3. introduction to chemistry

159
Chapter 1 INTRODUCTION TO CHEMISTRY

Upload: vian-roy

Post on 26-Oct-2014

46 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: 3. Introduction to Chemistry

Chapter 1

INTRODUCTION TO

CHEMISTRY

Page 2: 3. Introduction to Chemistry
Page 3: 3. Introduction to Chemistry
Page 4: 3. Introduction to Chemistry
Page 5: 3. Introduction to Chemistry
Page 6: 3. Introduction to Chemistry

Historical Development of CHEMISTRY

Page 7: 3. Introduction to Chemistry

• Do you think chemistry has existed even before its declaration as a science?

• What are the proof of its existence?

Page 8: 3. Introduction to Chemistry

History of ChemistryEarly practices of chemistry:

1. Metallurgy2. Use of fermentation in making wine and beer

(10,000 yrs ago)3. Leather tanning in Mesopotamia

(7,000 yrs ago)4. Glass making by the Egyptians

(4,500 yrs ago)5. Use of enzymes to make cheese

(3,000 yrs ago)

Page 9: 3. Introduction to Chemistry

History of Chemistry

Fermentation in making wine and beer (10,000 yrs ago)

Page 10: 3. Introduction to Chemistry

History of Chemistry

Leather tanning in Mesopotamia (7,000 yrs ago)

Page 11: 3. Introduction to Chemistry

History of Chemistry

Glass making by the Egyptians (4,500 yrs ago) using sand, limestone and baking soda

Page 12: 3. Introduction to Chemistry

History of Chemistry

Use of enzymes to make cheese (3,000 yrs ago)

Page 13: 3. Introduction to Chemistry

History of Chemistry

• 600 B.C. • highlights extraction and working of metals.

Egyptians extracted copper, gold, silver and lead from their ores and work on brass and bronze.

• dyeing and alcoholic beverages production• extraction of oils and alkaloid from plants

Page 14: 3. Introduction to Chemistry

History of Chemistry

• 600 - 200 B.C.• highlights the Greeks curiosity, intellect and

vigorous imagination. • Original ideas and many fundamental scientific

problems was recognized by the philosophers of Ancient Greece.

• Democritus, Aristotle and Leucippus are among those Greek philosophers.

Page 15: 3. Introduction to Chemistry

Greek ideasAll substances are made of 4

elementsFire - hotAir - lightWater - wetEarth - cool, heavy

Blend these in different proportions to get all substances

Page 16: 3. Introduction to Chemistry

Thales (600 B.C.) Water

Page 17: 3. Introduction to Chemistry

Xenophanes (500 B.C.)

Earth Water

Page 18: 3. Introduction to Chemistry

Empedocles (440 B.C.)Four elements

Earth

Water

AirFire

(more commonly called dirt)

Page 19: 3. Introduction to Chemistry
Page 20: 3. Introduction to Chemistry

Two Forces shape matter

Love & Strife

Page 21: 3. Introduction to Chemistry
Page 22: 3. Introduction to Chemistry

First Table of the Elements

Hot Dry

ColdWet

Page 23: 3. Introduction to Chemistry

Fifth ElementQuintessence

Philosopher’s stone

Page 24: 3. Introduction to Chemistry

Fifth Element makes up the celestial bodies

Gold is the perfect metal.All other metals are less perfect.

The fifth element is so divine that it can turn the lesser (more base) metals into gold.

Page 25: 3. Introduction to Chemistry

Elixir of life (a fountain of youth)

Fifth Element

Page 26: 3. Introduction to Chemistry
Page 27: 3. Introduction to Chemistry
Page 28: 3. Introduction to Chemistry

Chinese ideasAll matters constitute of 5 elements

MetalWoodWaterFireEarth

"Different combinations of earth, metal, wood, water and fire form everything in the world."

Page 29: 3. Introduction to Chemistry
Page 30: 3. Introduction to Chemistry
Page 31: 3. Introduction to Chemistry

Chinese ideas"Water corresponds to moisture and the direction

of down.” “Fire corresponds to blaze and the direction of

up.”“Wood is curvy or straight in nature.” “Metal is unstable under fire.” “Earth is necessary for agriculture.” “Water becomes salty when travelling down.”

Page 32: 3. Introduction to Chemistry

Chinese ideas“Fire becomes bitter when blazing

upward.” “Wood may turn acid when it changes

shape.” “Metal may turn bitter when it becomes

unstable.” “Earth may turn sweet when used in

agriculture."

