semspub.epa.gov‚¬ n v i r o n epililila region 5 recordls ' ctr april 20, 2006 311931...
TRANSCRIPT
€ N V I R O N EPA Region 5 Records Ctr
ililill ' April 20, 2006 311931
Richard E. Boice. P.E. USEPA Region 5 77 West Jackson Boulevard Mail Code: SR-6J Chicago, IL 60604-3507
Re: Request to Discontinue Ambient Air Monitoring Midco 1 and Midco II Sites, Gary, Indiana
Dear Mr. Boice:
On behalf of the Midco Remedial Corporation (MRC). ENVIRON International Corporation (ENVIRON) submits the following request for discontinuation of ambient air monitoring at the Midco I and Midco II Sites (the "Sites"). In lieu of ambient air monitoring at the Sites, we propose to monitor air emissions at the sources of the emissions (the thermal oxidizers). To demonstrate compliance with the requirements specified in the Statement of Work (SOW) and the provisions of the Clean Air Act, which limits volatile organic compound (VOC) emissions to less than 3 pounds per hour, air dispersion factors will be utilized to estimate the potential concentration at the theoretical receptor due to the measured emissions.
Currently, as specified in Explanation of Significant Differences (ESD) #3. for the Midco 1 Superfund Site (Section V.E). and ESD #3 for the Midco II Superfund Site (Section V.E), both dated September 2004, the compliance point for the hypothetical resident has been changed from a theoretical resident at the site boundary to the nearest receptor location, as originally stipulated in the 1989 Record of Decision. The purpose of this change was to eliminate the need for unreasonably stringent air emission controls.
Ambient air monitoring for the Sites is specified in Section 6.5.2 of the Remedial Investigation/Remedial Action Investigation and Monitoring Plan, Midco I and II Sites. Gary. Indiana (ERM-North Central, Inc., May 14, 1993). The purpose of this ambient air monitoring was to ensure that a theoretical resident at the Sites" boundaries would not be exposed to risks above the limits set in the SOW. The results of ambient air monitoring performed at the Sites during the systems start-up and commissioning are included as attachments to this letter:
• Attachment 1 - Midco II Horizontal SVE Well Installation • Attachment 2 ~ Midco II SVE/AS System Start-Up Testing • Attachment 3 - Midco I SVE System Start-Up Testing • Attachment 4 - Midco II SVE/AS Conutiissioning Testing • Attachment 5 - Midco I SVE System Commissioning Testing • Attachment 6 - Analytical Reports
Given that only traces of non-carcinogenic compounds were detected in the samples, risks were not formally calculated using the air dispersion factors and risk constants presented in the USEPA-approved Final Design/Build Repori (Revision 3). Soil Vapor Extraction/Air Sparging System, Midco II Superfund Site (ENVIRON. April 2005), and Technical Memorandum No. 3 -Pressure and Flow Step Test Results, Head Loss Calculations, and Air Etnissions and Risk
' Incremental lifetime carcinogenic risk less than 1x10"̂ target risk level and hazard index of less than 1 using the risk factors outlined in the SOW.
www.environcorp.com 740 Waukegan Road, Suite 401, Deerfield, Illinois 60015 Tel: (847) 444-9200 Fax: (847) 444-9420
Richard E. Boice, P.E. - 2 - April 20, 2006
Calculations, Midco I Superfund Site (ENVIRON. September 19. 2005, revised November 7, 2005). The results of ambient air monitoring for SVE system start-up and commissioning are all well below the SOW-required hazard index of I and pose no carcinogenic risk.
As the nearest residents (i.e., receptors) are located approximately 1,500 feet from the Midco 1 Site and 4,600 feet from the Midco II Site, ambient air samples would need to represent air concentrations over areas of approximately 160 and 1,500 acres, respectively. It is technically impracticable to collect representative samples for such large areas. Specifically, the ability to evaluate upwind contributions from potentially multiple off-site sources (e.g. the Gary Airport) and variability in wind conditions makes this approach to monitoring for the purpose of risk evaluation impracticable.
To demonstrate continued compliance with air emission requirements, we propose to collect stack samples at each off-gas treatment system exhaust stack and to utilize the analytical results of actual emission samples in conjunction with dispersion models, such as U.S. Environmental Protection Agency's Screening Procedures. Version 3 (SCREEN3) and/or Industrial Source Complex Short-Term Model. Version 3 (1SCST3). to estimate air quality at the receptor locations. Using analytical data derived from SUMMA canister sampling of the thermal oxidizers" stacks and dispersion models is an accepted practice and an accurate and practical approach to estimate risks, and thus, to determine compliance.
During SVE system operation at the Midco 11 Site, thermal oxidizer stack sampling would be performed at the frequency specified in the Operations, Maintenance, Monitoring and Closure Plan for the Soil Vapor Extraction 'Air Sparging System, Midco II Site (the "OMMc&C Plan"; ENVIRON, March 2006). A similar frequency is proposed for thermal oxidizer stack sampling for the Midco 1 SVE system as defined in the OMM<&C Plan for the Midco I Site." The stack sample analytical results will be reported in the Quarterly Air Monthly Progress reports, while the modeling and risk calculation results would be reported under separate cover.
Written approval to discontinue ambient air monitoring as specified in the 1993 Ic&MP as described herein is requested from the Agency. Please feel free to contact Bruce Kennington at (312) 853-9430 or Ronald Hutchens at (847) 444-9200 with any questions regarding this request.
Sincerely,
ENVIRON International Corporation
^§--r^^_^ Bruce S. Kennington Ronald E. Hutchens, P.E.
Senior Manager Principal
Attachments
cc: Stephanie Andrews, IDEM
Omprakash Patel, Weston Solutions, Inc. Midco Remedial Corporation (see page 3 for Distribution List) Mark Travers. ENVIRON international Corporation
OMM&C Plan for the SVE system at the Midco I Site will be submitted to the Agency
Richard E. Boice, P.E. - 3 - April 20, 2006
Midco Remedial Corporation Distribution List
Arthur A. Schulcz, Sr., The Law Office of Arthur A. Schulcz William Dickett, Sidley Austin Brown 8L Wood (w/o CD) Michael Murphy. Rustoleum Corporation Rasheed Pasha, Rustoleum Corporation (w/o CD) Michael Loch, Motorola (w/o CD) Natalie Walsh, Walsh Law Offices Frank Brown, Rexam, Inc. (w/o CD) Bruce White, Karaganis White &. Magel, Ltd. Edward R. Andrus, Jr. (w/o CD)
@ AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
WORK ORDER #: 0411319
Work Order Summary
CLIENT:
PHONE:
FAX:
DATE RECEIVED:
DATE COMPLETED:
Mr. Bruce Kennington Environ Intemational 123 North Wacker Dr. Suite 250 Chicago, IL 60606
312-853-9430
312-853-9025
11/17/2004
11/28/2004
FRACTION* OIA 02A 03A 04A 05A 05AA 06A 07A 08A
NAME 2AMCOU01 2AMC0D01 2AMCODR01 2AMCODL01 2AMCOU01D 2AMCOU0ID Duplicate Lab Blank CCV LCS
BILL TO:
P.O.#
PROJECT*
CONTACT:
TEST
Mr. Felix Moran Environ International 740 Waukegan Road Suite 401 Deerfield,
Susan Al
Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15
IL 60015
iniz
RECEIPT VAC/PRES.
0.2psi 0.2psi
0.0 "Hg 0.0 "Hg 0.0 "Hg 0.0 "Hg
NA NA NA
CERTIFIED BY: ' . ' ; . i ' j - : f : f > £ r y y < '
DATE: 12/01/04
Laboratory Director
Certfication numbers: CA NELAP - 0211 OCA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004 NY NELAP -11291, UT NELAP - 9166389892
Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, Expiration date: 06/30/06
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards
This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 , (800) 985-5955 . FAX (916) 985-1020
Page 1 of 23
AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
Summary of Detected Compounds MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
Client Sample ID: 2AMCOU01
LabID#:0411319-01A No Detections Were Found.
Client Sample ID: 2AMC0D01
LabID#:0411319-02A
Compound
Acetone 2-Butanone (Methyl Ethyl Ketone)
Client Sample ID: 2AMCODR01
Lab ID#: 0411319-03A
Compound
2-Butanone (Methyl Ethyl Ketone) Toluene m.p-Xylene
Client Sample ID: 2AMCODL01
LabID#:0411319-04A
Compound
Acetone 2-Butanone (Methyl Ethyl Ketone) Toluene m.p-Xylene
Client Sample ID: 2AMCOU01D
LabID#:0411319-0SA
Compound
Acetone 2-Butanone (Methyl Ethyl Ketone) Toluene m.p-Xylene
Rpt. Limit (ppbv)
2.6 0.66
Rpt. Limit (ppbv)
0.67 0.67 0.67
Rpt. Limit (ppbv)
2.7 0.67 0.67 0.67
Rpt. Limit (ppbv)
2.7 0.67 0.67 0,67
Amount (ppbv)
4.0 0.97
Amount (ppbv)
0,83 1.5
0.84
Amount (ppbv)
4.1 3.6 1.7 1,1
Amount (ppbv)
3.0 0,74 1.6
0,91
Rpt. Limit (uG/m3)
6.3 1.9
Rpt. Limit (uG/m3)
2.0 2.5 2.9
Rpt. Limit (uG/m3)
6.4 2.0 2.5 2.9
Rpt. Limit (uG/m3)
6.4 2.0 2.5 2.9
Amount (uG/m3)
9.6 2.9
Amount (uG/m3)
2.4 5.5 3.6
Amount (uG/m3)
9.6 11 6.3 4.6
Amount (uG/m3)
7.1 2.2 6.2 3.9
Page 4 of 23
AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
Summary of Detected Compounds MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
Client Sample ID: 2AMCOIJ01D Duplicate
LabID#:0411319-05AA
Compound
Acetone 2-Butanone (Methyl Ethyl Ketone) Toluene m.p-Xylene
Rpt. Limit (ppbv)
2.7 0.67 0.67 0.67
Amount (ppbv)
3.1 0.86 1.6
0.98
Rpt. Limit (uG/m3)
6.4 2.0 2.5 2.9
Amount (uG/m3)
7.5 2.5 6.2 4.3
Page 5 of 23
AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
WORK ORDER #: 0411433
Work Order Summary
CLIENT:
PHONE:
FAX:
DATE RECEIVED:
DATE COMPLETED:
Mr. Bruce Kennington Environ International 123 North Wacker Dr. Suite 250 Chicago, IL 60606
312-853-9430
312-853-9025
11/22/2004
12/02/2004
BILL TO:
P.O.#
Mr. Felix Moran Environ International 740 Waukegan Road Suite 401 Deerfield, IL 60015
PROJECT #
CONTACT: Susan Alaniz
FRACTION # OIA 02A 03A 04A 05A 06A 07A
NAME 2AMCOU02 2AMCOD02 2AMCODR02 2AMCODL02 Lab Blank CCV LCS
TEST Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15
RECEIPT VACyPRES.
