8/13/2019 2013 Mocktest 3 Paper 2

1/27

C

C/2013 1 II A 3/2

II A 3/2013/2

12/05/2013

E CDE : ACEG.. : 240

02:00 05:00 IE : 3.00 H

1. .

2. , .

.

3. ,

. .

.4. 3 (, ).

.

5. I 8 . (), (), () ()

.

6. II 4 . (), (), () ()

.

7. III 6 I () .

0 .

8. I 2 .

2 . .

.

9. I, 3

. , E (1)

(EGAIE AIG) .

10. II, 4

.

.

11. III, 4

. ,

(1) (EGAIE AIG) .

12. II, 8

2 .

.

8/13/2019 2013 Mocktest 3 Paper 2

2/27

C

C/2013 2 II A 3/2

A I (CHEI) 80 A

ECI I

AIGH BECIE E

8 C . E 4 A, B, C & D,

C :

F : 2 2H + I 2 HI ( ),

1,71,828 J1

1,80,142 J1. T

80 J 1

. A 27C

4104

3103

, KC. [A1.11 3

4 0.4 3.6 N

I , 0.1 M. C A AC CE /

( ) 10 ACK = 10

A AE 0.6 V+ =/

0.049 V 0.069 V 0.01 V N

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

3/27

C

C/2013 3 II A 3/2

F , H :

I C H

U H 0.0 1.6

V R H 2.8 4.1W R H 4.2 5.8

X Y H 6.0 7.7

Y C H 8.2 10

W ?

I V 0.01 M 0.1 M

( )

I Y 0.1 M HC 0.001 M NOH

I X

I W

T :

I, II II, III I, II, III II, III, IV

T [F(H2O)5NO2+

FSO4

3NO . H2SO4. S

.

C NO F

I +1 NO

I 3.87 BM F

H2O

I, II, III, IV II, III I, II, III II, III, IV

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

4/27

C

C/2013 4 II A 3/2

C :

6 7XF NF N [XF + +

5 4 62 PC () [PC [PC +

3 22 6 2 2 5 3[A(H O) H O [A(H O) OH H O+ + ++ +

P :

I, II, III I, III , II, III

T (L), (M) ,

M2+

, .

A , ?

R

R

E = 2 2 2M O( )+ +

C +4

T :

II, III I, II, III, IV I, III, IV I, II, IV

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

5/27

C

C/2013 5 II A 3/2

W ?

A

E :

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

6/27

C

C/2013 6 II A 3/2

ECI II

IE CEC AE E

4 C . E 4 A, B, C & D,

C C:

1 27C 200C .

A :

S = 4200 J1K1, L = 3.73 106J1 S = 1200 + 0.49T J1K1W ? (U :

373 4730.2, 0.24

300 373

= =

)

O

I (27C 100C)

. T E 27C 200C 11.17 J/K

T 27C 100C

840 J/K

T A2 A 2(A 2A) ,

300 K 4

35 O2 P T.

A 10 , A 50 ? M A/A2= 1.5 KP= 9

G 5.5 J/ M = 70

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

7/27

C

C/2013 7 II A 3/2

2 4 5 4H HC

B (N [B O (OH) ) P A + NC B C

W () ?

5 1 .

2 HC 1

A , B C 4 A, B C 1

T :

2 3HZH/HC B /RP KCN O

4 2 3 3 2NBH A O , O /H O(O)

2I + NOH H

KMO4/ H /+

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

8/27

C

C/2013 8 II A 3/2

ECI III

BECIE E

6 . E 0 9. F

CAEF. 5

5

A (M = 256 1) 6.4 . T

.

I 600 2 ,

105 ? A 0.2 2. T

.

F :

1, 2, 2, 3, 3, 3, 4, 4, 4, 4, 5, 5, 5, 5, 6, 6, 7, 7

A

Z 1 2A ( 10 )= 12

Z 6B

.

I A , H 20 STP

101. I .

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

9/27

C

C/2013 9 II A 3/2

H2SO4 :

A : 2P() P ()+

C :2

2PO () P ()+

A .

D 2 L 40% H2SO4 1.225

0.98 20% . C F .

A SO4 ( S O S

) C2+

C2+

1 : 1 . T C, S C

.

H ?

N2O, NO, NO2, KO2, N2O2, O2,+

2NO ,NO+, CO

+, B3O8

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

10/27

C

C/2013 10 II A 3/2

ECI I

AI ACH E

2 . E ,

. C I (A), (B), (C) & (D) C II

, , , & . .

C II C I.

C 1 C 2

OH

P C H COOH

C

2P C H CH COOH

OH

E

2 2P C H CH CH COOH

OH

C

2HO CH COOH

L

D

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

11/27

C

C/2013 11 II A 3/2

C 1 C 2

NHCO3

N

2, 4D

L

NOH

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

12/27

C

C/2013 12 II A 3/2

A II (HIC) 80 A

ECI I

AIGH BECIE E

8 C . E 4 A, B, C & D,

C :

A . T

30 60 . A (.. ,

.) . L 1 2

. T :

) 1 2 = 1 2 < 1 2 >

A 10 500 /3 1000 /

3. V

1.0 . I = 9.8 /2 ,

9.8 /2 :

9 / 10 / 11 / 12 /

T 37

. T

.

(T = 105)

73 10 74 10

72 10 75 10

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

13/27

C

C/2013 13 II A 3/2

C , (),

0. F

()

03

2 T

03 T

03

2 T

03 T

25 26

T 60 ,

. I 40

. T , . A 1.

T .

H ?

0.54 0.36 0.18 0.45

I ?