Page 33: 3. Introduction to Chemistry

History of Chemistry

• 400 - 1650 • highlights the rise and spread of alchemy, the pretended

art of changing baser metal into gold. • the quest for the miraculous “philosopher stone”• many useful apparatus were perfected• large number of new and important substances were

prepared/discovered• new techniques developed

Page 34: 3. Introduction to Chemistry

History of Chemistry

• 1400 - 1750 • highlights the development of systematic metallurgy by Georg

Bauer• medicinal application and preparation of remedies and drugs by

Paracelsus• Roger Bacon stressed competent knowledge through

experimentation• Francis Bacon exposed the fallibility of Aristotle’s doctrines• relationship between pressure and volume of gases was measured

by Robert Boyle

Page 35: 3. Introduction to Chemistry

History of Chemistry

• 1700 - 1777 B.C.• Georg Stahl suggested that all combustible

substances contained a “fiery principle”, phlogiston, which escaped as flame when heated

• oxygen gas was discovered by Joseph Priestley• quantitative and qualitative analysis improved

greatly by Joseph Black and Olaf Bergman

Page 36: 3. Introduction to Chemistry

Who’s Next? Antoine Lavoisier (1743-1794) overthrow completely the

phlogiston theory and provided explanation of combustion.

Joseph Proust (1754-1826) showed that a given compound always contains exactly the same proportion of elements by weight.

John Dalton (1766-1844) postulated that the fundamental differences among atoms are their masses.

Page 37: 3. Introduction to Chemistry

History of Chemistry

Early Greek Ideas on Matter

1. Democritus proposed the “atomos” which means “cannot be cut” as a building block of all matter (2,500 yrs ago)

2. Aristotle proposed that matter is made of the four elements- earth, air, water and fire (2,400 yrs ago)

Page 38: 3. Introduction to Chemistry

History of ChemistryDemocritus proposed the “atomos” which means “cannot be cut” as a building block of all matter (2,500 yrs ago).

His theory was ignored. It was only until the 20th century (1900s) that the concept of the atom was accepted by all scientists.

Page 39: 3. Introduction to Chemistry

History of ChemistryAristotle proposed that matter is made of the four elements- earth, air, water and fire (2,400 yrs ago).

It was even believed that a chemist can make gold from any matter by finding the right mix of earth, air, water and fire.

His idea became more popular than Democritus’ idea of the atomos.

Page 40: 3. Introduction to Chemistry

History of ChemistryEastern Alchemy

1. The Greeks passed on their knowledge to the Arabians who pursued alchemy (the ancient version of chemistry)

2. Alchemy is the study of:a. Transmuting base metals into gold and

silver (the philosopher’s stone)b. Discovering the universal cure for diseasec. Discovering immortality

Page 41: 3. Introduction to Chemistry

History of ChemistryAlchemy is the study of:

a. Transmuting base metals into gold and silver (the philosopher’s stone)

b. Discovering the universal cure for disease

c. Discovering immortality

Page 42: 3. Introduction to Chemistry

History of ChemistryAlchemy among the Arabs

1. Ar-Razi (1,100 yrs ago) is considered as one of the Fathers of Medicine.

2. Avicenna (1,000 yrs ago) wrote one of the most famous books in medicine (Al-Qanoon fittib: the Cannon of Medicine)

3. Arabian alchemists first practiced the scientific method and so laid the foundation for chemistry.

Page 43: 3. Introduction to Chemistry

History of Chemistry

Arabian physician-alchemists first practiced the scientific method and so laid the foundation for chemistry.

Page 44: 3. Introduction to Chemistry

History of ChemistryEarly Western Alchemy

1. Alchemical knowledge was transferred to Europe through an English Franciscan friar named Roger Bacon (900 yrs ago) who taught that alchemy should be used to produce medicines.

2. Ironically, early European alchemy would be dominated by the quest for transmuting metals into gold.

Page 45: 3. Introduction to Chemistry

History of ChemistryRoger Bacon taught that alchemy should be used to produce medicine. But European alchemists became obsessed with the search for the philosopher’s stone.

Page 46: 3. Introduction to Chemistry

History of Chemistry

Iatrochemistry in Renaissance Europe

1. Paracelsus (450 yrs ago) established the practice of iatrochemistry which is the use of alchemy to produce medicines made of minerals such as mercury.

2. He also taught that medicines must be made as “pure substances” or substances that are free from contaminants.

Page 47: 3. Introduction to Chemistry

History of ChemistryParacelsus (450 yrs ago) founded iatrochemistry. He also taught that medicines must be made as “pure substances” or substances that are free from contaminants.

