01/26/15 safety data sheet page 1 of 11
TRANSCRIPT
01/26/15 SAFETY DATA SHEET Page 1 of 11
[Prepared in accordance with the Ordinance WE no. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010-Europe] __________________________________________________________________________________________________ SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND THE COMPANY/UNDERTAKING __________________________________________________________________________________________________ 1.1 PRODUCT IDENTIFIER
PRODUCT NUMBER : EUROCOLOR 9005BR TRADEMARK : STENCIL PAINT PASTE CHEMICAL NAME : ORGANIC COATING CHEMICAL FAMILY : WATER EMULSION AIR DRY COATING DESCRIPTION : Non-Flammable Water Emulsion Coatings
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES AVDISED AGAINST
APPLICATION : WATER SOLUBLE PAINT USED IN THE PROCESS OF STEEL STRUCTURE PAINTING. FOR PROFESSIONAL USE.
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET
MANUFACTURER : Williams-Hayward International Coatings, Inc Address : 7425 West 59th Street Summit IL 60501 USA Telephone : +1 708 458 0015
DISTRIBUTOR : P.H.U. "STEP" Robert Zawalich Address : Fabryczna 4; 58-100 Swidnica Telephone : 0048 857 04 66
EMAIL ADDRESS OF THE PERSON RESPONSIBLE FOR THE SAFETY DATA SHEET : [email protected]
1.4 EMERGENCY NUMBERS USA : +1 800-424-9300 EUROPE : 0048 857 04 66 (Monday to Friday 8am to 4pm) 112 or 48 505 141 723 (4pm to 8am) __________________________________________________________________________________________________ SECTION 2. HAZARDS IDENTIFICATION __________________________________________________________________________________________________
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE
PRODUCT DEFINITION: Mixture
__________________________________________________________________________________________________
2.2 LABEL ELEMENTS HAZARD PICTOGRAMS:
SIGNAL WORD : CAUTION HAZARD STATEMENTS: CONTAINS COMPOUNDS HARMFUL IF SWALLOWED PRECAUTIONARY STATEMENTS: FOR PROFESSIONAL USE ONLY KEEP OUT OF REACH OF CHILDREN PREVENTION : COMBUSTIBLE. Keep away from heat and open flame. Avoid prolonged contact with skin and breathing of vapor or spray mist. Use with adequate ventilation. RESPONSE : Wash thoroughly after handling. Close container after each use. DISPOSAL : Dispose of in accordance with all local, regional, national, and international regulations. HAZARDOUS INGREDIENTS: Not applicable
SPECIAL PACKAGING REQUIREMENTS CONTAINERS TO BE FITTED WITH CHILD-RESISTANT FASTENINGS: Not applicable TACTILE WARNING OF DANGER: Not applicable 2.3 OTHER HAZARDS
OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION: None known. __________________________________________________________________________________________________ SECTION 3. COMPOSITION, INFORMATION ON INGREDIENTS __________________________________________________________________________________________________
3.2 MIXTURES PERCENT INGREDIENT DESCRIPTION CAS NUMBER BY WGT EINECS
WATER (NON-HAZARDOUS) 7732-18-5 55.0 231-791-2
As of now, the stipulated substances do not possess any identification number in accordance with the REACH ordinance and are subject to the regulations for the temporary period.
The full scope of R expressions is listed in point 16 of this document.
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__________________________________________________________________________________________________ SECTION 4. FIRST AID MEASURES __________________________________________________________________________________________________ 4.1 DESCRIPTION OF FIRST AID MEASURES GENERAL NOTES All of the safety notes and recommendations listed upon product labeling should be adhered to. The effects of exposure are listed in point 11 of this document. SKIN CONTACT Wash with soap and water. An emollient cream or lotion is beneficial. Remove clothing which has come in direct contact with the product. If irritation occurs, call a physician. EYE CONTACT Wash with plenty of water for 10 to 15 minutes. Protect the eye which has not been subject to irritation, take out contact lenses. If eye irritation occurs, call an optician.
INHALATION Remove to fresh air. If not breathing, give artificial respiration. Have a trained person administer oxygen. CALL A PHYSICIAN.
INGESTION DO NOT SWALLOW. If swallowed, do not induce vomiting. CALL A PHYSICIAN. Wash mouth with water. Drink water. Never apply anything to the mouth of an unconscious person.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND CHRONIC ACUTE SKIN CONTACT : No known significant effects or critical hazards EYE CONTACT : No known significant effects or critical hazards INHALATION : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. INGESTION : No known significant effects or critical hazards
CHRONIC SKIN CONTACT : Prolonged contact may cause irritation EYE CONTACT : No specific data INHALATION : No specific data INGESTION : No specific data
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED
NOTES TO PHYSICIAN: If gasses have been inhaled, from the decomposition of the product, symptoms may be delayed. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
SPECIFIC TREATMENTS: No specific treatment __________________________________________________________________________________________________ SECTION 5. FIRE-FIGHTING MEASURES __________________________________________________________________________________________________ 5.1 EXTINGUISHING MEDIA
EXTINGUISHING MEDIA: Fire powder, carbon dioxide, sprayed water stream
IMPROPER MEANS OF EXTINGUISHING: Compact water stream - the risk of spreading fire. 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE
THE DANGEROUS PRODUCTS OF THE BURNING PROCESS: The occurrence of fire may produce dangerous gases: sulphur oxides, nitrogen oxides as well as low particle mass carbohydrates. In the case of stove systems formaldehyde and ammonium may also be produced. Refrain from inhaling the combustion products as they may impose a threat to human health.
