gasoline:

25% weathered 8006-61-9 PTM 5,000 30097unleaded gasoline:




unweathered 8006-61-9 PTM 5,000 30096used motor oil composite 64742-65-0 D 50,000 31465valeraldehyde-2,4-DNPH 2057-84-3 ACN 100 33090γ-valerolactone 108-29-2 ACN 1,000 34080 enquirevinyl acetate 108-05-4 PTM 2,000 30216vinyl chloride 75-01-4 PTM 2,000 30089vinyl chloride 75-01-4 PTM 2,500 30093m-xylene 108-38-3 DMSO 6.51mg/mL 36414m-xylene 108-38-3 PTM 2,000 30424o-xylene 95-47-6 DMSO 0.97mg/mL 36415o-xylene 95-47-6 PTM 2,000 30425p-xylene 106-42-3 DMSO 1.52mg/mL 36416p-xylene 106-42-3 PTM 2,000 30426

free dataAAvvaaiillaabbllee oonn OOuurr WWeebbssiittee:: LLoott CCeerrttiiffiiccaatteess,, DDaattaa PPaacckkss,, aanndd MMSSDDSSssFor complete information detailing manufacturing and testing for Restek inventoried reference standards, visit our website at wwwwww..rreesstteekk..ccoomm//ddaattaappaacckkss. To view certificates and/or an MSDS, enter the catalog number of the product in the Search feature. For a free data pack (Adobe® PDF file), enter the catalognumber and lot number of the product.


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ANALYTICAL

REFERENCE

MATERIALS

ENVIRONMENTALMATERIALS

500 Series Drinking Water Analyses . . . . . . . . . . . . . . . .407-419

600 Series Wastewater Analyses . . . . . . . . . . . . . . . . . . . .420-425

Method 418.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .426

Method 1311 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .426

Method 1664 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .426

Method 3500 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .426

8000 Series Solid Waste Analyses . . . . . . . . . . . . . . . . . . .427-441

Contract Lab Program . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .442-451

PCBs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .451-452

Organotins . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .452

Minnesota Dept. of Agriculture Pesticides . . . . . . . . . . . . . . .453

International Environmental Mixes . . . . . . . . . . . . . . . . .454-456

Underground Storage Tank Monitoring . . . . . . . . . . . .457-467

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Bottom: Don McCandless, Head Coach

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406-419_ARM_500series.qxp 11/20/2008 8:59 AM Page 406

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ANALYTICAL REFERENCE MATERIALS | ENVIRONMENTAL MATERIALS

500 Series Methods

UUSS EEPPAA MMeetthhoodd NNoo.. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. ..CCoommppoouunndd CCllaassss

501.1, 501.2, 501.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Trihalomethanes

502.1, 502.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatile Halogenated Organics

504.1 . . . . . . . . . . . . . . . . . . . . . . . .Ethylene Dibromide/Dibromochloropropane

505 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Organohalide Pesticides & PCBs

506 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Phthalate & Adipate Esters

507 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Nitrogen & Phosphorus Pesticides

508, 508.1, 508A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chlorinated Pesticides

515, 515.4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chlorinated Acid Herbicides

521 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Nitrosamines

524.1, 524.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatile Organics

525, 525.1, 525.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Semivolatile Organics

526 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Semivolatile Organics

UUSS EEPPAA MMeetthhoodd NNoo.. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. ..CCoommppoouunndd CCllaassss

527 . . . . . . . . . . . . . . . . . . . . . . . . . . . .Pesticides & Flame Retardants (GC/MS)

528 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Phenols

529 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Nitroaromatics & Nitramines

531.1, 531.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Carbamates

532 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Phenylurea Pesticides

535 . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chloroacetanilide Herbicide Degradates

547 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Glyphosate

549.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Paraquat/Diquat

551.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chlorinated Pesticides & Herbicides

552, 552.1, 552.2, 552.3 . . . . . . . . . . . . . . . . . . . .Haloacetic Acids and Dalapon

555 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chlorinated Acids

— . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Drinking Water Odor Standard

500 Series Methods - US EPA Safe Drinking Water Act (SDWA)

Method 501.1, 501.2, 501.3 (Trihalomethanes)

did you know?We have more than 2,000 pure, characterized, neat compounds in our inventory!If you do not see the EXACT mixture you need listed on any of these pages, contact us for a custom standard.

bromodichloromethanebromoform

chloroformdibromochloromethane

501 Trihalomethane Mix

200µg/mL each in P&T methanol, 1mL/ampulcat. # 30036 (ea.)

2,000µg/mL each in P&T methanol, 1mL/ampulcat. # 30211 (ea.)

benzenecarbon tetrachloride1,4-dichlorobenzene1,2-dichloroethane

1,1-dichloroethene1,1,1-trichloroethanetrichloroethenevinyl chloride

DW-VOC Mix #1 (8 components)



chlorobenzene1,2-dichlorobenzenecis-1,2-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropaneethylbenzene

styrenetetrachloroethenetoluenem-xyleneo-xylenep-xylene

DW-VOC Mix #2 (12 components)



methylene chloride1,2,4-trichlorobenzene

1,1,2-trichloroethaneDW-VOC Mix #3



also availableRRttxx®®--550022..22 GGCC CCoolluummnnssSee ppaaggee 9922 for details.

30036: 501 Trihalomethane Mix30037: DW-VOC Mix #130038: DW-VOC Mix #230209: DW-VOC Mix #3

Revised DW-VOC Kit (200μg/mL)

Contains 1mL each of these mixtures.cat. # 30210 (kit)

30211: 501 Trihalomethane Mix30219: DW-VOC Mix #130220: DW-VOC Mix #230235: DW-VOC Mix #3

DW-VOC Kit #2 (2,000μg/mL)


NEW!

NEW!

kit

kit


408 www.restek.com


500 Series MethodsMethod 502.1, 502.2 (Volatile Halogenated Organics)

benzenebromobenzenebromochloromethanebromodichloromethanebromoformbromomethane (methyl bromide)n-butylbenzenesec-butylbenzenetert-butylbenzenecarbon tetrachloridechlorobenzenechloroethane (ethyl chloride)chloroformchloromethane (methyl chloride)2-chlorotoluene4-chlorotoluenedibromochloromethane1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane (EDB)dibromomethane1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzenedichlorodifluoromethane (CFC-12)1,1-dichloroethane1,2-dichloroethane1,1-dichloroethenecis-1,2-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropane1,3-dichloropropane2,2-dichloropropane1,1-dichloropropenecis-1,3-dichloropropenetrans-1,3-dichloropropeneethylbenzenehexachloro-1,3-butadiene

(hexachlorobutadiene)isopropylbenzene (cumene)4-isopropyltoluene (p-cymene)

methylene chloride (dichloromethane)naphthalenen-propylbenzenestyrene1,1,1,2-tetrachloroethane1,1,2,2-tetrachloroethanetetrachloroethenetoluene1,2,3-trichlorobenzene1,2,4-trichlorobenzene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethenetrichlorofluoromethane (CFC-11)1,2,3-trichloropropane1,2,4-trimethylbenzene1,3,5-trimethylbenzenevinyl chloridem-xyleneo-xylenep-xylene

Volatiles MegaMix® with Gases(60 components)


1-chloro-2-fluorobenzene502.2 Internal Standard #1

2,000µg/mL in P&T methanol, 1mL/ampulcat. # 30040 (ea.)

2-bromo-1-chloropropane fluorobenzene502.2 Internal Standard Mix #2


1-bromo-2-chloroethane1-chloro-3-fluorobenzene

fluorobenzene

8021/502.2 Surrogate Mix #1


1-bromo-2-chloroethane4-bromochlorobenzene

1-chloro-3-fluorobenzenefluorobenzene



benzenebromobenzenebromochloromethanebromodichloromethanebromoformn-butylbenzenesec-butylbenzenetert-butylbenzenecarbon tetrachloridechlorobenzenechloroform2-chlorotoluene4-chlorotoluenedibromochloromethane1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethanedibromomethane1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,1-dichloroethane1,2-dichloroethane1,1-dichloroethenecis-1,2-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropane1,3-dichloropropane2,2-dichloropropane

1,1-dichloropropenecis-1,3-dichloropropenetrans-1,3-dichloropropeneethylbenzenehexachloro-1,3-butadiene

(hexachlorobutadiene)isopropylbenzene (cumene)4-isopropyltoluene (p-cymene)methylene chloride (dichloromethane)naphthalenen-propylbenzenestyrene1,1,1,2-tetrachloroethane1,1,2,2-tetrachloroethanetetrachloroethenetoluene1,2,3-trichlorobenzene1,2,4-trichlorobenzene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethene1,2,3-trichloropropane1,2,4-trimethylbenzene1,3,5-trimethylbenzenem-xyleneo-xylenep-xylene

502.2 MegaMix® (54 components)

Includes all target analytes except the six gases, which are available separately as 502.2 Calibration Mix #1.



bromomethanechloroethanechloromethane

dichlorodifluoromethane (CFC-12)trichlorofluoromethane (CFC-11)vinyl chloride

502.2 Calibration Mix #1 (gases)



bromodichloromethanebromoformcarbon tetrachloridechloroform1,1-dichloroethane1,1-dichloroethenetrans-1,2-dichloroethene

1,3-dichloropropane2,2-dichloropropanecis-1,3-dichloropropenetrans-1,3-dichloropropenemethylene chloride1,1,1-trichloroethanetrichloroethene

502.2 Calibration Mix #2 (14 components)


No data pack available.

Antifoam Agent for Purge & Trap Samples

Foam generated as purge gas passes through a sample can enter the analyticaltrap, and possibly into the GC column. Our silica-containing antifoam agent iseffective over a wide pH range, and will not conflict with chromatography oftarget analytes.

Neat, 1mL/ampulcat. # 31822 (ea.)


www.restek.com 409


500 Series Methods

bromochloromethanedibromochloromethane1,2-dibromo-3-chloropropane1,2-dibromoethanedibromomethane1,2-dichloroethanecis-1,2-dichloroethene

1,2-dichloropropane1,1-dichloropropene1,1,1,2-tetrachloroethane1,1,2,2-tetrachloroethanetetrachloroethene1,1,2-trichloroethane1,2,3-trichloropropane



benzenetert-butylbenzenechlorobenzeneisopropylbenzenen-propylbenzene

styrenetoluene1,3,5-trimethylbenzenem-xylene



bromobenzenen-butylbenzenesec-butylbenzene2-chlorotoluene1,3-dichlorobenzene

ethylbenzene1,2,4-trichlorobenzene1,2,4-trimethylbenzeneo-xylenep-xylene



4-chlorotoluene1,2-dichlorobenzene1,4-dichlorobenzenehexachlorobutadiene

4-isopropyltoluenenaphthalene1,2,3-trichlorobenzene



Method 502.1, 502.2 (Volatile Halogenated Organics),cont'd

30042: 502.2 Calibration Mix #130043: 502.2 Calibration Mix #230044: 502.2 Calibration Mix #330045: 502.2 Calibration Mix #430046: 502.2 Calibration Mix #530047: 502.2 Calibration Mix #6

502.2 VOA Calibration Kit #1 (2,000μg/mL)


30042: 502.2 Calibration Mix #130431: 502.2 MegaMix

502.2 VOA Calibration Kit #2 (2,000μg/mL)


30439: 502.2 Calibration Mix #130432: 502.2 MegaMix

502.2 VOA Calibration Kit #3 (200μg/mL)


Method 505 (Organohalide Pesticides & PCBs)

Method 504.1 (Ethylene Dibromide/Dibromochloropropane)

Method 506 (Phthalate & Adipate Esters)

1,2-dibromo-3-chloropropane1,2-dibromoethane

1,2,3-trichloropropane504.1 Calibration Mix


aldrinalachloratrazineγ-BHC (lindane)α-chlordaneγ-chlordanedieldrinendrin

heptachlorheptachlor epoxide (isomer B)hexachlorobenzenehexachlorocyclopentadienemethoxychlorcis-nonachlortrans-nonachlorsimazine

505 Organohalide Pesticide Mix (16 components)

200µg/mL each in methanol, 1mL/ampulcat. # 32024 (ea.)

Toxaphene Solutions

1,000µg/mL in hexane, 1mL/ampulcat. # 32005 (ea.)

2,000µg/mL in methanol, 1mL/ampulcat. # 32015 (ea.)

5,000µg/mL in isooctane, 1mL/ampulcat. # 32071 (ea.)

benzyl butyl phthalatebis(2-ethylhexyl)adipatebis(2-ethylhexyl)phthalatedi-n-butylphthalate

di-n-octyl phthalatediethylphthalatedimethylphthalate

506 Calibration Mix (7 components)

1,000µg/mL in isooctane, 1mL/ampulcat. # 31845 (ea.)

benzyl butyl phthalate 250µg/mLbis(2-ethylhexyl)adipate 1,200bis(2-ethylhexyl)phthalate 250di-n-butylphthalate 100

di-n-octyl phthalate 650diethylphthalate 100dimethylphthalate 100

506 Laboratory Performance Check Mix (7 components)

In P&T methanol, 1mL/ampulcat. # 31844 (ea.)


kit

kit

kit


410 www.restek.com


500 Series Methods

Method 507 (Nitrogen & Phosphorus Pesticides)

Method 508, 508.1, 508A (Chlorinated Pesticides)

alachlorametrynatratonatrazinebromacilbutachlorbutylatechlorprophamcyanazine (Bladex)cycloatediphenamidEPTCetridiazole (Terrazole)fenarimolfluridone (Sonar)hexazinone (Velpar)metolachlormetribuzinMGK-264

molinatenapropamide (Devrinol)norflurazonpebulateprometonprometrynepronamide (propyzamide)propachlorpropazinesimazinesimetryntebuthiuronterbacilterbutryntriadimefontricyclazole (Beam)trifluralinvernolate

Organonitrogen Pesticide Mix #1 (Rev), Method 525.2(37 components)

500µg/mL each in acetone, 1mL/ampulcat. # 33012 (ea.)

chlorpyrifos (Dursban)dichlorvos (DDVP)disulfoton sulfoneethoprop (ethoprophos)

methyl paraoxon (parathion methyl-O-analog)

mevinphos (phosdrin)stirofos (tetrachlorvinphos)

Organophosphorus Pesticide Mix #1 (Rev), Method 525.2(7 components)


carboxindiazinondisulfoton

fenamiphosmerphosterbufos

Method 525.2 Nitrogen/Phosphorus Pesticide Mix #2(6 components)

1,000µg/mL each in acetone, 1mL/ampulcat. # 32423 (ea.)

pentachloronitrobenzene508.1 Internal Standard

100µg/mL in ethyl acetate, 1mL/ampulcat. # 32091 (ea.)

4,4'-dibromobiphenyl508.1 Surrogate

500µg/mL in ethyl acetate, 1mL/ampulcat. # 32092 (ea.)

4,4'-DDT endrin508.1 GC Degradation Check Mix

100µg/mL each in ethyl acetate, 1mL/ampulcat. # 32093 (ea.)

Method 508, 508.1, 508A (Chlorinated Pesticides)cont'd

δ-BHC 0.4µg/mLchlorothalonil 0.5

chlorpyrifos 0.02DCPA (Dacthal) 0.5

508 Performance Check Mix

At concentrations listed in methyl tert-butyl ether, 1mL/ampulcat. # 32045 (ea.)

aldrinα-BHCβ-BHCδ-BHCγ-BHC (lindane)4,4'-DDD4,4'-DDE4,4'-DDTdieldrin

endosulfan Iendosulfan IIendosulfan sulfateendrinendrin aldehydeheptachlorheptachlor epoxide (isomer B)methoxychlor



chlorobenzilateα-chlordaneγ-chlordanechlornebDCPA (Dacthal)etridiazole

hexachlorobenzenecis-permethrin*trans-permethrin*propachlortrifluralin

*1,000µg/mL total permethrin. Exact content of each isomer listed on certificateof analysis.



alachloratrazinechlorthalonilcyanazine

hexachlorocyclopentadienemetolachlormetribuzinsimazine



4,4'-DDT 200µg/mLendrin 100µg/mL

Organochlorine Pesticide System Evaluation Mix

In methyl tert-butyl ether, 1mL/ampulcat. # 32417 (ea.)

Decachlorobiphenyl, 508A

200µg/mL in acetone, 1mL/ampulcat. # 32029 (ea.)


10µg/mL in isooctane, 1mL/ampulcat. # 32289 (ea.)

Toxaphene Solutions1,000µg/mL in hexane, 1mL/ampul

cat. # 32005 (ea.)2,000µg/mL in methanol, 1mL/ampul

cat. # 32015 (ea.) 5,000µg/mL in isooctane, 1mL/ampul

cat. # 32071 (ea.)

did you know?We have more than 2,000 pure, characterized, neat compounds in our inventory! Ifyou do not see the EXACT mixture you need listed on any of these pages, contactus for a custom standard.


www.restek.com 411


500 Series MethodsMethod 508, 508.1, 508A (Chlorinated Pesticides)cont'd

32045: 508 Performance Check Mix32091: 508.1 Internal Standard Mix32092: 508.1 Surrogate Mix32093: 508.1 GC Degradation Check Mix32094: 508.1 Calibration Mix #132095: 508.1 Calibration Mix #232096: 508.1 Calibration Mix #3

508.1 Pesticide Kit


Method 515, 515.4 (Chlorinated Acid Herbicides)

4,4'-dibromooctafluorobiphenylHerbicide Internal Standard

250µg/mL in hexane, 1mL/ampulcat. # 32053 (ea.)

2,000µg/mL in methyl tert-butyl ether, 1mL/ampulcat. # 31856 (ea.)

2,4-dichlorophenylacetic acid (DCAA)

Herbicide Surrogate

FFrreeee AAcciidd FFoorrmm::

200µg/mL in methanol, 1mL/ampulcat. # 32049 (ea.)

1,000µg/mL in acetone, 1mL/ampulcat. # 32439 (ea.)

2,4-dichlorophenyl acetic acid methyl ester (DCAA methyl ester)DDeerriivvaattiizzeedd FFoorrmm::


dinoseb methyl ether 4µg/mLDCAA methyl ester 5004,4'-dibromooctafluorobiphenyl 2503,5-dichlorobenzoic acid methyl ester 6004-nitroanisole 1,600

Herbicide Lab Performance Check Mix


2,4-D2,4-DB2,4,5-T2,4,5-TP

dicambadichlorpropdinoseb

Herbicide Mix #1 (7 components)



2,4-D methyl ester2,4-DB methyl ester2,4,5-T methyl ester2,4,5-TP methyl ester

dicamba methyl esterdichlorprop methyl esterdinoseb methyl ether

DDeerriivvaattiizzeedd FFoorrmm::

200µg/mL each in hexane, 1mL/ampulcat. # 32055 (ea.)

Method 515, 515.4 (Chlorinated Acid Herbicides)cont'd

dalapon

Herbicide Mix #2



dalapon methyl esterDDeerriivvaattiizzeedd FFoorrmm::


acifluorfenbentazonchlorambenDCPA diacid

3,5-dichlorobenzoic acid4-nitrophenolpentachlorophenolpicloram




acifluorfen methyl esterbentazon methyl esterchloramben methyl esterDCPA (Dacthal)

3,5-dichlorobenzoic acid methyl ester4-nitroanisolepentachloroanisolepicloram methyl ester



acifluorfen methyl ester 50µg/mLbentazon methyl ester 100chloramben methyl ester 50dalapon methyl ester 1002,4-D methyl ester 1002,4-DB methyl ester 100DCPA (Dacthal) 100dicamba methyl ester 503,5-dichlorobenzoic acid

methyl ester 50

dichlorprop methyl ester 100dinoseb methyl ether 100pentachloroanisole 10picloram methyl ester 50quinclorac methyl ester 502,4,5-T methyl ester 252,4,5-TP (Silvex) methyl ester 25

515.4 Methylated Chlorinated Acids Mix (16 components)


acifluorfen (Blazer) 50µg/mLbentazon 100chloramben 502,4-D 100dalapon 1002,4-DB 100DCPA diacid

(tetrachloroterephthalic acid) 50dicamba 50

3,5-dichlorobenzoic acid 50dichlorprop 100dinoseb 100pentachlorophenol 10picloram 50quinclorac 502,4,5-T 252,4,5-TP (Silvex) 25

515.4 Calibration Mix (16 components)

In acetone, 1mL/ampulcat. # 32443 (ea.)

also availableAdditional chlorinated acid herbicides mixes:

see Method 555, ppaaggee 441199..and Method 8321, ppaaggee 444400.

kit


412 www.restek.com


500 Series MethodsMethod 521 (Nitrosamines)

N-nitrosodiethylamineN-nitrosodimethylamineN-nitrosodi-n-butylamineN-nitrosodi-n-propylamine

N-nitrosomethylethylamineN-nitrosopiperidineN-nitrosopyrrolidine

Nitrosamine Calibration Mix, Method 521 (7 components)

1,000µg/mL each in methylene chloride, 1mL/ampulcat. # 31898 (ea.)

N-nitrosodimethylamine-d6N-Nitrosodimethylamine-d6

1,000µg/mL in methylene chloride, 1mL/ampulcat. # 33910 (ea.)

N-nitrosodi-n-propylamine-d14N-Nitrosodi-n-propylamine-d14


4-bromofluorobenzene1,2-dichlorobenzene-d4

fluorobenzene524 Internal Standard/Surrogate Mix


4-bromofluorobenzene α,α,α-trifluorotoluene

Surrogate Standard


1-bromo-4-fluorobenzene 1,2-dichlorobenzene-d4

524.2 Surrogate Standard


perfluorotributylamine (PFTBA)


PFTBA (MS Tuning Compound)


Neat, 1gcat. # 33027 (ea.)

Method 524.1, 524.2 (Volatile Organics)

benzenebromobenzenebromochloromethanebromodichloromethanebromoformbromomethane (methyl bromide)n-butylbenzenesec-butylbenzenetert-butylbenzenecarbon tetrachloridechlorobenzenechloroethane (ethyl chloride)chloroformchloromethane (methyl chloride)2-chlorotoluene4-chlorotoluenedibromochloromethane1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane (EDB)dibromomethane1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzenedichlorodifluoromethane (CFC-12)1,1-dichloroethane1,2-dichloroethane1,1-dichloroethenecis-1,2-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropane1,3-dichloropropane

2,2-dichloropropane1,1-dichloropropenecis-1,3-dichloropropenetrans-1,3-dichloropropeneethylbenzenehexachloro-1,3-butadiene

(hexachlorobutadiene)isopropylbenzene (cumene)4-isopropyltoluene (p-cymene)methylene chloride (dichloromethane)naphthalenen-propylbenzenestyrene1,1,1,2-tetrachloroethane1,1,2,2-tetrachloroethanetetrachloroethenetoluene1,2,3-trichlorobenzene1,2,4-trichlorobenzene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethenetrichlorofluoromethane (CFC-11)1,2,3-trichloropropane1,2,4-trimethylbenzene1,3,5-trimethylbenzenevinyl chloridem-xyleneo-xylenep-xylene

Volatiles MegaMix® with Gases (60 components)


FREEQuality assurance

data availableonline!

To view certificates and/or an MSDS, enterthe catalog number of the product in theSearch feature. For a free data pack (Adobe®

PDF file), enter the catalog number and lotnumber of the product.

www.restek.com/datapacks


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500 Series Methods


Method 524.1, 524.2 (Volatile Organics) cont'd

acetone2-butanone (MEK)1,1-dichloro-2-propanone

2-hexanone4-methyl-2-pentanone (MIBK)

Ketones Mix, 524.2 Rev. 4.1 (5 components)

5,000µg/mL each in 90% P&T methanol:10% water, 1mL/ampulcat. # 30602 (ea.)

diisopropyl ether (DIPE) 2,000µg/mLethyl-tert-butyl ether (ETBE) 2,000tert-amyl ethyl ether (TAEE) 2,000tert-amyl methyl ether (TAME) 2,000tert-butyl alcohol (TBA) 10,000

Oxygenates Standard


AAmmppuull 11::acetone2-butanone (MEK)2-hexanone

4-methyl-2-pentanone (MIBK)tetrahydrofuran

524 Calibration Mix #7 (12 components)Note: Due to compound interactions, this mixture is a two ampul set.

AAmmppuull 22::acrylonitrileallyl chlorideethyl methacrylatemethyl acrylate

methyl methacrylatenitrobenzenepentachloroethane


carbon disulfidechloroacetonitrile1-chlorobutanetrans-1,4-dichloro-2-butene1,1-dichloro-2-propanonediethyl ether

hexachloroethaneiodomethane (methyl iodide)methacrylonitrilemethyl tert-butyl ether2-nitropropanepropionitrile

524 Calibration Mix #8 (12 components)


acrylonitrileallyl chloridebenzenebromobenzenebromochloromethanebromodichloromethanebromoformn-butylbenzenesec-butylbenzenetert-butylbenzenecarbon disulfidecarbon tetrachloridechloroacetonitrilechlorobenzene1-chlorobutanechlorodibromomethane

(dibromochloromethane)chloroform2-chlorotoluene4-chlorotoluene1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane

(ethylene dibromide)dibromomethane1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzenetrans-1,4-dichloro-2-butene1,1-dichloroethane1,2-dichloroethane1,1-dichloroethenecis-1,2-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropane1,3-dichloropropane2,2-dichloropropane1,1-dichloropropenecis-1,3-dichloropropene

trans-1,3-dichloropropenediethyl ether (ethyl ether)ethylbenzeneethyl methacrylatehexachloro-1,3-butadienehexachloroethaneiodomethane (methyl iodide)isopropylbenzene (cumene)4-isopropyltoluene (p-cymene)methacrylonitrilemethyl acrylatemethyl tert-butyl ether (MTBE)methylene chloride (dichloromethane)methyl methacrylatenaphthalenenitrobenzene2-nitropropanepentachloroethanepropionitrile (ethylcyanide)n-propylbenzenestyrene1,1,1,2-tetrachloroethane1,1,2,2-tetrachloroethanetetrachloroethenetetrahydrofurantoluene1,2,3-trichlorobenzene1,2,4-trichlorobenzene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethene1,2,3-trichloropropane1,2,4-trimethylbenzene1,3,5-trimethylbenzenem-xyleneo-xylenep-xylene

Drinking Water VOA MegaMix®, 524.2 Rev. 4.1 (73 components)







30201: 524 Internal Standard/Surrogate Mix30042: 502.2 Calibration Mix #130043: 502.2 Calibration Mix #230044: 502.2 Calibration Mix #330045: 502.2 Calibration Mix #430046: 502.2 Calibration Mix #530047: 502.2 Calibration Mix #630202: 524 Calibration Mix #730203: 524 Calibration Mix #8

524 Rev. 4.0 Volatile Organics Kit (2,000μg/mL)


30042: 502.2 Calibration Mix #130431: 502.2 MegaMix30202: 524 Calibration Mix #730203: 524 Calibration Mix #830201: 524 Surrogate/Internal Standard Mix

Note: For a listing of additional individual VOA surrogate and internal standards,see page 423.

524 Rev. 4.0 VOA Kit #2 (2,000μg/mL)


also availableSSPPEE CCaarrttrriiddggeess aanndd DDiisskkssSee ppaaggeess 335566 aanndd 336611 for details.

kit

kit


414 www.restek.com


500 Series Methods

also availableSee ppaaggeess 440088--440099 for 502.2 MegaMix® and 502.2 calibration mixes.

aldrinα-BHCβ-BHCδ-BHCγ-BHC (lindane)α-chlordaneγ-chlordane4,4'-DDD4,4'-DDE4,4'-DDT

dieldrinendosulfan Iendosulfan IIendosulfan sulfateendrinendrin aldehydeendrin ketoneheptachlorheptachlor epoxide (isomer B)methoxychlor

Organochlorine Pesticide Mix AB # 3 (20 components)

2,000µg/mL each in hexane:toluene (1:1), 1mL/ampulcat. # 32415 (ea.)

carboxindiazinondisulfoton

fenamiphosmerphosterbufos

Method 525.2 Nitrogen/Phosphorus Pesticide Mix #2(6 components)


acenaphthene-d10chrysene-d12

phenanthrene-d10Method 525.2 Internal Standard Mix


2-nitro-m-xyleneperylene-d12

pyrene-d10triphenylphosphate

Method 525.2 Surrogate Standard Mix


2-chlorobiphenyl (BZ#1)2,3-dichlorobiphenyl (BZ#5)2,4,5-trichlorobiphenyl (BZ#29)2,2',4,4'-tetrachlorobiphenyl (BZ#47)2,2',3',4,6-pentachlorobiphenyl (BZ#98)2,2',4,4',5,6'-hexachlorobiphenyl (BZ#154)2,2',3,3',4,4',6-heptachlorobiphenyl (BZ#171)2,2',3,3',4,5',6,6'-octachlorobiphenyl (BZ#200)

Method 525.2 PCB Congener Mix (8 components)


Method 525, 525.1, 525.2 (Semivolatile Organics)

acetochloralachlor

metolachlorMethod 525.2 Herbicide Mix


CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeacetochlor M 100 33208alachlor M 100 33207metolachlor M 100 33209M=methanol

Method 525.2 Herbicide AnalytesVolume is 1mL/ampul. Concentration is µg/mL.

acenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(ghi)perylenebenzo(k)fluoranthenebenzylbutylphthalatebis(2-ethylhexyl)adipatebis(2-ethylhexyl)phthalatechrysenedibenzo(a,h)anthracenediethylphthalatedimethylphthalate

di-n-butylphthalate2,4-dinitrotoluene2,6-dinitrotoluenedi-n-octylphthalatefluoranthenefluorenehexachlorobenzenehexachlorocyclopentadieneindeno(1,2,3-cd)pyreneisophoronenaphthalenepentachlorophenol*phenanthrenepyrene

Method 525.2 Semivolatile Mix (revised) (28 components)

1,000µg/mL each in acetone, 1mL/ampul*cat. # 31899 (ea.)

*pentachlorophenol at 4,000µg/mL.

alachlorametrynatratonatrazinebromacilbutachlorbutylatechlorprophamcyanazine (Bladex)cycloatediphenamidEPTCetridiazole (Terrazole)fenarimolfluridone (Sonar)hexazinone (Velpar)metolachlormetribuzinMGK-264

molinatenapropamide (Devrinol)norflurazonpebulateprometonprometrynepronamide (propyzamide)propachlorpropazinesimazinesimetryntebuthiuronterbacilterbutryntriadimefontricyclazole (Beam)trifluralinvernolate

Organonitrogen Pesticide Mix #1 (Rev), Method 525.2(37 components)


chlorpyrifos (Dursban)dichlorvos (DDVP)disulfoton sulfoneethoprop (ethoprophos)

methyl paraoxon (parathion methyl-O-analog)

mevinphos (phosdrin)stirofos (tetrachlorvinphos)

Organophosphorus Pesticide Mix #1 (Rev), Method 525.2(7 components)


NEW!

NEW!

also availableTry our CLPesticides columns for these applications.

See ppaaggeess 8800--8822 for details.


www.restek.com 415


500 Series Methods

free dataAAvvaaiillaabbllee oonn OOuurr WWeebbssiittee:: LLoott CCeerrttiiffiiccaatteess,, DDaattaa PPaacckkss,, aanndd MMSSDDSSssFor complete information detailing manufacturing and testing for Restek inventoried reference standards, visit our website at wwwwww..rreesstteekk..ccoomm//ddaattaappaacckkss..To view certificates and/or an MSDS, enter the catalog number of the product in the Search feature. For a free data pack (Adobe® PDF file), enter the catalognumber and lot number of the product.



Foam generated as purge gas passes through a sample can enter the analyti-cal trap, and possibly into the GC column. Our silica-containing antifoam agentis effective over a wide pH range, and will not conflict with chromatography oftarget analytes.


chlorobenzilatechloronebchlorothalonilDCPA (Dacthal)

heptachlor epoxide (isomer A)trans-nonachlorcis-permethrintrans-permethrin

Organochlorine Pesticide Mix #2 (Rev), Method 525.2(8 components)


p-terphenyl-d14Method 525.2 Fortification Recovery Standard


4,4'-DDTDFTPP (decafluorotriphenylphosphine)endrin

Method 525.2 GC/MS Performance Check Mix


Method 526 (Semivolatile Organics)

Method 527 (Pesticides & Flame Retardants-GC/MS)

acetochlorcyanazinediazinon2,4-dichlorophenol1,2-diphenylhydrazinedisulfoton

fonofosnitrobenzeneprometonterbufos2,4,6-trichlorophenol

Semivolatile Calibration Mix, EPA 526 (11 components)



phenanthrene-d10

Internal Standard Mix, EPA 526


2-nitro-m-xylene triphenylphosphate

Surrogate Standard Mix, EPA 526


atrazinebifenthrinesbiol (Bioallethrin, S-cyclopentyl

isomer)bromacilesfenvalaratefenvalaratehexazinonekepone

mirexnitrofennorflurazonoxychlordaneprometrynepropazinethiobencarbvinclozolin

Pesticides Mix #1, Method 527 (16 components)


chloropyrifos (Dursban)dimethoatemalathion

parathionterbufos sulfone

Pesticides Mix #2, Method 527


1,3-dimethyl-2-nitrobenzeneperylene-d12

triphenylphosateSurrogate Standard, Method 527


2,2',4,4',5-pentabromodiphenyl ether (BDE-99)2,2',4,4',5,5'-hexabromobiphenyl2,2',4,4',5,5'-hexabromodiphenyl ether (BDE-153)2,2',4,4',6-pentabromodiphenyl ether (BDE-100)2,2',4,4'-tetrabromodiphenyl ether (BDE-47)

PBDE Mix

50µg/mL each in isooctane:ethyl acetate (4:1), 1mL/ampulcat. # 33098 (ea.)


phenanthrene-d10Internal Standard, Method 527


Method 525, 525.1, 525.2 (Semivolatile Organics)cont'd

2-nitro-m-xyleneperylene-d12

pyrene-d10triphenylphosphate

Method 525.2 Surrogate Standard Mix



phenanthrene-d10Method 525.2 Internal Standard Mix



416 www.restek.com


500 Series MethodsMethod 529 (Nitroaromatics & Nitramines)

did you know?We have more than 2,000 pure, characterized, neat compounds in our inventory! If you do not see the EXACT mixture you need listed on any of these pages, contact usfor a custom standard.

free dataAAvvaaiillaabbllee oonn OOuurr WWeebbssiittee:: LLoott CCeerrttiiffiiccaatteess,, DDaattaa PPaacckkss,, aanndd MMSSDDSSssFor complete information detailing manufacturing and testing for Restek inventoried reference standards, visit our website at wwwwww..rreesstteekk..ccoomm//ddaattaappaacckkss.To view certificates and/or an MSDS, enter the catalog number of the product in the Search feature. For a free data pack (Adobe® PDF file), enter the catalognumber and lot number of the product.