Page 48: 3. Introduction to Chemistry

History of ChemistryThe Element is Defined

1. Robert Boyle (300 years ago) defined the element as a pure substance which cannot be broken down into simpler substances.

2. He also worked on the behavior of gases and discovered Boyle’s Law: that the volume of gasses decreases with increasing pressure.

Page 49: 3. Introduction to Chemistry

History of Chemistry

Robert Boyle (300 yrs ago) defined that an element is a substance that cannot be broken down into simpler substance.

He is still an alchemist however, since he believed in transmutation.

Page 50: 3. Introduction to Chemistry

History of Chemistry

The Father of Modern Chemistry

1. Antoine-Laurent Lavoisier (200 yrs ago) is recognized as the Father of Modern chemistry.

2. Lavoisier is known for his exact measurements and meticulous experiments in the lab and for establishing the Law of Conservation of Mass.

3. The Law of Conservation of Mass states that mass is never gained or lost during chemical reactions.

Page 51: 3. Introduction to Chemistry

History of ChemistryAntoine-Laurent Lavoisier also

worked on:

1. Combustion2. Reduction3. and the nomenclature of

inorganic compounds

He was beheaded during the French revolution.

Page 52: 3. Introduction to Chemistry

It’s because he was a teacher!!!

Page 53: 3. Introduction to Chemistry

The Language of ChemistryThe Language of ChemistryCHEMICAL ELEMENTS -

– pure substances that cannot be decomposed by ordinary means to other substances.

SodiumBromine

Aluminum

Page 54: 3. Introduction to Chemistry

The Language of ChemistryThe Language of Chemistry• The elements,

their names, and symbols are given on the

PERIODIC TABLE

• How many elements are there?

Page 55: 3. Introduction to Chemistry

The Periodic Table

Dmitri Mendeleev (1834 - 1907)

Page 56: 3. Introduction to Chemistry

Glenn Seaborg(1912-1999)

• Discovered 8 new elements.

• One of whom an element was named.

Page 57: 3. Introduction to Chemistry

Branches of Chemistry

• Many major areas of study for specialization

• Several career opportunities• Also used in many other jobs

Page 58: 3. Introduction to Chemistry

1. Organic Chemistry

• Organic is the study of matter that contains carbon

• Organic chemists study the structure, function, synthesis, and identity of carbon compounds

• Useful in petroleum industry, pharmaceuticals, polymers

Page 59: 3. Introduction to Chemistry

2. Inorganic Chemistry

• Inorganic is the study of matter that does NOT contain carbon

• Inorganic chemists study the structure, function, synthesis, and identity of non-carbon compounds

• Polymers, Metallurgy

Page 60: 3. Introduction to Chemistry

3. Biochemistry

• Biochemistry is the study of chemistry in living things

• Cross between biology and chemistry

• Pharmaceuticals and genetics

Page 61: 3. Introduction to Chemistry

4. Physical Chemistry

• Physical chemistry is the physics of chemistry… the forces of matter

• Much of IPC is computational

• Develop theoretical ideas for new compounds

Page 62: 3. Introduction to Chemistry

5. Analytical Chemistry

• Analytical chemistry is the study of high precision measurement

• Find composition and identity of chemicals

• Forensics, quality control, medical tests

Page 63: 3. Introduction to Chemistry
Page 64: 3. Introduction to Chemistry

Or Do You Feel Like This When Doing Science?

Page 65: 3. Introduction to Chemistry

The Scientific Methodprocess that lies

at the center of scientific inquiry

Page 66: 3. Introduction to Chemistry

Steps in the Scientific Method?

making observationsformulating hypothesisperforming experiments

Page 67: 3. Introduction to Chemistry

Observations?

Water boils at 100 °C.

Kristel weighs 43 kilograms.

The leaves are turning yellow.

The coffee is hot.

Quantitative}

Qualitative}

Page 68: 3. Introduction to Chemistry

Hypothesis?

a possible explanation for the observation.

Page 69: 3. Introduction to Chemistry

Experiments

carried out to test the hypothesis

involves information gathering

Page 70: 3. Introduction to Chemistry

? Question ?

What do you do once a set of hypotheses that agree with various observations is obtained?