0.0 "Hg 0.0 "Hg 0.0 "Hg 0.0 "Hg
NA NA NA
CERTIFIED BY: !l~--.i¥ :̂=-,',;v .̂>-' c:y. -•^s^-f'^y^sr-'y^
Laboratory Director
DATE: 12/07/04
Certfication numbers: CA NELAP - 0211 OCA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004 NY NELAP -11291, UT NELAP - 9166389892
Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, Expiration date: 06/30/06
Air Toxics Ltd, certifies that the test results contained in this report meet all requirements of the NELAC standards
This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd,
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630
(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020
Paoe 1 of l8
AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
Summary of Detected Compounds MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
Client Sample ID: 2AMCOU02
LabID#:04n433-01A
Compound
Acetone
Client Sample ID: 2AMCOD02
Lab ID#: 0411433-02A
Compound
Acetone 2-Butanone (Methyl Ethyl Ketone) Toluene m.p-Xylene o-Xylene
1,2,4-Trimethylbenzene
Client Sample ID: 2AMCODR02
LablD#:0411433-03A
Compound
Toluene
Client Sample ID: 2AMCODL02
LabID#:0411433-04A
Compound
Acetone 2-Butanone (Methyl Ethyl Ketone) Toluene m.p-Xylene
Rpt. Limit (ppbv)
2.7
RpL Limit (ppbv)
2.7 0.67 0.67 0.67 0.67 0.67
Rpt. Limit (ppbv)
0.67
RpL Limit (ppbv)
2.7 0.67 0.67 0.67
Amount (ppbv)
3.6
Amount (ppbv)
5.0 3.9 1.1 1.9
0.78 1.5
Amount (ppbv)
0.72
Amount (ppbv)
3.0 0.98 0.97 1.2
Rpt. Limit (uG/m3)
6.4
Rpt. Limit (uG/m3)
6.4 2.0 2.5 2.9 2.9 3.3
Rpt. Limit (uG/m3)
2.5
Rpt. Limit (uG/m3)
6.4 2.0 2.5 2.9
Amount (uG/m3)
8.6
Amount (uG/m3)
12 12 4.1 8,4 3.4 7.4
Amount (uG/m3)
2.7
Amount (uG/m3)
7.0 2,9 3,7 5.2
Page 4 of 18
AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
WORK ORDER #: 0411490
Work Order Summary
CLIENT:
PHONE:
FAX:
DATE RECEIVED:
DATE COMPLETED:
FRACTION # OIA 02A 03A 04A 05A 06A 07A
Mr. Bruce Kennington Environ International 123 North Wacker Dr. Suite 250 Chicago, IL 60606
312-853-9430
312-853-9025
11/24/2004
12/05/2004
NAME 2AMCOU03 2AMCOD03 2AMCODR03 2AMCODL03 Lab Blank CCV LCS
BILL TO:
P.O.#
PROJECT #
CONTACT:
TEST
Mr. Felix Moran Environ International 740 Waukegan Road Suite 401 Deerfield, IL 60015
Susan Alaniz
Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15
RECEIPT VAC/PRES.
5.5 "Hg 5.5 "Hg 6,0 "Hg 5.5 "Hg
NA NA NA
CERTIFIED BY: yyy:>i^-^--'\p)r^-j y > ' : . / j ' ? f * ! : 3 > - ^ - ^
DATE: 12/09/04
Laboratory Director
Certfication numbers: CA NELAP - 0211 OCA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004 NY NEL/>LP -11291, UT NELAP - 9166389892
Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, Expiration date: 06/30/06
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards
This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd,
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 . (800) 985-5955 , FAX (916) 985-1020
Page 1 cfl8
AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
Summary of Detected Compounds MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
Client Sample ID: 2AMCOU03
LabID#:0411490-01A No Detections Were Found.
Client Sample ID: 2AMCOD03
Lab 1D#: 0411490-02A No Detections Were Found.
Client Sample ID: 2AMCODR03
LabID#:0411490-03A Rpt. Limit Amount Rpt. Limit Amount
Compound (ppbv) (ppbv) (uG/m3) (uG/m3)
2-Butanone (Methyl Ethyl Ketone) 0.84 1.1 2.5 3.3
Client Sample ID: 2AMCODL03
LabID#:0411490-04A No Detections Were Found.
Page 4 of 18
A T T A C H M E N T 2
Midco II SVE/AS System Start-Up Testing Ambient Air Monitoring Summary
AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
WORK ORDER #: 0601125
Work Order Summary
CLIENT:
PHOIVE:
FAX:
DATE RECEIVED:
DATE COMPLETED:
Mr. Felix Moran Environ International 740 Waukegan Road Suite 401 Deerfield, IL 60015
847444-9200
847-444-9420
01/09/2006
01/20/2006
BILL TO: Mr. Michael Wieczorek Environ Intemational 123 North Wacker Dr. Suite 250 Chicago, IL 60606
P.O.#
PROJECT* 21-8601 AJ Midco II
CONTACT: Susan Alaniz
FRACTION # OIA 02A 03A 04A 04 AA 05A 06A 07A
NAME 2AMU007 2AMDR007 2AMDL007 2AMDC007 2AMDC007 Duplicate Lab Blank CCV LCS
TEST Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15
RECEIPT VAC/PRES.
6.0 "Hg 3.0 "Hg 0.0 "Hg 0.0 "Hg 0.0 "Hg
NA NA NA
CERTIFIED BY: ':>e:'.'^::yr^J yy^ • -yP^^-^^^*^'.
DATE: 01/20/06
Laboratory Director
Certfication numbers: AR DEQ - 03-084-0, CA NELAP - 0211 OCA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004 NY NELAP -11291, UT NELAP - 9166389892
Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, Expiration date: 06/30/06
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards
This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630
(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020
Page I of 20
AIR TOXICS LTD. Summary of Detected Compounds
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
Client Sample ID: 2AMU007
Lab ID#: 0601125-OlA No Detections Were Found.
Client Sample ID: 2AMDR007
Lab ID#: 0601125-02A
Compound
Toluene
Client Sample ID: 2AMDL007
Lab ID#: 0601125-03A
Compound
Ethanol
Client Sample ID: 2AMDC007
Lab ID#: 0601125-04A
Compound
2-Butanone (Methyl Ethyl Ketone) Heptane Toluene Ethyl Benzene m,p-Xylene
Rpt. Limit (ppbv)
0.74
Rpt. Limit (ppbv)
2.7
Rpt. Limit (ppbv)
0.67 0.67 0.67 0.67 0.67
Amount (ppbv)
1.0
Amount (ppbv)
3.2
Amount (ppbv)
0.69 0.72 2.2
0.77 1.7
Rpt. Limit (uG/m3)
2.8
Rpt. Limit (uG/m3)
5.0
Rpt. Limit (uG/m3)
2.0 2.7 2.5 2.9 2.9
Amount (uG/m3)
4.0
Amount (uG/m3)
6.0
Amount (uG/m3)
2.0 2.9 8.2 3.4 7.5
Client Sample ID: 2AMDC007 Duplicate
LabID#:0601125-04AA
Compound
2-Butanone (Methyl Ethyl Ketone) Toluene Ethyl Benzene m.p-Xylene
Rpt. Limit (ppbv)
0,67 0.67 0.67 0,67
Amount (ppbv)
0.88 2.2
0.79 1.8
Rpt. Limit (uG/m3)
2.0 2.5 2.9 2.9
Amount (uG/m3)
2.6 8.5 3.4 7.8
Page 4 of 20
A T T A C H M E N T 3
Midco I SVE System Start-Up Testing Ambient Air Monitoring Summary
AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
WORK ORDER #: 0603308
Work Order Summary
CLIENT:
PHONE:
FAX:
DATE RECEIVED:
DATE COMPLETED:
Mr. Felix Moran Environ International 740 Waukegan Road Suite 401 Deerfield, IL 60015
847-444-9200
847-444-9420
03/15/2006
03/22/2006
FRACTION # OIA 02A 03A 04A 05A 06A 07A
NAME 1AMDL007 1AMU007 IAMDC007 IAMDR007 Lab Blank CCV LCS
BELL TO:
P.O.#
PROJECT#
CONTACT:
TEST
Mr. Felix Moran Environ International 740 Waukegan Road Suite 401 Deerfield, IL 60015
21-8601ALMIDCO1
Susan Alaniz
Modified TO-15/TICs Modified TO-15/TICs Modified TO-15/TICs Modified TO-15/TICs Modified TO-15/TICs Modified TO-15/TICs Modified TO-15/TICs
RECEIPT VAC/PRES.