3,5-dinitroaniline1,3-dinitrobenzene2-amino-4,6-dinitrotoluene4-amino-2,6-dinitrotoluene2,4-dinitrotoluene2,6-dinitrotoluenenitrobenzene

2-nitrotoluene3-nitrotoluene4-nitrotolueneRDXtetryl1,3,5-trinitrobenzene2,4,6-trinitrotoluene

Nitroaromatics and Nitramine Explosives in Drinking Water(14 components)

1,000µg/mL each in acetonitrile, 1mL/ampulcat. # 33900 (ea.) enquire

3,4-dinitrotoluene529 Internal Standard Mix

2,000µg/mL in ethyl acetate, 1mL/ampulcat. # 33901 (ea.) enquire

2-nitromesitylene529 Surrogate Standard #1


1,2,4-trimethyl-5-nitrobenzene529 Surrogate Standard #2


nitrobenzene-d5529 Surrogate Standard #3


Method 528 (Phenols)

4-chloro-3-methylphenol2-chlorophenolo-cresol2,4-dichlorophenol2,4-dimethylphenol2,4-dinitrophenol

2-methyl-4,6-dinitrophenol2-nitrophenol4-nitrophenolpentachlorophenolphenol2,4,6-trichlorophenol

Phenol Calibration Mix, EPA 528 (12 components)


3-nitro-o-xylene 1,000µg/mL2,3,4,5-tetrachlorophenol 2,000

Internal Standard Mix, EPA 528

In methylene chloride, 1mL/ampulcat. # 31696 (ea.)

4-chloro-3-methylphenol 100µg/mL2-chlorophenol 100o-cresol 1002,4-dichlorophenol 1002,4-dimethylphenol 1002,4-dinitrophenol 500

2-methyl-4,6-dinitrophenol 5002-nitrophenol 1004-nitrophenol 500pentachlorophenol 500phenol 1002,4,6-trichlorophenol 100

Phenols Fortification Mix, EPA 528 (12 components)

In methanol, 1mL/ampulcat. # 31695 (ea.)

Surrogate Standard Mix, EPA 528

2-chlorophenol-d4 1,000µg/mL2,4-dimethylphenol-3,5,6-d3 1,0002,4,6-tribromophenol 2,000



www.restek.com 417


500 Series MethodsMethod 531.1, 531.2 (Carbamates)

Method 532 (Phenylurea Pesticides)

also availableSee the LC Applications section forcarbamate pesticides chromatogramsppaaggee 550077.

4-bromo-3,5-dimethylphenyl-N-methylcarbamate (BDMC)Internal Standard


aldicarb sulfoxide 100µg/mLBDMC 10

3-hydroxycarbofuran 2methiocarb 20

531.1 Performance Check Mix


aldicarbaldicarb sulfonealdicarb sulfoxidecarbaryl (Sevin)carbofuran

3-hydroxycarbofuranmethiocarbmethomyloxamylpropoxur (Baygon)

531.1 Carbamate Pesticide Calibration Mixture (10 components)


aldicarbaldicarb sulfonealdicarb sulfoxidecarbaryl (Sevin)carbofuran3-hydroxycarbofuran

methiocarbmethomyl1-naphtholoxamylpropoxur (Baygon)

531.2 Carbamate Pesticide Calibration Mixture (11 components)

100µg/mL in acetonitrile, 1mL/ampulcat. # 32435 (ea.)

carbazole monuronPhenylurea Surrogate Mixture

500µg/mL each in methanol:acetonitrile (50:50), 1mL/ampulcat. # 32433 (ea.)

diflubenzurondiuronfluometuronlinuron

propanilsidurontebuthiuronthidiazuron

Phenylurea Pesticide Mixture (8 components)

200µg/mL each in acetonitrile:acetone (90:10), 1mL/ampulcat. # 32434 (ea.)

Method 535 (Chloroacetanilide Herbicide Degradates)

butachlor ESA sodium saltMethod 535 Internal Standard


dimethachlor ESA sodium saltMethod 535 Surrogate Standard


CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeacetochlor ESA sodium salt M 100 33092acetochlor OA M 100 33094alachlor ESA sodium salt M 100 33096alachlor OA M 100 33099metolachlor ESA sodium salt M 100 33200metolachlor OA M 100 33201

M=methanol

Method 535 Individual Compounds

Volume is 1mL/ampul. Concentration is µg/mL.

Method 547 (Glyphosate)

Method 549.2 (Paraquat/Diquat)

glyphosateGlyphosate Standard

1,000µg/mL in DI water, 1mL/ampulcat. # 32426 (ea.)

1,000µg/mL in DI water, 5mL/ampulcat. # 32427 (ea.)

aminomethyl phosphonic acid (AMPA)AMPA (glyphosate metabolite)

100µg/mL in DI water, 1mL/ampulcat. # 32428 (ea.)

diquat dibromide paraquat dichlorideParaquat & Diquat Calibration Mix

1,000µg/mL each in water, 1mL/ampulcat. # 32437 (ea.)

Ultra Quat Reagent Solution

Use with Ultra Quat HPLC column. Dilute to 1 liter water, per instructions.In water, 20mL/bottle

cat. # 32441 (ea.)

NEW!

NEW!

NEW!


418 www.restek.com


500 Series Methods

Methods 552, 552.1, 552.2, 552.3 (Haloacetic Acidsand Dalapon)

Method 551.1 (Chlorinated Pesticides & Herbicides) Method 551.1 (Chlorinated Pesticides & Herbicides)cont'd


1-bromo-4-fluorobenzene551.1 Internal Standard


decafluorobiphenyl551.1 Surrogate Standard


alachloratrazinebromacilcyanazine (Bladex)endrinendrin aldehydeendrin ketoneγ-BHC (lindane)

heptachlorheptachlor epoxide (isomer B)hexachlorobenzenehexachlorocyclopentadienemethoxychlormetolachlorsimazinetrifluralin

Method 551.1 Pesticide/Herbicide Mix (16 components)


alachlor 83µg/mLγ-BHC (lindane) 0.2bromacil 83bromodichloromethane 30

endrin 30hexachlorocyclopentadiene 20trichloroethylene 30

Method 551.1 MTBE Lab Performance Check Mix(7 components)


bromochloroacetonitrilebromodichloromethanebromoformcarbon tetrachloridechloroformchloropicrindibromoacetonitriledibromochloromethane1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane (EDB)

dichloroacetonitrile1,1-dichloro-2-propanonetetrachloroethylenetrichloroacetonitrile1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethylene1,2,3-trichloropropane1,1,1-trichloro-2-propanone

Disinfection By-Product and Chlorinated Solvents Mix(19 components)


chloral hydrateChloral Hydrate

1,000µg/mL in acetonitrile, 1mL/ampulcat. # 30609 (ea.)

bromochloroacetonitrilechloropicrindibromoacetonitriledichloroacetonitrile

1,1-dichloro-2-propanonetrichloroacetonitrile1,1,1-trichloro-2-propanone

Disinfection By-Product Mix (7 components)


alachlor 83µg/mLγ-BHC 0.2bromacil 83bromodichloromethane 30

endrin 30hexachlorocyclopentadiene 20trichloroethylene 30

Laboratory Performance Check Solution/ Pentane Extract(7 components)

In pentane, 1mL/ampulcat. # 32442 (ea.)

bromochloroacetic acidbromodichloroacetic acidchlorodibromoacetic aciddibromoacetic aciddichloroacetic acid

monobromoacetic acidmonochloroacetic acidtribromoacetic acidtrichloroacetic acid

Haloacetic Acid Mix (9 components)

1,000µg/mL each in methyl tert-butyl ether, 1mL/ampulcat. # 31896 (ea.)

methyl bromochloroacetatemethyl bromodichloroacetatemethyl chlorodibromoacetatemethyl dibromoacetatemethyl dichloroacetate

methyl monobromoacetatemethyl monochloroacetatemethyl tribromoacetatemethyl trichloroacetate

Haloacetic Acid Methyl Ester Mix (9 components)


bromochloroacetic aciddibromoacetic aciddichloroacetic acid

monobromoacetic acidmonochloroacetic acidtrichloroacetic acid

Haloacetic Acid Mix #1 (6 components)


methyl bromochloroacetatemethyl dibromoacetatemethyl dichloroacetate

methyl monobromoacetatemethyl monochloroacetatemethyl trichloroacetate

Haloacetic Acid Methyl Ester Mix #1 (6 components)



www.restek.com 419


500 Series MethodsMethod 555 (Chlorinated Acids)


Methods 552, 552.1, 552.2, 552.3 (Haloacetic Acidsand Dalapon) cont'd

Drinking Water Odor Standard

bromochloroacetic acid 400µg/mLbromodichloroacetic acid 400chlorodibromoacetic acid 1,000dibromoacetic acid 200dichloroacetic acid 600

monobromoacetic acid 400monochloroacetic acid 600tribromoacetic acid 2,000trichloroacetic acid 200

Haloacetic Acid Mix #2 (9 components)


methyl bromochloroacetate 400µg/mL

methyl bromodichloroacetate 400methyl chlorodibromoacetate 1,000methyl dibromoacetate 200

methyl dichloroacetate 600methyl monobromoacetate 400methyl monochloroacetate 600methyl tribromoacetate 2,000methyl trichloroacetate 200

Haloacetic Acid Methyl Ester Mix #2 (9 components)


dalaponDalapon (2,2-dichloropropionic acid)




dalapon methyl esterDalapon Methyl Ester



acifluorfen (Blazer)bentazonchloramben2,4-D

dicambadichlorproppicloram2,4,5-TP (Silvex)

Chlorinated Acids by HPLC, Mix A (8 components)

1,000µg/mL each in acetonitrile, 1mL/ampulcat. # 32431 (ea.)

2,4-DB3,5-dichlorobenzoic aciddinosebMCPA

MCPP (mecoprop)4-nitrophenolpentachlorophenol2,4,5-T

Chlorinated Acids by HPLC, Mix B (8 components)


2,4-dichlorophenoxyacetic acid (2,4-D)2,4,5-TP (Silvex)

Chlorinated Acid Herbicide Mix


(+/-)-geosmin 2-methylisoborneol

Unpleasant odor in drinking water is associated with the growthand decay of microorganisms. The threshold value for thesecompounds is low (10ppt) and purge and trap analyses usuallyare used to quantify them.

100µg/mL in P&T methanol, 1mL/ampulcat. # 30608 (ea.)

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeIInntteerrnnaall SSttaannddaarrdd::1,2,3-trichloropropane MTBE 1,000 31648

SSuurrrrooggaatteess ffoorr MMeetthhoodd 555522,, 555522..11::2,3-dichloropropionic acid MTBE 1,000 316503,5-dichlorobenzoic acid MTBE 1,000 316523,5-dichlorobenzoic acid methyl ester MTBE 1,000 316492,3-dichloropropionic acid methyl ester MTBE 1,000 31651

SSuurrrrooggaatteess ffoorr MMeetthhoodd 555522..22::2-bromopropionic acid MTBE 1,000 316532,3-dibromopropionic acid MTBE 1,000 31655methyl 2-bromopropionate MTBE 1,000 31654methyl-2,3-dibromopropionate MTBE 1,000 31656

SSuurrrrooggaatteess ffoorr MMeetthhoodd 555522..33::2-bromobutanoic acid MTBE 2,000 318812-bromobutyrate MTBE 2,000 31882

MTBE = methyl tert-butyl ether

Internal Standards and Surrogates


Get More!Environmental Articles Online

www.restek.com/environmental


420 www.restek.com


600 Series Methods

UUSS EEPPAA MMeetthhoodd NNoo.. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. ..CCoommppoouunndd CCllaassss

601 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Purgeable Hydrocarbons

602 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Purgeable Aromatics

603 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Acrolein/Acrylonitrile

604 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Phenols

605 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Benzidine/3,3'-Dichlorobenzidine

606 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Phthalate Esters

607 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Nitrosamines

608 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Organochlorine Pesticides and PCBs


609 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Nitroaromatics/Isophorone

610 . . . . . . . . . . . . . . . . . . . . . . . . . . .Polycyclic Aromatic Hydrocarbons (PAHs)

611 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Haloethers

612 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chlorinated Hydrocarbons

615 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chlorinated Acid Herbicides

624 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Purgeable Halocarbons

625 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Semivolatiles

600 Series Methods - US EPA Clean Water Act (CWA)

Method 602 (Purgeable Aromatics)

Method 603 (Acrolein/Acrylonitrile)


Method 606 (Phthalate Esters)

Method 605 (Benzidine/3,3’-Dichlorobenzidine)

benzenechlorobenzene1,2-dichlorobenzene1,3-dichlorobenzene

1,4-dichlorobenzeneethylbenzenetoluene

602 Purgeable Aromatics Calibration Mix (7 components)


acrolein acrylonitrileAcrolein/Acrylonitrile

2,000µg/mL each in DI water, 1mL/ampulcat. # 30600 (ea.)

Acrolein10,000µg/mL in P&T methanol, 1mL/ampul

cat. # 30499 (ea.) 10,000µg/mL in water, 1mL/ampul

cat. # 30478 (ea.)

Acrylonitrile2,000µg/mL in P&T methanol, 1mL/ampul

cat. # 30246 (ea.)

4-chloro-3-methylphenol2-chlorophenol2,4-dichlorophenol2,4-dimethylphenol2,4-dinitrophenol2-methyl-4,6-dinitrophenol

2-nitrophenol4-nitrophenolpentachlorophenolphenol2,4,6-trichlorophenol

604 Phenols Calibration Mix (11 components)

2,000µg/mL each in methanol, 1mL/ampulcat. # 31029 (ea.)

bis(2-ethylhexyl)phthalatebutyl benzyl phthalatediethyl phthalate

dimethyl phthalatedi-n-butyl phthalatedi-n-octyl phthalate

606 Phthalate Esters Calibration Mix


benzidine 3,3'-dichlorobenzidine605 Benzidines Calibration Mix




Method 601 (Purgeable Hydrocarbons)

bromodichloromethanebromoformcarbon tetrachloridechlorobenzene2-chloroethyl vinyl etherchloroformdibromochloromethane1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,1-dichloroethane1,2-dichloroethane

1,1-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropanecis-1,3-dichloropropenetrans-1,3-dichloropropenemethylene chloride1,1,2,2-tetrachloroethanetetrachloroethene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethene

VOA Purgeable Halocarbon Mix #1 (23 components)



www.restek.com 421


600 Series MethodsMethod 610 (Polycyclic Aromatic Hydrocarbons[PAHs])

Method 609 (Nitroaromatics/Isophorone)

Method 608 (Organochlorine Pesticides & PCBs)

aldrinα-BHCβ-BHCδ-BHCγ-BHC (lindane)4,4'-DDD4,4'-DDE4,4'-DDT

dieldrinendosulfan Iendosulfan IIendosulfan sulfateendrinendrin aldehydeheptachlorheptachlor epoxide (isomer B)

608 Calibration Mix (16 components)

200µg/mL each in hexane:toluene (1:1), 1mL/ampulcat. # 32022 (ea.)




2,4-dinitrotolueneisophorone

2,6-dinitrotoluenenitrobenzene

609 Nitroaromatics & Isophorone Calibration Mix

2,000µg/mL each in hexane, 1mL/ampulcat. # 31033 (ea.)

acenaphtheneacenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(k)fluoranthenebenzo(ghi)perylene

chrysenedibenzo(a,h)anthracenefluoranthenefluoreneindeno(1,2,3-cd)pyrenenaphthalenephenanthrenepyrene

SV Calibration Mix #5 / 610 PAH Mix (16 components)


Method 607 (Nitrosamines)

N-nitrosodimethylamineN-nitroso-di-n-propylamine

N-nitrosodiphenylamine607 Nitrosamines Calibration Mix



acenaphthene 1,000µg/mLacenaphthylene 1,000anthracene 1,000benzo(a)anthracene 500benzo(a)pyrene 500benzo(b)fluoranthene 500benzo(k)fluoranthene 500benzo(ghi)perylene 500

chrysene 500dibenzo(a,h)anthracene 500fluoranthene 500fluorene 1,000indeno(1,2,3-cd)pyrene 500naphthalene 1,000phenanthrene 500pyrene 500

610 PAH Calibration Mix A (16 components)

For HPLC/fluorescence detection.


acenaphthene 1,000µg/mLacenaphthylene 2,000anthracene 100benzo(a)anthracene 100benzo(a)pyrene 100benzo(b)fluoranthene 200benzo(k)fluoranthene 100benzo(ghi)perylene 200

chrysene 100dibenzo(a,h)anthracene 200fluoranthene 200fluorene 200indeno(1,2,3-cd)pyrene 100naphthalene 1,000phenanthrene 100pyrene 100

610 PAH Calibration Mix B (16 components)

For HPLC/UV detection.

In methylene chloride:methanol (1:1), 1mL/ampulcat. # 31455 (ea.)

32022: 608 Calibration Mix32006: Aroclor 101632007: Aroclor 122132008: Aroclor 123232009: Aroclor 124232010: Aroclor 124832011: Aroclor 125432012: Aroclor 126032005: toxaphene32021: chlordane (technical)

Please see page 425 for individual Aroclor, toxaphene, and chlordane information.

608 Complete Kit


Method 612 (Chlorinated Hydrocarbons)

2-chloronaphthalene1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzenehexachlorobenzene

hexachlorobutadienehexachlorocyclopentadienehexachloroethane1,2,4-trichlorobenzene

612 Chlorinated Hydrocarbons Calibration Mix (9 components)

2,000µg/mL each in isooctane, 1mL/ampulcat. # 31035 (ea.)

bis(2-chloroethoxy)methanebis(2-chloroethyl)etherbis(2-chloroisopropyl)ether

4-bromophenyl phenyl ether4-chlorophenyl phenyl ether

611 Haloethers Calibration Mix


Method 611 (Haloethers)

kit


422 www.restek.com


600 Series Methods


see Method 555, ppaaggee 441199and Method 8321, ppaaggee 444400

benzenebromodichloromethanebromoformcarbon tetrachloridechlorobenzene2-chloroethyl vinyl etherchloroformdibromochloromethane1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,1-dichloroethane1,2-dichloroethane

1,1-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropanecis-1,3-dichloropropenetrans-1,3-dichloropropeneethylbenzenemethylene chloride1,1,2,2-tetrachloroethanetetrachloroethenetoluene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethene

Volatiles MegaMix®, EPA Method 624 (26 components)


bromochloromethane2-bromo-1-chloropropane

1,4-dichlorobutane624 Internal Standard Mix


4-bromofluorobenzenefluorobenzene

pentafluorobenzene624 Surrogate Standard Mix


4-bromofluorobenzene α,α,α-trifluorotolueneSurrogate Standard



trichlorofluoromethane (CFC-11)vinyl chloride

624 Calibration Mix #1 (gases)


benzenecarbon tetrachloridechlorobenzene2-chloroethyl vinyl etherdibromochloromethane1,1-dichloroethane

1,1-dichloroethene1,2-dichloropropanemethylene chloridetetrachloroethene1,1,2-trichloroethanetrichloroethene



bromodichloromethanebromoformchloroform1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,2-dichloroethane

trans-1,2-dichloroethenecis-1,3-dichloropropenetrans-1,3-dichloropropeneethylbenzene1,1,2,2-tetrachloroethanetoluene1,1,1-trichloroethane




Herbicide Surrogate






Method 615 (Chlorinated Acid Herbicides)

2,4-D2,4-DB2,4,5-T2,4,5-TP









dalapon

Herbicide Mix #2





MCPA MCPP

Herbicide Mix #3



MCPA methyl ester MCPP methyl esterDDeerriivvaattiizzeedd FFoorrmm::


Method 624 (Purgeable Halocarbons)


www.restek.com 423


600 Series Methods

EPA Method 624 on an Rtx®-VMS column.

Method 624 (Purgeable Halocarbons) cont'd

30020: 624 Calibration Mix #130021: 624 Calibration Mix #230022: 624 Calibration Mix #330023: 624 Internal Standard Mix30243: 624 Surrogate Standard Mix

624 Complete Kit


30020: 624 Calibration Mix #130021: 624 Calibration Mix #230022: 624 Calibration Mix #330023: 624 Internal Standard Mix

624 Kit


Individual VOA Surrogate and Internal Standardsfor EPA Methods

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceebenzene-d6 PTM 2,000 300252-bromochlorobenzene PTM 2,000 302284-bromochlorobenzene PTM 2,000 30230bromochloromethane PTM 2,000 302252-bromo-1-chloropropane PTM 2,000 302264-bromofluorobenzene PTM 2,000 30026chlorobenzene-d5 PTM 2,000 302231-chloro-2-fluorobenzene PTM 2,000 300401,2-dichlorobenzene-d4 PTM 2,000 300491,4-dichlorobutane PTM 2,000 302271,2-dichloroethane-d4 PTM 2,000 300271,4-difluorobenzene PTM 2,000 30032ethylbenzene-d5 PTM 2,000 30028ethylbenzene-d10 PTM 2,000 30029fluorobenzene PTM 2,000 30030pentafluorobenzene PTM 2,000 30031toluene-d8 PTM 2,000 30224α,α,α-trifluorotoluene PTM 2,000 30048

PTM = Purge & trap grade methanol


Our Rtx®-VMS capillary GC column

is optimized for EPA Method 624!

See ppaaggee 9900 for more information.1. chloromethane2. vinyl chloride3. bromomethane4. chloroethane5. trichlorofluoromethane6. 1,1-dichloroethene7. methylene chloride8. trans-1,2-dichloroethene9. 1,1-dichloroethane

10. bromochloromethane11. chloroform12. carbon tetrachloride13. 1,1,1-trichloroethane14. benzene15. pentafluorobenzene16. 1,2-dichloroethane17. fluorobenzene18. trichloroethene19. 1,2-dichloropropane

20. bromodichloromethane21. 2-chloroethyl vinyl ether22. cis-1,3-dichloropropene23. toluene24. tetrachloroethene25. trans-1,3-dichloropropene26. 2-bromo-1-chloropropane27. 1,1,2-trichloroethane28. dibromochloromethane29. ethylbenzene30. chlorobenzene31. bromoform32. 4-bromofluorobenzene33. 1,4-dichlorobutane34. 1,1,2,2-tetrachloroethane35. 1,3-dichlorobenzene36. 1,4-dichlorobenzene37. 1,2-dichlorobenzene

1.00 2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00

Column: Rtx®-VMS, 30m, 0.25mm ID, 1.40µm (cat#19915)Conc.: 20 ppb in 5mL of RO waterConcentrator: Tekmar LSC-3000 Purge and TrapTrap: Vocarb 3000 (type K)Purge: 11 min. @ 40mL/min. (ambient temperature)Dry purge: 1 min. @ 40mL/min. (MCS bypassed using

Silcosteel® tubing)Desorb preheat: 245°CDesorb: 250°C for 2 min., Flow 10mL/min.Bake: 260°C for 8 min.

GC Interface: 1:10 split at injection port. 1mm ID liner.GC: Agilent 6890 Oven temp.: 40°C (hold 4 min.) to 95°C @ 24°C/min. (hold 3 min.), to

210°C @ 40°C/min. (hold 6 min.)Carrier gas: helium @ ~1mL/min. constant flow

Adjust dichlorodifluoromethane to a retention time of 2.54 min. @ 40°C

Detector: Agilent 5973 MSDScan range: 25-300amu

1

23

4

5

6

78

910

1112

13

14

15

16

17 18

19

20

21 22

23 24,25

27

2628

29 30

31

32

33,34 3536

37

GC_EV00425

kit

kit


424 www.restek.com


600 Series Methods


Foam generated as purge gas passes through a sample can enter the analyticaltrap, and possibly into the GC column. Our silica-containing antifoam agent is effective over a wide pH range, and will not conflict with chromatography of targetanalytes.


Method 625 (Semivolatiles)

acenaphtheneacenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(ghi)perylenebenzo(k)fluoranthenebenzyl butyl phthalatebis(2-chloroethoxy)methanebis(2-chloroethyl)etherbis(2-chloroisopropyl)etherbis(2-ethylhexyl)phthalate4-bromophenyl phenyl ether4-chloro-3-methylphenol2-chloronaphthalene2-chlorophenol4-chlorophenyl phenyl etherchrysenedibenzo(a,h)anthracene1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene2,4-dichlorophenoldiethylphthalate2,4-dimethylphenoldimethylphthalate

di-n-butylphthalate4,6-dinitro-2-methylphenol2,4-dinitrophenol2,4-dinitrotoluene2,6-dinitrotoluenedi-n-octylphthalatediphenylamine*fluoranthenefluorenehexachlorobenzenehexachloro-1,3-butadienehexachlorocyclopentadiene*hexachloroethaneindeno(1,2,3-cd)pyreneisophoronenaphthalenenitrobenzene2-nitrophenol4-nitrophenolN-nitrosodimethylamine*N-nitroso-di-n-propylaminepentachlorophenolphenanthrenephenolpyrene1,2,4-trichlorobenzene2,4,6-trichlorophenol

Semivolatiles MegaMix®, EPA Method 625 (54 components)


*Listed as an “additional compound” in Method 625 (listed compound N-nitrosodiphenylamine decomposes to MegaMix component diphenylamine). Thesix other “additional compounds” are components in other Restek referencemixes used for Method 625: benzidine is included in cat.# 31030 (page 420); β-BHC, δ-BHC, endosulfan I, endosulfan II, endrin are in cat.# 32291 (page 428)and cat.# 32415 (page 429).

also availableTry Restek’s Rxi®-5Sil MS columns for EPA Methods625 and 8270.

Guaranteed for low GC/MS bleed, excellent phenolresponse, and the resolution needed to quantify critical pairs and structural isomers.

See ppaaggee 7788 for more information.


acenaphthene-d10chrysene-d121,4-dichlorobenzene-d4

naphthalene-d8perylene-d12phenanthrene-d10

SV Internal Standard Mix



CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeanthracene-d10 D 2,000 31037decafluorobiphenyl D 2,000 31041decafluorobiphenyl A 1,000 318554,4'-dibromobiphenyl D 2,000 310394,4'-dibromooctafluorobiphenyl D 2,000 310402-fluorobiphenyl D 2,000 310911-fluoronaphthalene D 2,000 310922-fluorophenol D 2,000 31047naphthalene-d8 D 2,000 31043nitrobenzene-d5 D 2,000 31044pentafluorophenol D 2,000 31048phenanthrene-d10 D 2,000 31045phenol-d6 D 2,000 31049pyridine-d5 D 2,000 31046p-terphenyl-d14 D 1,000 318282,4,6-tribromophenol M 1,000 31401

D= methylene chlorideM = methanol

Individual Semivolatile Surrogate and InternalStandards for EPA MethodsVolume is 1mL/ampul. Concentration is µg/mL.

31029: 604 Phenols Mix31030: 605 Benzidines Mix31031: 606 Phthalate Esters Mix31032: 607 Nitrosamines Mix31033: 609 Nitroaromatics/Isophorone Mix31011: 610 PAH Mix (SV Calibration Mix #5)31034: 611 Haloethers Mix31035: 612 Chlorinated Hydrocarbons Mix

Kit components described on pages 420–421.

625 Kit

Because most laboratories do not routinely analyze pesticides, PCBs, toxaphene, andchlordane in their calibration mixtures for Method 625, these mixtures are not includedin the 625 Kit. They may be purchased separately or in the 608 Complete Kit (cat. #32060, page 421).


kit


www.restek.com 425


600 Series Methods

also availableFor a complete listing of solutions of individual environmental compounds,please see ppaaggeess 339999--440044.

Aroclor Solutions

4-bromofluorobenzeneVOA Tuning Compound


decafluorotriphenylphosphine (DFTPP)SV Tuning Compound


Tuning Mixtures

benzidine4,4'-DDT

DFTPPpentachlorophenol

GC/MS Tuning Mixture


Technical Chlordane, Toxaphene Solutions





Neat, 1gcat. # 33027 (ea.)

A = acetoneH = hexaneI = isooctaneTO = transformer oil (PCB-free)

Volume is 1mL/ampul. Concentration is µg/mL unless otherwise noted.

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceechlordane (technical) H 1,000 32021chlordane (technical) I 5,000 32072chlordane (technical) M 2,000 32016toxaphene H 1,000 32005toxaphene I 5,000 32071toxaphene M 2,000 32015H = hexaneI = isooctaneM = methanol


CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeAroclor 1016 H 1,000 32006Aroclor 1016 I 200 32064Aroclor 1016 TO 50mg/kg 32075Aroclor 1016 TO 500mg/kg 32076Aroclor 1221 H 1,000 32007Aroclor 1221 I 200 32065Aroclor 1221 TO 50mg/kg 32077Aroclor 1221 TO 500mg/kg 32078Aroclor 1232 H 1,000 32008Aroclor 1232 I 200 32066Aroclor 1232 TO 50mg/kg 32079Aroclor 1232 TO 500mg/kg 32080Aroclor 1242 H 1,000 32009Aroclor 1242 I 200 32067Aroclor 1242 TO 50mg/kg 32081Aroclor 1242 TO 500mg/kg 32082Aroclor 1248 H 1,000 32010Aroclor 1248 I 200 32068Aroclor 1248 TO 50mg/kg 32083Aroclor 1248 TO 500mg/kg 32084Aroclor 1254 H 1,000 32011Aroclor 1254 I 200 32069Aroclor 1254 TO 50mg/kg 32085Aroclor 1254 TO 500mg/kg 32086Aroclor 1260 H 1,000 32012Aroclor 1260 I 200 32070Aroclor 1260 TO 50mg/kg 32087Aroclor 1260 TO 500mg/kg 32088Aroclor 1262 H 1,000 32409Aroclor 1268 H 1,000 32410Aroclor 1016/1260 H 1,000 32039Aroclor 1016/1260 I 200 32299Aroclor 1016/1260 A 400 32456


Restek’s Learning NetworkSign up for our widely acclaimed seminars today!

Visit www.restek.com/seminars

RReesstteekk ttrraaiinniinngg sseemmiinnaarrss are full-day courses presented in anengaging multimedia format. They are equally valuable to beginning chromatographers, those who have moderate experience and wanta better understanding of the subject matter, and those interestedin the “best practices” and latest technologies. NNoo ssaalleess ppiittcchh iisspprreesseenntteedd, just the facts on how to make your chromatographyresults better. Visit wwwwww..rreesstteekk..ccoomm//sseemmiinnaarrss for more information.


426 www.restek.com


8000 Series Methods


418.1 . . . . . . . . . . . . . . . . . .Total Recoverable Petroleum Hydrocarbons (TRPH)

1311 . . . . . . . . . . . . . . . . . .Toxicity Characteristics Leaching Procedure (TCLP)

1664 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Oil & Grease

3500 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Organic Extraction Surrogates

8010 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Halogenated Volatile Organics

8011 . . . . . . . . . . . . . . . . . . .1,2-Dibromoethane, 1,2-Dibromo-3-Chloropropane

8020 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Aromatic Volatile Organics

8021 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatile Organics

8040 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Phenols

8061A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Phthalate Esters

8080, 8081 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chlorinated Pesticides

8082, 8082A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .PCBs


8095 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Explosives by GC

8100 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Polycyclic Aromatic Hydrocarbons

8140, 8141 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Organophosphorus Pesticides

8150, 8151, 8151A . . . . . . . . . . . . . . . . . . . . . . . . . .Chlorinated Acid Herbicides

8240 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatile Organic Compounds (VOC)

8260, 8260A, 8260B . . . . . . . . . . . . . . . . . . .Volatile Organic Compounds (VOC)

8270D, 8270C . . . . . . . . . . . . . . . . . . . . . . . . . .Semivolatile Organic Compounds

8310 . . . . . . . . . . . . . . . . . . . . . . . . . .Polycyclic Aromatic Hydrocarbons (PAHs)

8315 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Aldehydes/Ketones-DNPH by HPLC

8321 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chlorinated Acids by HPLC

8330 . . . . . . . . . . . . . . . . . . . . . . . . . . .Nitroaromatics and Nitramines by HPLC

8000 Series Methods - Resource Conservation and Recovery Act (RCRA)

Method 418.1 (Total Recoverable PetroleumHydrocarbons [TRPH])

Method 1311 (Toxicity Characteristics LeachingProcedure [TCLP]) cont'd

chlorobenzene 25.0% (v/v)n-hexadecane 37.5%

isooctane 37.5%418.1 Calibration Mix

1mL/ampulcat. # 30080 (ea.)

Method 1311 (Toxicity Characteristics LeachingProcedure [TCLP])

benzene2-butanone (MEK)carbon tetrachloridechlorobenzenechloroform1,4-dichlorobenzene

1,2-dichloroethane1,1-dichloroethenetetrachloroethenetrichloroethenevinyl chloride

TCLP VOA Mix (11 components)

2,000µg/mL each in P&T methanol:water (90:10), 1mL/ampulcat. # 30024 (ea.)

2-methylphenol3-methylphenol4-methylphenol

pentachlorophenol2,4,5-trichlorophenol2,4,6-trichlorophenol

TCLP Acid Mix


1,4-dichlorobenzene2,4-dinitrotoluenehexachlorobenzenehexachlorobutadiene

hexachloroethanenitrobenzenepyridine

TCLP B/N Mix (7 components)


γ-BHC (lindane)endrinheptachlor

heptachlor epoxide (isomer B)methoxychlor

TCLP Pesticide Mix


2,4-D (free acid) Silvex (free acid)TCLP Herbicide Mix


toxapheneTCLP Toxaphene Mix


chlordane (technical)TCLP Chlordane Mix


Method 1664 (Oil & Grease)

hexadecane stearic acid

See page 361 for Resprep Oil & Grease SPE Disks.

1664 Oil & Grease Mix


Method 3500 (Organic Extraction Surrogates)

High-Concentration Surrogates and

Matrix Spike Mixtures for SW-846

• Highest concentrations commercially available—reduces costper sample extract.

• Convenient 1mL and 5mL packaging.

See Method 8270, pages 435-438.

did you know?Restek reference materials include a silanized vial for sample transfer.

426-434_arm_8000series1.qxp 11/20/2008 9:04 AM Page 426

www.restek.com 427


8000 Series MethodsMethod 8010 (Halogenated Volatile Organics)

benzyl chloridebromodichloromethanebromoformcarbon tetrachloridechlorobenzene1,2-dichlorobenzene1,3-dichlorobenzene1,1-dichloroethene

trans-1,2-dichloroethenecis-1,3-dichloropropenetrans-1,3-dichloropropenemethylene chloridetetrachloroethenetrichloroethene1,2,3-trichloropropane

8010A Calibration Mix #2 (15 components)


bromobenzene2-chloroethyl vinyl etherchloroformdibromochloromethanedibromomethane1,4-dichlorobenzene1,1-dichloroethane

1,2-dichloroethane1,2-dichloropropane1,1,1,2-tetrachloroethane1,1,2,2-tetrachloroethane1,1,1-trichloroethane1,1,2-trichloroethane

To analyze compounds listed in Methods 8010 and 8020 concurrently, add BTEXStandard to the calibration curve mix (see above).