Page 71: 3. Introduction to Chemistry

They are assembled into a

theory

Page 72: 3. Introduction to Chemistry

Theory… a philosophya concepta model a systema scheme

Page 73: 3. Introduction to Chemistry

Theory

often called a model, it is a set of tested hypotheses that gives an overall explanation of some phenomena

Page 74: 3. Introduction to Chemistry

Theories interpretations or possible

explanations changes eventually as more

information becomes available attempts to explain observed

natural behaviors

Page 75: 3. Introduction to Chemistry

Law…

a binding rulea piece of legislationa general principlea control or authoritya branch of knowledge

Page 76: 3. Introduction to Chemistry

Natural Laws?

a scientific truth a statement of a generally observed behaviors a summary of what happens

Page 77: 3. Introduction to Chemistry

Parts of scientific method

Experiment

Theory

PredictionTheory

Modified as needed

Page 78: 3. Introduction to Chemistry

Points to Ponder?

chemists/scientists are humans sometimes/oftentimes:

prejudice misinterprets data lose objectivity play politics etc., etc.

Page 79: 3. Introduction to Chemistry

Points to Ponder?

chemistry/science is affected: budget and profit motives wars and politics fads and religious beliefs

Page 80: 3. Introduction to Chemistry

Examples Galileo was forced to recant his

astronomical observations in the face of strong religious resistance

Lavoisier was beheaded because of his political affiliations

great progress in Nitrogen chemistry resulted from the desire to produce explosives to fight wars

Page 81: 3. Introduction to Chemistry

Nature of Science Terms• Fact: an observation that has been repeatedly confirmed

and for all practical purposes is accepted as “true”.

• Hypothesis: A tentative statement about the natural world leading to deductions that can be tested. If the deductions are verified, the hypothesis is corroborated. If false, the hypothesis must be abandoned or revised.

• Law: A descriptive generalization about how some aspect of the natural world behaves under stated circumstances.

• Theory: A well-substantiated explanation of some aspect of the natural world that can incorporate facts, laws, inferences, and tested hypothesis.

Page 82: 3. Introduction to Chemistry

Graphs

Page 83: 3. Introduction to Chemistry

Bar Graphshows how many of something

are in each category

0

2

4

6

8

10

A B C D F

Chemistry Grades

Page 84: 3. Introduction to Chemistry

Pie Graph shows how a whole is broken into parts

40%

25%20%

15%Entertainment (40%)

Food (25%)

Clothing (20%)

Savings (15%)

Percentage ofWeekly Income

Page 85: 3. Introduction to Chemistry

Line Graphshows continuous change

0

10

20

30

40

50

60

Jan Feb Mar Apr

Month

Sh

are

Pri

ce (

$)

Stock Price over Time

Page 86: 3. Introduction to Chemistry

Elements of a “good” line graph

• axes labeled, with units

• use the available space

• title• neat

Temp. v. Vol. for a Gas at Constant Pressure

0123456789

10

120 140 160 180 200 220 240

Temp. (K)

Vo

lum

e (

L)

Page 87: 3. Introduction to Chemistry

Graphs

• Line Graph– Used to show trends or continuous change

• Bar Graph– Used to display information collected by

counting

• Pie Graph– Used to show how some fixed quantity is

broken down into parts

0

20

40

60

80

1s t

Qtr

2nd

Qtr

3r d

Qtr

4th

Qtr

Page 88: 3. Introduction to Chemistry

Pie Graph

Page 89: 3. Introduction to Chemistry

Pie Graphs

Earth's Crust

Oxygen49%

Silicon26%

Other9%

Aluminum8%

Iron5%

Calcium3%

Oxygen

Silicon

Other

Aluminum

Iron

Calcium

Page 90: 3. Introduction to Chemistry

Measurement of Matter

Page 91: 3. Introduction to Chemistry

Measurement

Metric – The Universal Language of Measurement

Page 92: 3. Introduction to Chemistry

Measurement

is a process of comparing a known quantity like measuring device to an unknown quantity or the things or objects to be measured. It is the process of determining how many times a certain quantity is contained in a standard measuring device.

Page 93: 3. Introduction to Chemistry

• The loss of the Mars Climate Orbiter on September 23, 1999, was a most unfortunate and highly avoidable event.

• The cause of the mishap has been traced to a mix-up over units. Preliminary findings indicated that one team used English units (e.g., inches, feet and pounds) while the other used metric units for maneuvers required to place the spacecraft in the proper Mars orbit.

• The 'root cause' of the loss of the spacecraft was the failed translation of English units into metric units.

• For nearly three centuries, engineers and scientists have been struggling with English units.