9.0 "Hg 9.0 "Hg 5,5 "Hg 9.0 "Hg
NA NA NA
CERTIFIED BY: C---,-'^^''''-'- ;>'l'/'.,<••7.'i^^^:-->^ ^ -
DATE: 03/22/06
Laboratory Director
Certfication numbers: CA NELAP - 0211 OCA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004 NY NELAP -11291, UT NELAP - 9166389892
Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, Expiration date: 06/30/06
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards
This repori shall not be reproduced, excepl in full, wilhoul ihe wriuen approval of Air Toxics Lid.
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630
(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020
Page 1 of 18
AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
Summary of Detected Compounds MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
Client Sample ED: 1AMDL007
Lab ID#: 0603308-OlA No Detections Were Found.
Client Sample ID: 1AMU007
Lab ID#: 0603308-02A No Detections Were Found.
Client Sample ID: 1AMDC007
Lab m # : 0603308-03A No Detections Were Found.
Client Sample ID: 1AMDR007
Lab ID#: 0603308-04A No Detections Were Found.
Page 4 of 18
A T T A C H M E N T 4
Midco II SVE/AS Commissioning Testing Ambient Air Monitoring Summary
AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
WORK ORDER #: 0602295
Work Order Summary
CLIENT:
PHONE:
FAX:
DATE RECEIVED:
DATE COMPLETED:
Mr. Felix Moran Environ International 740 Waukegan Road Suite 401 Deerfield, IL 60015
847-444-9200
847444-9420
02/13/2006
02/22/2006
FRACTION # OIA 02A 03A 04A 05A 06A 07A
NAME 2AMDR08 2AMDL08 2AMDC08 2AMU08 Lab Blank CCV LCS
BILL TO:
P.O.#
PROJECT #
CONTACT:
TEST
Mr. Felix Moran Environ International 740 Waukegan Road Suite 401 Deerfield, IL 60015
21-8601AJ Midco II
Susan Alaniz
Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modifiec TO-15
RECEIPl VAC/PRES.
10.0 "Hg 4.0 "Hg 9.0 "Hg 10.0 "Hg
NA NA NA
CERTIFIED BY: ;iv^^.'.ar&,.^ c'->''- y ^ ^ i ' ' ' ' ' ' ^ ^ ^ y ^ -
Laboratory Director
DATE: 02,'22/06
Certfication numbers: AR DEQ - 03-084-0, CA NELAP - 0211 OCA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004 NY NELAP -11291, UT NELAP - 9166389892
Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, Expiration date: 06/30/06
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards
This repori shall noi be reproduced, excepl in full, wiihoui ihe wriiien approval of Air Toxics Lid.
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020
Page 1 of IS
AIR TOXICS LTD. Summary of Detected Compounds
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
Client Sample ID: 2AMDR08
LabID#:0602295-01A No Detections Were Found.
Client Sample ID: 2AMDL08
Lab ID#: 0602295-02A
Compound
Acetone 2-Butanone (Methyl Ethyl Ketone)
Client Sample ID: 2AMDC08
Lab ID#: 0602295-03A
Compound
Rpt. Limit (ppbv)
3.1 0.78
Rpt. Limit (ppbv)
Amount (ppbv)
6.2 0.98
Amount (ppbv)
Rpt. Limit (uG/m3)
7.4 2.3
Rpt. Limit (uG/m3)
Amount (uG/m3)
15 2.9
Amount (uG/m3)
Toluene 0.96 1.6 3.6 6.0
Client Sample ID: 2AMU08
Lab ID#: 0602295-04A No Detections Were Found.
Page 4 of 18
AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
WORK ORDER #: 0602429
Work Order Summary
CLIENT:
PHONE:
FAX:
DATE RECEIVED:
DATE COMPLETED:
Mr. Felix Moran Environ International 740 Waukegan Road Suite 401 Deerfield, IL 60015
847-444-9200
847-444-9420
02/21/2006
02/27/2006
FRACTIONS OIA 02A 03 A 04A 05A 06A 07A
NAME 2AMDWR09 2AMU09 2AMDWC09 2AMDWL09 Lab Blank CCV LCS
BILL TO:
P.O.#
PROJECT*
CONTACT:
TEST
Mr. Felix Moran Environ International 740 Waukegan Road Suite 401 Deerfield, IL 60015
21-8601AJ Midco II
Susan Alaniz
Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15
RECEIPT VAC/PRES.
6.0 "Hg 6.0 "Hg 5.5 "Hg 5.5 "Hg
NA NA NA
CERTIFIED BY: • • s i ^ - ^ j r ^ - ' yy^ '
:> 'i^i 'Z' '-i?^:^^sr'-y^—-^;
Laboratory Director
DATE: 02'28/06
Certfication numbers: AR DEQ - 03-084-0, CA NELAP - 021 lOCA, LA NELAP/LELAP- Al 30763, NJ NELAP - CA004 NY NELAP -11291, UT NELAP - 9166389892
Name of Accredifing Agency: NELAP/Fiorida Department of Health, Scope of Applicafion: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, Expiration date: 06/30/06
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards
This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.
180 BLUE RAVINE ROAD. SUITE B FOLSOM. CA - 95630
(916) 985-1000 , (800) 985-5955 , FAX (916) 985-1020
Page 1 of 18
AIR TOXICS LTD. Summary of Detected Compounds
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
Client Sample ID: 2AMDWR09
Lab ID#: 0602429-OlA No Detections Were Found.
Client Sample ID: 2AMU09
Lab ID#: 0602429-02A No Detections Were Found.
Client Sample ID: 2AMDWC09
Lab ID#: 0602429-03A
Compound Rpt. Limit
(ppbv) Amount (ppbv)
Rpt. Limit (uG/m3)
Amount (uG/m3)
Acetone 3.3 3.6 7.8 8.6
Client Sample ID: 2AMDWL09
Lab ID#: 0602429-04A No Detections Were Found.
Page 4 of 18
AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
WORK ORDER #: 0603207
Work Order Summary
CLIENT:
PHONE:
FAX:
DATE RECEIVED:
DATE COMPLETED:
Mr. Felix Moran Environ Intemational 740 Waukegan Road Suite 401 Deerfield, IL 60015
847-444-9200
847-444-9420
03/09/2006
03/15/2006
FRACTION # OIA 02A 03A 04A 05A 06A 07A
NAME
2AMDC10 2AMDL10 2AMDR10 2AMU10 Lab Blank CCV LCS
BILL TO:
P.O.#
PROJECT #
CONTACT:
TEST
Mr. Felix Moran Environ International 740 Waukegan Road Suite 401 Deerfield, IL 60015
21-8601A] Midco 11
Susan Alaniz
Modified TO-15/TICs Modified TO-15/TICs Modified TO-15/TICs Modified TO-15/TICs Modified TO-15/TICs Modified TO-15/TICs Modified TO-15/TICs
RECEIPT VAC/PRES.
4,0 "Hg 3.5 "Hg 4.5 "Hg 3.0 "Hg
NA NA NA
CERTIFIED BY: ^ ^ ^ ' j ^ J C >'^ - ^ ^ . .i<':>->ar-,f'^
Laboratory Director
DATE: 03/16/06
Certfication numbers: CA NELAP - 0211 OCA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004 NY NELAP - 11291, UT NELAP - 9166389892
Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, Expiration date: 06/30/06
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards
This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 . (800) 985-5955 , FAX (916) 985-1020
Page 1 of 18
AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
Summary of Detected Compounds MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
Client Sample ID: 2AMDC10
Lab ID#: 0603207-OlA
Compound Rpt. Limit
(ppbv) Amount (ppbv)
Rpt. Limit (uG/m3)
Amount (uG/m3)
Acetone 3.1 5.2 7.4 12
Client Sample ID: 2AMDL10
Lab ID#: 0603207-02A No Detections Were Found.
Client Sample ID: 2AMDR10
Lab ID#: 0603207-03A
Compound
Acetone
Compound
Rpt. Limit Amount (ppbv) (ppbv)
3.2 3.5
TENTATIVELY IDENTIFIED COMPOUNDS
CAS Number
Rpt. Limit (uG/m3)
7.5
Match Quality
Amount (uG/m3)
8.4
Amount ppbv
Disulfide, dimethyl 624-92-0 97% 7.8 N J
Client Sample ID: 2AMU10
Lab ID#: 0603207-04A No Detections Were Found.
Page 4 of 18
A T T A C H M E N T 5
Midco I SVE System Commissioning Testing Ambient Air Monitoring Summary
AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
WORK ORDER #: 0604005
Work Order Summary
CLIENT:
PHONE:
FAX:
DATE RECEIVED:
DATE COMPLETED:
Mr. Felix Moran Environ International 740 Waukegan Road Suite 401 Deerfield, IL 60015
847-444-9200
847^144-9420
04/03/2006
04/09/2006
FRACTION # OIA 02A 03A 04A 04 A A 05A 06A 07A
NAME 1AMU08 1AMDL08 IAMDC08 1AMDR08 1AMDR08 Duplicate Lab Blank CCV LCS
BELL TO:
P.O.#
PROJECT #
CONTACT:
TEST
Mr. Felix Moran Environ International 740 Waukegan Road Suite 401 Deerfield, IL 60015
218601ALMidcol
Susan Alaniz
Modified TO-15/TICs Modified TO-15/TICs Modified TO-15/TICs Modified TO-15/TICs Modified TO-15/TICs Modified TO-15/TICs Modified TO-15/TICs Modified TO-15/TICs
RECEIFl VAC/PRES.