8010A Calibration Mix #3 (13 components)


benzeneethylbenzenetoluene

m-xyleneo-xylenep-xylene

BTEX Standard



2,000µg/mL each in P&T methanol (m-xylene and p-xylene at 1,000µg/mL), 1mL/ampulcat. # 30488 (ea.)

Method 8010 (Halogenated Volatile Organics) cont'd

Method 8011 (1,2-Dibromoethane, 1,2-Dibromo-3-chloropropane)

1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane (EDB)

8011 Calibration Mix—EDB/DBCP


Method 8020 (Aromatic Volatile Organics)

benzenechlorobenzene1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene

ethylbenzenetoluenem-xyleneo-xylenep-xylene

8020A Calibration Mix (10 components)







bromochloromethane2-bromo-1-chloropropane

1,4-dichlorobutane

NNoottee:: Method 8010 does not specify internal standards to be used. The analystmust select appropriate internal standards based on the particular samples beinganalyzed. Potential internal standards are listed on page 423.

624 Internal Standard Mix




Requires a high-purity VOC single-stage regulator. See page 386. No data pack available.

BTEX Gas Mix

CCyylliinnddeerr CCoonnssttrruuccttiioonn:: aluminumCCyylliinnddeerr FFiittttiinngg:: CGA-180 outlet

1ppm in nitrogen, 104 liters @ 1,800psicat. # 34414 (ea.)

100ppb in nitrogen, 104 liters @ 1,800psicat. # 34428 (ea.)

1ppm in nitrogen, 110 liters @ 1,800psi (Pi-marked Cylinder)cat. # 34414-PI (ea.)

100ppb in nitrogen, 110 liters @ 1,800psi (Pi-marked Cylinder)cat. # 34428-PI (ea.)

allyl chloride1-chlorohexane4-chlorotoluene1,2-dibromo-3-chloropropane

1,2-dibromoethanecis-1,4-dichloro-2-butenetrans-1,4-dichloro-2-butene

8010B Calibration Mix #4


CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee4-bromofluorobenzene PTM 2,000 300261,4-difluorobenzene PTM 2,000 30032fluorobenzene PTM 2,000 30030α,α,α-trifluorotoluene PTM 2,000 30048


Internal and Surrogate Standards


SSppeeccttrraa 110044LL CCyylliinnddeerrss::

Size: 8 x 24 cm. Volume/Pressure: 104 liters of gas @ 1,800psiWeight: 1.5 lbs./0.7 kg

SSccoottttyy 111100LL CCyylliinnddeerrss ((PPii--mmaarrkkeedd CCyylliinnddeerrss ffoorr EEUU RReegguullaattiioonnss))::

Size: 8.3 x 29.5 cm. Volume/Pressure: 110 liters of gas @ 1,800psiWeight: 2.2 lbs./1 kgUS DOT Specs: 3AL2216

tech tip


428 www.restek.com


8000 Series MethodsMethod 8021 (Volatile Organics)


2-fluorophenol 2,4,6-tribromophenol8040 Surrogate Mix

2,000µg/mL each in isopropanol, 1mL/ampulcat. # 31090 (ea.)

4-chloro-3-methylphenol2,4-dichlorophenol2-methyl-4,6-dinitrophenol3-methylphenol2-nitrophenol

4-nitrophenolpentachlorophenolphenol2,4,6-trichlorophenol

8040 Phenols Mix #1 (9 components)


sec-butyl-4,6-dinitrophenol (dinoseb)2-chlorophenol2,6-dichlorophenol2,4-dimethylphenol2,4-dinitrophenol

2-methylphenol4-methylphenol2,3,4,6-tetrachlorophenol2,4,5-trichlorophenol

8040 Phenols Mix #2 (9 components)


Method 8061A (Phthalate Esters)

benzyl butyl phthalate bis(2-ethylhexyl)phthalate8061A Matrix Spike Solution


Benzyl Benzoate (Internal Standard)


dibenzyl phthalatediphenyl isophthalate

diphenyl phthalate8061A Surrogate Standard


Method 8080, 8081 (Chlorinated Pesticides)



Organochlorine Pesticide Mix AB #1 (20 components)


Method 8061A (Phthalate Esters) cont'd

1-bromo-2-chloroethane1-chloro-3-fluorobenzene

fluorobenzene8021/502.2 Surrogate Mix #1


1-bromo-2-chloroethane4-bromochlorobenzene

1-chloro-3-fluorobenzenefluorobenzene



2-bromochlorobenzene 1,4-dichlorobutane8021 Surrogate Mix


2-bromo-1-chloropropane fluorobenzene502.2 Internal Standard Mix #2


benzyl butyl phthalatebis(2-n-butoxyethyl)phthalatebis(2-ethoxyethyl)phthalatebis(2-ethylhexyl)phthalate (dioctylbis(2-methoxyethyl)phthalatebis(4-methyl-2-pentyl)phthalatedi-n-butylphthalatediethylphthalate

di-n-hexyl phthalatedimethylphthalatedi-nonyl phthalatedi-n-octyl phthalatedipentylphthalatephthalic acid dicyclohexyl esterphthalic acid diisobutyl ester

EPA 8061A Phthalate Esters Mixture (15 components)

1,000µg/mL each in hexane:acetone (80:20), 1mL/ampulcat. # 33227 (ea.)

hexyl 2-ethylhexyl phthalateEPA 8061A Hexyl 2-Ethylhexyl Phthalate Standard

1,000µg/mL in hexane:acetone (80:20), 1mL/ampulcat. # 33228 (ea.)

33227: EPA 8061A Phthalate Esters Mixture33228: EPA 8061A Hexyl 2-Ethylhexyl Phthalate Standard

EPA 8061A Phthalate Esters Kit


NEW!

NEW!

NEW!




www.restek.com 429


8000 Series Methods

aldrin 8µg/mLα-BHC 8β-BHC 8δ-BHC 8γ-BHC (lindane) 8α-chlordane 8γ-chlordane 84,4'-DDD 164,4'-DDE 164,4'-DDT 16

dieldrin 16endosulfan I 8endosulfan II 16endosulfan sulfate 16endrin 16endrin aldehyde 16endrin ketone 16heptachlor 8heptachlor epoxide (isomer B) 8methoxychlor 80


In hexane:toluene (1:1), 1mL/ampulcat. # 32292 (ea.)

Method 8080, 8081 (Chlorinated Pesticides) cont'd

Method 8082, 8082A (PCBs)

2-chlorobiphenyl (BZ #1)2,3-dichlorobiphenyl (BZ #5)2,2',5-trichlorobiphenyl (BZ #18)2,4',5-trichlorobiphenyl (BZ #31)2,2',3,5'-tetrachlorobiphenyl (BZ #44)2,2',5,5'-tetrachlorobiphenyl (BZ #52)2,3',4,4'-tetrachlorobiphenyl (BZ #66)2,2',3,4,5'-pentachlorobiphenyl (BZ #87)2,2',4,5,5'-pentachlorobiphenyl (BZ #101)2,3,3',4',6-pentachlorobiphenyl (BZ #110)2,2',3,4,4',5'-hexachlorobiphenyl (BZ #138)2,2',3,4,5,5'-hexachlorobiphenyl (BZ #141)2,2',3,5,5',6-hexachlorobiphenyl (BZ #151)2,2',4,4',5,5'-hexachlorobiphenyl (BZ #153)2,2',3,3',4,4',5-heptachlorobiphenyl (BZ #170)2,2',3,4,4',5,5'-heptachlorobiphenyl (BZ #180)2,2',3,4,4',5',6-heptachlorobiphenyl (BZ #183)2,2',3,4',5,5',6-heptachlorobiphenyl (BZ #187)2,2',3,3',4,4',5,5',6-nonachlorobiphenyl (BZ #206)

PCB Congener Mix, Method 8082A (19 components)

100µg/mL each in isooctane, 1mL/ampulcat. # 32416 (ea.)

Method 8095 (Explosives by GC)

3,4-dinitrotoluene8095 Surrogate

1,000µg/mL in methanol, 1mL/ampulcat. # 31452 (ea.) enquire

2-methyl-4-nitroaniline8095 Surrogate


2-amino-4,6-dinitrotoluene4-amino-2,6-dinitrotoluene1,3-dinitrobenzene2,4-dinitrotoluene2,6-dinitrotoluene

HMX*RDXtetryl1,3,5-trinitrobenene2,4,6-trinitrotoluene

8095 Matrix Spike Mix A (10 components)

200µg/mL each in acetonitrile (*HMX at 2,000µg/mL), 1mL/ampulcat. # 31609 (ea.) enquire

3,5-dinitroaniline*nitrobenzenenitroglycerine2-nitrotoluene

3-nitrotoluene4-nitrotoluenePETN

8095 Matrix Spike Mix B (7 components)

1,000µg/mL each in acetonitrile (*3,5-dinitroaniline at 200µg/mL), 1mL/ampulcat. # 31610 (ea.) enquire

2-amino-4,6-dinitrotoluene4-amino-2,6-dinitrotoluene1,3-dinitrobenzene2,4-dinitrotoluene2,6-dinitrotoluene

HMXRDXtetryl1,3,5-trinitrobenzene2,4,6-trinitrotoluene

8095 Calibration Mix A (10 components)


3,5-dinitroaniline*nitrobenzenenitroglycerine2-nitrotoluene

3-nitrotoluene4-nitrotoluenePETN

8095 Calibration Mix B (7 components)

5,000µg/mL each in acetonitrile (*3,5-dinitroaniline at 1,000µg/mL), 1mL/ampulcat. # 31608 (ea.) enquire

These materials support nitroaromatic, nitramine, andnitroester analyses by GC/ECD (Method 8095).1,2 Compoundslisted are explosives, manufacturing intermediates, or degrada-tion products. Method 8095 mixtures contain the componentsat concentration ratios appropriate for ECD.

RReeffeerreenncceess ((NNoott aavvaaiillaabbllee ffrroomm RReesstteekk..))1US Environmental Protection Agency. Test Methods for Evaluating Solid Waste,Physical/Chemical Methods. SW-846, Proposed Draft Update IVB, Office of SolidWaste, Washington, DC, 1999.2M. E. Walsh, T. Ranney, J. Chromatogr. Sci., Vol. 36, pp. 406-416, August 1998.

decachlorobiphenyl 2,4,5,6-tetrachloro-m-xylene

Pesticide Surrogate Mix






decachlorobiphenyl 200µg/mL 2,4,5,6-tetrachloro-m-xylene 100Pesticide Surrogate Mix


also availableMethod 8095 single-component explosives solutions. See next page.

200µg/mL each in acetone, 5mL/ampulcat. # 32457 (ea.) NEW!


430 www.restek.com


8000 Series MethodsMethods 8140, 8141 (Organophosphorus Pesticides)

azinphos methylbolstar (sulprofos)chlorpyrifoscoumaphosdemeton, O & Sdiazinondichlorvosdisulfotonethopropfensulfothion

fenthionmerphosmethyl parathionmevinphosnaledphorateronnelstirofostokuthion (prothiofos)trichloronate

8140/8141 OP Pesticide Calibration Mix A (20 components)

200µg/mL each in hexane:acetone (95:5), 1mL/ampulcat. # 32277 (ea.)

dimethoateEPNmalathionmonocrotophos

parathionsulfoteppTEPP

8141 OP Pesticide Calibration Mix B (7 components)

200µg/mL each in hexane:acetone (95:5), 1mL/ampulcat. # 32278 (ea.)

8140/8141 Internal Standards & Surrogates



also availableAdditional nitrogen/phosphorus pesticide mixes are listed on ppaaggee 441144..

Restek OPP standards are stablefor at least 12 months.





Method 8100 (Polycyclic Aromatic Hydrocarbons)

benzo(j)fluoranthenedibenzo(a,h)acridinedibenzo(a,j)acridine7H-dibenzo(c,g)carbazole

dibenzo(a,e)pyrenedibenzo(a,h)pyrenedibenzo(a,i)pyrene3-methylcholanthrene

PAH Supplement Mix for Method 8100 (8 components)


The preparation of accurate and stable OP pesticide standards iscomplicated by their sensitivity to light, pH, heat, and water.Restek has spent many years researching OP pesticide mixtures.Based on this research, our procedures include:

• Solvents are assayed to ensure low water content.• Reference mixtures are packaged in deactivated amber

ampules, under an inert atmosphere.• Purity is determined by a combination of GC/FID, GC/FPD,

GC/NPD, DSC, or HPLC/UV.

NNPPDD DDeetteeccttoorr::Internal Standard: 1-bromo-2-nitrobenzene (cat.# 32279)Surrogate: 4-chloro-3-nitrobenzotrifluoride (cat.# 32282)

FFPPDD DDeetteeccttoorr::Internal Standard: none recommendedSurrogate: tributylphosphate (cat.# 32280) and triphenylphosphate (cat.# 32281)



ACN=acetonitrileM = methanol

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee2-amino-4,6-dinitrotoluene ACN 1,000 31670 enquire4-amino-2,6-dinitrotoluene ACN 1,000 31671 enquireammonium picrate ACN 2,000 31890 enquire3,5-dinitroaniline ACN 1,000 31661 enquire1,3-dinitrobenzene ACN 1,000 31662 enquire1,4-dinitrobenzene ACN 2,000 33205 enquire2,4-dinitrotoluene ACN 1,000 31663 enquire2,6-dinitrotoluene ACN 1,000 31664 enquireEGDN M 1,000 31601 enquireHMX ACN 1,000 31665 enquirenitrobenzene ACN 1,000 31657 enquirenitroglycerin M 1,000 31498 enquirenitroguanidine M 1,000 31602 enquire2-nitrotoluene ACN 1,000 31659 enquire3-nitrotoluene ACN 1,000 31660 enquire4-nitrotoluene ACN 1,000 31658 enquirePETN (pentaerythritol tetranitrate) M 1,000 31600 enquirepicric acid M 1,000 31499 enquirepropylene glycol dinitrate (PGDN) M 1,000 31821 enquireRDX ACN 1,000 31666 enquiretetryl ACN 1,000 31667 enquire1,3,5-trinitrobenzene ACN 1,000 31668 enquire2,4,6-trinitrotoluene ACN 1,000 31669 enquire

Single-Component Explosives Solutions


Method 8095 (Explosives by GC) cont'd

also availableOur 30m, 0.32mm ID, 0.50µm Rtx®-OPPesticidescolumn provides fast analyses, low bleed, andbetter resolution than alternative choices.

See ppaaggee 7799 for details.

Stable for at least

12months


www.restek.com 431


8000 Series Methods



see Method 555, ppaaggee 441199 and Method 8321, ppaaggee 444400

Method 8150, 8151, 8151A (Chlorinated Acid Herbicides)

Picloram


3,5-dichlorobenzoic acid methyl ester

3,5-Dichlorobenzoic Acid Methyl Ester Surrogate Standard



3,5-dichlorobenzoic acid3,5-Dichlorobenzoic Acid Surrogate Standard


MCPA


MCPP


4,4'-dibromooctafluorobiphenylHerbicide Internal Standard





Herbicide Surrogate






2,4-D2,4-DB2,4,5-T2,4,5-TP









dalapon

Herbicide Mix #2








MCPA MCPP

Herbicide Mix #3



MCPA methyl ester MCPP methyl esterDDeerriivvaattiizzeedd FFoorrmm::


acifluorfenbentazonchlorambenDCPA diacid

3,5-dichlorobenzoic acid4-nitrophenolpentachlorophenolpicloram




acifluorfen methyl esterbentazon methyl esterchloramben methyl esterDCPA (Dacthal)

3,5-dichlorobenzoic acid methyl ester4-nitroanisolepentachloroanisolepicloram methyl ester




432 www.restek.com


8000 Series Methods





bromodichloromethanebromoformcarbon tetrachloridechlorobenzene2-chloroethyl vinyl etherchloroformdibromochloromethane1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,1-dichloroethane1,2-dichloroethane

1,1-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropanecis-1,3-dichloropropenetrans-1,3-dichloropropenemethylene chloride1,1,2,2-tetrachloroethanetetrachloroethene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethene

VOA Purgeable Halocarbon Mix #1 (23 components)


allyl alcohol2-chloroethanolethanol

isobutyl alcoholpropargyl alcohol

8240 Alcohols Mix


allyl chloridebenzyl chloride1,2-dibromo-3-chloropropane1,2-dibromoethanedibromomethanecis-1,4-dichloro-2-butene

trans-1,4-dichloro-2-butene1,4-dioxaneiodomethanepentachloroethane1,1,1,2-tetrachloroethane1,2,3-trichloropropane

8240 Volatiles Mix #1A (12 components)


carbon disulfide2-picoline

pyridine8240 Volatiles Mix #2A


acrylonitrileethyl methacrylatemalononitrilemethacrylonitrile

methyl methacrylatepropionitrilestyrene

8240 Nitriles Mix (7 components)


restek innovation!XXyylleennee--FFrreeee,, HHiigghhllyy--PPuurriiffiieedd CChhlloorroopprreennee SSttaannddaarrddThe R&D chemists at Restek developed a novel procedure that produces a pure, quantitative chloroprene solution specially stabilized in purge & trap-grademethanol. The entire procedure is performed under carefully monitored conditionsto prevent any contamination or polymerization of the highly reactive, neat chloro-prene. The final solution is specially stabilized, allowing analysts to make dilutionsfor working standards in unmodified purge & trap-grade methanol.

NNoottee:: Because chloroprene is not analyzed by many laboratories, it is not includedin our 8240 VOA mixes. Chloroprene is included in our 8260B MegaMix® CalibrationMix. Refer to ppaaggee 443333..

acetone2-butanone (MEK)


VOA Calibration Mix #1 (ketones)


Method 8240 (Volatile Organic Compounds [VOC])

ethylene glycol propylene glycolGlycols Standard









BTEX Standard






Requires a high-purity VOC single-stage regulator. See page 386.No data pack available.

BTEX Gas Mix





100ppb in nitrogen, 110 liters @ 1,800psi (Pi-marked Cylinder)cat. # 34428-PI (ea.)


www.restek.com 433


8000 Series Methods

chlorobenzene-d51,4-dichlorobenzene-d4

fluorobenzene8260A Internal Standard Mix


4-bromofluorobenzenedibromofluoromethane

1,2-dichloroethane-d4toluene-d8

8260A Surrogate Mix


benzenechlorobenzene1,1-dichloroethene

toluenetrichloroethylene

8260B Matrix Spike Mix



1,4-difluorobenzenepentafluorobenzene

8260 Internal Standard Mix


4-bromofluorobenzenedibromofluoromethane

toluene-d88260 Surrogate Mix


bromoformchlorobenzenechloromethane

1,1-dichloroethane1,1,2,2-tetrachloroethane

8240/8260 System Performance Check Mix


chloroform1,1-dichloroethene1,2-dichloropropane

ethylbenzenetoluenevinyl chloride

8240/8260 Calibration Check Mix


Method 8260, 8260A, 8260B (Volatile Organic Compounds [VOC])

acetonitrileacrylonitrileallyl chloridebenzenebromobenzenebromochloromethanebromodichloromethanebromoformn-butylbenzenesec-butylbenzenetert-butylbenzenecarbon disulfidecarbon tetrachloridechlorobenzene2-chloroethanolchloroformchloroprene2-chlorotoluene4-chlorotoluenedibromochloromethane1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane (EDB)dibromomethane1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzenecis-1,4-dichloro-2-butenetrans-1,4-dichloro-2-butene1,1-dichloroethane1,2-dichloroethane1,1-dichloroethenecis-1,2-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropane1,3-dichloropropane2,2-dichloropropane1,1-dichloropropenecis-1,3-dichloropropene

trans-1,3-dichloropropenediethyl ether (ethyl ether)1,4-dioxaneethylbenzeneethyl methacrylatehexachloro-1,3-butadieneiodomethaneisobutyl alcoholisopropylbenzene (cumene)4-isopropyl toluene (p-cymene)methacrylonitrilemethyl acrylatemethyl methacrylatemethylene chloride (dichloromethane)naphthalenenitrobenzene2-nitropropanepentachloroethanepropionitrilen-propylbenzenestyrene1,1,1,2-tetrachloroethane1,1,2,2-tetrachloroethanetetrachloroethenetetrahydrofurantoluene1,2,3-trichlorobenzene1,2,4-trichlorobenzene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethene1,2,3-trichloropropane1,1,2-trichlorotrifluororethane (CFC-113)1,2,4-trimethylbenzene1,3,5-trimethylbenzenem-xyleneo-xylenep-xylene

8260B MegaMix® Calibration Mix (76 components)


2-Chloroethyl Vinyl Ether


30633: 8260B MegaMix30265: 2-chlorethyl vinyl ether

8260B MegaMix® Calibration Mix Kit


1,4-Dioxane-d8


4-Bromofluorobenzene







Neat, 1gcat. # 33027 (ea.)






kit


434 www.restek.com


8000 Series Methods

also availableOur Rtx®-VMS column is your best choice for EPAMethod 8260.

• Fastest cycle times for VOCs. • Tuned selectivity for VOCs.• Excellent separation of gases.

See ppaaggee 9900 for more information.

Chloroprene


Vinyl Acetate


Acrolein


10,000µg/mL in water, 1mL/ampulcat. # 30478 (ea.)

Method 8260, 8260A, 8260B (Volatile Organic Compounds [VOC]) cont'd

1,2-Dichlorotetrafluoroethane (CFC-114)



CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeethanol W 10,000 30466methanol W 10,000 30467tert-amyl alcohol PTM 10,000 30631ethanol PTM 2,000 30288methyl tert-butyl ether (MTBE) PTM 2,000 30402tert-amyl ethyl ether (TAEE) PTM 2,000 30617diisopropyl ether (DIPE) PTM 2,000 30627ethyl-tert-butyl ether (ETBE) PTM 2,000 30628tert-amyl methyl ether (TAME) PTM 2,000 30629tert-butanol-d9 PTM 20,000 30618tert-butanol PTM 50,000 30470

PTM = purge & trap grade methanolW = DI water

Single-Component Oxygenates Solutions


diisopropyl ether (DIPE) 2,000µg/mLethyl-tert-butyl ether (ETBE) 2,000tert-amyl methyl ether (TAME) 2,000

tert-butyl alcohol 10,000methyl tert-butyl ether (MTBE) 2,000

California Oxygenates Mix


tert-amyl ethyl ether (TAEE) 2,000µg/mL

tert-amyl methyl ether (TAME) 2,000tert-butyl alcohol (TBA) 10,000

diisopropyl ether (DIPE) 2,000ethyl-tert-butyl ether (ETBE) 2,000methyl tert-butyl ether (MTBE) 2,000

Oxygenates


vinyl acetateethyl acetateisopropyl acetate

n-propyl acetaten-butyl acetate

8260B Acetate Mix


n-amyl acetatebutyl acetateethyl acetateisopropyl acetate

methyl acetatepropyl acetatevinyl acetate

8260B Acetate Mix (Revised) (7 components)






30042: 502.2 Calibration Mix #130043: 502.2 Calibration Mix #230044: 502.2 Calibration Mix #330045: 502.2 Calibration Mix #430046: 502.2 Calibration Mix #530047: 502.2 Calibration Mix #630067: 4-bromofluorobenzene (2,500µg/mL)30240: 8260A Surrogate Mix (2,500µg/mL)30241: 8260A Internal Standard Mix (2,500µg/mL)30075: 8240/8260 System Performance Check Mix30005: VOA Matrix Spike Mix (2,500µg/mL)

Components are listed on pages 408, 409, 433, and 442.

8260A Volatile Organics Kit (2,000μg/mL)

Changes in this revision of the method include modification ofthe recommended internal standard and surrogate solutions.


30042: 502.2 Calibration Mix #130043: 502.2 Calibration Mix #230044: 502.2 Calibration Mix #330045: 502.2 Calibration Mix #430046: 502.2 Calibration Mix #530047: 502.2 Calibration Mix #630067: 4-bromofluorobenzene (2,500µg/mL)30073: 8260 Surrogate Mix (2,500µg/mL)30074: 8260 Internal Standard Mix (2,500µg/mL)30075: 8240/8260 System Performance Check Mix30005: VOA Matrix Spike Mix (2,500µg/mL)

Components are listed on pages 408, 409, 433, and 442.

8260 Volatile Organics Kit (2,000μg/mL)


kit

kit

426-434_arm_8000series1.qxp 11/20/2008 9:05 AM 4

www.restek.com 435


8000 Series Methods

Method 8270D, 8270C (Semivolatile Organic Compounds)






2-fluorobiphenylnitrobenzene-d5

p-terphenyl-d14

B/N Surrogate Mix (4/89 SOW)





2-fluorophenolphenol-d6

2,4,6-tribromophenolAcid Surrogate Mix (4/89 SOW)





acenaphthene1,4-dichlorobenzene2,4-dinitrotoluene

N-nitroso-di-n-propylaminepyrene1,2,4-trichlorobenzene

B/N Matrix Spike Mix





4-chloro-3-methylphenol2-chlorophenol4-nitrophenol

pentachlorophenolphenol

Acid Matrix Spike Mix





benzidine4,4'-DDT

DFTPPpentachlorophenol

GC/MS Tuning Mixture


acenaphthane-d10chrysene-d121,4-dichlorobenzene-d41,4-dioxane-d8


Revised SV Internal Standard Mix (7 components)




p-terphenyl-d14pyrene-d10

Revised B/N Surrogate Mix









Neat, 1gcat. # 33027 (ea.)




435-441_ARM_8000series2.qxp 11/20/2008 9:06 AM Page 435

436 www.restek.com


8000 Series MethodsMethod 8270D, 8270C (Semivolatile Organic Compounds) cont'd

acenaphtheneacenaphthyleneanilineanthraceneazobenzene1

benzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(ghi)perylenebenzo(k)fluoranthenebenzyl alcoholbenzyl butyl phthalatebis(2-chloroethoxy)methanebis(2-chloroethyl)etherbis(2-chloroisopropyl)etherbis(2-ethylhexyl)adipatebis(2-ethylhexyl)phthalate4-bromophenyl phenyl ethercarbazole4-chloroaniline4-chloro-3-methylphenol2-chloronaphthalene2-chlorophenol4-chlorophenyl phenyl etherchrysenedibenzo(a,h)anthracenedibenzofuran1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene2,4-dichlorophenoldiethyl phthalate2,4-dimethylphenoldimethyl phthalatedi-n-butyl phthalate1,2-dinitrobenzene1,3-dinitrobenzene1,4-dinitrobenzene

4,6-dinitro-2-methylphenol2,4-dinitrophenol2,4-dinitrotoluene2,6-dinitrotoluenedi-n-octyl phthalatediphenylamine2

fluoranthenefluorenehexachlorobenzenehexachlorobutadienehexachlorocyclopentadienehexachloroethaneindeno(1,2,3-cd)pyreneisophorone1-methylnaphthalene2-methylnaphthalene2-methylphenol3-methylphenol4-methylphenolnaphthalene2-nitroaniline3-nitroaniline4-nitroanilinenitrobenzene2-nitrophenol4-nitrophenolN-nitrosodimethylamineN-nitroso-di-n-propylaminepentachlorophenolphenanthrenephenolpyrenepyridine2,3,4,6-tetrachlorophenol2,3,5,6-tetrachlorophenol1,2,4-trichlorobenzene2,4,5-trichlorophenol2,4,6-trichlorophenol

*3-methylphenol and 4-methylphenol concentration is 500µg/mL.

8270 MegaMix® (76 components)

1,000µg/mL each in methylene chloride, 1mL/ampul*cat. # 31850 (ea.)

same list as 8270 MegaMix above

8270 MegaMix® and 8270 Matrix Spike Mix include 3-methylphenol and 4-methylphenol at 1/2 x concentrationof other components.

**3-methylphenol and 4-methylphenol concentration is 100µg/mL.

8270 Matrix Spike Mix (76 components)

11,2-diphenylhydrazine (8270-listed analyte) decomposes to azobenzene (mixcomponent) in the injector.2N-nitrosodiphenylamine (8270-listed analyte) decomposes to diphenylamine(mix component) in the injector.

200µg/mL each in methanol:methylene chloride (80:20), 5mL/ampul**cat. # 31687 (ea.)

200µg/mL each in methanol:methylene chloride (80:20), 10mL/ampul**cat. # 33073 (ea.)

acenaphthenebenzo(a)pyrene1,4-dichlorobenzenedi-n-octyl phthalate

diphenylaminefluoranthenehexachlorobutadiene

8270 B/N Calibration Check Mix (7 components)


4-chloro-3-methylphenol2,4-dichlorophenol2-nitrophenol

pentachlorophenolphenol2,4,6-trichlorophenol

8270 Acid Calibration Check Mix


2,4-dinitrophenolhexachlorocyclopentadiene

4-nitrophenolN-nitroso-di-n-propylamine

SV System Performance Check Mix (SPCC)


benzidine3,3'-dichlorobenzidine

3,3'-dimethylbenzidine8270 Benzidines Mix






also availableOur Rxi®-5Sil MS columns provide high response for 2,4-dinitrophenol, show excellent peak shape ofpyridine, and produce outstanding resolution of PAHs.

See ppaaggee 8888..

EASIERcalibration


www.restek.com 437


8000 Series Methods


31850: 8270 MegaMix31834: 605 Benzidines Calibration Mix31625: Appendix IX Mix #131806: Appendix IX Mix #2

8270/Appendix IX Kit


2-acetylaminofluorene4-aminobiphenylp-dimethylaminoazobenzene3,3'-dimethylbenzidineα,α,-dimethylphenethylamine

(free base)methapyrilene (free base)1-naphthylamine2-naphthylamine5-nitro-o-toluidine

N-nitrosodibutylamineN-nitrosodiethylamineN-nitrosomethylethylamineN-nitrosomorpholineN-nitrosopiperidineN-nitrosopyrrolidine1,4-phenylenediamine2-picolineo-toluidine

Appendix IX Mix #1 (18 components)


acetophenoneAramiteatrazinebenzaldehydebiphenylε-caprolactamchlorobenzilate1-chloronaphthalenediallatedibenzo(a,j)acridine2,6-dichlorophenol7,12-dimethylbenz(a)anthracene1,4-dioxanediphenyl etherethyl methacrylateethyl methanesulfonate

hexachloropropeneisodrinisosafrole (cis & trans)kepone3-methylcholanthrenemethyl methanesulfonate1,4-naphthoquinone4-nitroquinoline-N-oxidepentachlorobenzenepentachloroethanepentachloronitrobenzenephenacetinpronamidesafrole1,2,4,5-tetrachlorobenzene1,3,5-trinitrobenzene

Appendix IX Mix #2 (32 components)

1,000µg/mL each in methylene chloride, 1mL/ampulcat. # 31806 (ea.) enquire

dimethoatedisulfotonfamphurmethyl parathionO,O,O-triethyl phosphorothioate

parathion (ethyl parathion)phoratesulfoteppzinophos (thionazine)

Organophosphorus Pesticide Mix, 8270/Appendix IX(9 components)


Method 8270D, 8270C (Semivolatile Organic Compounds) cont'd

benzoic acid4-chloro-3-methylphenol2-chlorophenol2,4-dichlorophenol2,6-dichlorophenol2,4-dimethylphenol4,6-dinitro-2-methylphenol2,4-dinitrophenoldinoseb2-methylphenol

3-methylphenol4-methylphenol2-nitrophenol4-nitrophenolpentachlorophenolphenol2,3,4,6-tetrachlorophenol2,4,5-trichlorophenol2,4,6-trichlorophenol



anilinebenzidine4-chloroaniline3,3'-dichlorobenzidinediphenylamine*2-nitroaniline

3-nitroaniline4-nitroanilineN-nitrosodimethylamineN-nitrosodi-n-propylaminepyridine

*N-nitrosodiphenylamine (8270-listed analyte) decomposes to diphenylamine(mix component) in the injector.


2,000µg/mL each in methylene chloride:methanol (85:15), 1mL/ampulcat. # 31619 (ea.)


Benzoic Acid





Aramitebis(2-chloroethyl)etherbis(2-chloroethoxy)methanebis(2-chloroisopropyl)ether4-bromophenyl phenyl etherchlorobenzilate2-chloronaphthalene4-chlorophenyl phenyl ether1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,3-dinitrobenzene

hexachlorobenzenehexachlorobutadienehexachlorocyclopentadienehexachloroethanehexachloropropeneisodrinkeponepentachlorobenzenepentachloronitrobenzene1,2,4,5-tetrachlorobenzene1,2,4-trichlorobenzene



kit


438 www.restek.com


8000 Series Methods

Aroclor Solutions



acenaphtheneacenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(ghi)perylenebenzo(k)fluoranthenechrysenedibenzo(a,h)anthracene

fluoranthenefluoreneideno(1,2,3-cd)pyrene3-methylcholanthrene1-methylnaphthalene2-methylnaphthalenenaphthalenephenanthrenepyrene



diallate (cis & trans)dimethoatedisulfotonfamphurmethyl parathion

parathionphoratepronamidethionazine (zinophos)0,0,0-triethyl phosphorothioate



Aramite





31618: 8270 Calibration Mix #131619: 8270 Calibration Mix #231620: 8270 Calibration Mix #331621: 8270 Calibration Mix #431622: 8270 Calibration Mix #531623: 8270 Calibration Mix #631625: Appendix IX Mix #1

8270/Appendix IX Calibration Kit (2,000μg/mL)


31618: 8270 Calibration Mix #131619: 8270 Calibration Mix #231620: 8270 Calibration Mix #331621: 8270 Calibration Mix #431622: 8270 Calibration Mix #5

8270 Calibration Kit (2,000μg/mL)


Method 8270D, 8270C (Semivolatile Organic Compounds) cont'd

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeAroclor 1016 H 1,000 32006Aroclor 1016 I 200 32064Aroclor 1016 TO 50mg/kg 32075Aroclor 1016 TO 500mg/kg 32076Aroclor 1221 H 1,000 32007Aroclor 1221 I 200 32065Aroclor 1221 TO 50mg/kg 32077Aroclor 1221 TO 500mg/kg 32078Aroclor 1232 H 1,000 32008Aroclor 1232 I 200 32066Aroclor 1232 TO 50mg/kg 32079Aroclor 1232 TO 500mg/kg 32080Aroclor 1242 H 1,000 32009Aroclor 1242 I 200 32067Aroclor 1242 TO 50mg/kg 32081Aroclor 1242 TO 500mg/kg 32082Aroclor 1248 H 1,000 32010Aroclor 1248 I 200 32068Aroclor 1248 TO 50mg/kg 32083Aroclor 1248 TO 500mg/kg 32084Aroclor 1254 H 1,000 32011Aroclor 1254 I 200 32069Aroclor 1254 TO 50mg/kg 32085Aroclor 1254 TO 500mg/kg 32086Aroclor 1260 H 1,000 32012Aroclor 1260 I 200 32070Aroclor 1260 TO 50mg/kg 32087Aroclor 1260 TO 500mg/kg 32088Aroclor 1262 H 1,000 32409Aroclor 1268 H 1,000 32410Aroclor 1016/1260 H 1,000 32039Aroclor 1016/1260 I 200 32299Aroclor 1016/1260 A 400 32456

free dataAAvvaaiillaabbllee oonn OOuurr WWeebbssiittee:: LLoott CCeerrttiiffiiccaatteess,, DDaattaa PPaacckkss,, aanndd MMSSDDSSssFor complete information detailing manufacturing and testing for Restek inventoried reference standards, visit our website at wwwwww..rreesstteekk..ccoomm//ddaattaappaacckkss. To view certificates and/or an MSDS, enter the catalog number of the product in the Search feature. For a free data pack (Adobe® PDF file), enter the catalognumber and lot number of the product.

acetophenoneazobenzene*benzyl alcoholbis(2-ethylhexyl)phthalatebutyl benzyl phthalatedibenzofurandiethyl phthalatedimethyl phthalatedi-n-butyl phthalatedi-n-octyl phthalate2,4-dinitrotoluene

2,6-dinitrotolueneethyl methanesulfonateisophoroneisosafrole (cis & trans)methyl methanesulfonate1,4-naphthoquinonenitrobenzene4-nitroquinoline-1-oxidephenacetinsafrole1,3,5-trinitrobenzene

*1,2-diphenylhydrazine (8270-listed analyte) decomposes to azobenzene(mix component) in the injector.