• The loss of the Mars Climate Orbiter on September 23, 1999, was a most unfortunate and highly avoidable event.

• The cause of the mishap has been traced to a mix-up over units. Preliminary findings indicated that one team used English units (e.g., inches, feet and pounds) while the other used metric units for maneuvers required to place the spacecraft in the proper Mars orbit.

• The 'root cause' of the loss of the spacecraft was the failed translation of English units into metric units.

• For nearly three centuries, engineers and scientists have been struggling with English units.

Page 94: 3. Introduction to Chemistry

In his first annual message to Congress (1790 January), President George Washington pressed for uniformity in currency, weights, and measures. Secretary of State Thomas Jefferson urged Congress to reduce the existing separate systems of dry and liquid measures to one set of measures.

Over 200 years later, we still have separate systems. For example, our dry quart is larger than our liquid quart, so four cups of flour and 4 cups of milk should be measured with separate measuring devices-which differ in size!

Jefferson's second plan put before Congress was to reduce every branch [of measurement] to the same decimal ratio already established for coin, and thus bring the calculations of the principal affairs of life within the arithmetic of every man who can multiply and divide plain numbers.

Congress took no action.  Washington urged action again in his second annual message to Congress (1790 December 08) and the House referred the matter to the Senate, whose committee in this matter declined (1791 March 01) due to negotiations in progress with the French and British Governments to obtain an international standards of measurements.

Page 95: 3. Introduction to Chemistry

Currency is based on 10.

Page 96: 3. Introduction to Chemistry

In the same year of 1790 King Louis XVI of France was also weary of the inconsistencies of measurement that was hurting trade.

He ordered a new system of measurements be developed.

Page 97: 3. Introduction to Chemistry

Earlier in that century, Fahrenheit and Celsius used water as the basis of their thermometers. Their thermometers were calibrated using water, which everyone had access to. This made their thermometers useful.

Page 98: 3. Introduction to Chemistry

METRIC SYSTEM

The scientific system of measurement is often referred to as the International

System of Units, or SI. Scientists throughout the world use the metric system of measurement. It is based on units of ten.

The meter was originally defined as 1/10,000,000 of the distance from the equator to the North Pole.

Page 99: 3. Introduction to Chemistry

Everyone has access to the Earth, so this new system was to be based on the size of the Earth.

The idea was to measure a part of Earth’s surface over a few degrees, then calculate distance from Equator to North Pole.

Page 100: 3. Introduction to Chemistry

A survey team was suppose to measure the distance between Barcelona, Spain going through Paris and up to the English Channel.

Page 101: 3. Introduction to Chemistry

By dividing the distance from the equator to the north pole by 10 million, a convenient length was defined.

It was a little longer than a yard, and the name would be from the Greek word, Metron,

meaning to measure.

10,000,000Equator to North PoleEquator to North Pole

Page 102: 3. Introduction to Chemistry
Page 103: 3. Introduction to Chemistry

The motto for the metric system was:

“For all people, for all time”

Page 104: 3. Introduction to Chemistry

Based on 10 & using Arabic Numerals

Since the number system in use was no longer Roman Numerals, but the decimal number system borrowed from the Arab worlds and from India, the measurement system should also be based on 10 to make conversions easy.

Page 105: 3. Introduction to Chemistry

Since we have 10 fingers, a number system based on 10 was developed.

Page 106: 3. Introduction to Chemistry

Place Value

Roman Numerals did not take advantage of place value. X in Roman Numerals meant ten. XXX meant thirty. It didn’t matter where the X was placed; it always had the value of 10

Page 107: 3. Introduction to Chemistry

Decimal

• The word decimal from from Latin decimalis meaning “of a tithe” A tithe was traditionally one tenth of income, so deci- meant one tenth.

• The new measuring system should also be based on tens and tenths.

Page 108: 3. Introduction to Chemistry
Page 109: 3. Introduction to Chemistry
Page 110: 3. Introduction to Chemistry

CubitsYardsMilesNautical MilesFeetHandsInchesLeaguesChainsFurlongs

Page 111: 3. Introduction to Chemistry

sq. milessq. yardssq. ft.sq. in.acres

Page 112: 3. Introduction to Chemistry

BarrelCubic inchesCubic feetCubic yardsMinimsDrops

Gallons, imperial gallons, quarts, pints, fluid ounces, pecks, bushels

Page 113: 3. Introduction to Chemistry

1 gram defined as the mass of one cubic centimeter of water (or one milliliter [mL] of water_.