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__________________________________________________________________________________________________ SECTION 5. FIRE FIGHTING MEASURES
ADDITIONAL INFORMATION: The product is not flammable. Acrylic emulsions are non-flammable substances. They may splatter if temperature exceeds 100C. Dried polymer films are capable of burning. All of the containers which are endangered by fire should be cooled within the safe distances with the well distributed stream of water.
5.3 ADVICE FOR FIREFIGHTERS
PARTICULAR EQUIPMENT IN THE PROCESS OF FIRE FIGHTING: Means of protection are standard in the case of the occurrence of fire. Do not remain in the area endangered by fire spreading without the proper chemical protective clothing as well as without the breathing apparatus equipped with an independent air system. __________________________________________________________________________________________________ SECTION 6. ACCIDENTAL RELEASE MEASURES __________________________________________________________________________________________________
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
INDIVIDUAL MEANS OF PROTECTION: The general principles of hygiene and safety should be adhered to. Block the passer-by access. Ensure proper ventilation. Avoid direct contact with the product. Do not breathe in vapors.
6.2 ENVIRONMENTAL PRECAUTIONS THE INDISPENSABLE MEANS OF NATURAL ENVIRONMENT PROTECTION Do not allow for the product to enter the ground and underground water sewerage installation system. If a large amount is spilled in the natural environment, take the steps necessary to limit the spreading within the natural environment. Inform proper rescue teams.
6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Keep unnecessary people away. Dike and contain spill with inert material (dry sand, fuller's earth, etc) and transfer the liquid to containers for recovery or proper disposal. Emulsions can be coagulated by stepwise addition of lime and ferric sulphate until all of the water has been completely absorbed. The collected material should be treated as waste. Proceed in accordance with the stipulations of point 13. Clean the polluted location. ATTENTION! Floor may be slippery. Care should be exercised to avoid falls. Also see point 8.
6.4 REFERENCE TO OTHER SECTIONS See Section 1 for emergency contact information. See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information. __________________________________________________________________________________________________ SECTION 7. HANDLING AND STORAGE __________________________________________________________________________________________________
7.1 PRECAUTIONS FOR SAFE HANDLING
SUBSTANCE HANDLING: Use the product in accordance with the safety and hygiene principles, only in well- ventilated rooms. In each case of exposure, before the break as well as after the completion of work, carefully wash hands with soap and water. Do not inhale the product. Apply means of personal protection, which are in compliance with point 8 of this document. VENTILATION: Mechanical Local exhaust at point of contaminant (vapor, mist, or dust) release.
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__________________________________________________________________________________________________ SECTION 7. HANDLING AND STORAGE
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY COMPATIBILITIES
STORAGE: Store in original, tight containers only, in dry and well-ventilated locations. Recommended storage temperature 4-37C. Do not allow the substance to freeze. Store only inside buildings. 7.3 SPECIFIC END USE(S)
SPECIFIC APPLICATIONS: Acrylic latex emulsion, single ingredient, water soluble paint. To be applied directly upon metal or with the application of ground preparation coat. For professional use only.
MISCELLANEOUS: Precautionary Labeling: KEEP FROM FREEZING PRODUCT STABILITY MAY BE AFFECTED __________________________________________________________________________________________________ SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION __________________________________________________________________________________________________ 8.1 CONTROL PARAMETERS
INGREDIENT DESCRIPTION CAS NUMBER EXPOSURE LIMITS
WATER (NON-HAZARDOUS) 7732-18-5 ACGIH TLV: NR OSHA PEL: NR
8.2 EXPOSURE CONTROLS
EXPOSURE CONTROL WITHIN THE WORK PLACE Adhere to the general principles of hygiene and safety. Do not eat, drink, or smoke tobacco during the execution of work. Before the break and after completion of work. Carefully wash hands. Ensure that the workplace is ventilated or the whole room is ventilated in order for the concentration of the harmful agent within the air is below the allowable concentration limit. Avoid eye and skin contact.
ATTENTION! Residual monomer content under conditions to normal handling present no problems. However, high levels of monomer vapors can be released into workroom atmosphere when emulsions are heat cured or dried (rollers, ovens, infrared lamp, etc) if proper ventilation is not used.
PRECAUTIONS: Spray from emulsions must not be inhaled. Respirators should be provided if engineering controls are not adequate. Inhalation exposures to mists or dusts of acrylic polymer should be maintained at (LESS THAN) 10 mg/m3 8-hour TWA limit established for nuisance dusts.
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__________________________________________________________________________________________________ SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
SKIN PROTECTION: Use protective, impermeable gloves. The choice of proper gloves does not only depend on the material but also on other quality characteristics and is subject to change depending on the manufacturer. Gloves should be changed frequently and immediately replaced should any signs of wear, damage, or change of their looks (color, shape, flexibility) occur.
EYE PROTECTION: Apply tight, protective goggles. Splash-proof safety goggles (ANSI Z87.1, 1968).