2,000µg/mL each in methylene chloride, 1mL/ampulcat. # 31621 (ea.) enquire

kit

kit


www.restek.com 439


8000 Series Methods

acenaphthene 100µg/mLacenaphthylene 100anthracene 100benzo(a)anthracene 10benzo(a)pyrene 10benzo(b)fluoranthene 10benzo(ghi)perylene 10benzo(k)fluoranthene 5chrysene 10

dibenzo(a,h)anthracene 10fluoranthene 10fluorene 100indeno(1,2,3-cd)pyrene 101-methylnaphthalene 1002-methylnaphthalene 100naphthalene 100phenanthrene 100pyrene 10

EPA Method 8310 Quality Control Check (18 components)

Method 8315 (Aldehydes/Ketones-DNPH by HPLC)Method 8310 (Polycyclic Aromatic Hydrocarbons[PAHs])

acenaphtheneacenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(ghi)perylenebenzo(k)fluoranthenechrysene

dibenzo(a,h)anthracenefluoranthenefluoreneindeno(1,2,3-cd)pyrene1-methylnaphthalene2-methylnaphthalenenaphthalenephenanthrenepyrene

EPA Method 8310 PAH Mixture (18 components)

500µg/mL each in acetonitrile, 1mL/ampulcat. # 31841 (ea.)

decafluorobiphenylEPA Method 8310 Surrogate Standard


In acetonitrile, 1mL/ampulcat. # 31843 (ea.)

acetaldehyde-DNPHacetone-DNPHacrolein-DNPHbenzaldehyde-DNPHn-butyraldehyde-DNPHcrotonaldehyde-DNPH2,5-dimethylbenzaldehyde-DNPHformaldehyde-DNPH

hexaldehyde-DNPHisovaleraldehyde-DNPHpropionaldehyde-DNPHm-tolualdehyde-DNPHo-tolualdehyde-DNPHp-tolualdehyde-DNPHvaleraldehyde-DNPH

Aldehyde-Ketone-DNPH TO-11A Calibration Mix(15 components)

15µg/mL* each in acetonitrile, 1mL/ampulcat. # 31808 (ea.)

formaldehyde-DNPHFormaldehyde-DNPH Mix

500µg/mL* in acetonitrile, 1mL/ampulcat. # 31837 (ea.)

*Concentration calculated as aldehyde.

*Concentration calculated as aldehyde.

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeacetaldehyde-2,4-DNPH ACN 100 33074acetone-2,4-DNPH ACN 100 33075acrolein-2,4-DNPH ACN 100 33076benzaldehyde-2,4-DNPH ACN 100 330772-butanone-2,4-DNPH ACN 100 33078n-butyraldehyde-2,4-DNPH ACN 100 33079crotonaldehyde-2,4-DNPH ACN 100 330802,5-dimethylbenzaldehyde-2,4-DNPH ACN 100 33081formaldehyde-2,4-DNPH ACN 100 33082glycolaldehyde-2,4-DNPH ACN 100 33091hexaldehyde-2,4-DNPH ACN 100 33083isobutyraldehyde-2,4-DNPH ACN 100 33084isovaleraldehyde-2,4-DNPH ACN 100 33085methacrolein-2,4-DNPH ACN 100 33095propionaldehyde-2,4-DNPH ACN 100 33086m-tolualdehyde-2,4-DNPH ACN 100 33088o-tolualdehyde-2,4-DNPH ACN 100 33087p-tolualdehyde-2,4-DNPH ACN 100 33089valeraldehyde-2,4-DNPH ACN 100 33090

ACN=acetonitrile

DNPH Reference Materials


acetaldehyde-2,4-DNPHacetone-2,4-DNPHacrolein-2,4-DNPHbenzaldehyde-2,4-DNPHn-butyraldehyde-2,4-DNPHcrotonaldehyde-2,4-DNPHformaldehyde-2,4-DNPH

hexaldehyde-2,4-DNPHmethacrolein-2,4-DNPHmethyl ethyl ketone-2,4-DNPHpropionaldehyde-2,4-DNPHm-tolualdehyde-2,4-DNPHvaleraldehyde-2,4-DNPH

CARB 1004 Aldehyde/Ketone-DNPH Calibration Standard(13 components)


did you know?We have more than 2,000 pure, characterized,neat compounds in our inventory! If you do notsee the EXACT mixture you need listed on any ofthese pages, contact us for a custom standard.


440 www.restek.com


8000 Series Methods

Method 8321 (Chlorinated Acids by HPLC)

3,4-dinitrotoluene

8330 Internal Standards

EPA Method 8330 is used to measure explosives residues in waterand soil samples, using HPLC with UV detection. Target analytesare nitroaromatic and nitramine explosives and their degrada-tion products.


1,2-dinitrobenzene

8330 Surrogate


1,3-dinitrobenzene2,4-dinitrotolueneHMXnitrobenzene

RDX1,3,5-trinitrobenzene2,4,6-trinitrotoluene



2-amino-4,6-dinitrotoluene4-amino-2,6-dinitrotoluene2,6-dinitrotoluene2-nitrotoluene

3-nitrotoluene4-nitrotoluenetetryl



also availableSee ppaaggee 442255 for chlordane and toxaphene reference materials.

1,3-dinitrobenzene2-amino-4,6-dinitrotoluene4-amino-2,6-dinitrotoluene2,4-dinitrotoluene2,6-dinitrotolueneHMXnitrobenzene

2-nitrotoluene3-nitrotoluene4-nitrotolueneRDXtetryl1,3,5-trinitrobenzene2,4,6-trinitrotoluene

Nitroaromatics and Nitramine Explosives by HPLC(14 components)


did you know?When you order reference materials for Method 8330, be aware that obtainingpure, neat compounds for standards can be very difficult. Some of these commercial-grade materials contain desensitizing agents such as beeswax, water,or other manufacturing by-products. Many are shipped wet and must be carefullydried before preparation. To ensure the highest quality standards, Restek chemistsuse multiple analytical techniques including GC, HPLC, GC/MS, or DSC to verifyraw material purity. All compounds are 98% pure or higher.

acifluorfen (Blazer)bentazonchloramben2,4-D

dicambadichlorproppicloram2,4,5-TP (Silvex)

Chlorinated Acids by HPLC, Mix A (8 components)


2,4-DB3,5-dichlorobenzoic aciddinosebMCPA

MCPP (mecoprop)4-nitrophenolpentachlorophenol2,4,5-T

Chlorinated Acids by HPLC, Mix B (8 components)


2,4-dichlorophenoxyacetic acid (2,4-D)2,4,5-TP (Silvex)

Chlorinated Acid Herbicide Mix


Dalapon (2,2-dichloropropionic acid)




2-amino-4,6-dinitrotoluene4-amino-2,6-dinitrotoluene3,5-dinitroaniline1,3-dinitrobenzene2,4-dinitrotoluene2,6-dinitrotolueneHMXnitrobenzenenitroglycerin

2-nitrotoluene3-nitrotoluene4-nitrotoluenePETNRDXtetryl1,3,5-trinitrobenzene2,4,6-trinitrotoluene

Nitroaromatics and Nitramine Explosives by HPLC, EPA

8330B (17 components)


1,4-dinitrobenzene2,000µg/mL in acetonitrile, 1mL/ampul

cat. # 33205 (ea.) enquire

Method 8330 (Nitroaromatics and Nitramines by HPLC)

Method 8330 (Nitroaromatics and Nitramines by HPLC) cont'd


www.restek.com 441


8000 Series Methods

EPA 8330B analytes resolve well on the Ultra C18 column and Pinnacle® II Biphenyl column;

differing selectivities allow true confirmational analysis.

Method 8330 (Nitroaromatics and Nitramines by HPLC) cont'd

also availableSee materials for GC Method 8095 on ppaaggeess 442299--443300..

free literatureFor more information, download ourTrace-Level Explosives Analysis byHPLC applications note fromwwwwww..rreesstteekk..ccoomm. lliitt.. ccaatt..## 5599336611AA




Volume is 1mL/ampul. Concentration is µg/mL. 31450: 8330 Calibration Mix #131451: 8330 Calibration Mix #231452: 8330 Internal Standard Mix31453: 8330 Surrogate Mix

8330 Nitroaromatics Kit (1,000μg/mL)

Contains 1mL each of these mixtures.cat. # 31454 (kit) enquire

LC_EV0428

SSaammppllee:: 5500µµgg//mmLL eeaacchh ccoommppoouunndd ddiilluutteedd iinn aacceettoonniittrriillee8330 Calibration Mix #1 (cat.# 31450)8330 Calibration Mix #2 (cat.# 31451)PETN Standard(cat.# 31600)3,5-dinitroaniline Reference Mix (cat.# 31661)Nitroglycerin Standard (cat.# 31498)

Inj.: 10µL

CCoonnddiittiioonnss::Mobile phase: water:methanol

(44:56 v/v)Flow: 1.0mL/min.Temp.: 30°CDet.: UV detection @ 210nm

PPeeaakk LLiisstt1. HMX2. RDX3. 1,3,5-TNB4. 1,3-DNB5. 3,5-DNA6. NB7. tetryl8. 2,4,6-TNT9. NG

10. 2-A-4,6-DNT11. 4-A-2,6-DNT12. 2,4-DNT13. 2,6-DNT14. 2-NT15. 4-NT16. 3-NT17. PETN

Ultra C18Cat.#: 9174575Dimensions: 250mm x 4.6mmParticle size: 5µmPore size: 100Å

LC_EV0429

Pinnacle® II BiphenylCat.#: 9209565-700Dimensions: 150mm x 4.6mmParticle size: 5µmPore size: 110Å

also availableUltra C18 HPLC columns, ppaaggee 331144

Pinnacle® II Biphenyl HPLC columns, ppaaggee 330099

kit


442 www.restek.com


EPA Super fund Contract Lab Program (CLP)

UUSS EEPPAA MMeetthhoodd NNoo.. CCoommppoouunndd CCllaassss

SOM01.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatiles

04.2 and 04.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatiles

10/92 SOW . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatiles

3/90 SOW . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatiles

03.2 OLC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatiles

UUSS EEPPAA MMeetthhoodd NNoo.. CCoommppoouunndd CCllaassss

SOM01.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Semivolatiles

03.2 OLC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Semivolatiles

04.2 and 04.1 SOW . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Semivolatiles

4/89 and 3/90 SOW . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Semivolatiles

SOM01.1, 04.1, 3/90, 4/89 and 2/88 SOW . . . . . . . . . .Pesticides, Aroclor PCBs

EPA Superfund Contract Lab Program (CLP)

04.2, 04.1, and 10/92 SOW (Volatiles), QA Mixes

also availableSee ppaaggeess 553399--554466 for volatiles analysis chromatograms.

bromochloromethane4-bromofluorobenzenechlorobenzene-d5

1,2-dichloroethane-d41,4-difluorobenzenetoluene-d8

CLP 04.1 VOA Internal Standard/SMC Spike Mix


bromochloromethane1,4-difluorobenzene

chlorobenzene-d5VOA Internal Standard Mix


4-bromofluorobenzene1,2-dichloroethane-d4

toluene-d8VOA Surrogate Spike Mix


benzenechlorobenzene1,1-dichloroethene

toluenetrichloroethene

VOA Matrix Spike Mix



o-xylenep-xylene

VOA Screening Mix #1


n-dodecane n-nonaneVOA Screening Mix #2


4-bromofluorobenzeneVOA Tuning Compound


benzenebromoformcarbon tetrachloride1,2-dibromoethane1,4-dichlorobenzene1,2-dichloroethane

1,2-dichloropropanecis-1,3-dichloropropenetetrachloroethene1,1,2-trichloroethanetrichloroethene

L/C VOA Lab Control Sample #1 (11 components)


04.2, 04.1, and 10/92 SOW (Volatiles), QA Mixes cont'dSOM01.1 (Volatiles), QA Mixes





Neat, 1gcat. # 33027 (ea.)

benzene-d6chloroethane-d5chloroform-d1,2-dichlorobenzene-d41,2-dichloroethane-d41,1-dichloroethene-d2

1,2-dichloropropane-d61,3-dichloropropene-d4*1,1,2,2-tetrachloroethane-d2toluene-d8vinyl chloride-d3

*Mix of cis and trans isomers. Exact proportions will be reported on the datasheet.

SOM01.1 VOA Non-Ketone Deuterated Monitoring

Compounds (11 components)

500µg/mL each in deuterated methanol (MeOD), 1mL/ampulcat. # 30624 (ea.)

1,000µg/mL each in deuterated methanol (MeOD), 1mL/ampulcat. # 30635 (ea.)

2-butanone-d5 2-hexanone-d5

SOM01.1 VOA Ketone Deuterated Monitoring Compounds

500µg/mL each in deuterium oxide (D2O), 1mL/ampulcat. # 30625 (ea.)

1,000µg/mL each in deuterium oxide (D2O), 1mL/ampulcat. # 30636 (ea.)

30624: Non-Ketones30625: Ketones

SOM01.1 VOA DMC Kit

500µg/mL. 1mL each of these mixtures.cat. # 30630 (kit)

1,000µg/mL. 1mL each of these mixtures.cat. # 30637 (kit)

kit

442-453_ARM_clp.qxp 11/20/2008 9:09 AM Page 442

www.restek.com 443


EPA Super fund Contract Lab Program (CLP)3/90 SOW (Volatiles), Calibration Mixes


1,4-difluorobenzeneL/C VOA Internal Standard Mix


vinyl chlorideL/C VOA Lab Control Sample #2


04.2 and 04.1 (Volatiles), Calibration Mixes

benzenebromodichloromethanebromoformcarbon disulfidecarbon tetrachloridechlorobenzenechloroformcyclohexanedibromochloromethane1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,1-dichloroethane1,2-dichloroethane1,1-dichloroethenecis-1,2-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropanecis-1,3-dichloropropene

trans-1,3-dichloropropeneethylbenzeneisopropylbenzenemethyl acetatemethyl tert-butyl ether (MTBE)methylcyclohexanemethylene chloridestyrene1,1,2,2-tetrachloroethanetetrachloroethenetoluene1,2,4-trichlorobenzene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethene1,1,2-trichloro-1,2,2-trifluoroethane

(CFC-113)m-xyleneo-xylenep-xylene











benzenecarbon disulfideethylbenzenetoluene

vinyl acetateo-xylenep-xylene

VOA Calibration Mix #2 (7 components)


carbon tetrachloridechlorobenzenechloroform1,1-dichloroethane1,1-dichloroethene

1,2-dichloropropanemethylene chloride1,1,2-trichloroethanetrichloroethenem-xylene



bromodichloromethanebromoformdibromochloromethane1,2-dichloroethanecis-1,2-dichloroethenetrans-1,2-dichloroethene

cis-1,3-dichloropropenetrans-1,3-dichloropropenestyrene1,1,2,2-tetrachloroethanetetrachloroethene1,1,1-trichloroethane



bromomethanechloroethane

chloromethanevinyl chloride

VOA Calibration Mix #5 (gases)


CLP 04.1 VOA CAL2000 MegaMix® (40 components)

04.2, 04.1, and 10/92 SOW (Volatiles), QA Mixes cont'd

benzenebromodichloromethanebromoformcarbon disulfidecarbon tetrachloridechlorobenzenechloroformdibromochloromethane1,1-dichloroethane1,2-dichloroethane1,1-dichloroethenecis-1,2-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropane

cis-1,3-dichloropropenetrans-1,3-dichloropropeneethylbenzenemethylene chloridestyrene1,1,2,2-tetrachloroethanetetrachloroethenetoluene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethenem-xyleneo-xylenep-xylene

CLP VOA CAL2000 MegaMix® (28 components)


Vinyl Acetate


30632: CLP VOA CAL2000 MegaMix30216: vinyl acetate

CLP VOA CAL2000 MegaMix® Kit


30006: VOA Calibration Mix #1 (ketones)30042: 502.2 Calibration Mix #1 (gases)30456: CLP 04.1 VOA CAL2000 MegaMix

CLP 04.1 VOA Kit #3


30006: VOA Calibration Mix #1 (ketones)30010: VOA Calibration Mix #5 (gases)30632: CLP VOA CAL2000 MegaMix30216: vinyl acetate

CLP VOA Calibration Kit #2

Contains 1mL each of these mixtures. cat. # 30442 (kit)

kit

kit

kit


444 www.restek.com



04.2, 04.1, 4/89, and 3/90 SOW (Semivolatiles),QA Mixes

OLC 03.2 (Volatiles), Calibration Mixes

benzenebromochloromethanebromodichloromethanebromoformcarbon disulfidecarbon tetrachloridechlorobenzenechloroformcyclohexanedibromochloromethane

(chlorodibromomethane)1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane (EDB)1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,1-dichloroethane1,2-dichloroethane1,1-dichloroethenecis-1,2-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropane

cis-1,3-dichloropropenetrans-1,3-dichloropropeneethylbenzeneisopropylbenzene (cumene)methyl acetatemethylcyclohexanemethyl tert-butyl ether (MTBE)methylene chloride (dichloromethane)styrene1,1,2,2-tetrachloroethanetetrachloroethenetoluene1,2,3-trichlorobenzene1,2,4-trichlorobenzene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethene1,1,2-trichlorotrifluoroethane

(CFC-113)m-xylene*o-xylenep-xylene*

OLC 03.2 VOA MegaMix® (42 components)

2,000µg/mL each (*m- & p-xylene at 1,000µg/mL) in P&T methanol, 1mL/ampulcat. # 30492 (ea.)






2-chlorophenol-d42-fluorophenol

phenol-d62,4,6-tribromophenol

Acid Surrogate Standard Mix (3/90 SOW)




2-fluorophenolphenol-d6

2,4,6-tribromophenolAcid Surrogate Mix (4/89 SOW)






p-terphenyl-d14pyrene-d10

Revised B/N Surrogate Mix




acenaphthane-d10chrysene-d121,4-dichlorobenzene-d41,4-dioxane-d8


Revised SV Internal Standard Mix (7 components)



bromochloromethane1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane

1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene

L/C VOA Calibration Mix #6


30006: VOA Calibration Mix #130007: VOA Calibration Mix #230008: VOA Calibration Mix #3

30009: VOA Calibration Mix #430010: VOA Calibration Mix #530003: VOA Tuning Compound

See pages 442–443 for mix compositions.

Additional VOA Calibration Mixes Required:

SOM01.1 (Semivolatiles), QA Mixes

acenaphthylene-d8anthracene-d10benzo(a)pyrene-d12bis(2-chloroethyl)ether-d84-chloroaniline-d42-chlorophenol-d42,4-dichlorophenol-d3dimethylphthalate-d64,6-dinitro-2-methylphenol-d

fluoranthene-d10fluorene-d102-methylnaphthalene-d104-methylphenol-d8nitrobenzene-d52-nitrophenol-d44-nitrophenol-d4phenol-d5pyrene-d10

SOM01.1 Deuterated Monitoring Compound Mix

w/ SIM Compounds (18 components)


fluoranthene-d10 2-methylnaphthalene-d10

SOM01.1 Deuterated Monitoring Compound Mix

SIM Compounds


acenaphthene2,4-dinitrotoluene

N-nitroso-di-n-propylaminepyrene

SOM01.1 SVOA B/N Matrix Spike Mix



2-methylnonaneCCME F2 Surrogate Standard


SOM01.1 (Semivolatiles), QA Mixes cont'd


www.restek.com 445


EPA Super fund Contract Lab Program (CLP)04.2, 04.1, 4/89, and 3/90 SOW (Semivolatiles),QA Mixes cont'd

2-chlorophenol-d4 1,500µg/mL1,2-dichlorobenzene-d4 1,0002-fluorobiphenyl 1,0002-fluorophenol 1,500

nitrobenzene-d5 1,000phenol-d6 1,500p-terphenyl-d14 1,0002,4,6-tribromophenol 1,500

CLP 04.1 BNA Surrogate Mix (8 components)


acenaphthene2,4-dinitrotoluene

N-nitroso-di-n-propylaminepyrene

CLP 04.1 B/N Matrix Spike Mix


4-chloro-3-methylphenol2-chlorophenol4-nitrophenol

pentachlorophenolphenol

Acid Matrix Spike Mix




di-n-octyl phthalatephenanthrene

phenolSV Screening Mix


1,2-dichlorobenzene-d42-fluorobiphenyl

nitrobenzene-d5p-terphenyl-d14

B/N Surrogate Standard Mix (3/90 SOW)





p-terphenyl-d14B/N Surrogate Mix (4/89 SOW)





acenaphthene1,4-dichlorobenzene2,4-dinitrotoluene

N-nitroso-di-n-propylaminepyrene1,2,4-trichlorobenzene

B/N Matrix Spike Mix





Low Concentration Semivolatiles, QA Mixes

2-fluorophenol 1,000µg/mLphenol-d6 1,000

2,4,6-tribromophenol 3,000L/C Acid Surrogate Mix


2-chlorophenolphenol

2,4,6-trichlorophenolL/C Acid Lab Control Sample


AAmmppuull 11::benzo(a)pyrenebis(2-chloroethyl)etherdiethyl phthalate2,4-dinitrotolueneN-nitroso-di-n-propylaminehexachlorobenzene

hexachlorethaneisophoronenaphthaleneN-nitrosodiphenylamine1,2,4-trichlorobenzene

L/C B/N Lab Control Sample (12 components)For extended shelf life, 4-chloroaniline is provided as a separate solution.

AAmmppuull 22::4-chloroaniline

1,000µg/mL each in methylene chloride (4-chloroaniline at 2,000µg/mL), 1mL/ampulcat. # 31241 (ea.)







Neat, 1gcat. # 33027 (ea.)

also availableSee ppaaggeess 554477--556655 for chromatograms of semivolatiles analysis.


446 www.restek.com



CCLLPP OOLLMM 0044..11 SSeemmiivvoollaattiilleess DDiilluuttiioonnAtrazine and benzaldehyde react quickly with the methanol stabilizer used in mostbrands and grades of methylene chloride. This reaction will prevent you fromobtaining stable, working-level calibration standards. We prepare CCLLPP 0044..11 BB//NNMMeeggaaMMiixx®® and our BBeennzzaallddeehhyyddee standard from methylene chloride that is stabi-lized with amylene and is completely free of methanol. We strongly recommendscreening the methylene chloride used to dilute these mixtures and confirming thatit is free of methanol.

04.2 and 04.1 (Semivolatiles), Calibration Mixes

4-chloro-3-methylphenol2-chlorophenol2,4-dichlorophenol2,4-dimethylphenol2,4-dinitrophenol2-methyl-4,6-dinitrophenol2-methylphenol

4-methylphenol2-nitrophenol4-nitrophenolpentachlorophenolphenol2,4,5-trichlorophenol2,4,6-trichlorophenol

CLP 04.1 Phenols Calibration Mix (14 components)


benzidine 3,3'-dichlorobenzidineBenzidine Mix


SOM01.1 (Semivolatiles), Calibration Mixes

acenaphtheneacenaphthyleneacetophenoneanthraceneatrazinebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(ghi)perylenebenzo(k)fluoranthenebenzyl butyl phthalatebiphenylbis(2-chloroethoxy)methanebis(2-chloroethyl)etherbis(2-chloroisopropyl)ether

(2,2'-oxybis(1-chloropropane))bis(2-ethylhexyl)phthalate4-bromophenyl-phenyletherε-caprolactamcarbazole4-chloroaniline4-chloro-3-methylphenol2-chloronaphthalene2-chlorophenol4-chlorophenyl-phenyletherchrysenedibenzo(a,h)anthracenedibenzofuran3,3'-dichlorobenzidine2,4-dichlorophenoldiethylphthalate2,4-dimethylphenoldimethylphthalatedi-n-butylphthalate4,6-dinitro-2-methylphenol

2,4-dinitrophenol2,4-dinitrotoluene2,6-dinitrotoluenedi-n-octyl phthalatediphenylamine1

fluoranthenefluorenehexachlorobenzenehexachloro-1,3-butadiene

(hexachlorobutadiene)hexachlorocyclopentadienehexachloroethaneindeno(1,2,3-cd)pyreneisophorone2-methylnaphthalene2-methylphenol (o-cresol)3-methylphenol (m-cresol)*4-methylphenol (p-cresol)*naphthalene2-nitroaniline3-nitroaniline4-nitroanilinenitrobenzene2-nitrophenol4-nitrophenolN-nitroso-di-n-propylaminepentachlorophenolphenanthrenephenolpyrene1,2,4,5-tetrachlorobenzene2,3,4,6-tetrachlorophenol2,4,5-trichlorophenol2,4,6-trichlorophenol

*3-methylphenol and 4-methylphenol concentration is 500µg/mL.1 N-nitrosodiphenylamine (CLP-listed analyte) decomposes to diphenylamine(mix component) in the injector.

SOM01.1 SVOA MegaMix® (67 components)


33019: SOM01.1 SVOA MegaMix 1,000µg/mL33017: Benzaldehyde 2,000µg/mL

SOM01.1 SVOA MegaMix® Kit


acenaphtheneacenaphthyleneacetophenoneanthraceneatrazinebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(ghi)perylenebenzo(k)fluoranthenebenzyl butyl phthalatebiphenylbis(2-chloroethoxy)methanebis(2-chloroethyl)etherbis(2-chloroisopropyl)ether

(2,2'-oxybis(1-chloropropane))bis(2-ethylhexyl)phthalate4-bromophenyl phenyl etherε-caprolactamcarbazole4-chloroaniline2-chloronaphthalene4-chlorophenyl phenyl etherchrysenedibenzo(a,h)anthracenedibenzofuran

diethylphthalatedimethylphthalatedi-n-butyl phthalate2,4-dinitrotoluene2,6-dinitrotoluenedi-n-octyl phthalatediphenylamine1

fluoranthenefluorenehexachlorobenzenehexachloro-1,3-butadiene

(hexachlorobutadiene)hexachlorocyclopentadienehexachloroethaneindeno(1,2,3-cd)pyreneisophorone2-methylnaphthalenenaphthalene2-nitroaniline3-nitroaniline4-nitroanilinenitrobenzeneN-nitroso-di-n-propylaminephenanthrenepyrene

1 N-nitrosodiphenylamine (CLP-listed analyte) decomposes to diphenylamine(mix component) in the injector.

CLP 04.1 B/N MegaMix® (49 components)


33018: CLP 04.1 B/N MegaMix 1,000µg/mL33017: Benzaldehyde 2,000µg/mL

CLP 04.1 B/N MegaMix® Kit


Benzaldehyde


Benzaldehyde


kit

kit

also availableSee ppaaggee 7788 for details on our Rxi®-5Sil MSCapillary Columns for semivolatiles analysis.

tech tip


www.restek.com 447


EPA Super fund Contract Lab Program (CLP)4/89 and 3/90 SOW (Semivolatiles), Calibration Mixes

benzyl alcohol4-chloroaniline2-nitroaniline

3-nitroaniline4-nitroaniline

SV Calibration Mix #1


benzoic acid4-chloro-3-methylphenol2-chlorophenol2,4-dichlorophenol2,4-dimethylphenol2,4-dinitrophenol2-methyl-4,6-dinitrophenol2-methylphenol

4-methylphenol2-nitrophenol4-nitrophenolpentachlorophenolphenol2,4,5-trichlorophenol2,4,6-trichlorophenol

SV Calibration Mix #2 (15 components)


bis(2-chloroethoxy)methanebis(2-chloroethyl)etherbis(2-chloroisopropyl)etherbis(2-ethylhexyl)phthalate4-bromophenyl phenyl etherbutyl benzyl phthalate2-chloronaphthalene

4-chlorophenyl phenyl etherdimethylphthalatedi-n-butylphthalatedi-n-octylphthalate N-nitrosodimethylamineN-nitroso-di-n-propylamineN-nitrosodiphenylamine



carbazoledibenzofurandiethyl phthalate2,4-dinitrotoluene2,6-dinitrotoluenehexachlorobenzenehexachlorobutadiene

hexachlorocyclopentadienehexachloroethaneisophorone2-methylnaphthalenenitrobenzene1,2,4-trichlorobenzene







aldrinα-BHCβ-BHCδ-BHCγ-BHC (lindane)4,4'-DDD4,4'-DDE4,4'-DDTdieldrin

endosulfan Iendosulfan IIendosulfan sulfateendrinendrin aldehydeendrin ketoneheptachlorheptachlor epoxide (isomer B)methoxychlor


2,000µg/mL each in toluene:hexane (1:1), 1mL/ampulcat. # 31012 (ea.)

1,2-dichlorobenzene1,3-dichlorobenzene

1,4-dichlorobenzeneSV Calibration Mix #7


3,3'-Dichlorobenzidine2,000µg/mL in methanol, 1mL/ampul

cat. # 31026 (ea.) 2,000µg/mL in methylene chloride, 1mL/ampul

cat. # 31835 (ea.)




benzidine3,3'-dichlorobenzidine

3,3'-dimethylbenzidine8270 Benzidines Mix




31007: SV Calibration Mix #1 (anilines)31008: SV Calibration Mix #2 (phenols)31009: SV Calibration Mix #3 (base neutrals)31010: SV Calibration Mix #4 (base neturals)31011: SV Calibration Mix #5 (PAHs)31013: SV Calibration Mix #7 (dichlorobenzenes)31026: 3,3'-dichlorobenzidine

CLP Semivolatile Calibration Kit #2 (without pesticides)


31007: SV Calibration Mix #1 (anilines)31008: SV Calibration Mix #2 (phenols)31009: SV Calibration Mix #3 (base neutrals)31010: SV Calibration Mix #4 (base neturals)31011: SV Calibration Mix #5 (PAHs)31013: SV Calibration Mix #7 (dichlorobenzenes)31030: 605 Benzidines Calibration Mix (benzidine & 3,3'-dichlorobenzidine)

Semivolatile Calibration Kit #3 (with benzidine)



kit

kit


448 www.restek.com



03.2 (Semivolatiles), Calibration Mixes

acenaphthylene-d8 anthracene-d10 benzo(a)pyrene-d12 4-chloroaniline-d4 bis-(2-chloroethyl)ether-d8 2-chlorophenol-d4 2,4-dichlorophenol-d3 dimethylphthalate-d6

4,6-dinitro-methylphenol-d2 fluorene-d10 4-methylphenol-d8 nitrobenzene-d5 2-nitrophenol-d4 4-nitrophenol-d4 phenol-d5 pyrene-d10

OLC 03.2 SVOA Deuterated Monitoring Compounds (DMC)(16 components)


3,3'-Dichlorobenzidine2,000µg/mL in methylene chloride, 1mL/ampul

cat. # 31835 (ea.)

acenaphtheneacenaphthyleneacetophenoneanthraceneatrazinebenzaldehydebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(ghi)perylenebenzo(k)fluoranthenebenzyl butyl phthalatebiphenylbis(2-chloroethoxy)methanebis(2-chloroethyl)etherbis(2-chloroisopropyl)etherbis(2-ethylhexyl)phthalate4-bromophenyl phenyl etherε-caprolactamcarbazole4-chloro-3-methylphenol2-chloronaphthalene2-chlorophenol4-chlorophenyl phenyl etherchrysenedibenzo(a,h)anthracenedibenzofurandiethylphthalate2,4-dimethylphenol

dimethylphthalatedi-n-butyl phthalate2,4-dinitrophenol2,4-dinitrotoluene2,6-dinitrotoluenedi-n-octyl phthalatefluoranthenefluorenehexachlorobenzenehexachlorobutadienehexachlorocyclopentadienehexachloroethaneindeno(1,2,3-cd)pyreneisophorone2-methylnaphthalene2-methylphenol4-methylphenolnaphthalenenitrobenzene2-nitrophenolN-nitroso-di-n-propylamineN-nitrosodiphenylaminepentachlorophenolphenanthrenephenolpyrene1,2,4,5-tetrachlorobenzene2,4,6-trichlorophenol

OLC 03.2 SVOA MegaMix® (57 components)


Low Concentration Semivolatiles, Calibration Mixes

4,6-dinitro-2-methylphenol2,4-dinitrophenol2-nitroaniline3-nitroaniline

4-nitroaniline4-nitrophenol2,4,5-trichlorophenol

Fortification Mix (7 components)


Hexachlorophene2,000µg/mL in methylene chloride, 1mL/ampul

cat. # 31811 (ea.)

2,4-dinitrophenol*2-methyl-4,6-dinitrophenol*4-nitrophenol*

pentachlorophenol*2,4,6-tribromophenol (SS)*2,4,5-trichlorophenol*

*Must be calibrated at a level different from the other listed semivolatilecompounds.

L/C Phenol Mix A


4-chloro-3-methylphenol2-chlorophenol2,4-dichlorophenol2,4-dimethylphenol2-fluorophenol2-methylphenol

4-methylphenol2-nitrophenolphenolphenol-d6 (SS)2,4,6-trichlorophenol

L/C Phenol Mix B (11 components)


2-nitroaniline*3-nitroaniline*

4-nitroaniline*

*Must be calibrated at a level different from the other listed semivolatilecompounds.

L/C Aniline Mix A


4-chloroanilineL/C Aniline Mix B


31024: B/N Surrogate Mix (4/89 SOW)31009: SV Calibration Mix #331010: SV Calibration Mix #431011: SV Calibration Mix #531026: 3,3'-dichlorobenzidine31001: SV Tuning Compound (DFTPP)

Additional Required SV Calibration Mixes:

See pages 445 and 447 for mix compositions.