Page 114: 3. Introduction to Chemistry

Liter from Litron:

Measure of capacity

One liter of water has a mass of one kilogram

Page 115: 3. Introduction to Chemistry

SI Base Quantities

Base Quantity Name of Unit SymbolLength meter mMass kilogram kgTime second sCurrent ampere ATemperature kelvin KAmount of substance mole molLuminous intensity candela cd

Page 116: 3. Introduction to Chemistry

Prefixes Used with SI Units

Prefix Symbol Meaning

Tera- T 1012

Giga- G 109

Mega- M 106

Kilo- k 103

Deci- d 10-1

Centi- c 10-2

Milli- m 10-3

Micro- m 10-6

Nano- n 10-9

Pico- p 10-12

Page 117: 3. Introduction to Chemistry

LENGTH

1 meter, m = 100 centimeters, cm1 meter, m = 1000 millimeters, mm1 meter, m = 1,000,000 micrometers, um1 meter, m = 1,000,000,000 nanometers, nm

1 meter, m = 10,000,000,000 Angstrom, A1,000 meters, m = 1 kilometer

MASS

1 kilogram, kg = 1,000 grams, g1 gram, g = 1,000 milligrams, mg1,000 kilograms, kg = 1 metric ton

VOLUME

1 Liter, L = 1,000 milliliters, mL1 Liter, L = 1,000 cubic centimeters, cc

TEMPERATURE

0C = 5/9 (0F-32) 0F = 9/5 (0C + 32)Kelvin, K = 0C + 273

Page 118: 3. Introduction to Chemistry

METRIC-ENGLISH Equivalent

METRIC ENGLISH 2.54 centimeter, cm 1 inch, in.

1 meter, m 39.37 inches, in.

1 kilometer, km 1.06 quartz, qt

250 milliliter, mL 1 cup, c

1 kilogram, kg 2.2 pounds, lb.

1 meter, m 3.28 feet, ft.

90 centimeters, cm 1 yard, yd.

3.79 Liters, L 1 gallon, gal

Page 119: 3. Introduction to Chemistry

Matter - anything that occupies space and has mass.mass – measure of the quantity of matter

SI unit of mass is the kilogram (kg)

1 kg = 1000 g = 1 x 103 g

weight – force that gravity exerts on an object

weight = g x mass

Page 120: 3. Introduction to Chemistry

120

Volume – SI derived unit for volume is cubic meter (m3)

1 cm3 = (1 x 10-2 m)3 = 1 x 10-6 m3

1 dm3 = (1 x 10-1 m)3 = 1 x 10-3 m3

1 L = 1000 mL = 1000 cm3 = 1 dm3

1 mL = 1 cm3

Page 121: 3. Introduction to Chemistry

You are not changing the size, just the name.

Page 122: 3. Introduction to Chemistry

Convert 0.15 meters to centimeters

0.15 meters = centimeters

Starting amount End Amount

.01

1 centi

0.15 meters = 15 meters100

= 15 centimeters

If saying 15 hundredths, just say 15 centi-

equal

Page 123: 3. Introduction to Chemistry

Convert 5234 millimeters to meters

5234 millimeters = meters

Starting amount End Amount

milli

0.001

5234 millimeters 5234 meters1000

equal

Page 124: 3. Introduction to Chemistry

Convert 5234 millimeters to centimeters

5234 millimeters = centimeters

Starting amount End Amount

milli

0.001

5234. millimeters

equal equal

0.01

centi

523.4 centimeters

Page 125: 3. Introduction to Chemistry

Convert 5234 millimeters to inches

5234 millimeters = inches

Starting amount End Amount

milli

0.001

equal equal

0.01

centi 2.54 cm

1 inch

1 inch

2.54 cm

Page 126: 3. Introduction to Chemistry

Convert 21 grams per liter (21 g/L) to milligrams per milliliter (mg/mL)

21 gramsLiter

= mgmL

Starting amount End Amount

milli

0.001

equal equal

0.001

milli

Page 127: 3. Introduction to Chemistry

Convert 21 mg per liter (21 g/L) to grams per 100 cc

21 mgLiter

= g 100cc

Starting amount End Amount

0.001

milli

equal equal

1L1000cc

0.10.1

equal

0.00021

Page 128: 3. Introduction to Chemistry

DENSITY

Density is equals to the mass over volume

D = m/V

Unit (g/mL)

Page 129: 3. Introduction to Chemistry

Density – SI derived unit for density is kg/m3

1 g/cm3 = 1 g/mL = 1000 kg/m3

density = mass

volume d = mV

A piece of platinum metal with a density of 21.5 g/cm3 has a volume of 4.49 cm3. What is its mass?

d = mV

m = d x V = 21.5 g/cm3 x 4.49 cm3 = 96.5 g

Page 130: 3. Introduction to Chemistry

Calculating the Density of An Object

from Its Mass and Volume

A block of wood with a length of 1.08m, height of 6.2 cm and width of 5.1 cm has a mass of 2.52 kg. What is the density of the wood, expressed in grams per cubic centimeter?