RESPIRATORY PROTECTION: Follow OSHA Regulation 29CFR 1910.134 for Respiratory use. Use air-purifying respirator that respirator supplier has demonstrated to be effective for solvent vapors, when concentrations exceed the TLV up to the maximum level at which the respirator is effective. If the concentration of solvents is not known or exceeds the level at which the air-purifying respirator is effective, a positive pressure air supplied respirator (TC19C NIOSH/MSHA) is recommended. OTHER PROTECTIVE EQUIPMENT: Eyewash station, emergency shower.
The applied means of personal protection have to meet all of the requirements stipulated within the Ordinance of the Ministry of Economy dated 28 December 2005 (Journal of Acts No.259,pos.2173) as well as within the Directive 89/686/WE (with later amendments). The employee is obliged to ensure means of protection which are proper for the executed activities and which meet all of the quality criteria, also including their maintenance and cleaning.
What is to be applied are the procedures of monitoring of concentrations of dangerous components within the atmosphere as well as the procedures for controlling the purity of ambient air within the work post location - if such are available and justified within the given work post - in accordance with the proper Polish and European standards with the consideration of conditions existent within the exposure location as well as with the consideration of the proper measurement methodology which has been adjusted to the given work condition. This mode, type, and frequency of research and measurements should meet the requirements included within the ordinance of the Health Minister dated 20 April 2005 (Journal of Acts No.73,pos.645 with later amendments).
THE CONTROL OF NATURAL ENVIRONMENT EXPOSURE RISK: Prevent direct leaking of the product to the sewerage system/surface water system. It is forbidden to pollute surface waters and drainage ditches with the application of chemicals or used containers. The spilled product or uncontrolled leakages into surface waters should be communicated to the proper authority in accordance with the national and local regulations. Treat and store as chemical waste, in accordance with the national and local regulations.
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__________________________________________________________________________________________________ SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES __________________________________________________________________________________________________ 9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES
BOILING RANGE: 212 TO 375 (deg F) % VOLATILE (VOLUME): 66.35 100 TO 190 (deg C) % NVM (WEIGHT) : 44.29 VAPOR DENSITY: HEAVIER THAN AIR % NVM (VOLUME) : 33.64 EVAP RATE : SLOWER THAN BUTYL ACETATE DENSITY : 9.89 (lb/gl) : 1185.66 (gr/l) APPEARANCE : BLACK IN COLOR ODOR : SLIGHT AMINE ODOR WATER SOLUBLE: YES
9.2 OTHER INFORMATION
SOLVENTS : 8.339 (lb/gl) VOC (as shipped): (lb/gl) : 999.01 (gr/l) : (gr/l) __________________________________________________________________________________________________ SECTION 10. STABILITY AND REACTIVITY __________________________________________________________________________________________________
10.1 REACTIVITY No specific test data related to reactivity available for this product or its ingredients
10.2 CHEMICAL STABILITY Stable.
10.4 CONDITIONS TO AVOID Non Applicable.
10.5 INCOMPATIBLE MATERIALS Avoid contact with strong oxidizing agents.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may yield oxides of carbon, oxides of nitrogen and low molecular weight hydrocarbons. In baking systems, formaldehyde and ammonia may be present.
__________________________________________________________________________________________________ 11. TOXICOLOGICAL INFORMATION __________________________________________________________________________________________________
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__________________________________________________________________________________________________ 11. TOXICOLOGICAL INFORMATION
TARGET ORGANS: eyes
EFFECTS OF OVEREXPOSURE: INHALATION Vapor or mist can cause headache, nausea, and irritation of the nose, throat, and lungs. Overexposure can have narcotic effect EYE CONTACT Slightly irritating to eyes. SKIN CONTACT Irritating to skin upon repeated or prolonged contact.
PRIMARY ROUTES OF ENTRY: Dermal, Inhalation, Ingestion. __________________________________________________________________________________________________ 12. ECOLOGICAL INFORMATION __________________________________________________________________________________________________
12.1 TOXICITY
ECO-TOXICITY: This product contains chemicals which are harmful to fish.
12.2 MOBILITY IN SOIL
This product dissolves in water and spreads through the environment.
12.3 ADDITIONAL INFORMATION Large product quantities should be protected against accessing surface waters, sewerage system and soil.
Ecotoxicological information on this product's components appear in this section when such data is available
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__________________________________________________________________________________________________ SECTION 13. DISPOSAL CONSIDERATIONS __________________________________________________________________________________________________
13.1 WASTE TREATMENT METHODS
COMPOUND RECOMMENDATIONS: This product is classified as a non-hazardous waste.
The waste product should be subject to recycling or should be removed within certified incineration facilities or waste recycling/processing plants, in accordance with the obligatory regulation. It should not be removed along with communal waste.The remnants should be stored in original containers. The waste code should be provided within the location of the waste processing.
RECOMMENDATIONS WITH REGARD TO THE PACKAGING: Packaging, which may not be cleaned should be treated in the same manner as the product.
ENVIRONMENTAL PRECAUTIONS: CAUTION: Keep spills and cleaning runoff out of municipal sewers and open bodies of water. __________________________________________________________________________________________________ SECTION 14. TRANSPORT INFORMATION __________________________________________________________________________________________________
The product is not classified as dangerous during land, sea, or air transport.
