1/9 safety data sheet 29 cfr 1910

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Safety Data Sheet 29 CFR 1910.1200

Printing date 01/23/2019 Version number 1 Reviewed on 01/23/2019

1 Identification

· Product identifier

· Trade name: Alcohol based color marker ink

· Recom mended use of the chemical and restrictions on use: · Application of the substance / the preparation: Marker ink

· Details of the supplier of the safety data sheet · Supplier: Officeworks Ltd. 236-262 East Boundary Road Bentleigh East VIC 3165 Australia Tel: 1300 633 423 ABN:36 004 763 526·

· Further information obtainable from:

·• 1.4 Emergency telephone number: Australia P OISONS INFOR M ATION CE NTRE 13 11 26

· Reference Nu mber: CP19-003552 - GZ, CANEC1901383101

2 Hazard(s) identification

· Classification of the substance or mixture Classification according to OSHA Hazard Com munication Standard (29 CFR 1910.1200)

G HS02 Flame

Flam. Liq. 2 H225 Highly flam mable liquid and vapor.

G HS05 Corrosion

Eye Dam. 1 H318 Causes serious eye damage.

G HS07

Skin Sens. 1 H317 May cause an allergic skin reaction.

STOT SE 3 H336 May cause drowsiness or dizziness.

· Information concerning particular hazards for human and environment: The product has to be labeled due to the calculation procedure of OSHA Hazard Communication Standard (29 CFR 1910.1200).

· Classification system: The classification is according to the latest edition of OSHA Hazard Com munication Standard (29 CFR 1910.1200), and extended by company and literature data.

· Label elements · Labelling according to OS H A Hazard Com munication Standard (29 CFR 1910.1200) · Hazard pictograms

G HS02 GHS05 GHS07

· Signal word Danger (Contd. on page 2)

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Trade name: Alcohol based color marker ink

(Contd. of page 1)

· Hazard-determining components of labeling: Rosin 4,4'-carbonimidoylbis[N,N-diethylaniline] monohydrochloride 1-methoxy-2-propanol · Hazard statements H225 Highly flammable liquid and vapor. H318 Causes serious eye damage. H317 May cause an allergic skin reaction. H336 May cause drowsiness or dizziness. · Precautionary statements P210 P240 P241 P242 P243 P261 P271 P272 P280

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALE D: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing. P310 P321

Immediately call a poison center/doctor. Specific treatment (see on this label).

P333+P313 P363

If skin irritation or rash occurs: Get medical advice/attention. W ash contaminated clothing before reuse.

P370+P378 P403+P233 P403+P235 P405

In case of fire: Use for extinction: CO2, powder or water spray. Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up.

P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

· Hazards not otherwise classified (HN O C) No further relevant information available.

3 Composition/information on ingredients

· Chemical characterization: Mixtures · Description: Mixture of the substances listed below with nonhazardous additions. For the wording of the listed hazard statements refer to Section 16.

· Composition:

64-17-5 ethanol 58.94-70.0%

20.0%

Flam. Liq. 2, H225

107-98-2 1-methoxy-2-propanol

Flam. Liq. 3, H226;

61901-87-9 C.I. Solvent Black 29

8050-09-7 Rosin

STOT SE 3, H336

0-11.06%

10.0%

Skin Sens. 1, H317

61901-92-6 C.I. Solvent Red 91

61116-28-7 C.I. Solvent Brown 43

12237-24-0 Solvent Blue 70

0-6.7%

0-6.4%

0-5.3%

1325-86-6 α,α-bis[4-(diethylamino)phenyl]-4-(ethylamino)naphthalene-1-methanol 0-5.0% (Contd. on page 3)

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(Contd. of page 2)

0-4.6% 12237-31-9 Solvent Yellow 79

12227-67-7 Solvent Yellow 82 0-4.5%

52256-37-8 hydrogen bis[2,4-dihydro-4-[(2-hydroxy-5-nitrophenyl)azo]-5-methyl-2-phenyl- 3H-pyrazol-3-onato(2-)]chromate(1-)

0-3.65%

82347-07-7 Solvent Red 218 0-3.5%

0-3.36%

0-3.03%

0-3.0%

12237-23-9 C.I. Solvent Black 28

12220-53-0 C.I. Acid Violet 66

6358-36-7 4,4'-carbonimidoylbis[N,N-diethylaniline] monohydrochloride

Eye Dam. 1, H318

37229-23-5 C.I. Solvent Blue 45 0-2.7%

6320-14-5 2-[3-(1,3-dihydro-1,3,3-trimethyl-2H-indol-2-ylidene)prop-1-enyl]-1,3,3- trimethyl-3H-indolium chloride

0-2.15%

4 First-aid measures

· Description of first aid measures · General description: Immediately remove any clothing soiled by the product. · After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately wash with water and soap and rinse thoroughly. · After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. · After swallowing: If symptoms persist consult doctor.