Page 131: 3. Introduction to Chemistry

Calculating the Mass of a Liquid from Its

Volume and Density

What is the mass of a 275 mL of ethanol? The density of ethanol is 0.789 g/mL

Page 132: 3. Introduction to Chemistry

Imran Syakir Mohamad

Chemistry DACS 1233 132

K = 0C + 273.15

0F = x 0C + 3295

273 K = 0 0C 373 K = 100 0C

32 0F = 0 0C 212 0F = 100 0C

Page 133: 3. Introduction to Chemistry

Convert 172.9 0F to degrees Celsius.

0F = x 0C + 3295

0F – 32 = x 0C95

x (0F – 32) = 0C95

0C = x (0F – 32)95

0C = x (172.9 – 32) = 78.395

Page 134: 3. Introduction to Chemistry

Percent Composition

Percent is the number of parts of a constituent in 100 parts of the whole.

Ex. A seawater contains 3.5% NaCl, by mass, means that in every 100 grams of seawater there is 3.5 g of NaCl present

Page 135: 3. Introduction to Chemistry

Uncertainties in Scientific Measurement

Precision – refers to the degree of reproducibility of a measured quantity

Accuracy – refers to how close a measured value is to the accepted or “real” value.

Page 136: 3. Introduction to Chemistry

Accuracy and Precision

Page 137: 3. Introduction to Chemistry

_____________ – how close a measurement is to the true value

__________ – how close a set of measurements are to each other

accurate&

precise

precisebut

not accurate

not accurate&

not precise

Page 138: 3. Introduction to Chemistry

Scientific Notation • Is a compact, simplest and easy way of

writing down very small and very large numbers using powers of ten or in exponential notation.

• The exponent tells the number of times the decimal point is moved from its original place to right or from the original place to the left.

• The exponent is NEGATIVE if the decimal point is moved from left to right and POSITIVE if it is moved from right to left.

Page 139: 3. Introduction to Chemistry

Scientific NotationThe number of atoms in 12 g of carbon:

602,200,000,000,000,000,000,000

6.022 x 1023

The mass of a single carbon atom in grams:

0.0000000000000000000000199

1.99 x 10-23

N x 10n

N is a number between 1 and 10

n is a positive or negative integer

Page 140: 3. Introduction to Chemistry

Example:

• 4,000,000 = 4.0 x 106

• 532,000,000 = 5.32 x 108

• 0.000000045 = 4.0 x 10-8

• 0.0032 = 3.2 x 10-3

Page 141: 3. Introduction to Chemistry

Scientific Notation568.762

n > 0

568.762 = 5.68762 x 102

move decimal left

0.00000772

n < 0

0.00000772 = 7.72 x 10-6

move decimal right

Addition or Subtraction

1. Write each quantity with the same exponent n

2. Combine N1 and N2 3. The exponent, n, remains the

same

4.31 x 104 + 3.9 x 103 =

4.31 x 104 + 0.39 x 104 =

4.70 x 104

Page 142: 3. Introduction to Chemistry

Scientific Notation

Multiplication

1. Multiply N1 and N2

2. Add exponents n1 and n2

(4.0 x 10-5) x (7.0 x 103) =(4.0 x 7.0) x (10-5+3) =

28 x 10-2 =2.8 x 10-1

Division

1. Divide N1 and N2

2. Subtract exponents n1 and n2

8.5 x 104 ÷ 5.0 x 109 =(8.5 ÷ 5.0) x 104-9 =

1.7 x 10-5

Page 143: 3. Introduction to Chemistry

Significant Figures• Any digit that is not zero is significant

1.234 kg 4 significant figures• Zeros between nonzero digits are significant

606 m 3 significant figures• Zeros to the left of the first nonzero digit are not

significant

0.08 L 1 significant figure• If a number is greater than 1, then all zeros to the right of

the decimal point are significant

2.0 mg 2 significant figures• If a number is less than 1, then only the zeros that are at

the end and in the middle of the number are significant

0.00420 g 3 significant figures

Page 144: 3. Introduction to Chemistry

How many significant figures are in each of the following measurements?