GPC Calibration Mix

bis(2-ethylhexyl) phthalate 10mg/mLcorn oil 250methoxychlor 2.0

perylene 0.2sulfur 0.8

CLP GPC Calibration Mix

Qualitative mixture useful for determining GPC dump/collecttimes. The compounds are dissolved in methylene chloride at theconcentrations listed.



bis(2-ethylhexyl) phthalate 5mg/mLcorn oil 250methoxychlor 1.0

perylene 0.2sulfur 0.8

Revised GPC Calibration Mix



did you know?Our PPeessttiicciiddee MMaattrriixx SSppiikkee MMiixx (cat.# 32018, ppaaggee 445500) can be used as a GPCcalibration verification solution.




www.restek.com 449



04.2, 04.1, 03.2, 3/90, 4/89, and 2/88 SOW (Pesticides),QA Mixes

WWoorrkkiinngg wwiitthh ssoolluuttiioonnss ccoonnttaaiinniinngg ddeeccaacchhlloorroobbiipphheennyyllDecachlorobiphenyl has poor solubility in most organic solvents. The maximum concentration that can be prepared in acetone, hexane, or isooctane is 200µg/mL.Temperature will affect the solubility as well. Storing solutions at reduced tempera-tures will cause decachlorobiphenyl to precipitate.

Products containing decachlorobiphenyl must be sonicated for a minimum of 10minutes prior to opening the ampul. Because each ultrasonic bath operates at adifferent energy level, 10 minutes is a guideline only. Longer sonication time willnot affect product quality.

These precautions apply to working solutions prepared in your laboratory as well.The amount of compound that precipitates depends on concentration AND temperature. If you store your standards at a temperature lower than 4°C (evendilute solutions), allow extra sonication time.

decachlorobiphenyl 2,4,5,6-tetrachloro-m-xylene



2,4,5,6-Tetrachloro-m-xylene



Decachlorobiphenyl (BZ #209)



10µg/mL in isooctane, 1mL/ampulcat. # 32289 (ea.)

Dibutylchlorendate


2,4,5-trichlorophenolFlorisil® Cartridge Check Standard


γ-chlordane 1µg/mL4,4'-DDE 2dieldrin 2endosulfan I 1

endosulfan sulfate 2endrin ketone 2methoxychlor 10

Pesticide Resolution Check Mix (7 components)

In hexane, 1mL/ampulcat. # 32001 (ea.)

γ-chlordane 1µg/mL4,4'-DDE 2decachlorobiphenyl (SS) 2dieldrin 2endosulfan I 1

endosulfan sulfate 2endrin ketone 2methoxychlor 102,4,5,6-tetrachloro-m-xylene (SS) 2

Pesticide Resolution Check Mix w/Surrogates (9 components)


α-BHC 1µg/mLβ-BHC 1γ-BHC (lindane) 1

4,4'-DDT 10endrin 5methoxychlor 25

Pesticide Performance Evaluation Mix


α-BHC 1µg/mLβ-BHC 1γ-BHC (lindane) 14,4'-DDT 10

decachlorobiphenyl (SS) 2endrin 5methoxychlor 252,4,5,6-tetrachloro-m-xylene (SS) 2

Pesticide Performance Evaluation Mix w/Surrogates(8 components)





04.2, 04.1, 03.2, 3/90, 4/89, and 2/88 SOW (Pesticides),QA Mixes cont'd

SOM01.1 (Pesticides), QA Mixes

decachlorobiphenyl 200µg/mL2,4,5,6-tetrachloro-m-xylene 100



aldrin 10µg/mLα-BHC 10β-BHC 10δ-BHC 10γ-BHC (lindane) 10α-chlordane 10γ-chlordane 10decachlorobiphenyl (SS) 20dieldrin 204,4'-DDD 204,4'-DDE 204,4'-DDT 20

endosulfan I 10endosulfan II 20endosulfan sulfate 20endrin 20endrin aldehyde 20endrin ketone 20heptachlor 10heptachlor epoxide (isomer B) 10methoxychlor 1002,4,5,6-tetrachloro-m-xylene (SS) 10

Organochlorine Pesticide Resolution Check Mix

(with surrogates) (22 components)

In hexane:toluene, 1mL/ampulcat. # 32454 (ea.)

tech tip


450 www.restek.com



aldrin 10µg/mLα-BHC 5β-BHC 10δ-BHC 10α-chlordane 10γ-chlordane 10

4,4'-DDD 204,4'-DDE 10endosulfan sulfate 20endrin 10endrin ketone 20

Pesticide Standard Mix B (2/88 SOW) (11 components)


α-BHC 5µg/mLγ-BHC (lindane) 54,4'-DDD 104,4'-DDT 10dieldrin 10

endosulfan I 5endrin 10heptachlor 5methoxychlor 50

Pesticide Standard Mix A (9 components)


aldrin 5µg/mLβ-BHC 5δ-BHC 5α-chlordane 5γ-chlordane 54,4'-DDE 10

endosulfan II 10endosulfan sulfate 10endrin aldehyde 10endrin ketone 10heptachlor epoxide (isomer B) 5

Pesticide Standard Mix B (11 components)






aldrin 8µg/mLα-BHC 8β-BHC 8δ-BHC 8γ-BHC (lindane) 8α-chlordane 8γ-chlordane 84,4'-DDD 164,4'-DDE 164,4'-DDT 16

dieldrin 16endosulfan I 8endosulfan II 16endosulfan sulfate 16endrin 16endrin aldehyde 16endrin ketone 16heptachlor 8heptachlor epoxide (isomer B) 8methoxychlor 80







CLP Pesticides Mixtures, Calibration Mixes

CLP Pesticides Mixtures, Calibration Mixes cont'd

aldrin 10µg/mLγ-BHC (lindane) 54,4'-DDT 20dieldrin 10endosulfan I 10

endosulfan II 20endrin aldehyde 25heptachlor 10heptachlor epoxide (isomer B) 10methoxychlor 100

Pesticide Standard Mix A (2/88 SOW) (10 components)


Low Concentration Pesticides Mixtures, QA Mixes

γ-BHC (lindane) 10µg/mLγ-chlordane 104,4'-DDE 20dieldrin 20

endosulfan sulfate 20endrin 20heptachlor epoxide (isomer B) 10

L/C Pesticide Lab Control Sample (7 components)


CLP Pesticides Mixtures, QA Mixes

aldrin 25µg/mLγ-BHC (lindane) 254,4'-DDT 50

dieldrin 50endrin 50heptachlor 25

Pesticide Matrix Spike Mix


aldrin 200µg/mLγ-BHC (lindane) 2004,4'-DDT 500

dieldrin 500endrin 500heptachlor 200

Pesticide Matrix Spike Mix (2/88 SOW)


aldrindibutylchlorendate (SS)

4,4'-DDTendrin

See complete listing of PCBs, page 452.

Pesticide Evaluation Mix (2/88 SOW)



www.restek.com 451



Pesticides Calibration Mixtures

Technical Chlordane, Toxaphene Solutions

Aroclor Solutions

α-BHC 8µg/mLγ-BHC (lindane) 84,4'-DDD 164,4'-DDT 16decachlorobiphenyl (SS) 16dieldrin 16

endosulfan I 8endrin 16heptachlor 8methoxychlor 802,4,5,6-tetrachloro-m-xylene (SS) 8

Pesticide Standard Mix A w/Surrogates (11 components)


aldrin 8µg/mLβ-BHC 8δ-BHC 8α-chlordane 8γ-chlordane 84,4'-DDE 16decachlorobiphenyl (SS) 16

endosulfan II 16endosulfan sulfate 16endrin aldehyde 16endrin ketone 16heptachlor epoxide (isomer B) 82,4,5,6-tetrachloro-m-xylene (SS) 8

Pesticide Standard Mix B w/Surrogates (13 components)


Components of these products are at 16x the Contract RequiredQuantitation Level (CRQL) and can be used to prepare calibra-tion mixes at 4x CRQL and at 1x CRQL by serial dilution.

please noteWe test our transformer oil solvent to ensure that it is PCB-free.

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceechlordane (technical) H 1,000 32021chlordane (technical) I 5,000 32072chlordane (technical) M 2,000 32016toxaphene H 1,000 32005toxaphene I 5,000 32071toxaphene M 2,000 32015

H = hexaneI = isooctaneM = methanol




CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeAroclor 1016 H 1,000 32006Aroclor 1016 I 200 32064Aroclor 1016 TO 50mg/kg 32075Aroclor 1016 TO 500mg/kg 32076Aroclor 1221 H 1,000 32007Aroclor 1221 I 200 32065Aroclor 1221 TO 50mg/kg 32077Aroclor 1221 TO 500mg/kg 32078Aroclor 1232 H 1,000 32008Aroclor 1232 I 200 32066Aroclor 1232 TO 50mg/kg 32079Aroclor 1232 TO 500mg/kg 32080Aroclor 1242 H 1,000 32009Aroclor 1242 I 200 32067Aroclor 1242 TO 50mg/kg 32081Aroclor 1242 TO 500mg/kg 32082Aroclor 1248 H 1,000 32010Aroclor 1248 I 200 32068Aroclor 1248 TO 50mg/kg 32083Aroclor 1248 TO 500mg/kg 32084Aroclor 1254 H 1,000 32011Aroclor 1254 I 200 32069Aroclor 1254 TO 50mg/kg 32085Aroclor 1254 TO 500mg/kg 32086Aroclor 1260 H 1,000 32012Aroclor 1260 I 200 32070Aroclor 1260 TO 50mg/kg 32087Aroclor 1260 TO 500mg/kg 32088Aroclor 1262 H 1,000 32409Aroclor 1268 H 1,000 32410Aroclor 1016/1260 H 1,000 32039Aroclor 1016/1260 I 200 32299Aroclor 1016/1260 A 400 3245632003: Pesticide Standard Mix A w/Surrogates

32004: Pesticide Standard Mix B w/Surrogates32005: Toxaphene32007: Aroclor 122132008: Aroclor 123232009: Aroclor 124232010: Aroclor 124832011: Aroclor 125432039: Aroclor 1016/1260

Pesticide Kit #3

Calibration mixes only for CLP 04.1. Includes pesticide standard mixes A & B at16x CRQL with surrogates.


AAcchhiieevviinngg tthhee BBeesstt RReessuullttss ffrroomm GGaass SSttaannddaarrddssIn order to achieve the best results from gas standards, proper handling and storage of gas solutions is of vital importance. Use the following tips to helpensure trouble-free performance:

• Before opening the sealed ampul, warm it to room temperature and invert ampulseveral times. This will redissolve any gases that may have migrated into theheadspace of the ampul.

• When diluting a gas standard, always add it to a solvent. Adding the gas standard to an empty vessel prior to adding solvent will result in the loss of gas compounds.

• When diluting a gas standard in solvent, make sure the pipette or needle tip isdirectly above, or immersed below, the solvent surface.

• We recommend that any unused portion of gas standard be disposed of after ithas been removed from the sealed ampul. If it is necessary to store the unusedportion, place it into a tightly capped vial and store it in the freezer.

• We recommend that any gas solutions that have been stored outside of a sealedampul be disposed of after 7 days.

kit

tech tip

also availableSee ppaaggeess 8800--8811 for Rtx®-CLPesticides and Rtx®-CLPesticide2 capillary columns for pesticides analysis.

See ppaaggee 445522 for our complete listing of PCBs and congeners.


452 www.restek.com


PCBs, Organotin

also availableAdditional PCB congener mixes:

See EPA Method 8082: cat.# 32416 ppaaggee 442299..

See EPA Method 525: cat.# 32420 ppaaggee 441144.

2,4,4'-trichlorobiphenyl (BZ #28)2,2',5,5'-tetrachlorobiphenyl (BZ #52)2,2',4,5,5'-pentachlorobiphenyl (BZ #101)2,2',3,4,4',5'-hexachlorobiphenyl (BZ #138)2,2',4,4',5,5'-hexachlorobiphenyl (BZ #153)2,2',3,4,4',5,5'-heptachlorobiphenyl (BZ #180)

PCB Congener Standard #1


2,4,4'-trichlorobiphenyl (BZ #28)2,2',5,5'-tetrachlorobiphenyl (BZ #52)2,2',4,5,5'-pentachlorobiphenyl (BZ #101)2,3',4,4',5-pentachlorobiphenyl (BZ #118)2,2',3,4,4',5'-hexachlorobiphenyl (BZ #138)2,2',4,4',5,5'-hexachlorobiphenyl (BZ #153)2,2',3,4,4',5,5'-heptachlorobiphenyl (BZ #180)



butyltin trichloridedibutyltin dichloride

tetrabutyltintributyltin chloride

Butyltin Chloride Calibration Mixture


Tributyltin Chloride Calibration Mixture


diphenyltin dichloridephenyltin trichloride

tetraphenyltintriphenyltin chloride

Phenyltin Chloride Calibration Mixture


Tri-n-propyltin Chloride Surrogate


Tripentyltin Chloride Surrogate


Tetra-n-propyltin Internal Standard2,000µg/mL in methylene chloride, 1mL/ampul

cat. # 31474 (ea.)

Tetrapentyltin Internal Standard


Organotin Mixes

PCB Congeners

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee2,4,4'-trichlorobiphenyl (BZ #28) I 10 322832,2',5,5'-tetrachlorobiphenyl (BZ #52) I 10 322842,2',4,5,5'-pentachlorobiphenyl (BZ #101) I 10 322852,3',4,4',5-pentachlorobiphenyl (BZ #118) I 10 322932,2',3,4,4',5'-hexachlorobiphenyl (BZ #138) I 10 322862,2',4,4',5,5'-hexachlorobiphenyl (BZ #153) I 10 322872,2',3,4,4',5,5'-heptachlorobiphenyl (BZ #180) I 10 32288decachlorobiphenyl (BZ #209) I 10 32289

I = isooctane


PCB Congeners cont'd

32006: Aroclor 101632007: Aroclor 122132008: Aroclor 123232009: Aroclor 124232010: Aroclor 124832011: Aroclor 125432012: Aroclor 1260

PCB Kit #1

1,000µg/mL each in hexane, 1mL/ampulcat. # 32089 (kit)

32064: Aroclor 101632065: Aroclor 122132066: Aroclor 123232067: Aroclor 124232068: Aroclor 124832069: Aroclor 125432070: Aroclor 1260

PCB Kit #2

200µg/mL each in isooctane, 1mL/ampulcat. # 32090 (kit)

32007: Aroclor 122132008: Aroclor 123232009: Aroclor 124232010: Aroclor 124832011: Aroclor 125432039: Aroclor 1016/1260

PCB Kit #3

1,000µg/mL each in hexane, 1mL/ampulcat. # 32400 (kit)

32065: Aroclor 122132066: Aroclor 123232067: Aroclor 124232068: Aroclor 124832069: Aroclor 125432299: Aroclor 1016/1260

PCB Kit #4

200µg/mL each in isooctane, 1mL/ampulcat. # 32401 (kit)

PCB Kits

kit

kit

kit

kit


www.restek.com 453


Minnesota Dept. of Agriculture Pesticides

Minnesota Dept. of Agriculture List 1 Pesticides on an Rxi®-1ms column.

acetochloralachloratrazinecyanazinedesethylatrazinedesisopropylatrazinedimethenamid*ethalfluralin

metolachlormetribuzinpendimethalinprometonpropachlorpropazinesimazinetrifluralin

*Added to Minnesota Department of Agriculture List 1 pesticide (neutrals) inci-dent investigation requirements, effective January 1, 2000.¹ CAS # 87674-68-8manufactured by several companies under various trade names.¹Analytical Lists for Pesticide Incident Investigations, Minnesota Department ofAgriculture, Guidance Document 26 (3/99), St. Paul, MN. For a copy, visit theirweb site at: www.mda.state.mn.us

Minnesota Ag List 1 Pesticides Mix A (16 components)

200ppm each in acetone, 1mL/ampulcat. # 32406 (ea.)

chlorpyrifosEPTCfonofos

phorateterbufostriallate

Minnesota Ag List 1 Pesticides Mix B

200ppm each in acetone, 1mL/ampulcat. # 32407 (ea.)

Minnesota Department of Agriculture List 1 Pesticides

32406: Minnesota Ag List Pesticides Mix A32407: Minnesota Ag List Pesticides Mix B

Minnesota Ag List 1 Pesticide Kit


GC_EV00837

1. 2-fluorophenol (SS)2. phenol-d6 (SS)3. 1,4-dichlorobenzene-d4 (IS)4. nitrobenzene-d5 (SS)5. naphthalene-d8 (IS)6. EPTC7. 2-fluorobiphenyl (SS)8. acenaphthene-d10 (IS)9. propachlor

10. desisopropyl atrazine11. desethyl atrazine12. 2,4,6-tribromophenol (SS)13. ethalfluralin14. trifluralin15. phorate16. simazine17. prometon18. atrazine

19. propazine20. terbufos21. fonofos22. phenanthrene-d10 (IS)23. triallate24. metribuzin25. dimethenamid26. acetochlor27. alachlor28. cyanazine29. metolachlor30. chlorpyrifos31. pendimethalin32. p-terphenyl-d14 (SS)33. chrysene-d12 (IS)34. perylene-d12 (IS)

Column: Rxi®-1ms, 30m, 0.25mm ID, 0.25µm (cat.# 13323)

Sample: Minnesota Ag List 1 Pesticides Mix A (cat.# 32406), Minnesota Ag List 1 Pesticides Mix B (cat.# 32407), SV Internal Standard Mix (cat.# 31206), B/N Surrogate Mix (4/89 SOW) (cat.# 31024), Acid Surrogate Mix (4/89 SOW) (cat.# 31025)

Inj.: 1.0µL, 10µg/mL each analyte (internal standards 25µg/mL), split (10:1)4mm Drilled Uniliner® inlet liner (hole near bottom) (cat.# 20771)

Instrument: Agilent 6890Inj. temp.: 250°CCarrier gas: helium, constant flowFlow rate: 1.2mL/min.Oven temp.: 70°C (hold 1 min.) to 180°C @ 20°C/min.,

to 230°C @ 5°C/min., to 325°C @ 40°C/min. (hold 3.5 min.)

Det.: Agilent 5973 MSDTransfer line

temp.: 280°CScan range: 35-550amuSolvent delay: 2.50 min.Tune: DFTPPIonization: EI

kit


454 www.restek.com


International Mixes

aldicarbbendiocarbcarbaryl (Sevin)

carbofurantriallate

Canadian Drinking Water Carbamates Mix


aldrinγ-BHC (lindane)α-chlordaneγ-chlordane2,4'-DDE4,4'-DDE2,4'-DDT

4,4'-DDTdieldrinheptachlorheptachlor epoxide (isomer B)methoxychloroxychlordanetrifluralin

Canadian Drinking Water Chlorinated Pesticides Mix(14 components)

200µg/mL each in hexane:toluene, 1mL/ampulcat. # 31866 (ea.)

azinphos methyl (Guthion)chlorpyrifos (Dursban)Diazinondimethoatemalathion

parathion (ethyl)phoratetemephos (Abate)terbufos

Canadian Drinking Water OP Pesticides Mix (9 components)


Canada cont'd

Canada

n-pentacontane (C50)C50 in Toluene

10µg/mL in toluene, 1mL/ampulcat. # 31685 (ea.)

n-undecane (C11)CCME F1 Surrogate Standard


2-methylnonaneCCME F2 Surrogate Standard


n-decane (C10)n-hexane (C6)

tolueneCCME F1 Retention Time Marker


benzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(k)fluoranthenedibenzo(a,h)anthracene

fluorantheneindeno(1,2,3-cd)pyrenenaphthalenephenanthrenepyrene

CCME PAH Calibration Mix (10 components)


n-decane (C10)n-hexadecane (C16)

n-tetratriacontane (C34)CCME PHC Calibration Mix

5,000µg/mL each in toluene, 1mL/ampulcat. # 31684 (ea.)

benzenebromodichloromethanebromoformcarbon tetrachloridechlorobenzenechloroformdibromochloromethane1,2-dichlorobenzene1,4-dichlorobenzene1,2-dichloroethane

1,1-dichloroetheneethylbenzenemethylene chloridetetrachloroethenetoluenetrichloroethenem-xyleneo-xylenep-xylene

Canadian Drinking Water Volatiles Mix (19 components)


alachloratrazinecyanazine (Bladex)metolachlor

metribuzinprometrynesimazine

Canadian Drinking Water Triazine Herbicides Mix(7 components)


bromoxynil2,4-Ddicamba2,4-dichlorophenoldiclofop methyldinoseb

pentachlorophenolpicloram2,4,5-T2,3,4,6-tetrachlorophenol2,4,6-trichlorophenol

Canadian Drinking Water Phenoxyacid Herbicides Mix(11 components)


CCoouunnttrryy//MMiisscceellllaanneeoouuss CCoommppoouunndd CCllaassss

Canada: CCME . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Alkanes; PAHs

Canada: Drinking Water . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatiles; Pesticides

Canada: RBCA - Atlantic Provinces . . . . . . . . . . . . .Aromatics; Aliphatics; PAHs

European Union . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Pesticides

Japan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Odor Compounds

Korea . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatiles; Pesticides

ISO/DIS-9377 Water Quality Testing . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

International Environmental Mixes


also availablePPeettrroolleeuumm SSttaannddaarrddss && SSuullffuurr SSttaannddaarrddss!!See pages 472-475 for more information.

454-456_ARM_intnl.qxp 11/20/2008 9:11 AM Page 454

www.restek.com 455


International MixesCanada - Atlantic Provinces

acenaphtheneanthracenebenzo(a)pyrenechrysenen-decane (C10)n-dodecane (C12)

n-dotriacontane (C32)n-heneicosane (C21)n-hexadecane (C16)n-octacosane (C28)naphthalene

Atlantic RBCA EPH Mix (11 components)

1,000µg/mL each in hexane:methylene chloride, 1mL/ampulcat. # 31872 (ea.)

n-dotriacontane (C32) isobutylbenzeneAtlantic RBCA EPH Surrogate Standard


benzenen-decane (C10)ethylbenzenen-heptane (C7)n-hexane (C6)1-methyl-3-ethylbenzene

n-octane (C8)toluene1,2,4-trimethylbenzene1,3,5-trimethylbenzeneo-xylenep-xylene

Atlantic RBCA VPH Mix (12 components)


isobutylbenzeneAtlantic RBCA VPH Surrogate Standard


Europe

acephate 200µg/mLazinphos methyl (Guthion) 400chlorpyrifos 100demeton-s-methyl 200dichlorvos (DDVP) 500dimethoate 200ethion 200malathion 200

methamidophos 500methidathion 200omethoate 1,000pirimiphos methyl 100profenfos 200pyrazophos 500tokuthion (prothiofos) 200tolclofos-methyl 100

Organophosphorus Pesticide Mix, European Formulation(16 components)


2,4,4'-trichlorobiphenyl (BZ #28)2,2',5,5'-tetrachlorobiphenyl (BZ #52)2,2',4,5,5'-pentachlorobiphenyl (BZ #101)2,2',3,4,4',5'-hexachlorobiphenyl (BZ #138)2,2',4,4',5,5'-hexachlorobiphenyl (BZ #153)2,2',3,4,4',5,5'-heptachlorobiphenyl (BZ #180)



2,4,4'-trichlorobiphenyl (BZ #28)2,2',5,5'-tetrachlorobiphenyl (BZ #52)2,2',4,5,5'-pentachlorobiphenyl (BZ #101)2,3',4,4',5-pentachlorobiphenyl (BZ #118)2,2',3,4,4',5'-hexachlorobiphenyl (BZ #138)2,2',4,4',5,5'-hexachlorobiphenyl (BZ #153)2,2',3,4,4',5,5'-heptachlorobiphenyl (BZ #180)



Desethyl-atrazine1,000µg/mL in acetone, 1mL/ampul

cat. # 32445 (ea.)

Desisopropylatrazine1,000µg/mL in acetone, 1mL/ampul

cat. # 32446 (ea.)

Terbuthylazine1,000µg/mL in acetone, 1mL/ampul

cat. # 32447 (ea.)

Propazine1,000µg/mL in acetone, 1mL/ampul

cat. # 32448 (ea.)

Prometryne1,000µg/mL in acetone, 1mL/ampul

cat. # 32449 (ea.)

Japan

acrylonitrilebenzene1,3-butadienechloroform1,2-dichloroethane

dichloromethanetetrachloroethenetrichloroethenevinyl chloride


Japan Calibration Mix (9 components)


(+/-)-geosmin 2-methylisoborneol

Drinking Water Odor Standard

Unpleasant odor in drinking water is associated with the growthand decay of microorganisms. The threshold value for thesecompounds is low (10ppt) and purge and trap analyses usuallyare used to quantify them.


Europe cont'd








456 www.restek.com


International Mixes

stearyl stearateStearyl Stearate Test Solution


2,000µg/mL in cyclohexane, 10mL/ampul (enough to check one Florisil cartridge)cat. # 31636 (ea.)

diesel fuel #2 composite motor oil

Florisil® Cartridge Quality Control Standard Mixture, Rev.3


diesel fuel #2 composite mineral oil

Florisil® Cartridge Quality Control Standard Mixture, Rev.2


n-Tetracontane (C40)Neat, 100mg

cat. # 31859 (ea.)

n-Decane (C10)Neat, 1mL/ampul

cat. # 31858 (ea.)

Stearyl StearateNeat, 100mg

cat. # 31860 (ea.)

n-decane (C10) 20µL/L n-tetracontane (C40) 20mg/LExtraction Solvent Stock Solution #2


ISO/DIS 9377 Water Quality Testing

• For GC analysis of total petroleum hydrocarbons (TPH) in water.

• Calibration standard available as Diesel #2/ motor oil andDiesel #2/mineral oil.

Reference mixtures for ISO/DIS 9377 (German H-53), a gaschromatography/flame ionization detection (GC/FID) method.

diesel fuel #2 composite motor oilDiesel #2/Motor Oil


diesel fuel #2 composite mineral oilDiesel #2/Mineral Oil


diesel #2 (additive-free)mineral oil (additive-free [i.e., USP grade] bp 325-460

or C18-C32 retention time range)

Standard Mixture Stock Solution

5,000µg/mL each in cyclohexane, 1mL/ampul (prepares 8mL of 1.25µg/µL calibration curve high point) Total hydrocarbon concentration 10,000µg/mL

cat. # 31630 (ea.)

diesel #2 (additive-free)motor oil (additive-free bp 325–460 or C18–C32 retention time range)

Quality Control Standard Mixture, Revised

500µg/mL each in acetone, 1mL/ampul (1mL is enough mix to spike one 900mL quality control sample). Total hydrocarbon concentration 1,000µg/mL

cat. # 31641 (ea.)

Quality Control Standard Mixture

diesel #2 (additive-free)mineral oil (additive-free [i.e., USP grade] bp 391–522

or C24–C40 retention time range)500µg/mL each in acetone, 1mL/ampul (1mL is enough mix to spike one quality control sample). Total hydrocarbon concentration 1,000µg/mL

cat. # 31631 (ea.)

n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)n-eicosane (C20)n-docosane (C22)n-tetracosane (C24)

n-hexacosane (C26)n-octacosane (C28)n-triacontane (C30)n-dotriacontane (C32)n-tetratriacontane (C34)n-hexatriacontane (C36)n-octatriacontane (C38)n-tetracontane (C40)

System Performance Test Standard Mixture of n-Alkanes(16 components)


n-decane (C10) 20µL/L n-tetracontane (C40) 20mg/LExtraction Solvent Stock Solution #1


ISO/DIS 9377 Water Quality Testing cont'dKorea

carbaryl (Sevin)diazinonfenitrothion

malathionparathion, ethyl


Korean Drinking Water—Pesticides Mix

1,000µg/mL each in P&T methanol, 1mL/ampulcat. # 32411 (ea.) enquire

benzenebromodichloromethanebromoformcarbon tetrachloridechloroformdibromochloromethane1,1-dichloroetheneethylbenzenemethylene chloride

phenoltetrachloroethenetoluene1,1,1-trichloroethanetrichloroethenem-xyleneo-xylenep-xylene


Korean Drinking Water—VOC Mix A (17 components)

100µg/mL each in P&T methanol, 1mL/ampulcat. # 30480 (ea.) enquire


www.restek.com 457


UST Monitoring

Retention Time StandardsUsed during initial sample screening, to determine retentiontime windows for each petroleum product. Gasoline generallyelutes in the window from C6 to C10 (or C12), and diesel fuelfrom C10 (or C12) to C24 (or C28). Retention above C24 (orC28) indicates oil or lubricant contamination.

n-hexane (C6)n-decane (C10)n-dodecane (C12)n-tetracosane (C24)

n-octacosane (C28)n-triacontane (C30)n-tetracontane (C40)

Leaking Underground Storage Tank Retention Time Standard(7 components)

25µg/mL each in 1mL methylene chloride, 1mL/ampulcat. # 31200 (ea.)

n-decane (C10)n-pentacosane (C25)

n-hexatriacontane (C36)Retention Time Marker Standard


n-hexane (C6)n-decane (C10)

n-dodecane (C12)Retention Time Marker


n-hexane (C6)n-dodecane (C12)

n-octacosane (C28)n-pentatriacontane (C35)

TNRCC 1005 Retention Time Markers Mix

200µg/mL each in pentane, 1mL/ampulcat. # 31698 (ea.)


n-pentacosane (C25)n-hexatriacontane (C36)

Retention Time Marker - Alaska


Fuel Composite Standards

Unleaded Gasoline Composite Standard




Diesel Fuel #2 Composite Standard




Kerosene Composite Standard




Motor Oil Composite Standards

Motor Oil Composite Standard

Prepared from an equal volume blend of 5W30, 10W30, 10W40,and 20W50 motor oils. After blending, a precisely weighedamount of the composite is added to a volumetric flask to pro-duce the standard.


Used Motor Oil Composite Standard

Prepared from an equal volume blend from five gasoline pow-ered vehicles (belonging to Restek employees). After blending, aprecisely weighed amount of the composite is added to a volu-metric flask to produce the standard.


free literatureEEPPAA OOffffiiccee ooff UUnnddeerrggrroouunndd SSttoorraaggee TTaannkkss ((OOUUSSTT))RReeccoommmmeennddeedd MMeetthhooddss

Download your free copy from wwwwww..rreesstteekk..ccoomm

Fast Factslliitt.. ccaatt..## 5599339977

See ppaaggeess 446611--446677 for information on UST technicalliterature for individual states.

also availableOther fuels, oils and lubricant oils available on request as custom products.

Underground Storage Tank Monitoring (UST):General

CCaatteeggoorryy CCoommppoouunndd CCllaassss

Retention Time Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Fuel Composite Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Motor Oil Composite Standards . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Single Source Fuel Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Military Fuels (Jet Propellant) . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Fuel Oil Degradation Test . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Mineral Spirits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

PVOC, GRO and BTEX . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Gasoline Surrogate and Internal Standards . . . . . . . . . . . . . . . . . . . . . .Volatiles

Diesel Surrogate and Internal Standards . . . . . . . . . . . . . . . . . . .Hydrocarbons

Diesel/Biodiesel Blend . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

457-460_ARM_USTintro.qxp 11/20/2008 9:12 AM Page 457

458 www.restek.com


UST MonitoringSingle Source Fuels Single Source Fuels cont'd

Military Fuels (Jet Propellant)

Unleaded Gasoline Standard

Prepared from a single source (one refinery) product.5,000µg/mL in P&T methanol, 1mL/ampul

cat. # 30096 (ea.)

Kerosene Standard

Prepared from a single source (one refinery) product.5,000µg/mL in methylene chloride, 1mL/ampul

cat. # 31229 (ea.)

Diesel Fuel #2 Standard

Prepared from a single source (one refinery) product.5,000µg/mL in methylene chloride, 1mL/ampul

cat. # 31233 (ea.)

Fuel Oil #4 Standard

Fuel oil #4 is typically used in limited applications in which thefuel cannot be preheated prior to burning. The fuel is a blend ofdistillate (fuel oil #2) and residual (fuel oil #6) to meet ASTM vis-cosity specifications. Fuel oil #4 used to prepare this mixture hasa kinematic viscosity of 21.9 at 38°C (100°F), measured usingASTM D-445.5,000µg/mL in methylene chloride, 1mL/ampul


cat. # 31244 (ea.)


Fuel oil #5 is typically used in applications in which there is littleor no preheating of the fuel prior to burning. A blend of distillate(fuel oil #2) and residual (fuel oil #6), the fuel oil #5 used to pre-pare this mixture has a kinematic viscosity of 106.5 at 38°C(100°F), measured using ASTM D-445.




This fuel, sometimes called bunker C or residual, is a black vis-cous oil. Applications in which it may be used require the abilityto preheat the fuel prior to pumping and burning.




Aviation Gas Standard

100-octane low-lead fuel currently used in piston-type aircraft.




Jet Fuel A Standard

Commercial jet fuel A.5,000µg/mL in methylene chloride, 1mL/ampul



cat. # 31243 (ea.)

Creosote Oil Standard

Creosote oil, a widely used wood preservative produced by dis-tilling coal tar, contains chemicals that are classified as carcino-gens (e.g., benzo(a)pyrene). We offer this high concentrationstandard.


Hydraulic Oil Standard


JP-4 Military Fuel Standard












diesel/biodiesel 80:20

Diesel/Biodiesel 80:20 Blend Standard

The biodiesel component is methyl soyate.



www.restek.com 459


UST MonitoringFuel Oil Degradation Test

heptadecane (C17)octadecane (C18)pristane (2,6,10,14-tetramethylpentadecane)phytane (2,6,10,14-tetramethylhexadecane)

1Interpretation of Gas Chromatographic Data in Subsurface HydrocarbonInvestigations, R. Senn and M. Johnson, Ground Water Monitoring Review, Winter1987.

Fuel Oil Degradation Mix

Subsurface degradation of fuel oil spills can be estimated byexamining the ratios of C17/pristane and C18/phytane.1 To assistin identifying these four compounds from the complex fuel oilanalysis, we offer a product that contains these compounds forretention time determination.


Mineral Spirits

Mineral Spirits Standards




There are four general types of mineral spirits, classified accord-ing to boiling point range (BPR):

• Type I (Stoddard solvent) BPR 149–182°C • Type II (high flash point) BPR 177–196°C • Type III (odorless) BPR 149–196°C• Type IV (low dry point) BPR 149–174°C

We prepare our solutions from an equal volume blend of Type I,II, and III mineral spirits.

Stoddard Solvent Standard

Stoddard solvent is also known as Type I mineral spirits,Texsolve S, or Varsol® 1 mineral spirits. We offer this referencematerial for those who need to calibrate Stoddard solvent sepa-rately. This standard is dissolved in methanol for analysis byeither direct injection or purge and trap.