8.5 "Hg 9,0 "Hg 8.5 "Hg 10.0 "Hg 10.0 "Hg
NA NA NA
CERTIFIED BY: ' .ar^.-^ y:y'- - y i ' - ^ ^ ' ^ f ^ s ^ ' ' : ^ ^ - ^ •
Laboratory Director
DATE: 04/09/06
Certfication numbers: CA NELAP - 021 lOCA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004 NY NELAP -11291, UT NELAP - 9166389892
Name of Accredifing Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effecfive date: 07/01/05, Expiration date: 06/30/06
Air Toxics Ltd, cerfifies that the test results contained in this report meet all requirements of the NELAC standards This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630
(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020
Page 1 of 20
AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
Summary of Detected Compounds MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
Client Sample ID: 1AMIJ08
Lab ID#: 0604005-OlA No Detections Were Found.
Client Sample ID: 1AMDL08
Lab ID#: 0604005-02A
Compound
Acetone
Client Sample ID: 1AMDC08
Lab ID#: 0604005-03A
Compound
Acetone
Compound
1-Propene, 2-methyl-2-Propanol, 2-methyl-
Rpt. Limit (ppbv)
3.8
Rpt. Limit (ppbv)
Amount (ppbv)
3.9
Amount (ppbv)
3.7 8.0
TENTATIVELY IDENTIFIED COMPOUNDS
CAS Number
115-11-7 75-65-0
Rpt. Limit (uG/m3)
9.1
Rpt. Limit (uG/m3)
8.9
Match Quality
56% 72%
Amount (uG/m3)
9.2
Amount (uG/m3)
19
Amount ppbv
8.9 N J 5.4 N J
Client Sample ID: 1AMDR08
Lab ID#: 0604005-04A No Detections Were Found.
Client Sample ID: 1AMDR08 Duplicate
Lab ID#: 0604005-04AA No Detections Were Found.
Page 4 of 20
AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
WORK ORDER #: 0604149
Work Order Summary
CLIENT:
PHONE:
FAX:
DATE RECEIVED: DATE COMPLETED:
Mr. Felix Moran Environ Intemational 740 Waukegan Road Suite 401 Deerfield, IL 60015
847-444-9200
847^144-9420
04/07/2006
04/14/2006
BILL TO:
P.O.#
PROJECT #
CONTACT:
Mr. Felix Moran Environ Intemational 740 Waukegan Road Suite 401 Deerfield, n. 60015
218601ALMidcoISVE
Susan Alaniz
FRACTION #
-QiA
NAME
1QXD06 TEST Modified TO- smci
RECEIPT
VAC/PRES.
—5T5-^g -
03A 04A 05A 06A 07A 08A 09A
1OXI06 1AMDL09 1AMDC09 1AMDR09 1AMU09 Lab Blank CCV LCS
Modified TO-15/TIC!; 5.5 "Hg 8.5 "Hg 0.2 psi 8.0 "Hg 7.5 "Hg
NA NA NA
Modified TO-Modified TO-Modified TO-Modified TO-Modified TO-Modified TO-Modified TO-
ismcs 15/TICs 15/TICs 15/TICs 15^-105 15/TICs 15/TICs
CERTIFIED BY: y ^ ' r ^ ' j t ^ y ' yyr' ̂ ^ ^ . . . .
Laboratory Director
DATE: 04/14/06
Certfication numbers: CA NELAP - 0211 OCA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004 NY NELAP -11291, UT NELAP - 9166389892
Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, E.xpiration date: 06/30/06
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards
This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020
Paoe 1 of25
AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
Summary of Detected Compounds MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
:;Hent Sample ID: 1OXI06
LabID^>«404149-02A
Compound
TENTATIVELY IDENTIFIED COMPOUNDS
CAS Number Match Quality Amount
ppbv
Butane Butane, 2-methyl-
Pentane
Pentane, 2-methyl-
Hexane, 2,2,3-trimethyl-
106-97-8
78-78-4
109-66-0
1^3-5
16747^
40%
86%
86%
91%
56%
9200 N J 18000 NJ
9500 N J 46000 N J 46000 N J
Cyclopentane, methyl-Hexane, 2-methyl-Pentane, 3-ethyl-Cyclohexane, methyl-He p t a n e ^ - m e t h y l - ^
96-37-7
591-76-4
617-78-7
108-87-2
592-27-8
90%
80% 74% 86%
28000 N J 19000 NJ 32000 N J
0000 N J
Client Sample ID: 1AMDL09
Lab ID#: 0604149-03A
Compound
TENTATIVELY IDENTIFIED COMPOUNDS
CAS Number Match Quality
Acetone
2-Butanone (Methyl Ethyl Ketone)
2.6 0.66
7.4
1.1
6.3
1.9
Amount ppbv
Pentane
Client Sample ID: 1AMDC09
Lab ID#: 0604149-04A
Compound Rpt. Limit
(ppbv)
109-66-0
Amount (ppbv)
86%
Rpt. Limit (uG/m3)
5.1 NJ
Amount (uG/m3)
18
3.2
Client Sample ID: 1AMDR09
Lab ID#: 0604149-05A No Detections Were Found.
Client Sample ID: 1AMU09
Lab ID#: 0604149-06A
Compound Rpt. Limit Amount
(ppbv) (ppbv)
Page 5 of 25
Rpt. Limit (uG/m3)
Amount (uG/m3)
AIR TOXICS LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
Summary of Detected Compounds MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
Client Sample ID: 1AMU09
Lab ID#: 0604149-06A
Compound Rpt. Limit
(ppbv) Amount (ppbv)
Rpt. Limit (uG/m3)
Amount (uG/m3)
Acetone 3.6 3.5 J 8.5 8.4 J
Page 6 of 25
A T T A C H M E N T 6
Analytical Reports Ambient Air Monitoring
(on CD ROM)
AIR TOXICS LTD.@AN ENVIRONMENTAL ANALYTICAL LABORATORY
Air Toxics Ltd. Introduces the Electronic Report
Thank you for choosing Air Toxics Ltd. To better serve our customers, we are providing your report by e-mail. This document is provided in Portable Document Format which can be viewed with Acrobat Reader by Adobe.
This electronic report includes the following:• Work order Summary;• Laboratory Narrative;• Results; and• Chain of Custody (copy).
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630
(916) 985-1000 .FAX (916) 985-1020Hours 8:00 A.M to 6:00 P.M. Pacific
AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
@
Mr. Bruce KenningtonEnviron International123 North Wacker Dr. Suite 250Chicago, IL 60606
WORK ORDER #: 0411490
CLIENT: BILL TO:
PHONE:
Mr. Felix MoranEnviron International740 Waukegan RoadSuite 401Deerfield, IL 60015
312-853-9430
312-853-9025
11/24/2004DATE COMPLETED: 12/05/2004
P.O. #
PROJECT #
Work Order Summary
FAX:
DATE RECEIVED: CONTACT: Susan Alaniz
NAMEFRACTION # TEST VAC./PRES.RECEIPT
01A 2AMCOU03 Modified TO-15 5.5 "Hg02A 2AMCOD03 Modified TO-15 5.5 "Hg03A 2AMCODR03 Modified TO-15 6.0 "Hg04A 2AMCODL03 Modified TO-15 5.5 "Hg05A Lab Blank Modified TO-15 NA06A CCV Modified TO-15 NA07A LCS Modified TO-15 NA
CERTIFIED BY:
Laboratory Director
DATE:
Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, Expiration date: 06/30/06
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020
12/09/04
Page 1 of 18
This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards
Certfication numbers: CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004NY NELAP - 11291, UT NELAP - 9166389892
LABORATORY NARRATIVEModified TO-15
Environ InternationalWorkorder# 0411490
@AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Four 6 Liter Summa Canister samples were received on November 24, 2004. The laboratory performed analysis via modified EPA Method TO-15 using GC/MS in the full scan mode. The method involvesconcentrating up to 0.2 liters of air. The concentrated aliquot is then flash vaporized and swept through awater management system to remove water vapor. Following dehumidification, the sample passes directlyinto the GC/MS for analysis. See the data sheets for the reporting limits for each compound.
Method modifications taken to run these samples include:
Requirement ATL ModificationsTO-15BFB acceptance criteria CLP protocol (TO-15) SW-846 protocol
Concentration of IS spike 10 ppbv (TO-15) 25 ppbv
Dilutions for initial calibration Dynamic dilutions or static using canisters
Syringe dilutions
Daily CCV +- 30% Difference </= 30% Difference with two allowed out up to </=40%.; flag and narrate outliers
Primary ions for Quantification Freon 114: 85, Carbon Tetrachloride: 117, Trichloroethene: 130, Ethyl Benzene, m,p- and o-Xylene: 91, Vinyl Acetate: 43, 2-Butanone: 43, 4-Methyl-2-Pentanone: 43.
Freon 114: 135, Carbon Tetrachloride: 119, Trichloroethene: 95, Ethyl Benzene, m,p- and o-Xylene: 106, Vinyl Acetate: 86, 2-Butanone: 72, 4-Methyl-2-Pentanone: 58.
Sample collection media Summa canister ATL recommends use of summa canisters to insure data defensibility, but will report results from Tedlar bags at client request
Sample Drying System Nafion Dryer (TO-14A) Multisorbent
Sample Load Volume 400 mL (TO-14A) Varied to 0.2 L.
Blank Acceptance Criteria. < 0.20 ppbv (TO-14A) < RL
BFB Absolute Abundance Criteria (TO-14A)
Within 10% of that from the previous day.
CCV internal standard area counts are compared to ICAL, corrective action for > 40 % D.
Initial Calibration +- 30 %RSD (TO-14A) </= 30 % RSD with 2 compounds allowed out to </= 40 % RSD.
IS Recoveries Within 40% of mean over ICAL for blanks, and within 40 % of daily CCV for samples. (TO-15)
Within 40% of CCV recoveries for blank and samples.