24 mL 2 significant figures

3001 g 4 significant figures

0.0320 m3 3 significant figures

6.4 x 104 molecules 2 significant figures

560 kg 2 significant figures

Page 145: 3. Introduction to Chemistry

Significant Figures

Addition or SubtractionThe answer cannot have more digits to the right of the decimalpoint than any of the original numbers.

89.332

1.1+

90.432 round off to 90.4

one significant figure after decimal point

3.70-2.9133

0.7867

two significant figures after decimal point

round off to 0.79

Page 146: 3. Introduction to Chemistry

Significant Figures

Multiplication or DivisionThe number of significant figures in the result is set by the original number that has the smallest number of significant figures

4.51 x 3.6666 = 16.536366 = 16.5

3 sig figs round to3 sig figs

6.8 ÷ 112.04 = 0.0606926

2 sig figs round to2 sig figs

= 0.061

Page 147: 3. Introduction to Chemistry

Significant Figures

Exact NumbersNumbers from definitions or numbers of objects are consideredto have an infinite number of significant figures

The average of three measured lengths; 6.64, 6.68 and 6.70?

6.64 + 6.68 + 6.70

3= 6.67333 = 6.67

Because is an exact number

= 7

Page 148: 3. Introduction to Chemistry

Factor-Label Method of Solving Problems

1. Determine which unit conversion factor(s) are needed

2. Carry units through calculation

3. If all units cancel except for the desired unit(s), then the problem was solved correctly.

1 L = 1000 mL

How many mL are in 1.63 L?

1L

1000 mL1.63 L x = 1630 mL

Page 149: 3. Introduction to Chemistry

The speed of sound in air is about 343 m/s. What is this speed in miles per hour?

1 mi = 1609 m 1 min = 60 s 1 hour = 60 min

343m

sx

1 mi

1609 m

60 s

1 minx

60 min

1 hourx = 767

mi

hour

meters to milesseconds to hours

Page 150: 3. Introduction to Chemistry

AQ

6000 (4 x 972) + (76.4 x 29.3) – (12 x 7)

0.2022 0.00627 + 0.1956 + 0.00029

2.73 7.43

470(63.7 x 49) / 6.664

531.267 x 42 x 0.9963

Page 151: 3. Introduction to Chemistry

AQ

V = m/D

150lbs = 68.1kg = 68,100g V = 68,100g / (0.95g/cm3)

V = 72,000cm3

Depending upon the amount of fat a person has, the human body has a density of about 0.95g/cm3. If a person weighed 150lbs, what would be their volume in cm3?

V = mass/density

V = 755g / (2.564g/cm3)

= 294 cm3

What is the volume of 755g of a material with a density of 2.564g/mL?

184 K Liquid ethane boils at -89°C. What is its boiling point on the Kelvin scale?

Page 152: 3. Introduction to Chemistry

Final Note

Chemistry is a lot like love. Without chemistry, there won’t be any rage

of hormones or even couples made because

they are not in sync with each other

Page 153: 3. Introduction to Chemistry

Chemistry is like DOTA: Dealing of Things Aspect May mga recipes din … Dapat nagmimix ang

characters … para maganda ang product

Both aim to improve, … continue to discover and develop

Both are FUN

Page 154: 3. Introduction to Chemistry

Chemistry:

A journey of a thousand miles that begins with a single step…

It is like a bikini, what it reveals is essential… what it conceals is vital…

BVV

Page 155: 3. Introduction to Chemistry

Chemistry is omnipresent … at times we find ourselves “in chemistry” with other

people Cool at creative na pag Halo ng mga Elements na nagfo2rm ng Matter It Suggests that one must TRY to study hard & excel

Page 156: 3. Introduction to Chemistry

What they say about

Chemistry

Page 157: 3. Introduction to Chemistry

• “Mystery solver” ... • “like a shadow” … since birth… still

chemistry is with me.

• …confuses my senses … makes me feel interested…

Page 158: 3. Introduction to Chemistry

• Chemistry is like a song. Once you learned it, you’ll find yourself enjoying & loving it

• … is like SMART & Globe … “its simply AMAZING” & “makes Great Things Possible”

• … is a challenge.

Page 159: 3. Introduction to Chemistry

• So plant as many seeds of knowledge as you can

• OR THE ZOMBIES WILL EAT YOUR BRAIN!