4 / 18 / 30 / 26 /

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

14/27

C

C/2013 14 II A 3/2

27 28

A :

I , B , ,

?

2 2

0

I , 2

,

:

2

3

2

0

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

15/27

C

C/2013 15 II A 3/2

ECI II

IE CEC AE E

4 C . E 4 A, B, C & D,

C C:

A . I

. T :

T ( )

+

T ( )( )

+

T ( )( )

+

T

T . T

. N

. W ,

T

T

T

T

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

16/27

C

C/2013 16 II A 3/2

C ()

E

T . O

. T

A ,

T

A RLC 1000 . T 90.0 ;

0.500 ; 60 0. (T 2 10 = )

H H

R 80

3

A 4

2 10

3= /

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

17/27

C

C/2013 17 II A 3/2

ECI III

BECIE E

6 . E 0 9. F

CAEF. 5

5

S 2

. T

( ). O

, . T

. A

( .)

. N ,

. [T : 0 5 1 1 0 25 100 , . / .

= = , = , = , = , = , =

A = 1 . W

, , = 1 /.

W ( /).

A 25

. T

. W 25, 10 2/. I

( /) 100, 0 ?

T 64 T. T

2000. C ( ).

[G : 86 10 = /2 103

T =

(= 1 5) . T ()

() . W ?

T 45 , . A

2% 14% . I

, 15 .

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

18/27

C

C/2013 18 II A 3/2

ECI I

AI ACH E

2 . E ,

. C I (A), (B), (C) & (D) C II

, , , & . .

C II C I.

A . I .

= =

= =

=

M 1 2.

C 1 C 2

3 P =

2

2 F =

1

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

19/27

C

C/2013 19 II A 3/2

C 1 C 2

A

.

N

A

.

N

.

A

.

I

.

A

. C

.

I

.

C .

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

20/27

C

C/2013 20 II A 3/2

A III (AHEAIC) 80 A

ECI I

AIGH BECIE E

8 C . E 4 A, B, C & D, C :

.41 42

I 1 1

2 3

+ = 2 29 12 4 + 2 2 , ,

( ) ( )2 2

1 1 0 > , [, )

I [ ] , , : 3 4 5 6

I , ( ) ( )2 2

21 = [ ]2 2, : 8 + 10 + 10

A 2 2 22 2 + + + = 2 = ( ) ( )1 1 2 2 , , , ,

( )3 3 , ( )4 4 , . I , G , :

1

+ 1 2

2

+ 1 2 3

1 2 3

+

2

=

0 4 6 8

L ( )21

=

+

( )

( )21

1

=

+

. I A1 = (),,

1

= = , 2 =(),

1

=

1

= . T 1 2 :

0 1 3

2

13

11

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

21/27

C

C/2013 21 II A 3/2

I 1 2 3 , , 3 1 2 1 2 3

2 3 1

3 1 2

0

=

2

3 1

2 1

=

2

1

3

2

1

3

2

I ,

, ( )

+ +

:

2 2

2 2 2

+

+ + 2 2 2 + +

2 2

2 2 2

+

+ +

2

+

L ( )( )( )

0 1

1 1

> = +

=

, ,

,

. T = 1

(.. ( )1

, (1))

() (.., (1+) ( )1 ,

)

( .. 1

= 0

2

= )

T

2 2

18 1

= ( )2 2 , ; 0,

2

. T

:

3

4

6

N

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

22/27

C

C/2013 22 II A 3/2

ECI II

IE CEC AE E

4 C . E 4 A, B, C & D,

C C:

A 2 23 2 4 0 + = :

( )1 2, 2 0 + = = 1

2 2 4 7 0 =

2 2 2 4 4 0 + + =

L 4 3= +

. T

1 2

:

2 11

3 2 + 2

2 11

5 5 +

2 11

3 2+

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

23/27

C

C/2013 23 II A 3/2

W () ?

T . A . N

, .

S, 1/2.

L 0

8/13/2019 2013 Mocktest 3 Paper 2

24/27

C

C/2013 24 II A 3/2

ECI III

BECIE E

6 . E 0 9. F

CAEF. 5

5

L ( )

2

2

1

1 1

1

= > +

,

,

T () .

I 6 = =

, 6

+ +

L ( ) ( )( )2

216 22

= + + + . I

() ( ) ,

=

[ ( [. .

).

I( )

1

1

0 1

=

+ ( )

24

2 320

2

=

, 1

2

:

I 2+ , 1= , 1 1 3

( )25 + .

L ( ) ( ) ( ) ( ) = , (),() () . A

0,

( ) ( ) ( ) ( )0 0 0 021 4 , = =

( ) ( )0 07 = ( ) ( )0 0 = . T /4 .

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

25/27

C

C/2013 25 II A 3/2

ECI I

AI ACH E

2 . E ,

. C I (A), (B), (C) & (D) C II

, , , & . .

C II C I.

C 1 C 2

I 2 2 2 22 2 0 8 8 6 0 + = + + =

2

( )2

2

+

3

T (,) +

( )1

3 16

,

1

( )6 2,

1 1 3

2 1 1

+ += =

5 6 3 5 3 4 T = + + = .

16

0

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

26/27

C

C/2013 26 II A 3/2

C 1 C 2

2

11

=

+ , 4

( ) ( )1 1 1

4

+ + + =

1

I (1, 2, 3) (2, 1, 0)

2 3 2 + = ,

A

I ( )1 1 1 , , (1, 2, 3) 0 + + = 1

A

A

ACE F GH

8/13/2019 2013 Mocktest 3 Paper 2

27/27

C

C/2013 27 II A 3/2

ACE F GH

E II A 3/2/2013