14.1 UN NUMBER Not applicable
14.2 UN PROPER SHIPPING NAME PAINT, NON-FLAMMABLE LIQUID
14.3 TRANSPORTATION HAZARD CLASS Not applicable
14.4 PACKAGING GROUP Not applicable
14.5 SPECIAL PRECAUTIONS FOR USER
TRANSPORT WITHIN USER'S PREMISES: Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. __________________________________________________________________________________________________ SECTION 15. REGULATORY INFORMATION __________________________________________________________________________________________________ 15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE SUBSTANCE OR MIXTURE
LETTER LABELING AND DANGER LABELING: N/A THE NAMES OF DANGEROUS INGREDIENTS LOCATED UPON THE LABEL: N/A THE DETERMINATION ON THE TYPE OF THREAT: N/A THE DETERMINATION OF THE PROPER METHOD OF PRODUCT MANAGEMENT: N/A
APPLICABLE NATIONAL REGULATIONS: The Act on chemical substances and compounds dated 11 January 2001 (Journal of Acts No.11,pos.84 along with later amendments). The Act dated 9 January 2009 introducing changes to the Act on chemical substances and chemical compounds as well as to some other Acts (Journal of Acts No.20,pos.106).
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__________________________________________________________________________________________________ SECTION 15. REGULATORY INFORMATION
The Ordinance of the Health Ministry dated 4 September 2007 with regard to the criteria and the method of classification of dangerous compounds and substances (Journal of Acts No.174,pos.1222, with later amendments, Journal of Acts 2009,No.43,pos.353). The Ordinance of the Health Minister dated 5 March 2009 with regard to the labeling of dangerous substances and compounds (Journal of Acts No.53, pos.439). The Ordinance of the Labour and Social Policy Ministry dated 29 November 2002 with regard to the highest allowed concentrations and influences of compounds and coefficients harmful to human health within the work post (Journal of Acts No.217,pos.1833 with later amendments). The Statement of the Government dated 16 January 2009 with regard to changes introduced into Attachments A and B of the European Agreement connected to the international road transport of dangerous products (ADR) prepared in Geneva dated 30 September 1957 (Journal of Acts No.27,pos.162). The Waste Act dated 27 April 2001 (Journal of Acts No.62,pos.628 along with later amendments). The Ordinance of the Ministry of the Natural Environment and Natural Environment Protection dated 27 September 2001 with regard to the catalogue of waste products (Journal of Acts No.112,pos.1206). The Ordinance of the Ministry of Economy and Labour dated 5 July 2004 with regard to the limitations, bans or manufacturing conditions, turnover or the application of dangerous substances and dangerous compounds as well as on the products that contain the aforementioned (Journal of Acts No.168,pos.1762 along with later amendments). The Ordinance of the Ministry of Economy dated 21 December 2005 with regard to the substantial requirements for the means of individual protection (Journal of Acts No.259,pos.2173 dated 2005). The Ordinance of the Health Ministry dated 20 April 2005 with regard to the research and measurements of coefficients harmful to human health within the surroundings of the work post location (Journal of Acts No.73,pos.645 dated 2005 along with later amendments). The Ordinance of the Ministry of Economy dated 11 January 2007 with regard to the particular requirements connected to the limitation of the emission of airborne organic particles created as the result of the application of organic solvents applied in the case of some paint or varnish products as well as within vehicle renewal products (Journal of Acts No.11,pos.72).
OTHER APPLICABLE REGULATIONS: 1907/2006/WE The ordinance with regard to the registration, assessment, rendering of permissions and application of limitations with regard to chemicals (REACH), the creation of the European Chemical Agency, which change the directive 1999/45/WE as well as those which cancel the Ordinance of the European Council no 793/93 and the Ordinance of the European Committee no. 1488/94, and also the ordinance of the Council 76/769/EWG and the directive of the Committee 91/155/EWG, 93/67/EWG, 93/105/WE and 2000/21/WE.
1272/2008/WE The Ordinance of the European Parliament and the European Council dated 16 December 2008 with regard to the classification, labeling and packaging of substances and mixtures, which introduces changes and which waivers the directives of 67/548/EWG and 1999/45/WE and which introduces changes into the ordinance (WE)number 1907/2006.
67/548/EWG The Directive of the Council dated 27 June 1967 with regard to the rapprochement of the executive, legal forming and administrative regulations which refer to the issue of classification, packaging and labeling of dangerous substances.
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__________________________________________________________________________________________________ SECTION 15. REGULATORY INFORMATION
2001/58/WE The Directive of the Committee dated 27 July 2001 which changes, for the second time, the directive of 91/155/EWG which determines and introduces detailed agreements with regard to the particular information systems on the dangerous compounds in relation to dangerous substances in connection to the execution of article 27 of the Directive of the Council 67/548/EWG (safety information data chart).
15.2 CHEMICAL SAFETY ASSESSMENT
This product contains substances for which Chemical Safety Assessments are still required.
__________________________________________________________________________________________________ SECTION 16. OTHER INFORMATION __________________________________________________________________________________________________
THE FULL TEXT OF EXPRESSIONS R FROM POINT 3 Not available WORKSHOPS: Prior to the initiation of work with the product, the user should get acquainted with the health and safety regulations regarding chemical handling, and especially the workshop for the particular post.
ADDITIONAL INFORMATION: Product classification has been agreed based upon the actual concentration of each of the components and it presents real threats, which are imposed by this product. The real value of the concentrations of particular components always fits within the proper range. Therefore, for that reason final product classification may be different from the calculated classification based upon the general concentration values.
