1982 - paa con acryl-trt-mepip

8/7/2019 1982 - PAA con Acryl-Trt-MePip

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Synthesis and Characterization of a P oly(am idoa mine) wilhAmidn and Tertiary Amino Groups Regularly Alternatingalong (he Macromolecular ChainLU I S ~irsconi, M.Cnsrinri Tonzr, Gobrieiin Gor l ~s~he l l iDlparllmenlo dl Chlmlca Indl l


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Fig, 1 . "C N V R~pcclrum71.5 MHz.D1O.ef I &d#oxanel o lpolvmer 6 at room i empla1 and at 80'C (b) ,.. I . . L o .o.,.

"C NMR spectra werr run in D1O with I.4dloxanc as rntcrnal reference on a Bil ikcr CxP-3M ntlruminl operaunp nr 75.5 LIHL Wbdr angle X-m) oonder dlffracllon 5prdrr were runon a Phlllor PW lOIOcnunlcr dlflraclometcr, uslnr Cuh. radlalion.- "US' mearuicmcns r e r c carrlcd ou, on a Perkin-Flmcr USC-I r s n n l n g calonmctcr $ n ir ,wllh a scan rpscd o f 8C'm8n

l - T r , p h ~ n y i m a h v l p ~ ~ ~ ~ ~ : i i i31' Anhydrous i w r a l l n e (39.3 g, 0.46 moll wnr dlslolvcd=dr chloroform (2q0 ml). the rolulion war cooled 8n an ~cr-bath.m d rlphenylmeihyl chlorlde,F%cTCT{~~~ddell u l l ~ itirrmng. itlrrtng or Ihc reaction mixere vrs continued a

< a c l l 8n thcrub3equcnl rr 8. .,n i .,. . .hccllng ~ h chtcnceofplpcrnllnc hyTLC(CHCI,/2 - p r o p a n o l / c n c f h ~ l a m ~ ~ ~ ~ ,v l -rr i lo S I 0 31 4 rrr'r)riall~zrd from I 1 bcnrcnclhiptanelramplc had m p. IhR- t i ? * r til lrdscryloyichlondc (2.1 mol. 30.5mmol l ra~d~r ro l rcdn 0mlo l n chloroform(%olulbon ), andNaOH(1.32 g: 13 mmol) wardl?%olv , roo,,,,cm,,u l lh,nanme ursreparatcd, and ~ h ~ ~ ~ ~~ , ~ ~ ~ ~ ~ ~\ , I I , wmi0rp he cambtned cl,iorofurm exlracir were wsrhed ~ 7 t hq. rrcurnlccl P..lil \ a n iWi lc iu l~tatlo 1 :11(2 x 30 ml) and wllh aq. ~aturalcdNrC1 12 x 30 ml). Tihcn. l h c \ a e r r drlcd


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CnHIaN:O 1182.~mluedn 10ml of I.4-dloxanrhy gc#lllyunrmtn8.md 1 2 n HCI 14.4 ml) urr added Th: urinrc-iolourcd litin^ in^

h.,.cllt r l ~ , lrllllll. i i w c for I h. then wa>dl~uted I I ~ ,"I ot ila~cr .ini~ ncu~ra~llrd

nrerl~linine Iullh arrlonr > lrlil 0.6'3 g. (lia'tll1C,Hl2N2O), (140.2). Calc. C 59.97 H 8,63 N IY.98Found C 59.12 H 866 N 19.15

Thmkr are duc 8 0 the Hlwi8/,,iildNMR S l r l x e 01 N R I lSohlnni lor runnlns: thc N\IRspectra and lo Prof L Liln"::! ,Unl"cni,y of Bologna) for u~c fu l lscunlon

' I F Danu$io.P Fcrrutl. Polymer 11. 88 (1910)" R Anrbuccl. P, l'errurl, C Irnprois. M Dllf lnl, A L Scyrc. I' Conrl, Polymrr 19 . 1329ll97BI

R . ~ a r b s c i ~ .. rcrrucI. PO IY~C I 20. 1061 1979)'I R Rarbuccl,Y . Baron.. L Olvra. P Ferrut!. T. old!, M Pcrartnlo. C. B~r tog l~ololo. in"lIUP4C) Polgnlerxc am~nr ind ammonllim %all?". d ' E I Gorlhals. Pcrgamon Press.

Oxlord 1980. p. 203'I P Frrrull, L Ollva, R Rorbucci, M C Tann, l n o i Chlm A d a 41. 25 11980)" P. Feirull. N. Danlo. I..Olhn, R. Barbuccl. V Raronc. 1. Chem S o < . Drl ion Trans.1911. 519" R. Rarbt~cct.V. Brione, P Ferrutl. L. Ollva, J. Polym. Sci., Polsm. Symp. 61, 49 119811" M A. Marchl.ia. T Longo. P Ferruf~. xplricnrla 29. 93 (1973)" P l.crrull, E Irlarluicrll~.1 Nlcolalr, M Palma. F. Rlva. Polvmrr 18 , 387 119771)

"'I P Ferrutl. ~n "(IUPAC) Polymeric amlncr and ammonium n l l r " . rd: E J . Gonhalr.Pcrgamon pre,.. Oxford 1980. p. 105"I R l i r ruu . M.A. Marchlno. ~n "Blom~dlralanddental an~l lca lonr fpolymcrs", cds.. CG. Gcbelcrnand I kahl ll l. Plenam Pub1 Co , New YarX 1981, p 39' I ' F. Danurro. P . I'rrruu. t Ibr ronl , Chlm Ind. (Milan) 49. 271 (1967)"I L Rurcanl , M C Tan,,, P, 1-arrull.L Anglallnl. R. Barbuccl,M Carolarn. Polymer 23.1233 119821'" Y YMnron. R McGarvcv. H. Moiawetz, Macromaleculci 1. 154 11969)"' 0 hlonraudo. P. Rnocchlaro. P Mara%lgna.G. Overberger. MacromoIcculeiS. 197 (19721I*) H hrlchildarf. k H. R l e l h , I . Polym Scl., Polym. Lel l Cd 16, 379(1918l

1982 - paa con acryl-trt-mepip

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