Page 2 of 18
AN ENVIRONMENTAL ANALYTICAL LABORATORY
AIR TOXICS LTD.@Method Detection Limit Follow 40CFR Pt.136
App. BThe MDL met all relevant requirements in Method TO-15 (statistical MDL less than the LOQ). The concentration of the spiked replicate may have exceeded 10X the calculated MDL in some cases. A list of these compounds is available.
Receiving Notes
There were no receiving discrepancies.
The reported CCV for each daily batch may be derived from more than one individual analytical file due tothe client's request for non-standard compounds.
Non-standard compounds may have different acceptance criteria than the standard TO-14A/TO-15compound list as per contract or verbal agreement.
Analytical Notes
Eight qualifiers may have been used on the data analysis sheets and indicates as follows: B - Compound present in laboratory blank greater than reporting limit (background subtraction notperformed). J - Estimated value. E - Exceeds instrument calibration range. S - Saturated Peak. Q - Exceeds quality control limits. U - Compound analyzed for but not detected above the reporting limit. UJ- Non-detected compound associated with low bias in the CCV N - The identification is based on presumptive evidence.
File extensions may have been used on the data analysis sheets and indicates as follows: a-File was requantified b-File was quantified by a second column and detector r1-File was requantified for the purpose of reissue
Definition of Data Qualifying Flags
Page 3 of 18
MODIFIED EPA METHOD TO-15 GC/MS FULL SCANSummary of Detected Compounds
AIR TOXICS LTD.@ AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCOU03
Lab ID#: 0411490-01ANo Detections Were Found.
Client Sample ID: 2AMCOD03
Lab ID#: 0411490-02ANo Detections Were Found.
Client Sample ID: 2AMCODR03
Lab ID#: 0411490-03A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.84 1.1 2.5 3.32-Butanone (Methyl Ethyl Ketone)
Client Sample ID: 2AMCODL03
Lab ID#: 0411490-04ANo Detections Were Found.
Page 4 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCOU03
Lab ID#: 0411490-01A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s120111File Name:Dil. Factor: 1.64
Date of Collection: 11/23/04Date of Analysis: 12/1/04 05:23 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.82 Not Detected 5.7 Not DetectedFreon 1143.3 Not Detected 6.8 Not DetectedChloromethane
0.82 Not Detected 2.1 Not DetectedVinyl Chloride0.82 Not Detected 3.2 Not DetectedBromomethane0.82 Not Detected 2.2 Not DetectedChloroethane0.82 Not Detected 4.6 Not DetectedFreon 110.82 Not Detected 6.3 Not DetectedFreon 1130.82 Not Detected 3.2 Not Detected1,1-Dichloroethene3.3 Not Detected 7.8 Not DetectedAcetone
0.82 Not Detected 2.8 Not DetectedMethylene Chloride0.82 Not Detected 3.2 Not Detectedtrans-1,2-Dichloroethene0.82 Not Detected 3.3 Not Detected1,1-Dichloroethane0.82 Not Detected 2.4 Not Detected2-Butanone (Methyl Ethyl Ketone)0.82 Not Detected 3.2 Not Detectedcis-1,2-Dichloroethene0.82 Not Detected 4.0 Not DetectedChloroform0.82 Not Detected 4.5 Not Detected1,1,1-Trichloroethane0.82 Not Detected 5.2 Not DetectedCarbon Tetrachloride0.82 Not Detected 2.6 Not DetectedBenzene0.82 Not Detected 3.3 Not Detected1,2-Dichloroethane0.82 Not Detected 4.4 Not DetectedTrichloroethene0.82 Not Detected 3.8 Not Detected1,2-Dichloropropane0.82 Not Detected 3.7 Not Detectedcis-1,3-Dichloropropene0.82 Not Detected 3.4 Not Detected4-Methyl-2-pentanone0.82 Not Detected 3.1 Not DetectedToluene0.82 Not Detected 3.7 Not Detectedtrans-1,3-Dichloropropene0.82 Not Detected 4.5 Not Detected1,1,2-Trichloroethane0.82 Not Detected 5.6 Not DetectedTetrachloroethene3.3 Not Detected 13 Not Detected2-Hexanone
0.82 Not Detected 6.3 Not Detected1,2-Dibromoethane (EDB)0.82 Not Detected 3.8 Not DetectedChlorobenzene0.82 Not Detected 3.6 Not DetectedEthyl Benzene0.82 Not Detected 3.6 Not Detectedm,p-Xylene0.82 Not Detected 3.6 Not Detectedo-Xylene0.82 Not Detected 3.5 Not DetectedStyrene0.82 Not Detected 5.6 Not Detected1,1,2,2-Tetrachloroethane0.82 Not Detected 4.0 Not Detected1,2,4-Trimethylbenzene0.82 Not Detected 4.9 Not Detected1,3-Dichlorobenzene0.82 Not Detected 4.9 Not Detected1,4-Dichlorobenzene0.82 Not Detected 4.2 Not Detectedalpha-Chlorotoluene0.82 Not Detected 4.9 Not Detected1,2-Dichlorobenzene
Page 5 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCOU03
Lab ID#: 0411490-01A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s120111File Name:Dil. Factor: 1.64
Date of Collection: 11/23/04Date of Analysis: 12/1/04 05:23 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
3.3 Not Detected 24 Not Detected1,2,4-Trichlorobenzene3.3 Not Detected 14 Not DetectedDichlorofluoromethane
0.82 Not Detected 4.0 Not Detected1,3,5-Trimethylbenzene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
104 70-130Toluene-d8100 70-1301,2-Dichloroethane-d499 70-1304-Bromofluorobenzene
Page 6 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCOD03
Lab ID#: 0411490-02A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s120112File Name:Dil. Factor: 1.64
Date of Collection: 11/23/04Date of Analysis: 12/1/04 06:04 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.82 Not Detected 5.7 Not DetectedFreon 1143.3 Not Detected 6.8 Not DetectedChloromethane
0.82 Not Detected 2.1 Not DetectedVinyl Chloride0.82 Not Detected 3.2 Not DetectedBromomethane0.82 Not Detected 2.2 Not DetectedChloroethane0.82 Not Detected 4.6 Not DetectedFreon 110.82 Not Detected 6.3 Not DetectedFreon 1130.82 Not Detected 3.2 Not Detected1,1-Dichloroethene3.3 Not Detected 7.8 Not DetectedAcetone
0.82 Not Detected 2.8 Not DetectedMethylene Chloride0.82 Not Detected 3.2 Not Detectedtrans-1,2-Dichloroethene0.82 Not Detected 3.3 Not Detected1,1-Dichloroethane0.82 Not Detected 2.4 Not Detected2-Butanone (Methyl Ethyl Ketone)0.82 Not Detected 3.2 Not Detectedcis-1,2-Dichloroethene0.82 Not Detected 4.0 Not DetectedChloroform0.82 Not Detected 4.5 Not Detected1,1,1-Trichloroethane0.82 Not Detected 5.2 Not DetectedCarbon Tetrachloride0.82 Not Detected 2.6 Not DetectedBenzene0.82 Not Detected 3.3 Not Detected1,2-Dichloroethane0.82 Not Detected 4.4 Not DetectedTrichloroethene0.82 Not Detected 3.8 Not Detected1,2-Dichloropropane0.82 Not Detected 3.7 Not Detectedcis-1,3-Dichloropropene0.82 Not Detected 3.4 Not Detected4-Methyl-2-pentanone0.82 Not Detected 3.1 Not DetectedToluene0.82 Not Detected 3.7 Not Detectedtrans-1,3-Dichloropropene0.82 Not Detected 4.5 Not Detected1,1,2-Trichloroethane0.82 Not Detected 5.6 Not DetectedTetrachloroethene3.3 Not Detected 13 Not Detected2-Hexanone
0.82 Not Detected 6.3 Not Detected1,2-Dibromoethane (EDB)0.82 Not Detected 3.8 Not DetectedChlorobenzene0.82 Not Detected 3.6 Not DetectedEthyl Benzene0.82 Not Detected 3.6 Not Detectedm,p-Xylene0.82 Not Detected 3.6 Not Detectedo-Xylene0.82 Not Detected 3.5 Not DetectedStyrene0.82 Not Detected 5.6 Not Detected1,1,2,2-Tetrachloroethane0.82 Not Detected 4.0 Not Detected1,2,4-Trimethylbenzene0.82 Not Detected 4.9 Not Detected1,3-Dichlorobenzene0.82 Not Detected 4.9 Not Detected1,4-Dichlorobenzene0.82 Not Detected 4.2 Not Detectedalpha-Chlorotoluene0.82 Not Detected 4.9 Not Detected1,2-Dichlorobenzene
Page 7 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCOD03
Lab ID#: 0411490-02A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s120112File Name:Dil. Factor: 1.64
Date of Collection: 11/23/04Date of Analysis: 12/1/04 06:04 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
3.3 Not Detected 24 Not Detected1,2,4-Trichlorobenzene3.3 Not Detected 14 Not DetectedDichlorofluoromethane
0.82 Not Detected 4.0 Not Detected1,3,5-Trimethylbenzene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
104 70-130Toluene-d8100 70-1301,2-Dichloroethane-d4100 70-1304-Bromofluorobenzene
Page 8 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCODR03
Lab ID#: 0411490-03A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s120113File Name:Dil. Factor: 1.68
Date of Collection: 11/23/04Date of Analysis: 12/1/04 06:45 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.84 Not Detected 5.9 Not DetectedFreon 1143.4 Not Detected 6.9 Not DetectedChloromethane