(NDS) Highest Allowable Concentration
__________________________________________________________________________________________________
[Prepared in accordance with the Ordinance WE no. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010-Europe] __________________________________________________________________________________________________ SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND THE COMPANY/UNDERTAKING __________________________________________________________________________________________________ 1.1 PRODUCT IDENTIFIER
PRODUCT NUMBER : EUROCOLOR 9005BR TRADEMARK : STENCIL PAINT PASTE CHEMICAL NAME : ORGANIC COATING CHEMICAL FAMILY : WATER EMULSION AIR DRY COATING DESCRIPTION : Non-Flammable Water Emulsion Coatings
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES AVDISED AGAINST
APPLICATION : WATER SOLUBLE PAINT USED IN THE PROCESS OF STEEL STRUCTURE PAINTING. FOR PROFESSIONAL USE.
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET
MANUFACTURER : Williams-Hayward International Coatings, Inc Address : 7425 West 59th Street Summit IL 60501 USA Telephone : +1 708 458 0015
DISTRIBUTOR : P.H.U. "STEP" Robert Zawalich Address : Fabryczna 4; 58-100 Swidnica Telephone : 0048 857 04 66
EMAIL ADDRESS OF THE PERSON RESPONSIBLE FOR THE SAFETY DATA SHEET : [email protected]
1.4 EMERGENCY NUMBERS USA : +1 800-424-9300 EUROPE : 0048 857 04 66 (Monday to Friday 8am to 4pm) 112 or 48 505 141 723 (4pm to 8am) __________________________________________________________________________________________________ SECTION 2. HAZARDS IDENTIFICATION __________________________________________________________________________________________________
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE
PRODUCT DEFINITION: Mixture
__________________________________________________________________________________________________
2.2 LABEL ELEMENTS HAZARD PICTOGRAMS:
SIGNAL WORD : CAUTION HAZARD STATEMENTS: CONTAINS COMPOUNDS HARMFUL IF SWALLOWED PRECAUTIONARY STATEMENTS: FOR PROFESSIONAL USE ONLY KEEP OUT OF REACH OF CHILDREN PREVENTION : COMBUSTIBLE. Keep away from heat and open flame. Avoid prolonged contact with skin and breathing of vapor or spray mist. Use with adequate ventilation. RESPONSE : Wash thoroughly after handling. Close container after each use. DISPOSAL : Dispose of in accordance with all local, regional, national, and international regulations. HAZARDOUS INGREDIENTS: Not applicable
SPECIAL PACKAGING REQUIREMENTS CONTAINERS TO BE FITTED WITH CHILD-RESISTANT FASTENINGS: Not applicable TACTILE WARNING OF DANGER: Not applicable 2.3 OTHER HAZARDS
OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION: None known. __________________________________________________________________________________________________ SECTION 3. COMPOSITION, INFORMATION ON INGREDIENTS __________________________________________________________________________________________________
3.2 MIXTURES PERCENT INGREDIENT DESCRIPTION CAS NUMBER BY WGT EINECS
WATER (NON-HAZARDOUS) 7732-18-5 55.0 231-791-2
As of now, the stipulated substances do not possess any identification number in accordance with the REACH ordinance and are subject to the regulations for the temporary period.
The full scope of R expressions is listed in point 16 of this document.
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__________________________________________________________________________________________________ SECTION 4. FIRST AID MEASURES __________________________________________________________________________________________________ 4.1 DESCRIPTION OF FIRST AID MEASURES GENERAL NOTES All of the safety notes and recommendations listed upon product labeling should be adhered to. The effects of exposure are listed in point 11 of this document. SKIN CONTACT Wash with soap and water. An emollient cream or lotion is beneficial. Remove clothing which has come in direct contact with the product. If irritation occurs, call a physician. EYE CONTACT Wash with plenty of water for 10 to 15 minutes. Protect the eye which has not been subject to irritation, take out contact lenses. If eye irritation occurs, call an optician.
INHALATION Remove to fresh air. If not breathing, give artificial respiration. Have a trained person administer oxygen. CALL A PHYSICIAN.
INGESTION DO NOT SWALLOW. If swallowed, do not induce vomiting. CALL A PHYSICIAN. Wash mouth with water. Drink water. Never apply anything to the mouth of an unconscious person.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND CHRONIC ACUTE SKIN CONTACT : No known significant effects or critical hazards EYE CONTACT : No known significant effects or critical hazards INHALATION : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. INGESTION : No known significant effects or critical hazards
CHRONIC SKIN CONTACT : Prolonged contact may cause irritation EYE CONTACT : No specific data INHALATION : No specific data INGESTION : No specific data
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED
NOTES TO PHYSICIAN: If gasses have been inhaled, from the decomposition of the product, symptoms may be delayed. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
SPECIFIC TREATMENTS: No specific treatment __________________________________________________________________________________________________ SECTION 5. FIRE-FIGHTING MEASURES __________________________________________________________________________________________________ 5.1 EXTINGUISHING MEDIA
EXTINGUISHING MEDIA: Fire powder, carbon dioxide, sprayed water stream
IMPROPER MEANS OF EXTINGUISHING: Compact water stream - the risk of spreading fire. 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE
THE DANGEROUS PRODUCTS OF THE BURNING PROCESS: The occurrence of fire may produce dangerous gases: sulphur oxides, nitrogen oxides as well as low particle mass carbohydrates. In the case of stove systems formaldehyde and ammonium may also be produced. Refrain from inhaling the combustion products as they may impose a threat to human health.
