12% cerium hex-cem (2008)

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MATERIAL SAFETY DATA SHEET 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 12% CERIUM HEX-CEM PRODUCT CODE: 115393 COMPANY IDENTIFICATION: CUSTOMER SERVICE, R&D AND SALES: 440-899-2950 CHEMICAL FAMILY/USE: Metal Carboxylate IN CASE OF EMERGENCY CONTACT: CHEMTREC: 800-424-9300 (24 HOURS A DAY, 7 DAYS A WEEK) OUTSIDE THE US: + (703)-527-3887 (COLLECT CALLS ACCEPTED) HMIS: HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0 PERSONAL PROTECTION: B 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: Brown liquid. Causes severe eye, skin and respiratory irritation. Harmful if swallowed, inhaled or absorbed through the skin. EYE CONTACT: Causes severe irritation, experienced as discomfort or pain, excess blinking and tear production, marked excess redness and swelling of the conjunctiva and chemical burns of the eye. SKIN CONTACT: Brief contact with skin may cause slight irritation with itching and local redness. Prolonged contact may cause more severe irritation, with discomfort or pain, local redness and swelling, and possible tissue destruction. INHALATION: May cause irritation of the respiratory tract, experienced as nasal discomfort and discharge, coughing, and possibly accompanied by chest pain. Prolonged overexposure may cause injury to the respiratory tract. INGESTION: Moderately toxic. Aspiration into the lungs may occur during ingestion or vomiting, resulting in lung injury. Abdominal discomfort, nausea and vomiting may occur. 3. COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL NAME: PERCENT: ACGIH TLV: ACGIH STEL: OSHA PEL: OSHA STEL: Units that the TWAs and STELs are in: Page 1 of 5 TWO MILE RUN ROAD PLANT TELEPHONE NUMBER: 814-432-2125 OMG AMERICAS, INC. 12% CERIUM HEX-CEM DATE PRINTED: 02/14/2010 PRODUCT CODE: 115393 DATE REVISED: 01/24/2008 VENANGO COUNTY, FRANKLIN, PA 16323

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Page 1: 12% Cerium Hex-Cem (2008)

MATERIAL SAFETY DATA SHEET

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: 12% CERIUM HEX-CEMPRODUCT CODE: 115393

COMPANY IDENTIFICATION:

CUSTOMER SERVICE, R&D AND SALES: 440-899-2950

CHEMICAL FAMILY/USE: Metal Carboxylate

IN CASE OF EMERGENCY CONTACT:CHEMTREC: 800-424-9300 (24 HOURS A DAY, 7 DAYS A WEEK)OUTSIDE THE US: + (703)-527-3887 (COLLECT CALLS ACCEPTED)

HMIS:HEALTH: 2FLAMMABILITY: 1REACTIVITY: 0PERSONAL PROTECTION: B

2. HAZARDS IDENTIFICATIONEMERGENCY OVERVIEW: Brown liquid. Causes severe eye, skin and respiratory irritation. Harmful if swallowed,

inhaled or absorbed through the skin.

EYE CONTACT: Causes severe irritation, experienced as discomfort or pain, excess blinking and tearproduction, marked excess redness and swelling of the conjunctiva and chemical burns of theeye.

SKIN CONTACT: Brief contact with skin may cause slight irritation with itching and local redness. Prolongedcontact may cause more severe irritation, with discomfort or pain, local redness and swelling,and possible tissue destruction.

INHALATION: May cause irritation of the respiratory tract, experienced as nasal discomfort and discharge,coughing, and possibly accompanied by chest pain. Prolonged overexposure may cause injuryto the respiratory tract.

INGESTION: Moderately toxic. Aspiration into the lungs may occur during ingestion or vomiting, resultingin lung injury. Abdominal discomfort, nausea and vomiting may occur.

3. COMPOSITION/INFORMATION ON INGREDIENTS

CHEMICAL NAME: PERCENT: ACGIH TLV: ACGIH STEL: OSHA PEL: OSHA STEL: Units that theTWAs and STELsare in:

Page 1 of 5

TWO MILE RUN ROAD

PLANT TELEPHONE NUMBER: 814-432-2125

OMG AMERICAS, INC.

12% CERIUM HEX-CEM

DATE PRINTED: 02/14/2010

PRODUCT CODE: 115393

DATE REVISED: 01/24/2008

VENANGO COUNTY, FRANKLIN, PA 16323

Page 2: 12% Cerium Hex-Cem (2008)