0.84 Not Detected 2.1 Not DetectedVinyl Chloride0.84 Not Detected 3.3 Not DetectedBromomethane0.84 Not Detected 2.2 Not DetectedChloroethane0.84 Not Detected 4.7 Not DetectedFreon 110.84 Not Detected 6.4 Not DetectedFreon 1130.84 Not Detected 3.3 Not Detected1,1-Dichloroethene3.4 Not Detected 8.0 Not DetectedAcetone
0.84 Not Detected 2.9 Not DetectedMethylene Chloride0.84 Not Detected 3.3 Not Detectedtrans-1,2-Dichloroethene0.84 Not Detected 3.4 Not Detected1,1-Dichloroethane0.84 1.1 2.5 3.32-Butanone (Methyl Ethyl Ketone)0.84 Not Detected 3.3 Not Detectedcis-1,2-Dichloroethene0.84 Not Detected 4.1 Not DetectedChloroform0.84 Not Detected 4.6 Not Detected1,1,1-Trichloroethane0.84 Not Detected 5.3 Not DetectedCarbon Tetrachloride0.84 Not Detected 2.7 Not DetectedBenzene0.84 Not Detected 3.4 Not Detected1,2-Dichloroethane0.84 Not Detected 4.5 Not DetectedTrichloroethene0.84 Not Detected 3.9 Not Detected1,2-Dichloropropane0.84 Not Detected 3.8 Not Detectedcis-1,3-Dichloropropene0.84 Not Detected 3.4 Not Detected4-Methyl-2-pentanone0.84 Not Detected 3.2 Not DetectedToluene0.84 Not Detected 3.8 Not Detectedtrans-1,3-Dichloropropene0.84 Not Detected 4.6 Not Detected1,1,2-Trichloroethane0.84 Not Detected 5.7 Not DetectedTetrachloroethene3.4 Not Detected 14 Not Detected2-Hexanone
0.84 Not Detected 6.4 Not Detected1,2-Dibromoethane (EDB)0.84 Not Detected 3.9 Not DetectedChlorobenzene0.84 Not Detected 3.6 Not DetectedEthyl Benzene0.84 Not Detected 3.6 Not Detectedm,p-Xylene0.84 Not Detected 3.6 Not Detectedo-Xylene0.84 Not Detected 3.6 Not DetectedStyrene0.84 Not Detected 5.8 Not Detected1,1,2,2-Tetrachloroethane0.84 Not Detected 4.1 Not Detected1,2,4-Trimethylbenzene0.84 Not Detected 5.0 Not Detected1,3-Dichlorobenzene0.84 Not Detected 5.0 Not Detected1,4-Dichlorobenzene0.84 Not Detected 4.3 Not Detectedalpha-Chlorotoluene0.84 Not Detected 5.0 Not Detected1,2-Dichlorobenzene
Page 9 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCODR03
Lab ID#: 0411490-03A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s120113File Name:Dil. Factor: 1.68
Date of Collection: 11/23/04Date of Analysis: 12/1/04 06:45 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
3.4 Not Detected 25 Not Detected1,2,4-Trichlorobenzene3.4 Not Detected 14 Not DetectedDichlorofluoromethane
0.84 Not Detected 4.1 Not Detected1,3,5-Trimethylbenzene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
104 70-130Toluene-d8101 70-1301,2-Dichloroethane-d4100 70-1304-Bromofluorobenzene
Page 10 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCODL03
Lab ID#: 0411490-04A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s120114File Name:Dil. Factor: 1.64
Date of Collection: 11/23/04Date of Analysis: 12/1/04 07:26 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.82 Not Detected 5.7 Not DetectedFreon 1143.3 Not Detected 6.8 Not DetectedChloromethane
0.82 Not Detected 2.1 Not DetectedVinyl Chloride0.82 Not Detected 3.2 Not DetectedBromomethane0.82 Not Detected 2.2 Not DetectedChloroethane0.82 Not Detected 4.6 Not DetectedFreon 110.82 Not Detected 6.3 Not DetectedFreon 1130.82 Not Detected 3.2 Not Detected1,1-Dichloroethene3.3 Not Detected 7.8 Not DetectedAcetone
0.82 Not Detected 2.8 Not DetectedMethylene Chloride0.82 Not Detected 3.2 Not Detectedtrans-1,2-Dichloroethene0.82 Not Detected 3.3 Not Detected1,1-Dichloroethane0.82 Not Detected 2.4 Not Detected2-Butanone (Methyl Ethyl Ketone)0.82 Not Detected 3.2 Not Detectedcis-1,2-Dichloroethene0.82 Not Detected 4.0 Not DetectedChloroform0.82 Not Detected 4.5 Not Detected1,1,1-Trichloroethane0.82 Not Detected 5.2 Not DetectedCarbon Tetrachloride0.82 Not Detected 2.6 Not DetectedBenzene0.82 Not Detected 3.3 Not Detected1,2-Dichloroethane0.82 Not Detected 4.4 Not DetectedTrichloroethene0.82 Not Detected 3.8 Not Detected1,2-Dichloropropane0.82 Not Detected 3.7 Not Detectedcis-1,3-Dichloropropene0.82 Not Detected 3.4 Not Detected4-Methyl-2-pentanone0.82 Not Detected 3.1 Not DetectedToluene0.82 Not Detected 3.7 Not Detectedtrans-1,3-Dichloropropene0.82 Not Detected 4.5 Not Detected1,1,2-Trichloroethane0.82 Not Detected 5.6 Not DetectedTetrachloroethene3.3 Not Detected 13 Not Detected2-Hexanone
0.82 Not Detected 6.3 Not Detected1,2-Dibromoethane (EDB)0.82 Not Detected 3.8 Not DetectedChlorobenzene0.82 Not Detected 3.6 Not DetectedEthyl Benzene0.82 Not Detected 3.6 Not Detectedm,p-Xylene0.82 Not Detected 3.6 Not Detectedo-Xylene0.82 Not Detected 3.5 Not DetectedStyrene0.82 Not Detected 5.6 Not Detected1,1,2,2-Tetrachloroethane0.82 Not Detected 4.0 Not Detected1,2,4-Trimethylbenzene0.82 Not Detected 4.9 Not Detected1,3-Dichlorobenzene0.82 Not Detected 4.9 Not Detected1,4-Dichlorobenzene0.82 Not Detected 4.2 Not Detectedalpha-Chlorotoluene0.82 Not Detected 4.9 Not Detected1,2-Dichlorobenzene
Page 11 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCODL03
Lab ID#: 0411490-04A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s120114File Name:Dil. Factor: 1.64
Date of Collection: 11/23/04Date of Analysis: 12/1/04 07:26 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
3.3 Not Detected 24 Not Detected1,2,4-Trichlorobenzene3.3 Not Detected 14 Not DetectedDichlorofluoromethane
0.82 Not Detected 4.0 Not Detected1,3,5-Trimethylbenzene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
104 70-130Toluene-d8103 70-1301,2-Dichloroethane-d4101 70-1304-Bromofluorobenzene
Page 12 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab ID#: 0411490-05A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s120107File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 12/1/04 01:18 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.50 Not Detected 3.5 Not DetectedFreon 1142.0 Not Detected 4.1 Not DetectedChloromethane
0.50 Not Detected 1.3 Not DetectedVinyl Chloride0.50 Not Detected 1.9 Not DetectedBromomethane0.50 Not Detected 1.3 Not DetectedChloroethane0.50 Not Detected 2.8 Not DetectedFreon 110.50 Not Detected 3.8 Not DetectedFreon 1130.50 Not Detected 2.0 Not Detected1,1-Dichloroethene2.0 Not Detected 4.8 Not DetectedAcetone
0.50 Not Detected 1.7 Not DetectedMethylene Chloride0.50 Not Detected 2.0 Not Detectedtrans-1,2-Dichloroethene0.50 Not Detected 2.0 Not Detected1,1-Dichloroethane0.50 Not Detected 1.5 Not Detected2-Butanone (Methyl Ethyl Ketone)0.50 Not Detected 2.0 Not Detectedcis-1,2-Dichloroethene0.50 Not Detected 2.4 Not DetectedChloroform0.50 Not Detected 2.7 Not Detected1,1,1-Trichloroethane0.50 Not Detected 3.1 Not DetectedCarbon Tetrachloride0.50 Not Detected 1.6 Not DetectedBenzene0.50 Not Detected 2.0 Not Detected1,2-Dichloroethane0.50 Not Detected 2.7 Not DetectedTrichloroethene0.50 Not Detected 2.3 Not Detected1,2-Dichloropropane0.50 Not Detected 2.3 Not Detectedcis-1,3-Dichloropropene0.50 Not Detected 2.0 Not Detected4-Methyl-2-pentanone0.50 Not Detected 1.9 Not DetectedToluene0.50 Not Detected 2.3 Not Detectedtrans-1,3-Dichloropropene0.50 Not Detected 2.7 Not Detected1,1,2-Trichloroethane0.50 Not Detected 3.4 Not DetectedTetrachloroethene2.0 Not Detected 8.2 Not Detected2-Hexanone
0.50 Not Detected 3.8 Not Detected1,2-Dibromoethane (EDB)0.50 Not Detected 2.3 Not DetectedChlorobenzene0.50 Not Detected 2.2 Not DetectedEthyl Benzene0.50 Not Detected 2.2 Not Detectedm,p-Xylene0.50 Not Detected 2.2 Not Detectedo-Xylene0.50 Not Detected 2.1 Not DetectedStyrene0.50 Not Detected 3.4 Not Detected1,1,2,2-Tetrachloroethane0.50 Not Detected 2.4 Not Detected1,2,4-Trimethylbenzene0.50 Not Detected 3.0 Not Detected1,3-Dichlorobenzene0.50 Not Detected 3.0 Not Detected1,4-Dichlorobenzene0.50 Not Detected 2.6 Not Detectedalpha-Chlorotoluene0.50 Not Detected 3.0 Not Detected1,2-Dichlorobenzene
Page 13 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab ID#: 0411490-05A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s120107File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 12/1/04 01:18 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.0 Not Detected 15 Not Detected1,2,4-Trichlorobenzene2.0 Not Detected 8.4 Not DetectedDichlorofluoromethane
