14.2 acid-base theories. 14.2 there are 3 theories to describe acids and bases

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14.2 ACID-BASE THEORIES

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Page 1: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2ACID-BASE THEORIES

Page 2: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2There are 3 theories to describe acids and bases.

Page 3: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2There are 3 theories to describe acids and bases.1. Arrhenius

2. Brønsted-Lowry

3. Lewis

Page 4: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2There are 3 theories to describe acids and bases.1. Arrhenius

Acid is a molecule that produces H+ in waterThe H coming from the acid is in a polar bond. The more polar the bond, the easier it is pulled away from the acid.

In an organic acid, the H pulled away comes from the -COOH.

Page 5: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2There are 3 theories to describe acids and bases.1. Arrhenius

Acid is a molecule that produces H+ in waterThe H coming from the acid is in a polar bond. The more polar the bond, the easier it is pulled away from the acid.

In an organic acid, the H pulled away comes from the -COOH.

H+ is attracted to H2O to form H3O+

Page 6: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2There are 3 theories to describe acids and bases.1. Arrhenius

Acid is a molecule that produces H+ in waterThe H coming from the acid is in a polar bond. The more polar the bond, the easier it is pulled away from the acid.

In an organic acid, the H pulled away comes from the -COOH.

H+ is attracted to H2O to form H3O+

Base is a compound that produces OH- in water.

Page 7: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2There are 3 theories to describe acids and bases.1. Arrhenius

Acid is a molecule that produces H+ in waterThe H coming from the acid is in a polar bond. The more polar the bond, the easier it is pulled away from the acid.

In an organic acid, the H pulled away comes from the -COOH.

H+ is attracted to H2O to form H3O+

Base is a compound that produces OH- in water.

What is limiting about this definition?

Page 8: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2There are 3 theories to describe acids and bases.2. Brønsted-Lowry

Page 9: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2There are 3 theories to describe acids and bases.2. Brønsted-Lowry

An acid is a substance (molecule or ion) that donates aproton (H+)

Page 10: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2There are 3 theories to describe acids and bases.2. Brønsted-Lowry

An acid is a substance (molecule or ion) that donates aproton (H+)

Monoprotic acids donate 1 H+

Diprotic acids donate 2 H+

Triprotic acids donate 3 H+

The first ionization produces the greatest number of H+

Page 11: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2There are 3 theories to describe acids and bases.2. Brønsted-Lowry

An acid is a substance (molecule or ion) that donates aproton (H+)

Monoprotic acids donate 1 H+

Diprotic acids donate 2 H+

Triprotic acids donate 3 H+

The first ionization produces the greatest number of H+

A base is a substance (molecule or ion) that accepts a H+

Page 12: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2There are 3 theories to describe acids and bases.2. Brønsted-Lowry

An acid is a substance (molecule or ion) that donates aproton (H+)

Monoprotic acids donate 1 H+

Diprotic acids donate 2 H+

Triprotic acids donate 3 H+

The first ionization produces the greatest number of H+

A base is a substance (molecule or ion) that accepts a H+

What is limiting about this definition?

Page 13: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2There are 3 theories to describe acids and bases.3. Lewis definition

An acid is a substance (atom, molecule, or ion) that accepts

a pair of electrons.A base is a substance (atom, molecule, or ion) that donates

a pair of electrons.

Page 14: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2Example 1: Identify the Brønsted-Lowry acid and base in

each equation. NH4

+(aq) + CN-(aq) HCN(aq) + NH3(aq)

Page 15: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2Example 1: Identify the Brønsted-Lowry acid and base in

each equation. (CH3)3N(aq) + H2O(l) (CH3)3NH+(aq) + OH-(aq)

Page 16: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2Example 1: Identify the Brønsted-Lowry acid and base in

each equation. HCHO2(aq) + PO4

3-(aq) CHO2-(aq) + HPO4

2-(aq)

Page 17: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2Example 1: Identify the Brønsted-Lowry acid and base in

each equation. H3O+(aq) + HPO4

2-(aq) H2PO4-(aq) + H2O(l)

Page 18: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2Example 2: Identify if the following acids are monoprotic,

diprotic, or triprotic.H2SO4

Page 19: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2Example 2: Identify if the following acids are monoprotic,

diprotic, or triprotic.H2SO4

CH3COOH

Page 20: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2Example 2: Identify if the following acids are monoprotic,

diprotic, or triprotic.H2SO4

CH3COOH

HClO4

Page 21: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2Example 2: Identify if the following acids are monoprotic,

diprotic, or triprotic.H2SO4

CH3COOH

HClO4

H2CO3

Page 22: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2Example 2: Identify if the following acids are monoprotic,

diprotic, or triprotic.H2SO4

CH3COOH

HClO4

H2CO3

HSO41-

Page 23: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2Example 2: Identify if the following acids are monoprotic,

diprotic, or triprotic.H2SO4

CH3COOH

HClO4

H2CO3

HSO41-

H3PO4

Page 24: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2Example 3: What ion species would be present when the

following weak acids dissolve in water?

H3PO4

Page 25: 14.2 ACID-BASE THEORIES. 14.2 There are 3 theories to describe acids and bases

14.2Example 3: What ion species would be present when the

following weak acids dissolve in water?

H2CO3