3. COMPOSITION/INFORMATION ON INGREDIENTSCerium 2-Ethylhexanoate56797-01-4

49 NE NE NE NE

2-Ethylhexanoic Acid149-57-5

48 5+ NE NE NE mg/m3

Diethylene Glycol Butyl Ether112-34-5

3 NE NE NE NE

+Vapor and aerosol, inhalable fraction

4. FIRST AID MEASURESEYES:Immediately flush eyes with water and continue washing for at least 15 minutes. DO NOT remove contact lenses, if worn. Obtainmedical attention without delay, preferably from an ophthalmologist.SKIN:Immediately remove contaminated clothing and shoes. Wash skin thoroughly with soap and water for at least 15 minutes. Obtainmedical attention without delay. Wash clothing before reuse. Discard contaminated leather articles such as shoes and belt.INHALATION:Remove to fresh air. Give artificial respiration if not breathing. If breathing is difficult, oxygen may be given by qualified personnel.Obtain medical attention.INGESTION:If patient is conscious, give two glasses of milk or water at once. DO NOT INDUCE VOMITING. Obtain medical attention withoutdelay.MEDICAL CONDITIONS AGGRAVATED:Skin contact may aggravate an existing dermatitis.NOTE TO PHYSICIAN:Due to the irritating nature of the material, any aspiration during vomiting could result in severe lung injury. Therefore, emesis shouldnot be induced mechanically or pharmacologically. However, the acute peroral systemic toxicity of the material indicates thatevacuation of the stomach contents should be undertaken at the earliest possible time by means carrying the least likelihood ofaspiration (e.g. the use of gastric lavage with endotracheal intubation).

5. FIRE FIGHTING MEASURESFLASH POINT (° F) 230, PMCCOSHA FLAMMABILITY CLASSIFICATION:Combustible Liquid-Class III BEXTINGUISHING MEDIA:Apply alcohol-type or all-purpose-type foam by manufacturer's recommended techniques for large fires. Use carbon dioxide or drychemical media for small fires.SPECIAL FIREFIGHTING PROCEDURES:Use self-contained breathing apparatus and protective clothing.EXPLOSION LIMITS IN AIR - LOWER (%) UnknownEXPLOSION LIMITS IN AIR - UPPER (%) UnknownAUTOIGNITION TEMP (° F) UnknownUNUSUAL FIRE AND EXPLOSION HAZARDS:None known.

6. ACCIDENTAL RELEASE MEASURESACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:Wear suitable protective equipment. Avoid contact with eyes and skin. Collect for disposal. This product is toxic to fish; avoiddischarge to natural waters.

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Page 3: 12% Cerium Hex-Cem (2008)

7. HANDLING AND STORAGEHANDLING:Do not get in eyes, on skin or on clothing. Avoid breathing vapor. Do not swallow. Use only with adequate ventilation. Washthoroughly after handling. Sudden release of hot organic chemical vapors or mists from process equipment operating at elevatedtemperature and pressure, or sudden ingress of air into vacuum equipment, may result in ignitions without the presence of obviousignition sources. Any use of this product in elevated-temperature processes should be thoroughly evaluated to establish and maintainsafe operating conditions.STORAGE:Store in a cool, dry location away from incompatible materials.

8. EXPOSURE CONTROLS/PERSONAL PROTECTIONENGINEERING CONTROLS:Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below TLV'(s).RESPIRATORY PROTECTION EQUIPMENT:Use self-contained breathing apparatus in high vapor concentrations.PROTECTIVE GLOVES:PVC-coated.EYE AND FACE PROTECTION:Monogoggles.OTHER PROTECTIVE EQUIPMENT:Chemical apron, eye bath and safety shower.VENTILATION:General (mechanical) room ventilation is expected to be satisfactory where this product is stored and handled in closed equipment.Special, local ventilation is needed at points where vapors can be expected to escape to the workplace air.

9. PHYSICAL AND CHEMICAL PROPERTIESBoiling Range/Point 440° F for 2-Ethylhexanoic AcidVapor Pressure <0.01 mmHg @ 20° F for 2-Ethylhexanoic AcidVapor Density (AIR=1) Heavier than airFreezing Point UnknownMelting Point UnknownPhysical State LiquidColor Brown% Volatile by Weight 20%Volatile by Volume 23Evaporation Rate ( Butyl Acetate=1) Slower than etherSpecific Gravity @ 25°C 1.06Weight per gallon 8.8 lbs.

10. STABILITY AND REACTIVITYSTABILITY:Stable.HAZARDOUS POLYMERIZATION:Will not occur.HAZARDOUS THERMAL DECOMPOSITION/COMBUSTION PRODUCTS:Burning can produce the following products: carbon monoxide and/or carbon dioxide. Cerium oxide.INCOMPATIBILITY (MATERIALS TO AVOID):Caustic soda, lime, strong alkalies, oxidizing agents such as nitric acid, peroxides, amines, sulfuric acid, perchloric acid, or chromiumtrioxide.CONDITIONS TO AVOID:Avoid excess heat and incompatibilities.

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Page 4: 12% Cerium Hex-Cem (2008)

11. TOXICOLOGICAL INFORMATIONTOXICITY DATA:In a developmental toxicity study conducted under TSCA test rule, 2-ethylhexoic acid produced evidence of embryofetal toxicitywhen administered by stomach tube to laboratory animals during pregnancy. However, no statistically significant increase inmalformations was observed in offspring, even at maternally toxic doses.In recent Finnish studies, administration of 2-ethylhexoic acid in drinking water slightly retarded fetal development at dosagesapproaching 600 mg/kg/day during the critical phases of gestation. In addition, high dosages of 2-ethylhexoic acid administered bystomach tube may have inhibited embryo implantation, thereby causing embryo lethality.An increase in liver weight was observed in subchronic laboratory animal feeding studies.ACUTE ORAL LD50: No data at this time.ACUTE DERMAL LD50: No data at this time.ACUTE INHALATION LC50: No data at this time.