Petroleum Volatile Organic Compounds (PVOC),Gasoline Range Organics (GRO), & Benzene-Toluene-Ethylbenzene-Xylenes (BTEX)



BTEX Standard






BTEX Gas Mix

benzeneethylbenzenemethyl tert-butyl ether (MTBE)toluene


PVOC Mix (California) (7 components)


benzeneethylbenzenemethyl tert-butyl ether (MTBE)naphthalenetoluene

1,2,4-trimethylbenzene1,3,5-trimethylbenzenem-xyleneo-xylenep-xylene

PVOC/GRO Mix (Wisconsin) (10 components)


benzeneethylbenzene3-methylpentanenaphthalenetoluene

1,2,4-trimethylbenzene2,2,4-trimethylpentane (isooctane)m-xyleneo-xylene

GRO Mix (9 components)


benzene 500µg/mLethylbenzene 500heptane 5002-methylpentane 1,500toluene 1,500

1,2,4-trimethylbenzene 1,0002,2,4-trimethylpentane 1,500m-xylene 1,000o-xylene 1,000

GRO Mix (EPA) (9 components)


free literatureEEPPAA OOffffiiccee ooff UUnnddeerrggrroouunndd SSttoorraaggee TTaannkkss ((OOUUSSTT))RReeccoommmmeennddeedd MMeetthhooddss

Download your free copy from wwwwww..rreesstteekk..ccoomm

Fast Factslliitt.. ccaatt..## 5599339977

See ppaaggeess 446611--446677 for information on UST technicalliterature for individual states. Requires a high-purity VOC single-stage

regulator. See page 386.No data pack available.



1ppm in nitrogen, 110 liters @ 1,800psi (Pi-marked Cylinder)

cat. # 34414-PI (ea.) 100ppb in nitrogen, 110 liters @ 1,800psi (Pi-marked Cylinder)

cat. # 34428-PI (ea.)

SSppeeccttrraa 110044LL CCyylliinnddeerrss::Aluminum construction.Size: 8 x 24 cm. Volume/Pressure: 104 liters of gas @ 1,800psiCGA-180 outlet fitting.Weight: 1.5 lbs./0.7 kg

SSccoottttyy 111100LL CCyylliinnddeerrss::Aluminum construction.Size: 8.3 x 29.5 cm. Volume/Pressure: 110 liters of gas @ 1,800psiCGA-180 outlet fitting.Weight: 2.2 lbs./1 kgUS DOT Specs: 3AL2216

cylinder design


460 www.restek.com


UST MonitoringGasoline Surrogate and Internal Standards

Diesel Surrogate and Internal Standards

Petroleum Volatile Organic Compounds (PVOC),Gasoline Range Organics (GRO), & Benzene-Toluene-Ethylbenzene-Xylenes (BTEX) cont'd


1,2,4-trimethylbenzene 1,0002,2,4-trimethylpentane 1,500m-xylene 1,000o-xylene 1,000p-xylene 1,000

Gasoline Component Standard (10 components)

10,000µg/mL total in P&T methanol, 1mL/ampulcat. # 30486 (ea.)

CCeerrttiiffiieedd ffoorr::benzene*ethylbenzene*isopropyl benzene*methyl tert-butyl ether (MTBE)*naphthalene*

toluene*m-xylene*o-xylene*p-xylene*

*Concentration differs lot-to-lot. See on-line Certificate of Analysis for certifiedconcentrations.

Certified BTEX in Unleaded Gas Composite Standard(9 components)

5,500ppm gasoline in P&T methanol, 1mL/ampulcat. # 30237 (ea.)

CCeerrttiiffiieedd ffoorr::benzene*ethylbenzene*m-ethyltoluene*o-ethyltoluene*p-ethyltoluene*isopropylbenzene*methyl tert-butyl ether (MTBE)*naphthalene*

n-propylbenzene*toluene*1,2,3-trimethylbenzene*1,2,4-trimethylbenzene*1,3,5-trimethylbenzene*m-xylene*o-xylene*p-xylene*


Certified Aromatics in Gasoline (16 components)

5,500ppm gasoline in P&T methanol, 1mL/ampulcat. # 30485 (ea.)

CCeerrttiiffiieedd PPAAHHssacenaphthene*acenaphthylene*fluorene*1-methylnaphthalene*

2-methylnaphthalene*naphthalene*phenanthrene*


Certified PAHs in Diesel (7 components)

50,000ppm diesel #2 in methylene chloride, 1mL/ampulcat. # 31673 (ea.)

Diesel/Biodiesel Standard

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee4-bromofluorobenzene PTM 2,500 300674-bromofluorobenzene PTM 10,000 300821-chlorooctane PTM 10,000 30084α,α,α-trifluorotoluene PTM 2,500 30068α,α,α-trifluorotoluene PTM 10,000 30083

Recommended Internal Standard (PID) for EPA GRO Method

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee1-chloro-4-fluorobenzene PTM 2,500 30066



CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee1-chlorooctadecane D 10,000 310982-fluorobiphenyl D 10,000 31096o-terphenyl D 10,000 31097p-terphenyl D 10,000 31095

Recommended Internal Standards

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee5-α-androstane D 2,000 31065o-terphenyl A 2,000 31066

A = acetoneD = methylene chloride



The biodiesel component is methyl soyate.5,000µg/mL in methylene chloride, 1mL/ampul

cat. # 31880 (ea.)

also availableASTM Method D6584-00 and EN14105 Biodiesel Standards. See ppaaggee 447711.


www.restek.com 461


UST Monitoring

Alaska

AK101

Method for determination of aromatic and aliphatic hydrocarbonsin gasoline range organics.

Alaska Department of Environmental Conservation (ADEC) regulations indicate which products and indicator compounds areto be tested for each petroleum range. The analyst must use thefollowing Alaska Series Methods or appropriate SW-846 methodfor the indicator compounds. The Alaska UST procedurals man-ual indicates which products are to be tested for each petroleumrange.


n-pentacosane (C25)n-hexatriacontane (C36)

Retention Time Marker - Alaska


benzeneethylbenzene1-ethyl-2-methylbenzene1-ethyl-3-methylbenzene1-ethyl-4-methylbenzeneisopropylbenzenen-propylbenzene

toluene1,2,3-trimethylbenzene1,2,4-trimethylbenzene1,3,5-trimethylbenzenem-xyleneo-xylenep-xylene

Alaska UST Method AK101AA (14 components)


Alaska cont'd

Unleaded Gasoline Composite Standard




1-Chloro-4-fluorobenzene Mix


4-Bromofluorobenzene Mix


α,α,α-Trifluorotoluene




free literatureAAllaasskkaa UUSSTT MMoonniittoorriinngg

Download your free copy from wwwwww..rreesstteekk..ccoomm.

Fast Facts lliitt.. ccaatt..## 5599550033

for more infoSSttaattee ooff AAllaasskkaaMethod and regulatory information is available from:

Alaska Department of Environmental Conservation410 Willoughby AvenueJuneau, AK 99801-1795Phone: (907)465-5203Fax: (907)465-5218

www.dec.state.ak.us/regulations/index.htm


SSttaattee CCoommppoouunndd CCllaassss

Alaska . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Arizona . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

California/Los Angeles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Connecticut . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Florida . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Massachusetts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Michigan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Mississippi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Northwest (Oregon & Washington) . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Pennsylvania . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Tennessee/Mississippi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Texas . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Washington . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Wisconsin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Underground Storage Tank Monitoring (UST):State Specific Methods

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UST Monitoring

AK103

Diesel Fuel #2 Composite Standard




5-α-androstane


Alaska cont'd

o-Terphenyl



Method for determination of aromatic and aliphatic hydrocar-bons in residual range organics.

SAE30 motor oil:SAE40 motor oil (1:1)Residual Range Calibration Standard (RCS)


SAE30 motor oil:SAE40 motor oil (1:1)Residual Range Calibration Verification Standard (CVS)


Motor Oil Composite Standard



This fuel, sometimes called bunker C or residual, is a black vis-cous oil. Applications in which it may be used require the abilityto preheat the fuel prior to pumping and burning.




n-Triacontane-d62

500µg/mL in methylene chloride, 1mL/ampulcat. # 31816 (ea.)

squalaneo-terphenyl

tetrahydronaphtholSurrogate Standard Mixture


free literatureAAllaasskkaa UUSSTT MMoonniittoorriinngg



AK102

Method for determination of aromatic and aliphatic hydrocar-bons in diesel range organics.

n-decane (C10)n-undecane (C11)n-dodecane (C12)n-tridecane (C13)n-tetradecane (C14)n-pentadecane (C15)n-hexadecane (C16)n-heptadecane (C17)

n-octadecane (C18)n-nonadecane (C19)n-eicosane (C20)n-heneicosane (C21)n-docosane (C22)n-tricosane (C23)n-tetracosane (C24)n-pentacosane (C25)

DRO Mix (Tennessee/Mississippi) (16 components)


Kerosene Composite Standard







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UST MonitoringArizona

*For samples suspected of gasoline contamination, Los Angeles County requireslaboratories to calibrate and report these compounds.

California

Los Angeles County, CAWell Investigation Program (WIP)*

Connecticut

Florida


n-docosane (C22)n-dotriacontane (C32)

Extraction Retention Time Standard


10W30 motor oil:diesel fuel #2 (1:1 blend)DRO/GRO Calibration Standard


n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)n-eicosane (C20)

n-docosane (C22)n-tetracosane (C24)n-hexacosane (C26)n-octacosane (C28)n-triacontane (C30)n-dotriacontane (C32)

DRO/GRO Range Calibration Standard (12 components)


benzene naphthaleneGRO P&T Retention Time Standard


benzeneethylbenzenemethyl tert-butyl ether (MTBE)toluene


PVOC Mix (California) (7 components)


diisopropyl ether (DIPE) 2,000µg/mLethyl-tert-butyl ether (ETBE) 2,000tert-amyl methyl ether (TAME) 2,000tert-butyl alcohol 10,000methyl tert-butyl ether (MTBE) 2,000

California Oxygenates Mix


Methanol10,000µg/mL in DI Water, 1mL/ampul

cat. # 30467 (ea.)

Ethanol10,000µg/mL in DI Water, 1mL/ampul

cat. # 30466 (ea.)



benzenechlorobenzene1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzeneethylbenzene

methyl tert-butyl ether (MTBE)toluenem-xyleneo-xylenep-xylene

CA WIP VOA Standard (11 components)


n-nonane (C9)n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)n-eicosane (C20)n-docosane (C22)

n-tetracosane (C24)n-hexacosane (C26)n-octacosane (C28)n-triacontane (C30)n-dotriacontane (C32)n-tetratriacontane (C34)n-hexatriacontane (C36)

Connecticut ETPH Calibration Mixture (15 components)


free literatureCCaalliiffoorrnniiaa UUSSTT MMoonniittoorriinngg



n-nonatriacontane (C39)

*Ground transportation shipments only.

Florida TRPH Surrogate Mix

3,000µg/mL in carbon disulfide, 1mL/ampul*cat. # 31456 (ea.)

3,000µg/mL in carbon disulfide, 10mL/ampul*cat. # 31877 (ea.)

n-octane (C8)n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)n-eicosane (C20)n-docosane (C22)n-tetracosane (C24)

n-hexacosane (C26)n-octacosane (C28)n-triacontane (C30)n-dotriacontane (C32)n-tetratriacontane (C34)n-hexatriacontane (C36)n-octatriacontane (C38)n-tetracontane (C40)

*Ground transportation shipments only.

Florida TRPH Standard (17 components)


2,000µg/mL each in carbon disulfide, 1mL/ampul*cat. # 31878 (ea.)

free literatureFFlloorriiddaa UUSSTT MMoonniittoorriinngg



o-Terphenyl2,000µg/mL in acetone, 1mL/ampul


cat. # 31097 (ea.)


464 www.restek.com


UST Monitoring

Massachusetts APH Mix (26 components)

n-pentane (C5)n-nonane (C9)benzene2,5-dibromotoluene (SS)ethylbenzeneisooctane2-methylpentane

methyl tert-butyl ether (MTBE)naphthalenetoluene1,2,4-trimethylbenzenem-xyleneo-xylenep-xylene

MA VPH Matrix Spike Mix with Surrogate (14 components)


acenaphtheneacenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(k)fluoranthenebenzo(ghi)perylenechrysene

dibenzo(a,h)anthracenefluoranthenefluoreneindeno(1,2,3-cd)pyrene2-methylnaphthalenenaphthalenephenanthrenepyrene

MA EPH Aromatic Hydrocarbon Standard (17 components)


n-nonane (C9)n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)n-nonadecane (C19)

n-eicosane (C20)n-docosane (C22)n-tetracosane (C24)n-hexacosane (C26)n-octacosane (C28)n-triacontane (C30)n-hexatriacontane (C36)

MA EPH Aliphatic Hydrocarbon Standard (14 components)


n-nonane (C9)n-tetradecane (C14)n-nonadecane (C19)n-eicosane (C20)n-octacosane (C28)

acenaphtheneanthracenechrysenenaphthalenepyrene

MA EPH Matrix Spike Mix (10 components)



MA VPH Standard with Surrogate (14 components)

n-pentane (C5) 1,000µg/mLn-nonane (C9) 1,000benzene 5002,5-dibromotoluene (SS) 1,000ethylbenzene 500isooctane 1,5002-methylpentane 1,500

methyl tert-butyl ether (MTBE) 1,500naphthalene 1,000toluene 1,5001,2,4-trimethylbenzene 1,000m-xylene 1,000o-xylene 1,000p-xylene 1,000


2,5-dibromotoluene

MA VPH Surrogate Standard



benzene1,3-butadienebutylcyclohexanecyclohexanen-decane (C10)2,3-dimethylheptane2,3-dimethylpentanen-dodecane (C12)ethylbenzenen-heptane (C7)n-hexane (C6)isopentaneisopropylbenzene

4-isopropyltoluenemethyl tert-butyl ether (MTBE)1-methyl-3-ethylbenzenen-nonane (C9)n-octane (C8)toluenetoluene-d8 (IS)1,2,3-trimethylbenzene1,3,5-trimethylbenzenen-undecane (C11)m-xyleneo-xylenep-xylene

Massachusetts

n-pentane (C5) 1,000µg/mLn-nonane (C9) 1,000benzene 500ethylbenzene 500isooctane 1,5002-methylpentane 1,500methyl tert-butyl ether (MTBE) 1,500

naphthalene 1,000toluene 1,5001,2,4-trimethylbenzene 1,000m-xylene 1,000o-xylene 1,000p-xylene 1,000

MA Volatile Petroleum Hydrocarbon (VPH) Standard(13 components)


benzenen-butylcyclohexanen-decane (C10)2,5-dibromotoluene (SS)ethylbenzene2-methylpentanemethyl tert-butyl ether (MTBE)naphthalene

n-nonane (C9)n-pentane (C5)toluene1,2,4-trimethylbenzene2,2,4-trimethylpentane (isooctane)m-xyleneo-xylenep-xylene

MA VPH Standard with Surrogate Rev. 1.1 (July 2004)(16 components)


benzenen-butylcyclohexanen-decane (C10)2,5-dibromotoluene (SS)ethylbenzene2-methylpentanemethyl tert-butyl ether (MTBE)naphthalene

n-nonane (C9)n-pentane (C5)toluene1,2,4-trimethylbenzene2,2,4-trimethylpentane (isooctane)m-xyleneo-xylenep-xylene

MA VPH Matrix Spike Mix with Surrogate Rev. 1.1 (July 2004)(16 components)




1ppm in nitrogen, 21 liters @ 350psig (Pi-marked Cylinder)cat. # 34540-PI (ea.)

free literatureMMaassssaacchhuusseettttss UUSSTT MMoonniittoorriinngg




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UST Monitoring

Michigan

Mississippi

Northwest USA Regional Method (Oregon &Washington)also see Washington, page 467

1-chlorooctadecane o-terphenylMA EPH Surrogate Spike Mix


2-bromonaphthalene 2-fluorobiphenyl

MA Fractionation Surrogate Spike Mix


PPAAHHss::acenaphtheneacenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(k)fluoranthenebenzo(ghi)perylenechrysenedibenzo(a,h)anthracenefluoranthenefluoreneindeno(1,2,3-cd)pyrene2-methylnaphthalenenaphthalenephenanthrenepyrene

HHyyddrrooccaarrbboonnss::n-nonane (C9)n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)n-nonadecane (C19)n-eicosane (C20)n-docosane (C22)n-tetracosane (C24)n-hexacosane (C26)n-octacosane (C28)n-triacontane (C30)n-hexatriacontane (C36)

MA Fractionation Check Mix (31 components)


Massachusetts cont'd

benzene1,2-dibromoethane1,2-dichloroethaneethylbenzeneisopropylbenzene2-methylnaphthalenemethyl tert-butyl-ether (MTBE)

naphthalenetoluene1,2,4-trimethylbenzene1,3,5-trimethylbenzenem-xyleneo-xylenep-xylene

Michigan GRO Mix (14 components)


n-dodecane (C12)n-tetracosane (C24)

tolueneNW TPH-HCID Retention Time Mix


n-pentacosane (C25) 4-bromofluorobenzeneNW TPH-HCID Surrogate Mix












1-chlorooctadecane1-Chlorooctadecane Mix


Naphthalene-d8


also availableSee the GC Applications section for glycols applicationchromatograms - ppaaggeess 660022--660033.

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee2-fluorobiphenyl D 10,000 31096o-terphenyl D 10,000 31097p-terphenyl D 10,000 31095pentacosane (C25) D 10,000 31487D = methylene choride

NW TPH-Dx Surrogate Mix Standards

Volume is 1mL/ampul. Concentration is µg/mL

5-α-androstaneMA EPH Internal Standard



466 www.restek.com


UST Monitoring

Texas TNRCC Method 1006

1-Chlorooctane10,000µg/mL in P&T methanol, 1mL/ampul

cat. # 30084 (ea.)

n-hexane (C6)n-heptane (C7)n-octane (C8)n-decane (C10)n-dodecane (C12)

n-hexadecane (C16)n-heneicosane (C21)n-octacosane (C28)n-pentatriacontane (C35)

TNRCC 1006 Retention Time Marker Mix (9 components)

200µg/mL in pentane, 1mL/ampulcat. # 31814 (ea.)

Texas

Texas TNRCC Method 1005

n-hexane (C6)n-dodecane (C12)

n-octacosane (C28)n-pentatriacontane (C35)

TNRCC 1005 Retention Time Markers Mix



n-octacosane (C28)TX TPH Locator Mix


diesel fuel #2 composite unleaded gasoline compositeTX TPH Calibration Mix

10,000µg/mL each in pentane, 1mL/ampulcat. # 31483 (ea.)

diesel fuel #2 composite unleaded gasoline compositeTX TPH Matrix Spike Mix


Alternate Boiling Point/Carbon Number Distribution Marker

Stock Standard (9 components)

n-hexane (C6)n-octane (C8)n-decane (C10)n-dodecane (C12)n-hexadecane (C16)

n-heneicosane (C21)n-octacosane (C28)n-pentatriacontane (C35)n-hexatriacontane (C36)


Don’t see the UST mix you need? We can custom blend a UST mix to meet therequirements of your method. Visit our web site at wwwwww..rreesstteekk..ccoomm//ssoolluuttiioonnss.

Pennsylvania

Tennessee/Mississippi

benzene1,2-dibromoethane1,2-dichloroethaneethylbenzeneisopropyl benzenemethyl tert-butyl ether (MTBE)

naphthalenetoluenem-xyleneo-xylenep-xylene

PA DEP UST Standard (11 components)


free literatureTTeexxaass UUSSTT MMoonniittoorriinngg











α,α,α-Trifluorotoluene2,000µg/mL in P&T methanol, 1mL/ampul

cat. # 30048 (ea.) 2,500µg/mL in P&T methanol, 1mL/ampul

cat. # 30068 (ea.) 10,000µg/mL in P&T methanol, 1mL/ampul

cat. # 30083 (ea.)

1-chlorooctadecane1-Chlorooctadecane Mix



www.restek.com 467


UST Monitoring

Wisconsin

Washington

n-pentane (C5)n-hexane (C6)n-octane (C8)n-decane (C10)n-dodecane (C12)

1-methylnaphthalenenaphthalenetoluene1,2,3-trimethylbenzene

WA VPH Marker Standard (9 components)


n-pentane (C5)n-hexane (C6)n-octane (C8)n-decane (C10)n-dodecane (C12)benzeneethylbenzene1-methylnaphthalene

methyl tert-butyl ether (MTBE)naphthalenetoluene1,2,3-trimethylbenzenem-xyleneo-xylenep-xylene

WA VPH Standard (15 components)


acenaphthenebenzo(ghi)perylenenaphthalene

pyrenetoluene1,2,3-trimethylbenzene

WA EPH Aromatic Hydrocarbon Mix


n-octane (C8)n-decane (C10)n-dodecane (C12)

n-hexadecane (C16)n-heneicosane (C21)n-tetratriacontane (C34)

WA EPH Aliphatic Hydrocarbon Mix


Washington cont'd

acenaphtheneacenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(k)fluoranthenebenzo(ghi)perylenechrysene

dibenzo(a,h)anthracenefluoranthenefluoreneindeno(1,2,3-cd)pyrene2-methylnaphthalenenaphthalenephenanthrenepyrene1,2,3-trimethylbenzene

WA EPH Aromatic Hydrocarbon Standard (18 components)


n-decane (C10)n-dodecane (C12)n-hexadecane (C16)n-heneicosane (C21)acenaphthene

anthracenebenzo(a)pyrenebenzo(ghi)perylenenaphthalenepyrene

WA EPH Matrix Spike Mix (10 components)


n-octane (C8)n-decane (C10)n-dodecane (C12)n-hexadecane (C16)n-heneicosane (C21)n-tetratriacontane (C34)acenaphtheneacenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrene

benzo(b)fluoranthenebenzo(k)fluoranthenebenzo(ghi)perylenechrysenedibenzo(a,h)anthracenefluoranthenefluoreneindeno(1,2,3-cd)pyrenenaphthalenephenanthrenepyrene

WA EPH Fractionation Check Mix (22 components)


benzeneethylbenzenemethyl tert-butyl ethernaphthalenetoluene

1,2,4-trimethylbenzene1,3,5-trimethylbenzenem-xyleneo-xylenep-xylene

PVOC/GRO Mix (Wisconsin) (10 components)


n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)

n-eicosane (C20)n-docosane (C22)n-tetracosane (C24)n-hexacosane (C26)n-octacosane (C28)

DRO Mix (EPA/Wisconsin) (10 components)

2,000µg/mL each in methylene chloride, 1mL/ampulcat. # 31064 (ea.) did you know?

We have more than 2,000 pure, characterized, neat compounds in our inventory! Ifyou do not see the EXACT mixture you need listed on any of these pages, contactus for a custom standard.

free literatureNNoorrtthhwweesstt RReeggiioonnaall//WWaasshhiinnggttoonn UUSSTT MMoonniittoorriinngg



free literatureWWiissccoonnssiinn UUSSTT MMoonniittoorriinngg




ANALYTICAL

REFERENCE

MATERIALS

OTHER MATERIALS

ASTM Methods . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .469-471

Petroleum Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .472-475

Forensics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .476-478

USP OVI Solvents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .479-480

European Pharmacopoeia/ICH Solvents . . . . . . . . . . . . . . . . .480

Organic Acids . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .481

Fatty Acid Methyl Esters . . . . . . . . . . . . . . . . . . . . . . . . . . . .481-483

Derivatization Reagents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .484

Food Testing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .485

Test Mixes, GC & HPLC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .486-487

Top: Dave Krantz, Vice President of Operations

Bottom: Ann Glace, Manufacturing Technician

What’sNEW?


468-480_ARM_astm-usp.qxp 11/20/2008 9:15 AM Page 468

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ANALYTICAL REFERENCE MATERIALS | OTHER MATERIALS

ASTM Methods

MMeetthhoodd TTyyppee

E1387 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Fire Debris

E1618 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Fire Debris

D2887-01 . . . . . . . . . . . . . . . . . . . . . . . . . . .Simulated Distillation Petrochemical

D2887 . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Simulated Distillation Petrochemical

D3710-95 . . . . . . . . . . . . . . . . . . . . . . . . . . .Simulated Distillation Petrochemical

D4059-96 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .PCB Standards in Oil

D5197 . . . . . . . . . . . . . . . .Formaldehyde and Other Carbonyl Compounds in Air

D5836-03 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Air: Isocyanates & Oxazoladines

D6042-96 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Plastic Container Testing

D6352-98 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Polywax® Standards

D6584-00 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Biodiesel

D6730-01 . . . . . . . . . . . . . . . . . . . . . . .Determination of Individual Components

in Spark Ignition Engine Fuels

ASTM E1387 and E1618 (Fire Debris Analysis)

n-hexane (C6)n-octane (C8)n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)

n-eicosane (C20)2-ethyltoluene3-ethyltoluenetoluene1,2,4-trimethylbenzenep-xylene

E1387 Column Resolution Check Mix (13 components)


n-hexane (C6)n-octane (C8)n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)

n-eicosane (C20)2-ethyltoluene3-ethyltoluenetoluene1,2,4-trimethylbenzenep-xylene

E1618 Test Mix (13 components)

Components in this mix (0.5µL/mL or 0.05% volume/volumeeach) are at 10X the concentration of the final test solution spec-ified in ASTM 1618 and ASTM 1387.

0.05% volume/volume each in methylene chloride, 1mL/ampulcat. # 31613 (ea.)

These materials also can be used for underground storage tankmonitoring.

ASTM Simulated Distillation Petrochemical Mixtures

American Society for Testing and Materials (ASTMInternational) Method D2887-01 is used to determine the boil-ing range distribution of petroleum products and fractions hav-ing a final boiling point of 538°C (1,000°F) or lower; a boilingrange greater than 55°C (131°F) and a vapor pressure sufficient-ly low to permit sampling at ambient temperature.

n-pentane (C5)n-hexane (C6)n-heptane (C7)n-octane (C8)n-nonane (C9)n-decane (C10)n-undecane (C11)n-dodecane (C12)n-tetradecane (C14)n-pentadecane (C15)

n-hexadecane (C16)n-heptadecane (C17)n-octadecane (C18)n-eicosane (C20)n-tetracosane (C24)n-octacosane (C28)n-dotriacontane (C32)n-hexatriacontane (C36)n-tetracontane (C40)n-tetratetracontane (C44)

No data pack available.*This standard may only be shipped by FedEx ground, and only within the US.**The 5% w/w blend of neat hydrocarbons can be shipped in the US (overnight)and to our international customers.

ASTM D2887-01 Calibration Mix (20 components)

1% weight each in carbon disulfide, 1g solution/ampul*cat. # 31674 (ea.)

5% w/w in carbon disulfide, 1g /ampul**cat. # 31675 (ea.)

ASTM Methods

ASTM Methods D2887 and D3710-95

These calibration mixtures are made using pure, highly charac-terized neat material, prepared using NIST-traceable balance andweights. Each ampul is supplied with a data sheet indicating theexact concentration, and a sample chromatogram.

CCoommppoouunndd CCoonncc..((%% ww//ww))

n-hexane (C6) 6n-heptane (C7) 6n-octane (C8) 8n-nonane (C9) 8n-decane (C10) 12n-undecane (C11) 12n-dodecane (C12) 12n-tetradecane (C14) 12n-hexadecane (C16) 10

CCoommppoouunndd CCoonncc..((%% ww//ww))

n-octadecane (C18) 5n-eicosane (C20) 2n-tetracosane (C24) 2n-octacosane (C28) 1n-dotriacontane (C32) 1n-hexatriacontane (C36) 1n-tetracontane (C40) 1n-tetratetracontane (C44) 1

D2887 Calibration Mix (17 components)

Packaged 1mL/ampulcat. # 31222 (ea.)

CCoommppoouunndd CCoonncc..((%% vvooll//vvooll))

n-pentane (C5) 8n-hexane (C6) 6n-heptane (C7) 10n-octane (C8) 5n-decane (C10) 4n-dodecane (C12) 4n-tridecane (C13) 2n-tetradecane (C14) 2

CCoommppoouunndd CCoonncc..((%% vvooll//vvooll))

n-pentadecane (C15) 22-methylbutane 102-methylpentane 62,4-dimethylpentane 6toluene 12p-xylene 14n-propylbenzene 5n-butylbenzene 4

D3710-95 Calibration Mix (16 components)

Packaged 1mL/ampulcat. # 31223 (ea.)




NEW!


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ASTM Methods

ASTM Method D6042-96 (Plastic Container Testing)American Society for Testing and Materials (ASTMInternational) Method D6042-96—Test Method forDetermination of Phenolic Antioxidants and Erucamide SlipAdditives in Polypropylene Homopolymer Formulations UsingLiquid Chromatography—is a “consensus” or “referee” methodused among plastic manufacturers and the pharmaceutical com-panies that purchase plastic containers. Plastic container manu-facturers use this test to ensure the quality of their product totheir pharmaceutical customers. Pharmaceutical companies alsospecify this test and provide their own lists of target compoundsand concentration limits in purchase agreements.

This test calls for isopropanol extraction, HPLC separation, andUV detection. Restek offers a variety of reversed phase HPLCcolumns suitable for these separations. Restek also designed ananalytical reference material to validate this method. This mix-ture contains the common antioxidants and slips listed in ASTMD6042-96, along with BHT.

BHTerucamide slipvitamin EIrgafos 168

Irganox 3114Irganox 1010Irganox 1076

ASTM D6042-96 Calibration Mix (7 components)

50µg/mL each in isopropanol, 1mL/ampulcat. # 31628 (ea.)

Tinuvin PASTM D6042-96 Internal Standard Mix

51.8µg/mL in isopropanol, 1mL/ampulcat. # 31629 (ea.)



ASTM Method D5836-03 / OSHA 42, OSHA 47, NIOSH5522 (Analysis of Isocyanates in Indoor Air by HPLC)

Formaldehyde Oxazoladine

2,000µg/mL in toluene, 1mL/ampulcat. # 33004 (ea.)

ASTM D5836 and OSHA 42 are test methods for determining2,4-toluene diisocyanate (2,4-TDI) and 2,6-TDI in the workplace atmosphere. OSHA 47 is for 4,4'-methylenediphenylisocyanate (4,4'-MDI) in indoor air, and NIOSH Method 5522 is an analysis for 2,4-TDI, 2,6-TDI, 4,4'-MDI, and 1,6-hexam-ethylene diisocyanate (1,6-HDI) in air. Restek offers the 1,-(2-pyridyl)piperzine (1-2pp) derivative.

ASTM Method D5197 (Formaldehyde and OtherCarbonyl Compounds in Air)

acetaldehyde-2,4-DNPHacetone-2,4-DNPHacrolein-2,4-DNPHbenzaldehyde-2,4-DNPHn-butyraldehyde-2,4-DNPHcrotonaldehyde-2,4-DNPHformaldehyde-2,4-DNPH

hexaldehyde-2,4-DNPHmethacrolein-2,4-DNPHmethyl ethyl ketone-2,4-DNPHpropionaldehyde-2,4-DNPHm-tolualdehyde-2,4-DNPHvaleraldehyde-2,4-DNPH

CARB 1004 Aldehyde/Ketone-DNPH Calibration Standard(13 components)


CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeacetaldehyde-2,4-DNPH ACN 100 33074acetone-2,4-DNPH ACN 100 33075acrolein-2,4-DNPH ACN 100 33076benzaldehyde-2,4-DNPH ACN 100 330772-butanone-2,4-DNPH ACN 100 33078n-butyraldehyde-2,4-DNPH ACN 100 33079crotonaldehyde-2,4-DNPH ACN 100 330802,5-dimethylbenzaldehyde-2,4-DNPH ACN 100 33081formaldehyde-2,4-DNPH ACN 100 33082glycolaldehyde-2,4-DNPH ACN 100 33091hexaldehyde-2,4-DNPH ACN 100 33083isobutyraldehyde-2,4-DNPH ACN 100 33084isovaleraldehyde-2,4-DNPH ACN 100 33085methacrolein-2,4-DNPH ACN 100 33095propionaldehyde-2,4-DNPH ACN 100 33086m-tolualdehyde-2,4-DNPH ACN 100 33088o-tolualdehyde-2,4-DNPH ACN 100 33087p-tolualdehyde-2,4-DNPH ACN 100 33089valeraldehyde-2,4-DNPH ACN 100 33090ACN=acetonitrile

DNPH Reference Materials


CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee2,6-TDIP DMSO 1,000 330002,4-TDIP DMSO 1,000 330011,6-HDIP DMSO 1,000 330024,4'-MDIP DMSO 1,000 33003

DMSO = dimethyl sulfoxide

Isocyanates Singles


ASTM Method D4059-96 is used for determining PCB concen-trations in various types of transformer oil, using GC/ECDdetection. The analyst must dilute transformer oil samples in asolvent prior to injection. The oil in the sample has been shownto quench the ECD. Calibration mixtures of PCBs in transformeroil must be prepared and diluted identically to eliminate thedetector quenching bias resulting when samples are analyzed.

We prepare these solutions in a mineral oil-based transformer oil(Exxon® Univolt® N-61), which has been tested to ensure it isPCB-free.


PCB-Free Transformer Oil

Neat, 5mL cat. # 32424 (ea.) Neat, 50mL cat. # 32425 (ea.)

Aroclor Standards

ASTM Method D4059-96 (PCB Standards in Oil)

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeAroclor 1016 TO 50mg/kg 32075Aroclor 1016 TO 500mg/kg 32076Aroclor 1221 TO 50mg/kg 32077Aroclor 1221 TO 500mg/kg 32078Aroclor 1232 TO 50mg/kg 32079Aroclor 1232 TO 500mg/kg 32080Aroclor 1242 TO 50mg/kg 32081Aroclor 1242 TO 500mg/kg 32082Aroclor 1248 TO 50mg/kg 32083Aroclor 1248 TO 500mg/kg 32084Aroclor 1254 TO 50mg/kg 32085Aroclor 1254 TO 500mg/kg 32086Aroclor 1260 TO 50mg/kg 32087Aroclor 1260 TO 500mg/kg 32088TO = transformer oil (PCB-free)

Volume is 1mL/ampul.


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ASTM Methods

ASTM Method D6352-98 (Polywax® Standards)These high molecular weight hydrocarbon waxes are useful forsimulated distillation and other high-temperature GC work.

Volume is 1mL/ampul.CCoommppoouunndd qqttyy.. ccaatt..## ((eeaa..)) pprriicceePolywax 500 1g 36224Polywax 655 1g 36225Polywax 850 1g 36226Polywax 1000 1g 36227


Other Additives—Available from Restek as Custom

Formulations

Similar methods for extractables in plastic pharmaceutical containers are cited in the United States Pharmacopeia (USP),British Pharmacopoeia (BP), European Pharmacopoeia (EP), andJapanese Pharmacopoeia (JP). Customers may also have formula-tion-specific or product-specific test mixtures. Please contact usfor a custom mixture. Our current inventory of raw materialsincludes these popular antioxidants. We have many more that arenot listed and can obtain most compounds you may need.