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__________________________________________________________________________________________________ SECTION 5. FIRE FIGHTING MEASURES
ADDITIONAL INFORMATION: The product is not flammable. Acrylic emulsions are non-flammable substances. They may splatter if temperature exceeds 100C. Dried polymer films are capable of burning. All of the containers which are endangered by fire should be cooled within the safe distances with the well distributed stream of water.
5.3 ADVICE FOR FIREFIGHTERS
PARTICULAR EQUIPMENT IN THE PROCESS OF FIRE FIGHTING: Means of protection are standard in the case of the occurrence of fire. Do not remain in the area endangered by fire spreading without the proper chemical protective clothing as well as without the breathing apparatus equipped with an independent air system. __________________________________________________________________________________________________ SECTION 6. ACCIDENTAL RELEASE MEASURES __________________________________________________________________________________________________
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
INDIVIDUAL MEANS OF PROTECTION: The general principles of hygiene and safety should be adhered to. Block the passer-by access. Ensure proper ventilation. Avoid direct contact with the product. Do not breathe in vapors.
6.2 ENVIRONMENTAL PRECAUTIONS THE INDISPENSABLE MEANS OF NATURAL ENVIRONMENT PROTECTION Do not allow for the product to enter the ground and underground water sewerage installation system. If a large amount is spilled in the natural environment, take the steps necessary to limit the spreading within the natural environment. Inform proper rescue teams.
6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Keep unnecessary people away. Dike and contain spill with inert material (dry sand, fuller's earth, etc) and transfer the liquid to containers for recovery or proper disposal. Emulsions can be coagulated by stepwise addition of lime and ferric sulphate until all of the water has been completely absorbed. The collected material should be treated as waste. Proceed in accordance with the stipulations of point 13. Clean the polluted location. ATTENTION! Floor may be slippery. Care should be exercised to avoid falls. Also see point 8.
6.4 REFERENCE TO OTHER SECTIONS See Section 1 for emergency contact information. See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information. __________________________________________________________________________________________________ SECTION 7. HANDLING AND STORAGE __________________________________________________________________________________________________
7.1 PRECAUTIONS FOR SAFE HANDLING
SUBSTANCE HANDLING: Use the product in accordance with the safety and hygiene principles, only in well- ventilated rooms. In each case of exposure, before the break as well as after the completion of work, carefully wash hands with soap and water. Do not inhale the product. Apply means of personal protection, which are in compliance with point 8 of this document. VENTILATION: Mechanical Local exhaust at point of contaminant (vapor, mist, or dust) release.
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__________________________________________________________________________________________________ SECTION 7. HANDLING AND STORAGE
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY COMPATIBILITIES
STORAGE: Store in original, tight containers only, in dry and well-ventilated locations. Recommended storage temperature 4-37C. Do not allow the substance to freeze. Store only inside buildings. 7.3 SPECIFIC END USE(S)
SPECIFIC APPLICATIONS: Acrylic latex emulsion, single ingredient, water soluble paint. To be applied directly upon metal or with the application of ground preparation coat. For professional use only.
MISCELLANEOUS: Precautionary Labeling: KEEP FROM FREEZING PRODUCT STABILITY MAY BE AFFECTED __________________________________________________________________________________________________ SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION __________________________________________________________________________________________________ 8.1 CONTROL PARAMETERS
INGREDIENT DESCRIPTION CAS NUMBER EXPOSURE LIMITS
WATER (NON-HAZARDOUS) 7732-18-5 ACGIH TLV: NR OSHA PEL: NR
8.2 EXPOSURE CONTROLS
EXPOSURE CONTROL WITHIN THE WORK PLACE Adhere to the general principles of hygiene and safety. Do not eat, drink, or smoke tobacco during the execution of work. Before the break and after completion of work. Carefully wash hands. Ensure that the workplace is ventilated or the whole room is ventilated in order for the concentration of the harmful agent within the air is below the allowable concentration limit. Avoid eye and skin contact.
ATTENTION! Residual monomer content under conditions to normal handling present no problems. However, high levels of monomer vapors can be released into workroom atmosphere when emulsions are heat cured or dried (rollers, ovens, infrared lamp, etc) if proper ventilation is not used.
PRECAUTIONS: Spray from emulsions must not be inhaled. Respirators should be provided if engineering controls are not adequate. Inhalation exposures to mists or dusts of acrylic polymer should be maintained at (LESS THAN) 10 mg/m3 8-hour TWA limit established for nuisance dusts.
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__________________________________________________________________________________________________ SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
SKIN PROTECTION: Use protective, impermeable gloves. The choice of proper gloves does not only depend on the material but also on other quality characteristics and is subject to change depending on the manufacturer. Gloves should be changed frequently and immediately replaced should any signs of wear, damage, or change of their looks (color, shape, flexibility) occur.
EYE PROTECTION: Apply tight, protective goggles. Splash-proof safety goggles (ANSI Z87.1, 1968).