· Most important symptoms and effects, both acute and delayed No further relevant information available.

· Indication of any im mediate medical attention and special treatment needed No further relevant information available.

5 Fire-fighting measures

· Suitable extinguishing agents: C O ₂, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents: Water with full jet

· Special hazards arising from the substance or mixture: No further relevant information available.

· Special protective equipment and precautions for firefighters · Protective equipment: No special measures required.

6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures: Wear protective equipment. Keep unprotected persons away.

· Environmental precautions: Do not allow to enter sewers/ surface or ground water.

· Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent. Dispose contaminated material as waste according to section 13. Ensure adequate ventilation.

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(Contd. of page 3)

7 Handling and storage

· Precautions for safe handling: Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. For the general occupational hygienic measures refer to Section 8. · Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges.

· Conditions for safe storage, including any incompatibilities · Requirements to be met by storerooms and receptacles: Store in a cool location. · Information about storage in one com mon storage facility: Not required. · Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles.

8 Exposure controls/personal protection

· Components with limit values that require monitoring at the workplace:

64-17-5 ethanol (58.94-70.0%)

PEL (USA) Long-term value: 1900 mg/m³, 1000 ppm

REL (USA) Long-term value: 1900 mg/m³, 1000 ppm

TLV (USA) Short-term value: 1880 mg/m³, 1000 ppm

107-98-2 1-methoxy-2-propanol (20.0%)

REL (USA) Short-term value: 540 mg/m³, 150 ppm Long-term value: 360 mg/m³, 100 ppm

TLV (USA) Short-term value: 369 mg/m³, 100 ppm Long-term value: 184 mg/m³, 50 ppm

8050-09-7 Rosin (10.0%)

TLV (USA) DSEN, RSEN, L

· Regulatory information PEL (USA): Guide to Occupational Exposure Values (OSHA PELs) REL (USA): Guide to Occupational Exposure Values (NIOSH RELs) TLV (USA): Guide to Occupational Exposure Values (ACGIH)

· Additional information: The lists that were valid during the creation were used as basis.

· Based on the composition shown in Section 3, the following measures are suggested for occupational safety measure. · Appropriate engineering controls: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. W ash hands before breaks and at the end of work. Avoid contact with the eyes. Avoid contact with the eyes and skin. See Section 7 for information about design of technical facilities.

· Personal protective equipment: · Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. · Protection of hands:

Protective gloves

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Printing date 01/23/2019


Version number 1 Reviewed on 01/23/2019

(Contd. of page 4)

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material: The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection:

Tightly sealed goggles

9 Physical and chemical properties

· General Information · Appearance:

Form: Color:

· Odor: · Odor threshold:

Liquid M ulticolour Ethyl alcohol Not available

· pH-value: Not available

· Change in condition M elting point/Freezing point: Not available Initial boiling point and boiling range: 78.3 °C (172.9 °F)

· Flash point: 12 °C (53.6 °F)

Not available

Not available

Not available

· Flam mability (solid, gaseous):

· Auto-Ignition temperature:

· Decomposition temperature:

· Explosion limits: Lower: Upper:

Not available Not available

· Vapor pressure: Not available

· Density: Not available Not available Not available Not available

· Relative density: · Vapor density: · Evaporation rate:

· Solubility in / Miscibility with W ater: Not available

· Partition coefficient (n-octanol/water): Not available

· Viscosity: Dyna mic: Kinematic:

Not available Not available


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(Contd. of page 5)

· Other information No further relevant information available.

10 Stability and reactivity

· Reactivity: Contact with incompotible substances can cause decomposition or other chemical reactions.

· Chemical stability: Stable under proper operation and storage cconditions.

· Possibility of hazardous reactions: In contact with oxidants causes severe reactions, dand may cause a fire or explosion.

· Conditions to avoid: Incompatible materials,heat,flame and spark.

· Incompatible materials: Oxidants, alkali metals, alkaline earth metals etc.

· Hazardous decomposition products: Carbon monoxide, carbon dioxide etc.

11 Toxicological information

· Acute toxicity:

· LD/LC50 values that are relevant for classification:


Oral LD50

LD50

5,660 mg/kg (rat)

Dermal 13,000 mg/kg (rabbit)

64-17-5 ethanol

Oral LD50 7,060 mg/kg (rat)

Inhalative LC50/4 h 20,000 mg/l (rat)

· Skin corrosion/irritation: Irritating effect possible. · Serious eye damage/irritation: Strong irritant with the danger of severe eye injury. · Respiratory or skin sensitization: Sensitization possible through skin contact.

· Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant

· Carcinogenic categories

· IARC (International Agency for Research on Cancer)

None of the ingredients is listed.

· NTP (National Toxicology Program)


· OSHA-Ca (Occupational Safety & Health Administration)


12 Ecological information

· Toxicity · Aquatic toxicity: No further relevant information available.

· Persistence and degradability: No further relevant information available.

· Bioaccumulative potential: No further relevant information available.

· Mobility in soil: No further relevant information available. (Contd. on page 7)

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(Contd. of page 6)

· Other adverse effects No further relevant information available.

13 Disposal considerations

· Waste treatment methods · Recom mendation: M ust not be disposed of together with household garbage. Do not allow product to reach sewage system.

· Uncleaned packagings: · Recom mendation: Disposal must be made according to official regulations.

14 Transport information

· UN-Nu mber · DOT, IM D G, IATA U N1993

· UN proper shipping name · DOT · IMD G

Flam mable liquids, n.o.s. (Ethanol, 1-Methoxy-2-propanol) F L A M M A B L E LI Q UI D, N. O.S. (ET H A N O L (ETH Y L ALC O H OL), 1-METH OXY-2-PR OPAN OL)

· IATA FLA M M A BLE LIQ UID, N.O.S. (ETHA N OL, 1-MET H O X Y-2- PR OPAN OL)

· Transport hazard class(es)

· DOT, IM D G, IATA

· Class · Label

3 Flammable liquids 3

· Packing group · DOT, IM D G, IATA II

· Environmental hazards: Not applicable

· Special precautions for user · EMS Nu mber: · Stowage Category

W arning: Flammable liquids F-E,S-E B

· Transport in bulk according to Annex II of M A R P OL73/78 and the IBC Code Not applicable

· Transport/Additional information:

· DOT · Quantity limitations On passenger aircraft/rail: 5 L

On cargo aircraft only: 60 L

· IMD G · Limited quantities (LQ) · Excepted quantities (EQ)

1L Code: E2 M aximum net quantity per inner packaging: 30 ml M aximum net quantity per outer packaging: 500 ml


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(Contd. of page 7)

· UN " Model Regulation": U N 1993 FLA M M A BLE LIQUID, N.O.S. (ETHAN OL (ETHYL ALC O H OL), 1-METH OXY-2-PR OPAN OL), 3, II

15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture

· Sara

· Section 355 (extremely hazardous substances):


· Section 313 (Specific toxic chemical listings):


· TSCA (Toxic Substances Control Act):

64-17-5 ethanol


8050-09-7 Rosin

6358-36-7 4,4'-carbonimidoylbis[N,N-diethylaniline] monohydrochloride

· Proposition 65

· Chemicals known to cause cancer:


· Chemicals known to cause reproductive toxicity for females:


· Chemicals known to cause reproductive toxicity for males:


· Chemicals known to cause developmental toxicity:

64-17-5 ethanol

· New Jersey Right-to-Know List:

64-17-5 ethanol


· New Jersey Special Hazardous Substance List:

64-17-5 ethanol CA, MU, TE, F3

F3 107-98-2 1-methoxy-2-propanol

· Pennsylvania Right-to-Know List:

64-17-5 ethanol


· Pennsylvania Special Hazardous Substance List:


· Cancerogenity categories

· EPA (Environmental Protection Agency)


· TLV (Threshold Limit Value established by ACGIH)

64-17-5 ethanol A3

· NIOS H-Ca (National Institute for Occupational Safety and Health)


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16 Other information

· Relevant hazard statements H225 Highly flammable liquid and vapor. H226 Flammable liquid and vapor. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H336 May cause drowsiness or dizziness. · *************************************************************************************** The contents and format of this SDS are in accordance with 29 CFR 1910.1200.

DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable.

· Date of preparation / last revision 01/23/2019 / -

· Abbreviations and acronyms: IMD G: International Maritime Code for Dangerous Goods D OT: US Department of Transportation IATA: International Air Transport Association AC GIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Com mercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent NIOSH: National Institute for Occupational Safety OS HA: Occupational Safety & Health Flam. Liq. 2: Flammable liquids – Category 2 Flam. Liq. 3: Flammable liquids – Category 3 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Skin Sens. 1: Skin sensitisation – Category 1 STOT SE 3: Specific target organ toxicity (single exposure) – Category 3

· *************************************************************************************** End of document

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