12. ECOLOGICAL INFORMATIONECOTOXICOLOGICAL INFORMATION:No data at this time.CHEMICAL FATE INFORMATION:No data at this time.

13. DISPOSAL CONSIDERATIONSDISPOSAL METHOD:Disposal should be made in accordance with federal, state and local regulations.

14. TRANSPORT INFORMATIONDOT SHIPPING NAME: Not RegulatedDOT HAZARD CLASS: NoneUN/NA NUMBER: NoneDOT PACKING GROUP: None

AIR TRANSPORTATION: Not Regulated

OCEAN TRANSPORTATION: Not Regulated

15. REGULATORY INFORMATIONTSCA STATUS:All components of this product are listed on the TSCA inventory.TSCA 12(b) EXPORT NOTIFICATION:No components of this product are subject to TSCA 12(b) export notification requirements.CALIFORNIA PROPOSITION 65:This material may contain the following chemicals which are known to the State of California to cause cancer or birth defects and aresubject to the requirements of California Proposition 65:

SARA 302 EXTREMELY HAZARDOUS SUBSTANCE LIST:This product does not contain greater than 1.0% of any chemical substance on the SARA Extremely Hazardous Substance List.CLEAN AIR ACT S112 HAZARDOUS AIR POLLUTANTS:Glycol Ethers. Benzene (71-43-2).SARA (311, 312) HAZARD CLASS:Acute health hazard.SARA SECTION 313 TOXIC CHEMICALS:

AUSTRALIAN INVENTORY CHEMICAL SUBSTANCES:All components are listed on the Australian Core Inventory of Chemical Substances (ACOIN).CANADIAN INVENTORY:All components are on the Domestic Substance List (DSL).

Page 4 of 5

48%< 200 ppb

Glycol Ethers

12% CERIUM HEX-CEM PRODUCT CODE: 115393

3%

2-Ethylhexanoic Acid (149-57-5)- Birth DefectBenzene (71-43-2)- Cancer, Birth Defect

Page 5: 12% Cerium Hex-Cem (2008)

15. REGULATORY INFORMATIONEINECS REGULATIONS:All components are on the European Inventory of Existing Commercial Chemical Substances (EINECS).JAPAN:All components are listed on the Japanese Existing and New Chemical Substances (ENCS).KOREAN CHEMICAL INVENTORY:All components are on the Korean List of Existing Chemical Substances.PHILIPPINE INVENTORY:All components are listed on the Philippines Inventory of Chemicals and Chemical Substances (PICCS).CHINESE INVENTORY:All components are listed on the Chinese Inventory of Existing Chemical Substances.

16. OTHER INFORMATIONDISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES:The information in this document is believed to be correct as of the date issued. However, no warranty of merchantability, fitness forany particular purpose, or any other warranty is expressed or is to be implied regarding the accuracy or completeness of thisinformation, the results to be obtained from the use of this information or the product, the safety of this product, or the hazards relatedto its use. This information and product are furnished on the condition that the person receiving them shall make his owndetermination as to the suitability of the product for his particular purpose and on the condition that he assume the risk of his usethereof.

17. LABEL INFORMATIONSIGNAL WORD: CAUTIONTARGET ORGANS:Causes severe skin and eye burns. Harmful if inhaled, swallowed or absorbed through skin.EYES:Immediately flush eyes with water and continue washing for at least 15 minutes. DO NOT remove contact lenses, if worn. Obtainmedical attention without delay, preferably from an ophthalmologist.SKIN:Immediately remove contaminated clothing and shoes. Wash skin thoroughly with soap and water for at least 15 minutes. Obtainmedical attention without delay. Wash clothing before reuse. Discard contaminated leather articles such as shoes and belt.INHALATION:Remove to fresh air. Give artificial respiration if not breathing. If breathing is difficult, oxygen may be given by qualified personnel.Obtain medical attention.INGESTION:If patient is conscious, give two glasses of milk or water at once. DO NOT INDUCE VOMITING. Obtain medical attention withoutdelay.HANDLING:Do not get in eyes, on skin or on clothing. Avoid breathing vapor. Do not swallow. Use only with adequate ventilation. Washthoroughly after handling. Launder contaminated clothing before reuse.STORAGE:Store in a cool, dry location away from incompatible materials.ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:Wear suitable protective equipment. Avoid contact with eyes and skin. Collect for disposal. This product is toxic to fish; avoiddischarge to natural waters.EXTINGUISHING MEDIA:Apply alcohol-type or all-purpose-type foam by manufacturer's recommended techniques for large fires. Use carbon dioxide or drychemical media for small fires.

Page 5 of 512% CERIUM HEX-CEM PRODUCT CODE: 115393