RESPIRATORY PROTECTION: Follow OSHA Regulation 29CFR 1910.134 for Respiratory use. Use air-purifying respirator that respirator supplier has demonstrated to be effective for solvent vapors, when concentrations exceed the TLV up to the maximum level at which the respirator is effective. If the concentration of solvents is not known or exceeds the level at which the air-purifying respirator is effective, a positive pressure air supplied respirator (TC19C NIOSH/MSHA) is recommended. OTHER PROTECTIVE EQUIPMENT: Eyewash station, emergency shower.
The applied means of personal protection have to meet all of the requirements stipulated within the Ordinance of the Ministry of Economy dated 28 December 2005 (Journal of Acts No.259,pos.2173) as well as within the Directive 89/686/WE (with later amendments). The employee is obliged to ensure means of protection which are proper for the executed activities and which meet all of the quality criteria, also including their maintenance and cleaning.
What is to be applied are the procedures of monitoring of concentrations of dangerous components within the atmosphere as well as the procedures for controlling the purity of ambient air within the work post location - if such are available and justified within the given work post - in accordance with the proper Polish and European standards with the consideration of conditions existent within the exposure location as well as with the consideration of the proper measurement methodology which has been adjusted to the given work condition. This mode, type, and frequency of research and measurements should meet the requirements included within the ordinance of the Health Minister dated 20 April 2005 (Journal of Acts No.73,pos.645 with later amendments).
THE CONTROL OF NATURAL ENVIRONMENT EXPOSURE RISK: Prevent direct leaking of the product to the sewerage system/surface water system. It is forbidden to pollute surface waters and drainage ditches with the application of chemicals or used containers. The spilled product or uncontrolled leakages into surface waters should be communicated to the proper authority in accordance with the national and local regulations. Treat and store as chemical waste, in accordance with the national and local regulations.
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__________________________________________________________________________________________________ SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES __________________________________________________________________________________________________ 9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES
BOILING RANGE: 212 TO 375 (deg F) % VOLATILE (VOLUME): 66.35 100 TO 190 (deg C) % NVM (WEIGHT) : 44.29 VAPOR DENSITY: HEAVIER THAN AIR % NVM (VOLUME) : 33.64 EVAP RATE : SLOWER THAN BUTYL ACETATE DENSITY : 9.89 (lb/gl) : 1185.66 (gr/l) APPEARANCE : BLACK IN COLOR ODOR : SLIGHT AMINE ODOR WATER SOLUBLE: YES
9.2 OTHER INFORMATION
SOLVENTS : 8.339 (lb/gl) VOC (as shipped): (lb/gl) : 999.01 (gr/l) : (gr/l) __________________________________________________________________________________________________ SECTION 10. STABILITY AND REACTIVITY __________________________________________________________________________________________________
10.1 REACTIVITY No specific test data related to reactivity available for this product or its ingredients
10.2 CHEMICAL STABILITY Stable.
10.4 CONDITIONS TO AVOID Non Applicable.
10.5 INCOMPATIBLE MATERIALS Avoid contact with strong oxidizing agents.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may yield oxides of carbon, oxides of nitrogen and low molecular weight hydrocarbons. In baking systems, formaldehyde and ammonia may be present.
__________________________________________________________________________________________________ 11. TOXICOLOGICAL INFORMATION __________________________________________________________________________________________________
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__________________________________________________________________________________________________ 11. TOXICOLOGICAL INFORMATION
TARGET ORGANS: eyes
EFFECTS OF OVEREXPOSURE: INHALATION Vapor or mist can cause headache, nausea, and irritation of the nose, throat, and lungs. Overexposure can have narcotic effect EYE CONTACT Slightly irritating to eyes. SKIN CONTACT Irritating to skin upon repeated or prolonged contact.
PRIMARY ROUTES OF ENTRY: Dermal, Inhalation, Ingestion. __________________________________________________________________________________________________ 12. ECOLOGICAL INFORMATION __________________________________________________________________________________________________
12.1 TOXICITY
ECO-TOXICITY: This product contains chemicals which are harmful to fish.
12.2 MOBILITY IN SOIL
This product dissolves in water and spreads through the environment.
12.3 ADDITIONAL INFORMATION Large product quantities should be protected against accessing surface waters, sewerage system and soil.
Ecotoxicological information on this product's components appear in this section when such data is available
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__________________________________________________________________________________________________ SECTION 13. DISPOSAL CONSIDERATIONS __________________________________________________________________________________________________
13.1 WASTE TREATMENT METHODS
COMPOUND RECOMMENDATIONS: This product is classified as a non-hazardous waste.
The waste product should be subject to recycling or should be removed within certified incineration facilities or waste recycling/processing plants, in accordance with the obligatory regulation. It should not be removed along with communal waste.The remnants should be stored in original containers. The waste code should be provided within the location of the waste processing.
RECOMMENDATIONS WITH REGARD TO THE PACKAGING: Packaging, which may not be cleaned should be treated in the same manner as the product.
ENVIRONMENTAL PRECAUTIONS: CAUTION: Keep spills and cleaning runoff out of municipal sewers and open bodies of water. __________________________________________________________________________________________________ SECTION 14. TRANSPORT INFORMATION __________________________________________________________________________________________________
The product is not classified as dangerous during land, sea, or air transport.