0.50 Not Detected 2.4 Not Detected1,3,5-Trimethylbenzene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d8101 70-1301,2-Dichloroethane-d4102 70-1304-Bromofluorobenzene
Page 14 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCV
Lab ID#: 0411490-06A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s120104File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 12/1/04 10:23 AM
%RecoveryCompound
108Freon 11489Chloromethane73Vinyl Chloride70Bromomethane74Chloroethane82Freon 1179Freon 113771,1-Dichloroethene82Acetone88Methylene Chloride75trans-1,2-Dichloroethene801,1-Dichloroethane862-Butanone (Methyl Ethyl Ketone)84cis-1,2-Dichloroethene85Chloroform951,1,1-Trichloroethane109Carbon Tetrachloride75Benzene821,2-Dichloroethane83Trichloroethene851,2-Dichloropropane90cis-1,3-Dichloropropene924-Methyl-2-pentanone88Toluene91trans-1,3-Dichloropropene841,1,2-Trichloroethane92Tetrachloroethene942-Hexanone881,2-Dibromoethane (EDB)85Chlorobenzene87Ethyl Benzene83m,p-Xylene84o-Xylene86Styrene821,1,2,2-Tetrachloroethane781,2,4-Trimethylbenzene801,3-Dichlorobenzene801,4-Dichlorobenzene78alpha-Chlorotoluene761,2-Dichlorobenzene
Page 15 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCV
Lab ID#: 0411490-06A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s120104File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 12/1/04 10:23 AM
%RecoveryCompound
791,2,4-Trichlorobenzene131Dichlorofluoromethane801,3,5-Trimethylbenzene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
104 70-130Toluene-d8103 70-1301,2-Dichloroethane-d4101 70-1304-Bromofluorobenzene
Page 16 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
Lab ID#: 0411490-07A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s120105File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 12/1/04 11:02 AM
%RecoveryCompound
98Freon 11479Chloromethane71Vinyl Chloride
66 QBromomethane70Chloroethane75Freon 1177Freon 113721,1-Dichloroethene87Acetone83Methylene Chloride79trans-1,2-Dichloroethene861,1-Dichloroethane892-Butanone (Methyl Ethyl Ketone)71cis-1,2-Dichloroethene87Chloroform1001,1,1-Trichloroethane110Carbon Tetrachloride77Benzene881,2-Dichloroethane87Trichloroethene971,2-Dichloropropane93cis-1,3-Dichloropropene1034-Methyl-2-pentanone81Toluene97trans-1,3-Dichloropropene821,1,2-Trichloroethane86Tetrachloroethene1042-Hexanone881,2-Dibromoethane (EDB)81Chlorobenzene77Ethyl Benzene79m,p-Xylene80o-Xylene86Styrene801,1,2,2-Tetrachloroethane751,2,4-Trimethylbenzene791,3-Dichlorobenzene761,4-Dichlorobenzene102alpha-Chlorotoluene731,2-Dichlorobenzene
Page 17 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
Lab ID#: 0411490-07A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s120105File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 12/1/04 11:02 AM
%RecoveryCompound
911,2,4-TrichlorobenzeneNot SpikedDichlorofluoromethane
761,3,5-Trimethylbenzene
Q = Exceeds Quality Control limits.Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
105 70-130Toluene-d8100 70-1301,2-Dichloroethane-d4101 70-1304-Bromofluorobenzene
Page 18 of 18
AIR TOXICS LTD.@AN ENVIRONMENTAL ANALYTICAL LABORATORY
Air Toxics Ltd. Introduces the Electronic Report
Thank you for choosing Air Toxics Ltd. To better serve our customers, we are providing your report by e-mail. This document is provided in Portable Document Format which can be viewed with Acrobat Reader by Adobe.
This electronic report includes the following:• Work order Summary;• Laboratory Narrative;• Results; and• Chain of Custody (copy).
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630
(916) 985-1000 .FAX (916) 985-1020Hours 8:00 A.M to 6:00 P.M. Pacific
AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
@
Mr. Bruce KenningtonEnviron International123 North Wacker Dr. Suite 250Chicago, IL 60606
WORK ORDER #: 0411433
CLIENT: BILL TO:
PHONE:
Mr. Felix MoranEnviron International740 Waukegan RoadSuite 401Deerfield, IL 60015
312-853-9430
312-853-9025
11/22/2004DATE COMPLETED: 12/02/2004
P.O. #
PROJECT #
Work Order Summary
FAX:
DATE RECEIVED: CONTACT: Susan Alaniz
NAMEFRACTION # TEST VAC./PRES.RECEIPT
01A 2AMCOU02 Modified TO-15 0.0 "Hg02A 2AMCOD02 Modified TO-15 0.0 "Hg03A 2AMCODR02 Modified TO-15 0.0 "Hg04A 2AMCODL02 Modified TO-15 0.0 "Hg05A Lab Blank Modified TO-15 NA06A CCV Modified TO-15 NA07A LCS Modified TO-15 NA
CERTIFIED BY:
Laboratory Director
DATE:
Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, Expiration date: 06/30/06
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020
12/07/04
Page 1 of 18
This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards
Certfication numbers: CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004NY NELAP - 11291, UT NELAP - 9166389892
LABORATORY NARRATIVEModified TO-15
Environ InternationalWorkorder# 0411433
@AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Four 6 Liter Summa Canister samples were received on November 22, 2004. The laboratory performed analysis via modified EPA Method TO-15 using GC/MS in the full scan mode. The method involvesconcentrating up to 0.2 liters of air. The concentrated aliquot is then flash vaporized and swept through awater management system to remove water vapor. Following dehumidification, the sample passes directlyinto the GC/MS for analysis. See the data sheets for the reporting limits for each compound.
Method modifications taken to run these samples include:
Requirement ATL ModificationsTO-15BFB acceptance criteria CLP protocol (TO-15) SW-846 protocol
Concentration of IS spike 10 ppbv (TO-15) 25 ppbv
Dilutions for initial calibration Dynamic dilutions or static using canisters
Syringe dilutions
Daily CCV +- 30% Difference </= 30% Difference with two allowed out up to </=40%.; flag and narrate outliers
Primary ions for Quantification Freon 114: 85, Carbon Tetrachloride: 117, Trichloroethene: 130, Ethyl Benzene, m,p- and o-Xylene: 91, Vinyl Acetate: 43, 2-Butanone: 43, 4-Methyl-2-Pentanone: 43.
Freon 114: 135, Carbon Tetrachloride: 119, Trichloroethene: 95, Ethyl Benzene, m,p- and o-Xylene: 106, Vinyl Acetate: 86, 2-Butanone: 72, 4-Methyl-2-Pentanone: 58.
Sample collection media Summa canister ATL recommends use of summa canisters to insure data defensibility, but will report results from Tedlar bags at client request
Sample Drying System Nafion Dryer (TO-14A) Multisorbent
Sample Load Volume 400 mL (TO-14A) Varied to 0.2 L.
Blank Acceptance Criteria. < 0.20 ppbv (TO-14A) < RL
BFB Absolute Abundance Criteria (TO-14A)
Within 10% of that from the previous day.
CCV internal standard area counts are compared to ICAL, corrective action for > 40 % D.
Initial Calibration +- 30 %RSD (TO-14A) </= 30 % RSD with 2 compounds allowed out to </= 40 % RSD.
IS Recoveries Within 40% of mean over ICAL for blanks, and within 40 % of daily CCV for samples. (TO-15)
Within 40% of CCV recoveries for blank and samples.
Page 2 of 18
AN ENVIRONMENTAL ANALYTICAL LABORATORY
AIR TOXICS LTD.@Method Detection Limit Follow 40CFR Pt.136
App. BThe MDL met all relevant requirements in Method TO-15 (statistical MDL less than the LOQ). The concentration of the spiked replicate may have exceeded 10X the calculated MDL in some cases. A list of these compounds is available.
Receiving Notes
There were no receiving discrepancies.
The reported CCV for each daily batch may be derived from more than one individual analytical file due tothe client's request for non-standard compounds.
Non-standard compounds may have different acceptance criteria than the standard TO-14A/TO-15compound list as per contract or verbal agreement.
Analytical Notes
Eight qualifiers may have been used on the data analysis sheets and indicates as follows: B - Compound present in laboratory blank greater than reporting limit (background subtraction notperformed). J - Estimated value. E - Exceeds instrument calibration range. S - Saturated Peak. Q - Exceeds quality control limits. U - Compound analyzed for but not detected above the reporting limit. UJ- Non-detected compound associated with low bias in the CCV N - The identification is based on presumptive evidence.