• Ethanox 323• Ethanox 330• Ethanox 702• Ethanox 703• Irganox L06• Irganox L57

• Irganox L64• Irganox L109• Irganox L134• Irganox L135• Irganox 1035• Santanox R

• Ultranox 626• Vanlube 81• Vanlube 848• Vanlube 7723• Vanlube AZ• Vanlube NA

• Vanlube PCX• Vanlube SL• Vanlube SS

ASTM Method D6584-00 and EN14105 (Biodiesel)Determining Free and Total Glycerin in B-100 Biodiesel

Methyl Esters by GC

In the manufacture of biodiesel fuel, triglycerides are split intotheir monoalkyl ester components via transesterification. Thefatty acid monoalkyl esters can be used as fuel in diesel engines.Amounts of free glycerin and total glycerin indicate the quality ofthe conversion of the oil or fat to monoalkyl esters. D6584-00 isa test method for quantitative determination of free glycerin,total glycerin, and mono-, di-, and triglycerides in biodiesel fuelmethyl esters by GC, after silylation of the sample with N-methyl-N-(trimethylsilyl) trifluoroacetamide (MSTFA).

(s)-(-)-1,2,4-butanetriol(s)-(-)-1,2,4-Butanetriol

1,000µg/mL in pyridine, 1mL/ampulcat. # 33024 (ea.)


diolein (1,3-di[cis-octadecenoyl]glycerol)Diolein


glycerinGlycerin

500µg/mL in pyridine, 1mL/ampulcat. # 33020 (ea.)

monolein (1-mono[cis-9-octadecenoyl]-rac-glycerol)Monolein


monopalmitinMonopalmitin


tricaprin (1,2,3-tricaprinoylglycerol)Tricaprin



triolein (1,2,3-tri[cis-octadecenoyl]glycerol)Triolein


diesel/biodiesel 80:20


The biodiesel component is methyl soyate.


also availableRestek offers a full range of derivatization reagents in 10 x 1g and 25g packagesizes. See ppaaggee 448844.

benzene 1.00%tert-butanol 0.50%cyclohexane 28.9%n-decane 1.00%2,3-dimethylbutane 0.50%trans-1,2-dimethyl

cyclopentane 0.50%2,3-dimethylheptane 0.20%dodecane 0.25%ethanol 8.00%ethylbenzene 25.0%3-ethylpentane 0.20%n-heptane 2.00%n-hexane 2.00%2-methyl-2-butene 2.50%methyl tert-butyl ether 10.0%

1-methylcyclopentane 0.50%1-methyl-2-ethylbenzene 0.50%1-methylnaphthalene 0.25%5-methylnonane 0.20%naphthalene 0.50%n-nonane 2.00%n-octane 2.00%n-pentane 2.00%1,2,3,5-tetramethyl

benzene 0.25%toluene 7.00%tridecane 0.25%2,2,3-trimethylpentane2,3,3-trimethylpentane 0.50%undecane 0.50%p-xylene 1.00%

Oxy Set-Up Blend

ASTM method D6730-01 is specifically designed forthe determination of the individual hydrocarbonspresent in spark ignition fuels, as well as fuel blends containingoxygenates such as methyl tert-butyl ether, ethyl tert-butyl ether,tert-butanol, ethanol, etc.

Gravimetrically prepared and NIST-traceable.

2mL prescored ampulcat. # 33034 (ea.) enquire

ASTM Method D6730-01 (Determination of IndividualComponents in Spark Ignition Engine Fuels)

ASTM Method D6584-00 and EN14105 (Biodiesel)cont'd

ASTM Method D6042-96 (Plastic Container Testing)cont'd

NEW!


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Petroleum Standards

Petroleum StandardsThese petroleum standards are gravimetrically prepared,NIST-traceable by weight, and verified by one or more analyticalmethods.

Sulfur Simulated Distillation Standard

Speciated Sulfur System Suitability CheckoutStandard

EPA Ultra Low & Low Sulfur Diesel Standards andSamples in Diesel Fuel to Meet EPA Requirements forLab Qualification

30 ppm total sulfur by weight from ethanethiol60 ppm total sulfur by weight from 1-propanethiol30 ppm total sulfur by weight from 1-butanethiol60 ppm total sulfur by weight from 1-pentanethiol30 ppm total sulfur by weight from 1-hexanethiol60 ppm total sulfur by weight from 1-heptanethiol30 ppm total sulfur by weight from 3,5-dimethlybenzenethiol60 ppm total sulfur by weight from 1-octanethiol30 ppm total sulfur by weight from 1-nonanethiol60 ppm total sulfur by weight from 1-decanethiol30 ppm total sulfur by weight from 1-pentadecanethiolol60 ppm total sulfur by weight from 1-hexadecanethiol30 ppm total sulfur by weight from 1-octadecanethiolBalance: toluene/isooctane 1/15

SSDS

1mL pre-scored amber ampul.cat. # 33049 (ea.) enquire

0.50 ppm total sulfur by weight from dimethylsulfide35.0 ppm total sulfur by weight from tertiary butyl mercaptan50.0 ppm total sulfur by weight from thiopene15.0 ppm total sulfur by weight from dimethyl disulfide25.0 ppm total sulfur by weight from benzothiopeneBalance: isooctane

SSSSCS

1mL pre-scored amber ampul.cat. # 33050 (ea.) enquire

EPA Ultra Low Sulfur Diesel Accuracy Standard # 1

EPA Section 80.520(a)(1) and 80.510(b)1-10 ppm total sulfur in a diesel fuel matrix for motor vehicle diesel and diesel

additives subject to the 15 ppm sulfur standard. 1 x 200mL amber bottle.


EPA Ultra Low Sulfur Diesel Accuracy Standard # 2

EPA Section 80.520(a)(1) and 80.510(b)10-20 ppm total sulfur in a diesel fuel matrix for motor vehicle diesel and diesel



EPA Ultra Low Sulfur Diesel Precision Sample # 1

EPA Section 80.580-80.585 Title 40, Chapter 1, Part 80

Homogenous commercially available diesel fuel with sulfur content of 5-15 ppm. 1 x 200mL amber bottle.


EPA Low Sulfur Diesel Precision Sample # 2

EPA Section 80.580-80.585 Title 40, Chapter 1, Part 80Homogenous commercially available diesel fuel with sulfur content of 200-500 ppm. 1 x 200mL amber bottle.


EPA Low Sulfur Diesel Accuracy Standard # 3

EPA Section 80.520(c) and 80.510(c)100-200 ppm total sulfur in a diesel fuel matrix for motor vehicle diesel and diesel



EPA Low Sulfur Diesel Accuracy Standard # 4

EPA Section 80.520(c) and 80.510(c)400-500 ppm total sulfur in a diesel fuel matrix for motor vehicle diesel and diesel



also availableCustom ULSD and LSD calibration standards are also available in 100mL, 200mL,500mL, and 1 liter bottles.

Call our Analytical Reference Department at 800-356-1688 or 814-353-1300, oryour Restek representative for details.


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Petroleum Standards

Low Sulfur in Gasoline Calibration Standards cont'd

Low Sulfur in Gasoline Calibration Standards

Ultra Low & Low Sulfur in Diesel Fuel Calibration Kits

Sulfur in Isooctane Calibration Kits and CheckStandards


Blank100 ppm total sulfur from di-n-butylsulfide in diesel fuel200 ppm total sulfur from di-n-butylsulfide in diesel fuel300 ppm total sulfur from di-n-butylsulfide in diesel fuel400 ppm total sulfur from di-n-butylsulfide in diesel fuel500 ppm total sulfur from di-n-butylsulfide in diesel fuel

Cal Kit LSD 100 - 500

Set of six 20mL bottles.cat. # 33062 (kit) enquire

Blank1.0 ppm total sulfur from di-n-butylsulfide in diesel fuel2.5 ppm total sulfur from di-n-butylsulfide in diesel fuel5.0 ppm total sulfur from di-n-butylsulfide in diesel fuel10.0 ppm total sulfur from di-n-butylsulfide in diesel fuel15.0 ppm total sulfur from di-n-butylsulfide in diesel fuel20.0 ppm total sulfur from di-n-butylsulfide in diesel fuel

Cal Kit ULSD 1 - 20

Set of seven 20mL bottles.cat. # 33060 (kit) enquire

Blank20.0 ppm total sulfur from di-n-butylsulfide in diesel fuel35.0 ppm total sulfur from di-n-butylsulfide in diesel fuel50.0 ppm total sulfur from di-n-butylsulfide in diesel fuel75.0 ppm total sulfur from di-n-butylsulfide in diesel fuel100 ppm total sulfur from di-n-butylsulfide in diesel fuel

Cal Kit ULSD 20 - 100

Set of six 20mL bottles.cat. # 33061 (kit) enquire

Blank10 ppm sulfur from di-n-butylsulfide in gasoline by weight20 ppm sulfur from di-n-butylsulfide in gasoline by weight30 ppm sulfur from di-n-butylsulfide in gasoline by weight40 ppm sulfur from di-n-butylsulfide in gasoline by weight50 ppm sulfur from di-n-butylsulfide in gasoline by weight

Cal Kit SG 10 - 50


Set of six 5mL amber bottles.cat. # 33043 (kit) enquire

Blank50 ppm sulfur from di-n-butylsulfide in gasoline by weight65 ppm sulfur from di-n-butylsulfide in gasoline by weight80 ppm sulfur from di-n-butylsulfide in gasoline by weight95 ppm sulfur from di-n-butylsulfide in gasoline by weight110 ppm sulfur from di-n-butylsulfide in gasoline by weight125 ppm sulfur from di-n-butylsulfide in gasoline by weight

Cal Kit SG 50 - 125

Set of seven 5mL amber bottles.cat. # 33045 (kit) enquire

Blank110 ppm sulfur from di-n-butylsulfide200 ppm sulfur from di-n-butylsulfide300 ppm sulfur from di-n-butylsulfide400 ppm sulfur from di-n-butylsulfide500 ppm sulfur from di-n-butylsulfide

Cal Kit SG 110 - 500

Set of six 5mL amber bottles.cat. # 33047 (kit) enquire

Check Standard SG 25

25 ppm sulfur from di-n-butylsulfide in gasoline by weight. Set of five 5mL amber bottles.


Check Standard SG 75

75 ppm sulfur from di-n-butylsulfide in gasoline by weight. Set of five 5mL amber bottles.


Check Standard SG 175175 ppm sulfur from di-n-butylsulfide in gasoline by weight. Set of five 5mL amber bottles.


Blank0.125 w/w ppm total sulfur from di-n-butylsulfide in isooctane0.25 w/w ppm total sulfur from di-n-butylsulfide in isooctane0.50 w/w ppm total sulfur from di-n-butylsulfide in isooctane1.00 w/w ppm total sulfur from di-n-butylsulfide in isooctane2.50 w/w ppm total sulfur from di-n-butylsulfide in isooctane

Cal Kit SISO 0.125 - 2.5ppm

ASTM Methods D3120, D4045, D5453, D6920

Calibration kit for total sulfur by weight from di-n-butylsulfide in isooctane 0.125-2.5ppm range. Set of six 1mL pre-scored ampuls.

cat. # 33035 (kit) enquire

Check Standard SISO 0.75

0.75ppm total sulfur by weight from di-n-butylsulfide in isooctane. Set of five 1mL pre-scored ampuls.


please noteThese petroleum standards are gravimetrically prepared, NIST-traceable by weight, and verified by one or more analytical methods.

also availableCustom ULSD and LSD calibration standards are also available in 100mL, 200mL,500mL, and 1 liter bottles.


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Petroleum Standards


Total Sulfur & Total Nitrogen in IsooctaneCalibration Kits

Sulfur in Isooctane Calibration Kits and CheckStandards cont'd

also availableCustom total sulfur & total nitrogen in isooctane check standards also available.


Blank2.50 w/w ppm total sulfur from di-n-butylsulfide in isooctane5.00 w/w ppm total sulfur from di-n-butylsulfide in isooctane10.00 w/w ppm total sulfur from di-n-butylsulfide in isooctane15.00 w/w ppm total sulfur from di-n-butylsulfide in isooctane20.00 w/w ppm total sulfur from di-n-butylsulfide in isooctane25.00 w/w ppm total sulfur from di-n-butylsulfide in isooctane50.00 w/w ppm total sulfur from di-n-butylsulfide in isooctane

Cal Kit SISO 2.5 - 50 ppm

Calibration kit for total sulfur by weight from di-n-butylsulfide in isooctane 2.5-50 ppm range. Set of eight 1mL pre-scored ampuls.


Blank50 w/w ppm total sulfur from di-n-butylsulfide in isooctane75 w/w ppm total sulfur from di-n-butylsulfide in isooctane100 w/w ppm total sulfur from di-n-butylsulfide in isooctane250 w/w ppm total sulfur from di-n-butylsulfide in isooctane500 w/w ppm total sulfur from di-n-butylsulfide in isooctane1000 w/w ppm total sulfur from di-n-butylsulfide in isooctane

Cal Kit SISO 50 - 1000 ppm

Calibration kit for total sulfur by weight from di-n-butylsulfide in isooctane 50-100 ppm range. Set of seven 1mL pre-scored ampuls.


Blank1000 w/w ppm total sulfur from di-n-butylsulfide in isooctane1500 w/w ppm total sulfur from di-n-butylsulfide in isooctane2000 w/w ppm total sulfur from di-n-butylsulfide in isooctane4000 w/w ppm total sulfur from di-n-butylsulfide in isooctane6000 w/w ppm total sulfur from di-n-butylsulfide in isooctane

Cal Kit SISO 1000 - 6000

Calibration kit for total sulfur by weight from di-n-butylsulfide in isooctane 1000 - 6000 ppm range. Set of six 1mL pre-scored ampuls.


Check Standard SISO 3030 ppm total sulfur by weight from di-n-butylsulfide in isooctane. Set of five 1mL pre-scored ampuls.


Check Standard SISO 300300 ppm total sulfur by weight from di-n-butylsulfide in isooctane. Set of five 1mL pre-scored ampuls.


Check Standard SISO 30003000 pm total sulfur by weight from di-n-butylsulfide in isooctane. Set of five 1mL pre-scored ampuls.


Blank0.125 w/w ppm total sulfur from thiophene & total nitrogen

from pyridine in isooctane0.25 w/w ppm total sulfur from thiophene & total nitrogen





from pyridine in isooctane

Cal Kit SNISO 0.125 - 5.0

ASTM Methods D3120, D4045, D4629, D5453, D5762,D6069, D6920

Set of seven 1mL pre-scored amber ampuls.cat. # 33057 (kit) enquire






Cal Kit SNISO 5.0 - 50.0

Set of five 1mL pre-scored amber ampuls.cat. # 33058 (kit) enquire



from pyridine in isooctane100 w/w ppm total sulfur from thiophene & total nitrogen





Cal Kit SNISO 50.0 - 1000

Set of seven 1mL pre-scored amber ampuls.cat. # 33059 (kit) enquire

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Petroleum StandardsSulfur in Mineral Oil Calibration Kits and Check Standards

Blank2.00 w/w ppm total sulfur from di-n-butylsulfide in mineral oil5.00 w/w ppm total sulfur from di-n-butylsulfide in mineral oil7.00 w/w ppm total sulfur from di-n-butylsulfide in mineral oil10.00 w/w ppm total sulfur from di-n-butylsulfide in mineral oil15.00 w/w ppm total sulfur from di-n-butylsulfide in mineral oil20.00 w/w ppm total sulfur from di-n-butylsulfide in mineral oil

Cal Kit SMO 2 - 20

ASTM Methods D2622, D3120, D4045, D4294, D5453, D6212, D6313, D6428, D6445, D7039


Blank10.0 w/w ppm total sulfur from di-n-butylsulfide in mineral oil25.0 w/w ppm total sulfur from di-n-butylsulfide in mineral oil50.0 w/w ppm total sulfur from di-n-butylsulfide in mineral oil100 w/w ppm total sulfur from di-n-butylsulfide in mineral oil

Cal Kit SMO 10 - 100

Set of five 100mL bottles.cat. # 33065 (kit) enquire

Blank100 w/w ppm total sulfur from di-n-butylsulfide in mineral oil200 w/w ppm total sulfur from di-n-butylsulfide in mineral oil300 w/w ppm total sulfur from di-n-butylsulfide in mineral oil400 w/w ppm total sulfur from di-n-butylsulfide in mineral oil500 w/w ppm total sulfur from di-n-butylsulfide in mineral oil600 w/w ppm total sulfur from di-n-butylsulfide in mineral oil750 w/w ppm total sulfur from di-n-butylsulfide in mineral oil1000 w/w ppm total sulfur from di-n-butylsulfide in mineral oil

Cal Kit SMO 100 - 1000

Set of nine 100mL bottles.cat. # 33067 (kit) enquire

Blank1000 w/w ppm total sulfur from di-n-butylsulfide in mineral oil2500 w/w ppm total sulfur from di-n-butylsulfide in mineral oil5000 w/w ppm total sulfur from di-n-butylsulfide in mineral oil1.00% total sulfur by weight from di-n-butylsulfide in mineral oil1.50% total sulfur by weight from di-n-butylsulfide in mineral oil2.00% total sulfur by weight from di-n-butylsulfide in mineral oil2.50% total sulfur by weight from di-n-butylsulfide in mineral oil

Cal Kit SMO 1000 - 25000

Set of eight 100mL bottles.cat. # 33069 (kit) enquire

Blank2.50% total sulfur by weight from di-n-butylsulfide in mineral oil3.00% total sulfur by weight from di-n-butylsulfide in mineral oil3.50% total sulfur by weight from di-n-butylsulfide in mineral oil4.00% total sulfur by weight from di-n-butylsulfide in mineral oil4.50% total sulfur by weight from di-n-butylsulfide in mineral oil5.00% total sulfur by weight from di-n-butylsulfide in mineral oil

Cal Kit SMO 25000 - 50000


Check Standard SMO 11

11.0 w/w ppm total sulfur from di-n-butylsulfide in mineral oil. 1 liter bottle.



30.0 w/w ppm total sulfur from di-n-butylsulfide in mineral oil. 1 liter bottle.


Check Standard SMO 350350 w/w ppm total sulfur from di-n-butylsulfide in mineral oil. 1 liter bottle.


Check Standard SMO 30003000 w/w ppm total sulfur from di-n-butylsulfide. 1 liter bottle.



3.70% total sulfur by weight from di-n-butylsulfide in mineral oil.1 liter bottle.


please noteThese petroleum standards are gravimetrically prepared, NIST-traceable by weight, and verified by one or more analytical methods.

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Forensic: Fire Debris, Blood Alcohol

Weathered Petrochemical Standards

• Type I (Stoddard solvent) BPR 149–182°C • Type II (high flash point) BPR 177–196°C • Type III (odorless) BPR 149–196°C• Type IV (low dry point) BPR 149–174°C

We prepare our mineral spirits solutions from an equal volumeblend of Type I, II, and III mineral spirits.

Stoddard Solvent Standard10,000µg/mL in P&T methanol, 1mL/ampul

cat. # 30487 (ea.)

These solutions are prepared from a single source (one refinery)product. The weathered materials indicate the percent weightloss from the original material. Samples of regular and premiumgrade unleaded gasoline were blended in equal volumes.

There are four general types of mineral spirits, classifiedaccording to boiling point range (BPR):

IInnddeexx TTyyppee

Weathered Petrochemical Standards . . . . . . . . . . . . . . . . . . . . . . . . . .Forensics

Blood Alcohol Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Forensics

Bank Dye Standard . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Forensics

Explosives Solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Forensics

Exempt Drug Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Forensics

USP 467 Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Residual Solvents

European Pharmacopoeia Standards . . . . . . . . . . . . . . . . . . .Residual Solvents

please noteWe can custom prepare weathered accelerants for fire debris analysis.

Please complete the custom reference material request form atwwwwww..rreesstteekk..ccoomm//ssoolluuttiioonnss.

We’ll be glad to work with you!

Weathered Gasoline Kit

30096: Unleaded Gasoline Standard30097: Unleaded Gas Standard: 25% Weathered 30098: Unleaded Gas Standard: 50% Weathered30099: Unleaded Gas Standard: 75% Weathered


31229: Kerosene Standard31230: Kerosene Standard: 25% Weathered31231: Kerosene Standard: 50% Weathered31232: Kerosene Standard: 75% Weathered

Weathered Kerosene Kit


31233: Diesel Fuel #2 Standard31234: Diesel Fuel #2 Standard: 25% Weathered31235: Diesel Fuel #2 Standard: 50% Weathered31236: Diesel Fuel #2 Standard: 75% Weathered

Weathered Diesel Fuel #2 Kit


31225: Mineral Spirits Standard31226: Mineral Spirits Standard: 25% Weathered31227: Mineral Spirits Standard: 50% Weathered31228: Mineral Spirits Standard: 75% Weathered

Weathered Mineral Spirits Kit


Weathered Petrochemical Standards cont'd

Blood Alcohol Standards

acetaldehydeacetoneacetonitrileethanol (NIST certified value)

ethyl acetateisopropanolmethanolmethyl ethyl ketone

Blood Alcohol Mix Resolution Control Standard (8 components)

Use to verify the retention time for each compound normallyincluded in a blood alcohol test, and to verify that the com-pounds are resolved from and do not interfere with one anoth-er. Concentration of ethanol is NIST-traceable.

0.100g/dL each in water, 1mL/ampulcat. # 36256 (ea.)

30096: Unleaded Gasoline Standard30097: Unleaded Gas Standard: 25% Weathered 30098: Unleaded Gas Standard: 50% Weathered30099: Unleaded Gas Standard: 75% Weathered30436: Unleaded Gas Standard: 99% Weathered

Weathered Gasoline Kit #2


CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeunleaded gasoline: unweathered PTM 5,000 30096unleaded gasoline: 25% weathered PTM 5,000 30097unleaded gasoline: 50% weathered PTM 5,000 30098unleaded gasoline: 75% weathered PTM 5,000 30099unleaded gasoline: 99% weathered PTM 5,000 30436

PTM = P&T methanol

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceekerosene: unweathered D 5,000 31229kerosene: 25% weathered D 5,000 31230kerosene: 50% weathered D 5,000 31231kerosene: 75% weathered D 5,000 31232

D = methylene chloride

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceediesel fuel #2: unweathered D 5,000 31233diesel fuel #2: 25% weathered D 5,000 31234diesel fuel #2: 50% weathered D 5,000 31235diesel fuel #2: 75% weathered D 5,000 31236CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceemineral spirits: unweathered D 5,000 31225mineral spirits: unweathered D 50,000 31260mineral spirits: unweathered (5mL) D 50,000 31261mineral spirits: 25% weathered D 5,000 31226mineral spirits: 50% weathered D 5,000 31227mineral spirits: 75% weathered D 5,000 31228

Volume is 1mL/ampul unless otherwise noted. Concentration is µg/mL.

kit

kit

kit

kit

kit


www.restek.com 477


Forensic: Blood Alcohol, Bank Dyes, Explosives

1-N-(methylamino)anthraquinone (MAAQ)

Bank Dye Standard (MAAQ)Restek offers this qualitative standard to help investigators inmunicipal police stations and criminal laboratories fight crime.

100µg/mL in methylene chloride, 1mL/ampulcat. # 31823 (ea.)

We have developed calibration mixtures for performing multi-point instrument calibrations so that laboratories can constructcalibration curves. The data pack (which can be downloadedfrom our website at www.restek.com/datapacks) includes aCertificate of Analysis, raw material testing results, statistical QAresults, analytical balance printout, and gravimetric weight ofeach analyte. Ethanol in these mixes is National Institute ofStandards and Technology (NIST)-traceable.


Blood Alcohol Standards cont'd

did you know?Resolve blood alcohol samples in less than 3 minutes with our Rtx®-BAC1and Rtx®-BAC2 columns. For more information on these columns or to findout what's new for clinical/forensic analyses, visit wwwwww..rreesstteekk..ccoomm//CCFFTT.



These materials support nitroaromatic, nitramine, andnitroester analyses by GC/ECD (Method 8095).1,2 Compoundslisted are explosives, manufacturing intermediates or degrada-tion products. Method 8095 mixtures contain the components atconcentration ratios appropriate for ECD.



RReeffeerreenncceess ((NNoott aavvaaiillaabbllee ffrroomm RReesstteekk..))1US Environmental Protection Agency. Test Methods for Evaluating Solid Waste,Physical/Chemical Methods. SW-846, Proposed Draft Update IVB, Office of SolidWaste, Washington, DC, 1999.2M. E. Walsh, T. Ranney, J. Chromatogr. Sci., Vol. 36, pp. 406-416, August 1998.

Explosives Solutions

CCoommppoouunndd qqttyy.. ccaatt..## pprriiccee0.010g/dL forensic ethanol solution1mL/ampul 5-pk. 362761mL/ampul 10-pk. 362785mL/ampul ea. 362770.015g/dL forensic ethanol solution1mL/ampul 5-pk. 362321mL/ampul 10-pk. 363325mL/ampul ea. 36240 enquire20mL/ampul ea. 362480.02g/dL forensic ethanol solution1mL/ampul 5-pk. 362331mL/ampul 10-pk. 363335mL/ampul ea. 36241 enquire20mL/ampul ea. 362490.025g/dL forensic ethanol solution1mL/ampul 5-pk. 362341mL/ampul 10-pk. 363345mL/ampul ea. 3624220mL/ampul ea. 36250 enquire0.04g/dL forensic ethanol solution1mL/ampul 5-pk. 362351mL/ampul 10-pk. 363355mL/ampul ea. 3624320mL/ampul ea. 362510.05g/dL forensic ethanol solution1mL/ampul 5-pk. 362571mL/ampul 10-pk. 362595mL/ampul ea. 3625820mL/ampul ea. 362600.08g/dL forensic ethanol solution1mL/ampul 5-pk. 362621mL/ampul 10-pk. 362645mL/ampul ea. 3626320mL/ampul ea. 362650.1g/dL forensic ethanol solution1mL/ampul 5-pk. 362361mL/ampul 10-pk. 363365mL/ampul ea. 3624420mL/ampul ea. 362520.15g/dL forensic ethanol solution1mL/ampul 5-pk. 362371mL/ampul 10-pk. 363375mL/ampul ea. 3624520mL/ampul ea. 362530.16g/dL forensic ethanol solution1mL/ampul 5-pk. 364171mL/ampul 10-pk. 364185mL/ampul ea. 3641920mL/ampul ea. 364200.2g/dL forensic ethanol solution1mL/ampul 5-pk. 362381mL/ampul 10-pk. 363385mL/ampul ea. 3624620mL/ampul ea. 36254

Blood Alcohol Standards cont'dCCoommppoouunndd qqttyy.. ccaatt..## pprriiccee0.3g/dL forensic ethanol solution1mL/ampul 5-pk. 362391mL/ampul 10-pk. 363395mL/ampul ea. 3624720mL/ampul ea. 362550.4g/dL forensic ethanol solution1mL/ampul 5-pk. 362661mL/ampul 10-pk. 362685mL/ampul ea. 3626720mL/ampul ea. 36269

NEW!


478 www.restek.com


Forensic: Drugs of Abuse


CCoommppoouunndd CCAASS## SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeBBeennzzooddiiaazzeeppiinneessalprazolam 28981-97-7 PTM 1,000 34042 enquirebromazepam 1812-30-2 PTM 1,000 34043 enquirechlordiazepoxide 438-41-5 PTM 1,000 34044 enquireclobazam 22316-47-8 PTM 1,000 34045 enquireclonazepam 1622-61-3 PTM 1,000 34046 enquirediazepam 439-14-5 PTM 1,000 34047 enquireflunitrazepam 1622-62-4 PTM 1,000 34049 enquireflurazepam 1172-18-5 PTM 1,000 34050 enquirelorazepam 846-49-1 PTM 1,000 34051 enquirenitrazepam 146-22-5 PTM 1,000 34053 enquireoxazepam 604-75-1 PTM 1,000 34054 enquireprazepam 2955-38-6 PTM 1,000 34055 enquiretemazepam 896-50-4 PTM 1,000 34056 enquiretriazolam 28911-01-5 PTM 1,000 34057 enquireCCooccaaiinnee && MMeettaabboolliitteesscocaethylene 529-38-4 ACN 1,000 34066 enquirecocaine 53-21-4 PTM 1,000 34015 enquirebenzoylecgonine 519-09-5 PTM 1,000 34016 enquireecgonine 5796-31-6 PTM 1,000 34017 enquireecgonine methyl ester 38969-40-3 PTM 1,000 34018 enquireMMeetthhaaddoonnee && MMeettaabboolliitteessEDDP perchlorate 66729-78-0 M 1,000 34069 enquiremethadone 1095-90-5 PTM 1,000 34005 enquireAAmmpphheettaammiinneess && MMeettaabboolliitteessd-amphetamine 51-63-8 PTM 1,000 34020 enquire(+)methamphetamine 51-57-0 PTM 1,000 34021 enquire3,4-MDA HCl 4764-17-4 M 1,000 34070 enquire3,4-MDEA HCl 82801-81-8 M 1,000 34072 enquire3,4-MDMA HCl 42542-10-9 M 1,000 34071 enquirephenylpropanolamine HCl 154-41-6 M 1,000 34073 enquireOOppiiaatteess && MMeettaabboolliitteesscodeine 76-57-3 PTM 1,000 34000 enquiredextromethorphan HBr

monohydrate 125-69-9 M 1,000 34081 enquirehydrocodone 34195-34-1 PTM 1,000 34002 enquirehydromorphone 71-68-1 PTM 1,000 34063 enquiremorphine 6211-15-0 PTM 1,000 34006 enquireoxycodone 124-90-3 PTM 1,000 34007 enquireoxymorphone 76-41-5 PTM 1,000 34065 enquireCCaannnnaabbiinnooiidd && MMeettaabboolliitteesscannabidiol 13956-24-1 PTM 1,000 34011 enquirecannabinol 521-35-7 PTM 1,000 34010 enquireΔ9-THC 1972-08-3 M 1,000 34067 enquire(±)11-nor-9-carboxy-Δ9-THC 104874-50-2 M 100 34068 enquireBBaarrbbiittuurraatteessamobarbital 64-43-7 PTM 1,000 34028 enquireaprobarbital 77-02-1 PTM 1,000 34029 enquirebarbital 57-44-3 PTM 1,000 34030 enquirebutabarbital 125-40-6 PTM 1,000 34031 enquirebutalbital 77-26-9 PTM 1,000 34032 enquireDL-glutethimide 18389-24-7 PTM 1,000 34058 enquirehexobarbital 56-29-1 PTM 1,000 34033 enquiremephobarbital 115-38-8 PTM 1,000 34034 enquiremethohexital 151-83-7 PTM 1,000 34035 enquirepentobarbital 76-74-4 PTM 1,000 34036 enquirephenobarbital 50-06-6 PTM 1,000 34037 enquiresecobarbital 29071-21-4 PTM 1,000 34038 enquiretalbutal 115-44-6 PTM 1,000 34039 enquirethiamylal 337-47-3 PTM 1,000 34040 enquirethiopental 71-73-8 PTM 1,000 34041 enquire

GGHHBB1,4-butanediol 110-63-4 M 1,000 34078 enquireγ-butyrolactone (GBL) 96-48-0 ACN 1,000 34077 enquireα-methylene-γ-butyrolactone

(AMGBL) 547-65-9 ACN 1,000 34079 enquireγ-valerolactone 108-29-2 ACN 1,000 34080 enquireLLSSDDLAMPA 40158-98-3 ACN 1,000 34075 enquireLSD 50-37-3 ACN 25 34089 enquireLSD 50-37-3 ACN 100 34088 enquireOOtthheerrbenzphetamine 5411-22-3 PTM 1,000 34022 enquirecaffeine 58-08-2 M 1,000 34084 enquirecontinine 486-56-6 M 1,000 34086 enquirefenfluramine 16105-77-4 PTM 1,000 34023 enquirefentanyl 437-38-7 M 1,000 34082 enquirenor-fentanyl oxalate 1609-66-1 M 1,000 34083 enquirelevorphanol 5985-38-6 PTM 1,000 34003 enquiremeperidine 50-13-5 PTM 1,000 34004 enquiremeprobamate 57-53-4 PTM 1,000 34059 enquiremethaqualone 340-56-7 PTM 1,000 34064 enquiremethyprylon 125-64-4 PTM 1,000 34060 enquirenicotine 54-11-5 M 1,000 34085 enquirepentazocine 64024-15-3 PTM 1,000 34062 enquirephencyclidine 956-90-1 PTM 1,000 34027 enquirephendimetrazine 50-58-8 PTM 1,000 34025 enquirephenmetrazine 1707-14-8 PTM 1,000 34026 enquirephentermine 1197-21-3 PTM 1,000 34024 enquiredextro-propoxyphene 1639-60-7 PTM 1,000 34008 enquirethebaine 115-37-7 PTM 1,000 34009 enquire

Exempted Drug of Abuse Reference MaterialsVolume is 1mL/ampul. Concentration is µg/mL.

CCoommppoouunndd CCAASS## SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee

ACN = acetonitrileM = methanolPTM = purge & trap grade methanol

amiodarone 10µg/mLamphetamine 10caffeine 10codeine 10

diazepam 10doxepine 10haloperidol 1morphine 10

Forensic Drug Screen Test Mixture


D5-diazepam D5-doxepineForensic Drug Screen Internal Standard


NEW!

NEW!

Get More!Clinical/Forensic/

Toxicology Articles Onlinewww.restek.com/CFT


www.restek.com 479


USP OVI Solvents

The United States Pharmacopeia (USP) general chapter <467> Residual Solvents is a widely used compendial method intended foridentifying and quantifying residual solvents in drug substances, drug products, and excipients. In an attempt to better mirror theInternational Conference on Harmonization (ICH) guidelines, the USP has adopted a more comprehensive methodology in residualsolvent testing—the current USP30/NF25. The ICH publishes a guideline (Q3C) listing the acceptable amounts of solvent residues thatcan be present. In the ICH guideline, residual solvents are summarized by class, according to their toxicity. Class 1 compounds are car-cinogenic compounds that pose a risk to both the consumer and the environment. The use of these solvents is to be avoided, but ifthey are used, they must be tightly controlled. Class 2 compounds are nongenotoxic animal carcinogens, and concentrations of thesecompounds should be limited. Chromatographic analysis is needed for both the Class 1 and Class 2 residual solvents.

USP <467>

acetonitrile 2.05mg/mLchlorobenzene 1.80cyclohexane 19.40cis-1,2-dichloroethene 4.70trans-1,2-dichloroethene 4.701,4-dioxane 1.90ethylbenzene 1.84methanol 15.00

methylcyclohexane 5.90methylene chloride 3.00tetrahydrofuran 3.45toluene 4.45m-xylene 6.51o-xylene 0.98p-xylene 1.52

Residual Solvents Class 2 - Mix A (15 components)

In dimethyl sulfoxide, 1mL/ampulcat. # 36271 (ea.)