14.1 UN NUMBER Not applicable
14.2 UN PROPER SHIPPING NAME PAINT, NON-FLAMMABLE LIQUID
14.3 TRANSPORTATION HAZARD CLASS Not applicable
14.4 PACKAGING GROUP Not applicable
14.5 SPECIAL PRECAUTIONS FOR USER
TRANSPORT WITHIN USER'S PREMISES: Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. __________________________________________________________________________________________________ SECTION 15. REGULATORY INFORMATION __________________________________________________________________________________________________ 15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE SUBSTANCE OR MIXTURE
LETTER LABELING AND DANGER LABELING: N/A THE NAMES OF DANGEROUS INGREDIENTS LOCATED UPON THE LABEL: N/A THE DETERMINATION ON THE TYPE OF THREAT: N/A THE DETERMINATION OF THE PROPER METHOD OF PRODUCT MANAGEMENT: N/A
APPLICABLE NATIONAL REGULATIONS: The Act on chemical substances and compounds dated 11 January 2001 (Journal of Acts No.11,pos.84 along with later amendments). The Act dated 9 January 2009 introducing changes to the Act on chemical substances and chemical compounds as well as to some other Acts (Journal of Acts No.20,pos.106).
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__________________________________________________________________________________________________ SECTION 15. REGULATORY INFORMATION
The Ordinance of the Health Ministry dated 4 September 2007 with regard to the criteria and the method of classification of dangerous compounds and substances (Journal of Acts No.174,pos.1222, with later amendments, Journal of Acts 2009,No.43,pos.353). The Ordinance of the Health Minister dated 5 March 2009 with regard to the labeling of dangerous substances and compounds (Journal of Acts No.53, pos.439). The Ordinance of the Labour and Social Policy Ministry dated 29 November 2002 with regard to the highest allowed concentrations and influences of compounds and coefficients harmful to human health within the work post (Journal of Acts No.217,pos.1833 with later amendments). The Statement of the Government dated 16 January 2009 with regard to changes introduced into Attachments A and B of the European Agreement connected to the international road transport of dangerous products (ADR) prepared in Geneva dated 30 September 1957 (Journal of Acts No.27,pos.162). The Waste Act dated 27 April 2001 (Journal of Acts No.62,pos.628 along with later amendments). The Ordinance of the Ministry of the Natural Environment and Natural Environment Protection dated 27 September 2001 with regard to the catalogue of waste products (Journal of Acts No.112,pos.1206). The Ordinance of the Ministry of Economy and Labour dated 5 July 2004 with regard to the limitations, bans or manufacturing conditions, turnover or the application of dangerous substances and dangerous compounds as well as on the products that contain the aforementioned (Journal of Acts No.168,pos.1762 along with later amendments). The Ordinance of the Ministry of Economy dated 21 December 2005 with regard to the substantial requirements for the means of individual protection (Journal of Acts No.259,pos.2173 dated 2005). The Ordinance of the Health Ministry dated 20 April 2005 with regard to the research and measurements of coefficients harmful to human health within the surroundings of the work post location (Journal of Acts No.73,pos.645 dated 2005 along with later amendments). The Ordinance of the Ministry of Economy dated 11 January 2007 with regard to the particular requirements connected to the limitation of the emission of airborne organic particles created as the result of the application of organic solvents applied in the case of some paint or varnish products as well as within vehicle renewal products (Journal of Acts No.11,pos.72).
OTHER APPLICABLE REGULATIONS: 1907/2006/WE The ordinance with regard to the registration, assessment, rendering of permissions and application of limitations with regard to chemicals (REACH), the creation of the European Chemical Agency, which change the directive 1999/45/WE as well as those which cancel the Ordinance of the European Council no 793/93 and the Ordinance of the European Committee no. 1488/94, and also the ordinance of the Council 76/769/EWG and the directive of the Committee 91/155/EWG, 93/67/EWG, 93/105/WE and 2000/21/WE.
1272/2008/WE The Ordinance of the European Parliament and the European Council dated 16 December 2008 with regard to the classification, labeling and packaging of substances and mixtures, which introduces changes and which waivers the directives of 67/548/EWG and 1999/45/WE and which introduces changes into the ordinance (WE)number 1907/2006.
67/548/EWG The Directive of the Council dated 27 June 1967 with regard to the rapprochement of the executive, legal forming and administrative regulations which refer to the issue of classification, packaging and labeling of dangerous substances.
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__________________________________________________________________________________________________ SECTION 15. REGULATORY INFORMATION
2001/58/WE The Directive of the Committee dated 27 July 2001 which changes, for the second time, the directive of 91/155/EWG which determines and introduces detailed agreements with regard to the particular information systems on the dangerous compounds in relation to dangerous substances in connection to the execution of article 27 of the Directive of the Council 67/548/EWG (safety information data chart).
15.2 CHEMICAL SAFETY ASSESSMENT
This product contains substances for which Chemical Safety Assessments are still required.
__________________________________________________________________________________________________ SECTION 16. OTHER INFORMATION __________________________________________________________________________________________________
THE FULL TEXT OF EXPRESSIONS R FROM POINT 3 Not available WORKSHOPS: Prior to the initiation of work with the product, the user should get acquainted with the health and safety regulations regarding chemical handling, and especially the workshop for the particular post.
ADDITIONAL INFORMATION: Product classification has been agreed based upon the actual concentration of each of the components and it presents real threats, which are imposed by this product. The real value of the concentrations of particular components always fits within the proper range. Therefore, for that reason final product classification may be different from the calculated classification based upon the general concentration values.
(NDS) Highest Allowable Concentration
__________________________________________________________________________________________________