2-ethoxyethanol 800µg/mLethylene glycol 3,100formamide 1,100N,N-dimethylacetamide 5,450N,N-dimethylformamide 4,400

2-methoxyethanol (methyl Cellosolve) 250

N-methylpyrrolidone 2,650sulfolane 800

Residual Solvents Class 2 - Mix C (8 components)


CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeacetonitrile DMSO 2.05mg/mL 36281benzene DMSO 10mg/mL 36282carbon tetrachloride DMSO 20mg/mL 36283chlorobenzene DMSO 1.8mg/mL 36284chloroform DMSO 0.3mg/mL 36285cyclohexane DMSO 19.4mg/mL 362861,1-dichloroethene DMSO 40mg/mL 362871,2-dichloroethane DMSO 25mg/mL 36288cis-1,2-dichloroethylene DMSO 4.67mg/mL 36289trans-1,2-dichloroethylene DMSO 4.67mg/mL 362901,2-dimethoxyethane DMSO 0.5mg/mL 36291N,N-dimethylacetamide DMSO 5.45mg/mL 36292N,N-dimethylformamide DMSO 4.4mg/mL 362931,4-dioxane DMSO 1.9mg/mL 362942-ethoxyethanol DMSO 0.8mg/mL 36295ethylbenzene DMSO 1.84mg/mL 36296ethylene glycol DMSO 3.1mg/mL 36297formamide DMSO 1.1mg/mL 36298hexane DMSO 1.45mg/mL 36299methanol DMSO 15mg/mL 364012-methoxyethanol DMSO 0.25mg/mL 36402methylbutylketone DMSO 0.25mg/mL 36400methylcyclohexane DMSO 5.9mg/mL 36403 enquiremethylene chloride DMSO 3mg/mL 36404N-methylpyrrolidone DMSO 2.65mg/mL 36405nitromethane DMSO 0.25mg/mL 36406pyridine DMSO 1mg/mL 36407sulfolane DMSO 0.8mg/mL 36413tetrahydrofuran (THF) DMSO 3.6mg/mL 36408tetralin DMSO 0.5mg/mL 36409toluene DMSO 4.45mg/mL 364101,1,1-trichloroethane DMSO 50mg/mL 36411trichloroethene DMSO 0.4mg/mL 36412m-xylene DMSO 6.51mg/mL 36414o-xylene DMSO 0.97mg/mL 36415p-xylene DMSO 1.52mg/mL 36416

DMSO=dimethyl sulfoxide

USP <467> Singles

Volume is 1mL/ampul.

benzene 10mg/mLcarbon tetrachloride 201,2-dichloroethane 25

1,1-dichloroethene 401,1,1-trichloroethane 50

Residual Solvents - Class 1


chloroform 60µg/mL1,2-dimethoxyethane 100n-hexane (C6) 2902-hexanone 50

nitromethane 50pyridine 200tetralin 100trichloroethene 80

Residual Solvents Class 2 - Mix B (8 components)


free literatureRReessiidduuaall SSoollvveenntt AAnnaallyyssiiss

Download your free copy from wwwwww..rreesstteekk..ccoomm!

Flyer lliitt.. ccaatt..## PPHHFFLL11001188

These mixtures reflect the changes made in USP30/NF25effective July 1, 2008.

also availableFor other reference mixes for USP <467> and European Pharmacopoeia, see ppaaggee 448800. Class III solvents are available as custom mixes. Visitwwwwww..rreesstteekk..ccoomm//ssoolluuttiioonnss for our custom reference material request form.

For a list of OVI retention times,see ppaaggee 669911.

OVIRetention

Index


480 www.restek.com


USP OVI Solvents, European Pharmacopoeia/ICH Solvents

did you know?We prepare Rtx®-1301 (cat.# 16085) and Stabilwax® (cat.# 10640) capillarycolumns and the analytical reference materials to meet the requirements forEuropean Pharmacopoeia. Download lit. cat.# 59107, European PharmacopoeiaAnalysis of Residual Solvents from our website for more information.

benzene 2µg/mLcarbon tetrachloride 41,2-dichloroethane 5


European Pharmocopoeia/ICH Class 1 Mix

Prepared in water:dimethyl sulfoxide (90:10), 1mL/ampulcat. # 36228 (ea.)

European Pharmacopoeia MethodThe analysis of residual solvents in pharmaceutical products haschanged, particularly for products being sold into Europe. TheInternational Conference on Harmonization (ICH) Guidelinesfor Residual Solvents is becoming the international standard andis being adopted by more pharmacopoeias, including the UnitedStates Pharmacopeia, every year. The ICH method and com-pound list is more extensive than any method previously usedand poses new challenges. Compounds in Class 1 are solventsconsidered to be of highest risk and to be avoided in pharma-ceutical manufacturing. Use of Class 2 compounds is to be lim-ited, as they pose a lower, but present, threat to health.Compounds in Class 3 pose the lowest toxic potential and maybe used routinely in manufacturing.

benzene 2µg/mLcarbon tetrachloride 41,2-dichloroethane 5


European Pharmacopoeia/ICH Class 1 Mix (revised)

In water:dimethyl sulfoxide (90:10), 1mL/ampulcat. # 36261 (ea.)

acetonitrile 410µg/mLchloroform 601,2-dimethoxyethane 100N,N-dimethylacetamide 1,090 1,4-dioxane 3802-hexanone 50

methanol 3,000nitromethane 50pyridine 2001,2,3,4-tetrahydronaphthalene

(tetraline) 100

European Pharmocopoeia/ICH Class 2 Mix B (10 components)

Prepared in water:dimethyl sulfoxide (90:10), 1mL/ampulcat. # 36230 (ea.)

These Class 1 mixtures reflect the changes made in USP24/NF19effective January 1, 2000, and USP23/NF18 effective January 1,1995 to December 31, 1999. While these mixtures do not meet thecurrent USP guidelines, many labs still use these mixtures toobtain a detectable benzene peak for the direct injection meth-ods, Method I and Method V.

chloroform 60µg/mL1,4-dioxane 380

methylene chloride 600trichloroethene 80

USP <467> Calibration Mix #6


chloroform 60µg/mL1,4-dioxane 380


USP <467> Calibration Mix #7


benzene 2µg/mLchloroform 601,4-dioxane 380


USP <467> Calibration Mixture #4














Ethylene oxide is available in other solvents and concentrations. Request yourcustom formulation at [email protected].

Ethylene Oxide

500µg/mL in dimethyl sulfoxide, 1mL/ampulcat. # 36005 (ea.)

chlorobenzene 360µg/mLcyclohexane 3,880cis-1,2-dichloroethene 1,870N,N-dimethylformamide 880ethylbenzene 369n-hexane (C6) 290methylcyclohexane 1,180

methylene chloride 600tetrahydrofuran 720toluene 890trichloroethene 80m-xylene 1,302o-xylene 195p-xylene 304

European Pharmacopoeia/ICH Q3C(M) Class 2 Mix A, Revised(14 components)


2-ethoxyethanol 160µg/mLethylene glycol 620formamide 2202-methoxyethanol

(methyl Cellosolve) 50

N-methylpyrrolidone 530sulfolane 160

European Pharmacopoeia/ICH Q3C(M) Class 2 Mix C, Revised


USP <467> cont'd

Get More!Pharmaceutical Articles Online

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www.restek.com 481


Organic Acids, Fatty Acid Methyl Esters

Organic acids on an Allure® Organic Acids HPLC

column.

Organic Acids

citric acid 2,000µg/mlfumaric acid 10*malic acid 2,000

quinic acid 2,000tartaric acid 2,000

Fruit Juice Organic Acid Standard

In water, 1mL/ampulcat. # 35080 (ea.)

In water, 5mL/ampulcat. # 35081 (ea.)

PPeeaakk LLiisstt:: CCoonncc.. ((mmgg//mmLL))1. tartaric acid 12. quinic acid 13. malic acid 14. citric acid 15. fumaric acid 0.005

SSaammppllee::Inj.: 10µL standard solutionSolvent: water

CCoolluummnn:: AAlllluurree®® OOrrggaanniicc AAcciiddssCat.#: 9165585Dimensions: 300mm x 4.6mmParticle size: 5µmPore size: 60Å

CCoonnddiittiioonnss::Mobile phase: 100mM phosphate buffer, pH 2.5Flow: 0.5mL/min.Temp.: ambientDet.: UV @ 226nm

LC_0238

free literatureSSiinnggllee--CCoolluummnn MMeetthhoodd ffoorr HHPPLLCC AAnnaallyyssiiss ooff OOrrggaanniiccAAcciiddss iinn FFrruuiitt JJuuiicceess,, UUssiinngg aann AAlllluurree®® OOrrggaanniiccss AAcciiddssCCoolluummnnA highly aqueous mobile phase is needed to forceinteraction between polar organic acids and the sta-tionary phase in an HPLC column, but conventionalC18 phases collapse in 100% aqueous mobile phases.A 300mm Allure® Organic Acids column resolves keyorganic acids, such as tartaric and quinic acids, usingthe conditions specified for a two-column analysis inAOAC Method 986.13. Example chromatograms areincluded in this 2-page note.


Applications Notelliitt.. ccaatt..## 5599553300

*Fumaric acid is a trace impurity in malic acid, as well as an added componentof the mix. The amount of fumaric acid in malic acid will not affect the statedconcentration of malic acid, but can represent a significant and variable devia-tion from the low concentration of fumaric acid stated to be in the mix. All othercomponents of the mix are at the specified concentration.


Fatty Acid Methyl Esters

CChhaaiinn DDeessccrriippttiioonn %% bbyy WWeeiigghhttC14:0 methyl myristate 6.0C14:1 methyl myristoleate 1.0C16:0 methyl palmitate 16.0C16:1 methyl palmitoleate 5.0C18:0 methyl stearate 8.0C18:1 methyl oleate 13.0C18:1 methyl vaccenate 4.0C18:2 methyl linoleate 2.0C18:3 methyl linolenate 2.0C20:0 methyl arachidate 1.0C20:1 methyl 11-eicosenoate 9.0C20:2 methyl 11-14-eicosadienoate 1.0C20:4 methyl arachidonate 3.0C20:3 methyl 11-14-17-eicosatrienoate 1.0C20:5 methyl eicosapentaenoate 10.0C22:0 methyl behenate 1.0C22:1 methyl erucate 3.0C22:6 methyl docosahexaenoate 12.0C24:0 methyl lingnocerate 1.0C24:1 methyl nervonate 1.0

Marine Oil FAME Mix (20 components)

cat. # 35066 (100mg)

DDeessccrriippttiioonn %% bbyy WWeeiigghhttmethyl elaidate (C18:1 trans-9) 10.0methyl linoleate (C18:2 cis-9,12) 20.0methyl oleate (C18:1 cis-9) 10.0methyl petroselinate (C18:1cis-6) 8.0methyl petroselaidate (C18:1trans-6) 8.0methyl stearate (C18:0) 20.0methyl transvaccenate (C18:1 trans-11) 12.0methyl vaccenate (C18:1 cis-11) 12.0

cis/trans FAME Mix (8 components)

10mg/mL total in methylene chloride, 1mL/ampulcat. # 35079 (ea.)



481-487_ARM_FameTest.qxp 11/20/2008 9:17 AM Page 481

482 www.restek.com


Fatty Acid Methyl Esters

CChhaaiinn %% bbyy WWeeiigghhttC4:0 4.0C6:0 4.0C8:0 4.0C10:0 4.0C11:0 2.0C12:0 4.0C13: 2.0C14:0 4.0C14:1(cis-9) 2.0C15:0 2.0C15:1(cis-10) 2.0C16:0 6.0C16;1(cis-9) 2.0C17:0 2.0C17:1(cis-10) 2.0C18:0 4.0C18:1(trans-9) 2.0C18:1(cis-9) 4.0C18:2(all-trans-9,12) 2.0

CChhaaiinn %% bbyy WWeeiigghhttC18:2(all-cis-9,12) 2.0C18:3(all-cis-6,9,12) 2.0C18:3(all-cis-9,12,15) 2.0C20:0 4.0C20:1(cis-11) 2.0C20:2(all-cis-11,14,) 2.0C20:3(all-cis-8,11,14) 2.0C20:3(all-cis-11,14,17) 2.0C20:4(all-cis-5,8,11,14) 2.0C20:5(all-cis-5,8,11,14,17) 2.0C21:0 2.0C22:0 4.0C22:1(cis-13) 2.0C22:2(all-cis-13,16) 2.022:6 (all-cis-4,7,10,13,16,19) 2.0C23:0 2.0C24:0 4.0C24:1(cis-15) 2.0

Food Industry FAME Mix (37 components)


CChhaaiinn %% bbyy WWeeiigghhttC4:0 1.5C6:0 1.5C8:0 2.0C10:0 2.5C11:0 2.5C12:0 5.0C13: 2.5C14:0 2.5C14:1(cis-9) 1.5C15:0 1.5C16:0 10.0C16:1(cis-9) 5.0C17:0 2.5C18:0 5.0

CChhaaiinn %% bbyy WWeeiigghhttC18:1(trans-9) 2.5C18:1(cis-9) 15.0C18:2(all-trans-9,12) 2.5C18:2(all-cis-9,12) 10.0C18:3(all-cis-9,12,15) 5.0C20:0 2.5C20:1(cis-11) 1.5C20:5(all-cis-5,8,11,14,17) 2.5C22:0 2.5C22:1(cis-13) 1.5C22:6(all-cis-4,7,10,13,16,19) 2.5C23:0 1.5C24:0 2.5C24:1(cis-15) 2.5

NLEA FAME Mix (28 components)


Neat Fatty Acid Methyl Esters

Fatty Acid Methyl Esters cont'd




CChhaaiinn DDeessccrriippttiioonn CCAASS ## qqttyy.. ccaatt..## pprriicceeC6:0 methyl caproate 106-70-7 100mg 35037C7:0 methyl heptanoate 106-73-0 100mg 35038C8:0 methyl caprylate 111-11-5 100mg 35039C9:0 methyl nonanoate 1731-84-6 100mg 35040C10:0 methyl caprate 110-42-9 100mg 35041C11:0 methyl undecanoate 1731-86-8 100mg 35042C12:0 methyl laurate 111-82-0 100mg 35043C13:0 methyl tridecanoate 1731-88-0 100mg 35044C14:0 methyl myristate 124-10-7 100mg 35045C14:1 Δ 9 cis methyl myristoleate 56219-06-8 100mg 35046C15:0 methyl pentadecanoate 7162-64-1 100mg 35047C16:0 methyl palmitate 112-39-0 100mg 35048C16:1 Δ 9 cis methyl palmitoleate 1120-25-8 100mg 35049C17:0 methyl heptadecanoate 1731-92-6 100mg 35050C18:0 methyl stearate 112-61-8 100mg 35051C18:1 Δ 9 cis methyl oleate 112-62-9 100mg 35052C18:2 Δ 9,12 cis methyl linoleate 112-63-0 100mg 35053C18:3 Δ 9,12,15 cis methyl linolenate 301-00-8 100mg 35054C19:0 methyl nonadecanoate 1731-94-8 100mg 35055C20:0 methyl arachidate 1120-28-1 100mg 35056C20:1 Δ 11 cis methyl eicosenoate 2390-09-2 100mg 35057C20:2 Δ 11,14 cis methyl eicosadienoate 2463-02-7 100mg 35058C20:3 Δ 11,14,17 cis methyl eicosatrienoate 55682-88-7 100mg 35059C20:4 Δ 5,8,11,14 cis methyl arachidonate 2566-89-4 100mg 35060C21:0 methyl heneicosanoate 6064-90-0 100mg 35061C22:0 methyl behenate 929-77-1 100mg 35062C22:1 Δ 13 cis methyl erucate 1120-34-9 100mg 35063C24:0 methyl lignocerate 2442-49-1 100mg 35064C24:1 Δ 15 cis methyl nervonate 2733-88-2 100mg 35065

free literatureFFooooddss,, FFllaavvoorrss,, aanndd FFrraaggrraanncceess Includes important analysis tips, and chromatograms for analysis of fats and oils, carbohydrates, vitamins,amino acids, organic acids, preservatives, flavors and fragrances, essential oils, and chiral separations.Retention time indices and product listings for all relevant GC and HPLC products also are included.


Minicataloglliitt.. ccaatt..## 5599226600AA


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Fatty Acid Methyl EstersQuantitative Fatty Acid Methyl Ester (FAME) Mixtures

These mixtures can be used for quantification (AOCS Method CE 1-62) and approximate the compositions of the followingtypes of oils:

Important Information About FAME Mixtures:

We certify that all raw materials used in these mixes have a minimum purity of 99%. The exact composition of each mixture is deter-mined by precise gravimetric techniques, based on a weight/weight % basis, and is confirmed using high resolution capillary gas chromatography. A Certificate of Analysis, supplied with each product, lists mixture composition and analysis conditions andincludes a sample chromatogram. Products are packaged by volume and are guaranteed to contain a minimum amount of50mg/ampul. The FAMEs in these are trans isomer.

Improper storage or handling after opening may result in accelerated degradation of the unsaturated compounds. All materials mustbe stored under nitrogen at -18°C to prevent degradation.

AOCS #1: corn, poppy seed, cotton seed, soybean, walnut, safflower, sunflower, rice, bran, and sesame oil

AOCS #2: linseed, perilla, hempseed, and rubberseed oilAOCS #3: peanut, rapeseed, and mustard seed oilAOCS #4: olive, teaseed, and neatsfoot oilAOCS #5: coconut, palm kernel, babassu, and ouri-curi oilAOCS #6: lard, beef or mutton tallow, and palm oilFAME #1: oils of mid-range chain lengths (C16 - C18)FAME #2: oils of short to mid-range chain lengths (C6 - C14)FAME #3: oils of short to mid-range chain lengths (C8 - C16)

FAME #4: oils of mid-range to long chain lengths (C16 - C24)FAME #5: oils of mid-range to long chain lengths (C16 - C24)FAME #6: oils of long chain lengths (C20 - C21)FAME #7: oils of short chain lengths (C6 - C10)FAME #8: oils of short to mid-range chain lengths (C11 - C15)FAME #9: oils of mid-range to long chain lengths (C16 - C20)FAME #12: oils of mid-range to long chain lengths (C13 - C21)FAME #13: mustard seed oilFAME #14: cocoa butterFAME #15: peanut oil

methyl nervonate (24:1)

methyl lignocerate (24:0)

methyl docosadienoate (22:2)

methyl erucate (22:1)

methyl behenate (22:0)

methyl heneicosanoate (21:0)

methyl arachidonate (20:4)

methyl hom

o γlinolenate (20:3)

methyl eicosadienoate (20:2)

methyl eicosenoate (20:1)

methyl arachidate (20:0)

methyl nonadecanoate (19:0)

methyl linolenate (18:3)

methyl linoleate (18:2)

methyl oleate (18:1)

methyl stearate (18:0)

methyl heptadecanoate (17:0)

methyl palm

itoleate (16:1)

methyl palm

itate (16:0)

methyl pentadecanoate (15:0)

methyl m

yristate (14:0)

methyl tridecanoate (13:0)

methyl laurate (12:0)

methyl undecanoate (11:0)

methyl caprate (10:0)

methyl nonanoate (9:0)

methyl caprylate (8:0)

methyl heptanoate (7:0)

methyl caproate (6:0)

MMiixx ccaatt.. ## pprriiccee CCoommppoossiittiioonn ooff eeaacchh mmiixxttuurree lliisstteedd aass aa wweeiigghhtt//wweeiigghhtt %% bbaassiiss ((mmiinniimmuumm 5500mmgg//aammppuull))AOCS #1 35022 6.0 3.0 35.0 50.0 3.0 3.0AOCS #2 35023 7.0 5.0 18.0 36.0 34.0AOCS #3 35024 1.0 4.0 3.0 45.0 15.0 3.0 3.0 3.0 20.0 3.0AOCS #4 35025 11.0 3.0 80.0 6.0AOCS #5 35026 7.0 5.0 48.0 15.0 7.0 3.0 12.0 3.0AOCS #6 35027 2.0 30.0 3.0 14.0 41.0 7.0 3.0FAME #1 35010 20.0 20.0 20.0 20.0 20.0FAME #2 35011 20.0 20.0 20.0 20.0 20.0FAME #3 35012 20.0 20.0 20.0 20.0 20.0FAME #4 35013 20.0 20.0 20.0 20.0 20.0FAME #5 35014 20.0 20.0 20.0 20.0 20.0FAME #6 35015 20.0 20.0 20.0 20.0 20.0FAME #7 35016 20.0 20.0 20.0 20.0 20.0FAME #8 35017 20.0 20.0 20.0 20.0 20.0FAME #9 35018 20.0 20.0 20.0 20.0 20.0FAME #12 35021 20.0 20.0 20.0 20.0 20.0FAME #13 35034 3.0 1.0 2.0 20.0 15.0 10.0 1.0 10.0 2.0 1.0 30.0 2.0 1.0 2.0FAME #14 35035 0.1 26.3 0.4 0.3 33.7 34.3 3.1 0.2 1.3 0.1 0.2FAME #15 35036 10.0 3.0 50.0 30.0 1.5 1.5 3.0 1.0

ordering noteCustom fatty acid methyl ester mixtures also are available. Call 880000--335566--11668888 or 881144--335533--11330000, or contact your Restek representative for details.


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Derivatization Reagents

CCoommppoouunndd CCAASS## ccaatt..## pprriicceeMBTFA (N-methyl-bis-trifluoroacetamide)10-pk. (10x1g) 685-27-8 3561625g vial 685-27-8 35617TFAA (trifluoroacetic acid anydride)10-pk. (10x1g) 407-25-0 3561825g vial 407-25-0 35619PFAA (pentafluoropropionic acid anhydride)10-pk. (10x1g) 356-42-3 3562025g vial 356-42-3 35621HFAA (heptafluorobutyric acid anydride)10-pk. (10x1g) 336-59-4 3562225g vial 336-59-4 35623PFPOH (pentafluoropropanol)10-pk. (10x1g) 422-05-9 3562425g vial 422-05-9 35625

Acylation Derivatization Reagents

Acylation reagents offer the same types of advantages availablefrom silylation reagents: creating less polar, more volatile deriva-tives. In comparison to silylating reagents, the acylating reagentscan more readily target highly polar multi-functional com-pounds, such as carbohydrates and amino acids. In addition,acylating reagents offer the distinct advantage of introducingelectron-capturing groups, thus enhancing detectability during analysis.

• Most commonly used for Electron Capture Detection.• React with alcohols, amines and phenols.• Frequently used for drugs of abuse confirmation.

CCoommppoouunndd CCAASS## ccaatt..## pprriicceeTMPAH10-pk. (10x1g) 1899-02-1 3561425g vial 1899-02-1 35615

Alkylation Derivatization Reagents

Alkylation reagents reduce molecular polarity by replacing activehydrogens, such as carboxylic acids and phenols. Alkylationreagents can be used alone to form esters and amides or they canbe used in conjunction with acylation or silylation reagents. Atwo-step approach is commonly used in the derivatization ofamino acids, where multiple functional groups of these com-pounds may necessitate protection during derivatization.

Esterification is the reaction of an acid with an alcohol in thepresence of a catalyst. It is the most popular method of alkylationdue to the availability of reagents and ease of use. Alkyl esters arestable, and can be formed quickly and quantitatively. Retentionof the derivative can be varied by altering the length of the sub-stituted alkyl group. In addition to the formation of simpleesters, alkylation reagents can be used in extraction procedureswhere biological matrices are present.

• Adds alkyl groups to functional hydrogens (H).• Decreases polarity on compounds containing acidic

hydrogens, i.e., phenols, carboxylic acids.• Forms an ester.

• Replaces active hydrogen, reducing polarity and making thecompounds more volatile.

• Increases stability of derivatives.

CCoommppoouunndd CCAASS## ccaatt..## pprriicceeMSTFA (N-methyl-N-trimethylsilytrifluoroacetamide)10-pk. (10x1g) 24589-78-4 3560025g vial 24589-78-4 35601MSTFA w/1% TMCS (N-methyl-N-trimethylsilytrifluoroacetamide w/1%trimethylchlorosilane)10-pk. (10x1g) 24589-78-4 3560225g vial 24589-78-4 35603BSTFA (N,O-bis[trimethylsilyl]trifluoroacetamide)10-pk. (10x1g) 25561-30-2 3560425g vial 25561-30-2 35605BSTFA w/1% TMCS (N,O-bis[trimethylsilyltrifluoroacetamide] w/1% trimethylchlorosilane)10-pk. (10x1g) 25561-30-2 3560625g vial 25561-30-2 35607MTBSTFA w/1% TBDMCS (N-methyl-N[tert-butyldimethylsilyl trifluoroacetamide] w/1% tert-butyldimethylchlorosilane)10-pk. (10x1g) 77377-52-7 3560825g vial 77377-52-7 35610TMCS (trimethylchlorosilane)10-pk. (10x1g) 75-77-4 3561125g vial 75-77-4 35612

Silylation Derivatization Reagents

Silylation is the most widely used derivatization procedure forsample analysis by GC. In silylation, an active hydrogen isreplaced by an alkylsilyl group such as trimethylsilyl (TMS) ortert-butyldimethylsilyl (tert-BDMS). Silyl derivatives are morevolatile, less polar, and more thermally stable. As a result, GCseparation is improved and detection is enhanced.

Both TMS and tert-BDMS reagents are suitable for a wide vari-ety of compounds and can be used for many GC applications.Note that silylation reagents are generally moisture sensitive andmust be sealed to prevent deactivation.

DerivatizationReagents• Reagents available for acylation,

alkylation, and silylation.• Packaged in 10 x 1g vials or 25g vials.• High purity for accurate results.


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FAPAS® Proficiency Testing

Equal concentration of all compounds. Suitable for GC/MS analysis.

Varied concentrations. Suitable for GC/ECD analysis.

Equal concentration of all compounds. Suitable for GC/FPD, GC/NPD,& GC/MS analysis.

FAPAS-registered trademark of Central Science Laboratory, Sand Hutton, York,YO41, UK.

FAPAS® Food Testing Program*

• External check of quality for laboratories performing food testing.• Ensures accurate proficiency testing.

Laboratories testing food quality and safety are encouraged to routinely perform proficiency tests. Proficiency testing is an externalcheck of quality. It provides an independent and unbiased assessment of the performance of all aspects of the laboratory, both humanand hardware. Each participating laboratory is encouraged to use its normal analytical method, thereby simulating the testing of aroutine laboratory sample as closely as possible. While the outcome of the analysis may depend on the choice of method, it also couldbe affected by the performance of the laboratory equipment or the competence of the analyst. Using proficiency testing, those labo-ratories performing well can ensure high standards are maintained and those performing unsatisfactorily can implement correctiveaction rapidly. In an environment in which analytical laboratories compete intensively for work, proficiency testing provides themeans by which external customers can compare competence in carrying out specific tests. Together with laboratory accreditationand the use of validated methods, proficiency tests are an important requirement of the EU Additional Measures Directive 93/99/EECapplying to laboratories entrusted with the official control of food.

aldrinα-BHCβ-BHCγ-BHC (lindane)α-chlordane (cis)γ-chlordane (trans)4,4'-DDD4,4'-DDE2,4'-DDT4,4'-DDT

dieldrinα-endosulfan (I)β-endosulfan (II)endosulfan sulfateendrinheptachlorheptachlor epoxide (isomer B)hexachlorobenzeneoxychlordane

*Use of Restek calibration mixtures by laboratories participating in the FAPAS program is voluntary and no endorsement of any Restek product has been made by theCentral Science Laboratory. To obtain further information regarding the FAPAS program, or to participate, contact [email protected].

FAPAS® Series 5 OC Pesticide Mix 1 (19 components)


aldrin 10µg/mLα-BHC 10β-BHC 10γ-BHC (lindane) 10α-chlordane (cis) 10γ-chlordane (trans) 104,4'-DDD 204,4'-DDE 202,4'-DDT 204,4'-DDT 20

dieldrin 20α-endosulfan (I) 10β-endosulfan (II) 20endosulfan sulfate 20endrin 20heptachlor 10heptachlor epoxide (isomer B) 10hexachlorobenzene 10oxychlordane 10

FAPAS® Series 5 OC Pesticide Mix 2 (19 components)


chlorpyriphoschlorpyriphos-methyldiazinondichlorvosetrimphos

fenitrothionmalathionmethacriphosphosphamidonpirimiphos-methyl

FAPAS® Series 9 OP Pesticide Mix 1 (10 components)


also availablePlastic Container Testing Reference Materials.See ppaaggee 447700.

Get More!Food, Flavor & Fragrance

Articles Onlinewww.restek.com/FFF


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Column Test Mixes

nC10-FAME 0.42mg/mLnC11-FAME 0.42nC12-FAME 0.412,3-butanediol 0.53dicyclohexylamine 0.312,6-dimethylaniline 0.32

2,6-dimethylphenol 0.322-ethylhexanoic acid 0.38nonanal 0.401-octanol 0.36undecane (C11) 0.29decane (C10) 0.28

Grob Test Mix (Capillary GC)


1,2-butanediol 0.60mg/mLpyridine 0.60decane (C10) 0.60diethylenetriamine 1.20

diethanolamine 1.202-nonanol 0.602,6-dimethylaniline 0.60dodecane (C12) 0.60

Amine Column Test Mix (GC)

In methylene chloride:methanol (1:1), 1mL/ampulcat. # 35002 (ea.)

1,2-hexanediol 0.46mg/mLdecane (C10) 0.29undecane (C11) 0.29dodecane (C12) 0.29tridecane 0.29

1-octanol 0.36nonanal 0.402,6-dimethylaniline 0.322,6-dichlorophenol 0.57naphthalene 0.32

Isothermal Column Test Mix (GC)


benzene 1.00mg/mLbenzaldehyde 0.04

benzyl alcohol 3.004-methoxybenzyl alcohol 2.00

HPLC Normal Phase Test Mix #1


benzene 3.00mg/mLuracil 0.02

naphthalene 0.50biphenyl 0.06

HPLC Reversed Phase Test Mix #1

In methanol:water (75:25), 1mL/ampulcat. # 35005 (ea.)

benzoic acid 1.0%benzyl salicylate 36.2%1,8-cineole (eucalyptol) 0.5%trans cinnamaldehyde 0.5%cinnamyl acetate 0.3%cinnamyl alcohol 0.3%ethyl butyrate 36.2%

geraniol 0.6%hydroxycitronellal (3,7-dimethyl-

7-hydroxyoctanal) 5.0%d-limonene 20.0%thymol 0.3%vanillin 0.1%

Fragrance Materials Test Mix

The Fragrance Materials Association (FMA) has proposed a methodfor analyzing essential oils on polar and nonpolar capillary GCcolumns. A performance evaluation mixture should be used to aid indetecting inlet problems, stationary phase degradation, loss of reso-lution, changes in sensitivity, and the presence of reactive sites in thesample pathway. Our test mix is consistent with the mixture proposed by the FMA. The required 5% test solution is made bydiluting the 0.5mL of neat mixture to 10mL with acetone. The work-ing solution will be stable for up to one week if transferred to a darkcontainer and stored refrigerated.

Neat, 0.5mL in an amber ampulcat. # 31807 (ea.)







For use with temperature programmed conditions.

For Stabilwax®-DB, Rtx®-5Amine, and Rtx®-35Amine columns.

dimethyldichlorosilane (DMDCS)

Dimethyldichlorosilane (DMDCS) Deactivating Agent

Restek offers dimethyldichlorosilane (DMDCS), for deactivatingliners and other glassware. Simply dilute the neat material to a 5%solution in toluene, soak the glass item(s) in the solution for 15minutes, and rinse with toluene and methanol. DMDCS reactswith active hydroxyl groups on the glass surface to produce a deac-tivated surface. A detailed procedure is included with the product.



also availableSee ppaaggeess 662277--663377 for chromatograms of flavors andfragrances analysis.


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System Per formance Test Mixes

Caffeine at 5.0, 25.0, 125.0, 250.0, 500.0µg/mL in water in a five ampul kit.

HPLC OQ Linearity Test Mix Kit

Linear detector responses to concentration variations are animportant part of operation qualification (OQ) for HPLCinstruments. Our kit of five aqueous solutions of caffeine can beused to generate simple plots of UV response versus concentra-tion. Certificate of Analysis includes caffeine concentration, cal-culated variance in preparing each mixture, a linearity plot, andcoefficient of determination (r²) for the linear plot.

1mL each of these mixtures.cat. # 31805 (kit)

glucose 2.0mgfructose 2.1lactose 4.4

maltose 4.5sucrose 4.0

Carbohydrate HPLC Performance Check Mix

Performance qualification (PQ) determines the precision of theHPLC system. Our performance check mix for HPLC/RI consistsof five simple sugars in varied concentrations. We prepare thereference material in water, lyophilize it, and pack it dry forenhanced stability.

Dry components in 4mL screw-cap vial. Reconstitute in 1mL acetonitrile:water (75:25)to 2.0, 2.1, 4.4, 4.5, 4.0mg/mL, respectively.

cat. # 31809 (ea.)

amitriptyline hydrochloride 2,800µg/mL

ethylbenzene 1,700

quinizarin 94toluene 1,400uracil 28

HPLC Performance Test Mix

The National Institute of Standards and Technology (NIST) hasformulated a mixture that is highly effective for characterizingHPLC columns for efficiency, void volume, methylene selectivi-ty, retentiveness, and activity toward chelators and organic bases.Results can be used for column classification, for column selec-tion, for monitoring column performance over time, or for qual-ity control. We test our material against the NIST 870 standard.





n-heptadecane (C17) 1.5µg/mLn-octadecane (C18) 10n-nonadecane (C19) 2n-eicosane (C20) 100

n-docosane (C22) 1,000n-tetracosane (C24) 10,000

OQ Response Linearity Test Standard

In isooctane, 1mL/ampulcat. # 33906 (ea.)

azobenzene 6.5µg/mLmalathion 10

n-octadecane 100NPD Performance Evaluation Standard

In isooctane, 1mL/ampulcat. # 33907 (ea.)

n-tetradecane (C14)n-pentadecane (C15)

n-hexadecane (C16)FID Performance Evaluation Standard

0.03 w/w% each in hexane, 1mL/ampulcat. # 33908 (ea.)

1,2-dichlorobenzenenitrobenzene

tert-butyl disulfideOQ/PV Headspace Standard

2,000µg/mL each in ethanol, 1mL/ampulcat. # 33909 (ea.)

also availableIndividual ampuls of caffeine are available on ppaaggee 440000.

For Restek’s complete line of columntest mixes, visit our website at:www.restek.com/testmixes


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