File extensions may have been used on the data analysis sheets and indicates as follows: a-File was requantified b-File was quantified by a second column and detector r1-File was requantified for the purpose of reissue
Definition of Data Qualifying Flags
Page 3 of 18
MODIFIED EPA METHOD TO-15 GC/MS FULL SCANSummary of Detected Compounds
AIR TOXICS LTD.@ AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCOU02
Lab ID#: 0411433-01A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.7 3.6 6.4 8.6Acetone
Client Sample ID: 2AMCOD02
Lab ID#: 0411433-02A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.7 5.0 6.4 12Acetone0.67 3.9 2.0 122-Butanone (Methyl Ethyl Ketone)0.67 1.1 2.5 4.1Toluene0.67 1.9 2.9 8.4m,p-Xylene0.67 0.78 2.9 3.4o-Xylene0.67 1.5 3.3 7.41,2,4-Trimethylbenzene
Client Sample ID: 2AMCODR02
Lab ID#: 0411433-03A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.67 0.72 2.5 2.7Toluene
Client Sample ID: 2AMCODL02
Lab ID#: 0411433-04A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.7 3.0 6.4 7.0Acetone0.67 0.98 2.0 2.92-Butanone (Methyl Ethyl Ketone)0.67 0.97 2.5 3.7Toluene0.67 1.2 2.9 5.2m,p-Xylene
Page 4 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCOU02
Lab ID#: 0411433-01A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112314File Name:Dil. Factor: 1.34
Date of Collection: 11/18/04Date of Analysis: 11/23/04 09:59 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.67 Not Detected 4.7 Not DetectedFreon 1142.7 Not Detected 5.5 Not DetectedChloromethane
0.67 Not Detected 1.7 Not DetectedVinyl Chloride0.67 Not Detected 2.6 Not DetectedBromomethane0.67 Not Detected 1.8 Not DetectedChloroethane0.67 Not Detected 3.8 Not DetectedFreon 110.67 Not Detected 5.1 Not DetectedFreon 1130.67 Not Detected 2.6 Not Detected1,1-Dichloroethene2.7 3.6 6.4 8.6Acetone
0.67 Not Detected 2.3 Not DetectedMethylene Chloride0.67 Not Detected 2.6 Not Detectedtrans-1,2-Dichloroethene0.67 Not Detected 2.7 Not Detected1,1-Dichloroethane0.67 Not Detected 2.0 Not Detected2-Butanone (Methyl Ethyl Ketone)0.67 Not Detected 2.6 Not Detectedcis-1,2-Dichloroethene0.67 Not Detected 3.3 Not DetectedChloroform0.67 Not Detected 3.6 Not Detected1,1,1-Trichloroethane0.67 Not Detected 4.2 Not DetectedCarbon Tetrachloride0.67 Not Detected 2.1 Not DetectedBenzene0.67 Not Detected 2.7 Not Detected1,2-Dichloroethane0.67 Not Detected 3.6 Not DetectedTrichloroethene0.67 Not Detected 3.1 Not Detected1,2-Dichloropropane0.67 Not Detected 3.0 Not Detectedcis-1,3-Dichloropropene0.67 Not Detected 2.7 Not Detected4-Methyl-2-pentanone0.67 Not Detected 2.5 Not DetectedToluene0.67 Not Detected 3.0 Not Detectedtrans-1,3-Dichloropropene0.67 Not Detected 3.6 Not Detected1,1,2-Trichloroethane0.67 Not Detected 4.5 Not DetectedTetrachloroethene2.7 Not Detected 11 Not Detected2-Hexanone
0.67 Not Detected 5.1 Not Detected1,2-Dibromoethane (EDB)0.67 Not Detected 3.1 Not DetectedChlorobenzene0.67 Not Detected 2.9 Not DetectedEthyl Benzene0.67 Not Detected 2.9 Not Detectedm,p-Xylene0.67 Not Detected 2.9 Not Detectedo-Xylene0.67 Not Detected 2.8 Not DetectedStyrene0.67 Not Detected 4.6 Not Detected1,1,2,2-Tetrachloroethane0.67 Not Detected 3.3 Not Detected1,2,4-Trimethylbenzene0.67 Not Detected 4.0 Not Detected1,3-Dichlorobenzene0.67 Not Detected 4.0 Not Detected1,4-Dichlorobenzene0.67 Not Detected 3.5 Not Detectedalpha-Chlorotoluene0.67 Not Detected 4.0 Not Detected1,2-Dichlorobenzene
Page 5 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCOU02
Lab ID#: 0411433-01A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112314File Name:Dil. Factor: 1.34
Date of Collection: 11/18/04Date of Analysis: 11/23/04 09:59 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.7 Not Detected 20 Not Detected1,2,4-Trichlorobenzene2.7 Not Detected 11 Not DetectedDichlorofluoromethane
0.67 Not Detected 3.3 Not Detected1,3,5-Trimethylbenzene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
103 70-130Toluene-d8102 70-1301,2-Dichloroethane-d4101 70-1304-Bromofluorobenzene
Page 6 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCOD02
Lab ID#: 0411433-02A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112315File Name:Dil. Factor: 1.34
Date of Collection: 11/18/04Date of Analysis: 11/23/04 10:40 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.67 Not Detected 4.7 Not DetectedFreon 1142.7 Not Detected 5.5 Not DetectedChloromethane
0.67 Not Detected 1.7 Not DetectedVinyl Chloride0.67 Not Detected 2.6 Not DetectedBromomethane0.67 Not Detected 1.8 Not DetectedChloroethane0.67 Not Detected 3.8 Not DetectedFreon 110.67 Not Detected 5.1 Not DetectedFreon 1130.67 Not Detected 2.6 Not Detected1,1-Dichloroethene2.7 5.0 6.4 12Acetone
0.67 Not Detected 2.3 Not DetectedMethylene Chloride0.67 Not Detected 2.6 Not Detectedtrans-1,2-Dichloroethene0.67 Not Detected 2.7 Not Detected1,1-Dichloroethane0.67 3.9 2.0 122-Butanone (Methyl Ethyl Ketone)0.67 Not Detected 2.6 Not Detectedcis-1,2-Dichloroethene0.67 Not Detected 3.3 Not DetectedChloroform0.67 Not Detected 3.6 Not Detected1,1,1-Trichloroethane0.67 Not Detected 4.2 Not DetectedCarbon Tetrachloride0.67 Not Detected 2.1 Not DetectedBenzene0.67 Not Detected 2.7 Not Detected1,2-Dichloroethane0.67 Not Detected 3.6 Not DetectedTrichloroethene0.67 Not Detected 3.1 Not Detected1,2-Dichloropropane0.67 Not Detected 3.0 Not Detectedcis-1,3-Dichloropropene0.67 Not Detected 2.7 Not Detected4-Methyl-2-pentanone0.67 1.1 2.5 4.1Toluene0.67 Not Detected 3.0 Not Detectedtrans-1,3-Dichloropropene0.67 Not Detected 3.6 Not Detected1,1,2-Trichloroethane0.67 Not Detected 4.5 Not DetectedTetrachloroethene2.7 Not Detected 11 Not Detected2-Hexanone
0.67 Not Detected 5.1 Not Detected1,2-Dibromoethane (EDB)0.67 Not Detected 3.1 Not DetectedChlorobenzene0.67 Not Detected 2.9 Not DetectedEthyl Benzene0.67 1.9 2.9 8.4m,p-Xylene0.67 0.78 2.9 3.4o-Xylene0.67 Not Detected 2.8 Not DetectedStyrene0.67 Not Detected 4.6 Not Detected1,1,2,2-Tetrachloroethane0.67 1.5 3.3 7.41,2,4-Trimethylbenzene0.67 Not Detected 4.0 Not Detected1,3-Dichlorobenzene0.67 Not Detected 4.0 Not Detected1,4-Dichlorobenzene0.67 Not Detected 3.5 Not Detectedalpha-Chlorotoluene0.67 Not Detected 4.0 Not Detected1,2-Dichlorobenzene
Page 7 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCOD02
Lab ID#: 0411433-02A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112315File Name:Dil. Factor: 1.34
Date of Collection: 11/18/04Date of Analysis: 11/23/04 10:40 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.7 Not Detected 20 Not Detected1,2,4-Trichlorobenzene2.7 Not Detected 11 Not DetectedDichlorofluoromethane
0.67 Not Detected 3.3 Not Detected1,3,5-Trimethylbenzene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
103 70-130Toluene-d8103 70-1301,2-Dichloroethane-d4102 70-1304-Bromofluorobenzene
Page 8 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCODR02
Lab ID#: 0411433-03A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112316File Name:Dil. Factor: 1.34
Date of Collection: 11/18/04Date of Analysis: 11/23/04 11:22 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.67 Not Detected 4.7 Not DetectedFreon 1142.7 Not Detected 5.5 Not DetectedChloromethane
0.67 Not Detected 1.7 Not DetectedVinyl Chloride0.67 Not Detected 2.6 Not DetectedBromomethane0.67 Not Detected 1.8 Not DetectedChloroethane0.67 Not Detected 3.8 Not DetectedFreon 110.67 Not Detected 5.1 Not DetectedFreon 1130.67 Not Detected 2.6 Not Detected1,1-Dichloroethene2.7 Not Detected 6.4 Not DetectedAcetone
0.67 Not Detected 2.3 Not DetectedMethylene Chloride0.67 Not Detected 2.6 Not Detectedtrans-1,2-Dichloroethene0.67 Not Detected 2.7 Not Detected1,1-Dichloroethane0.67 Not Detected 2.0 Not Detected2-Butanone (Methyl Ethyl Ketone)0.67 Not Detected 2.6 Not Detectedcis-1,2-Dichloroethene0.67 Not Detected 3.3 Not DetectedChloroform0.67 Not Detected 3.6 Not Detected1,1,1-Trichloroethane0.67 Not Detected 4.2 Not DetectedCarbon Tetrachloride0.67 Not Detected 2.1 Not DetectedBenzene0.67 Not Detected 2.7 Not Detected1,2-Dichloroethane0.67 Not Detected 3.6 Not DetectedTrichloroethene0.67 Not Detected 3.1 Not Detected1,2-Dichloropropane0.67 Not Detected 3.0 Not Detectedcis-1,3-Dichloropropene0.67 Not Detected 2.7 Not Detected4-Methyl-2-pentanone0.67 0.72 2.5 2.7Toluene0.67 Not Detected 3.0 Not Detectedtrans-1,3-Dichloropropene0.67 Not Detected 3.6 Not Detected1,1,2-Trichloroethane0.67 Not Detected 4.5 Not DetectedTetrachloroethene2.7 Not Detected 11 Not Detected2-Hexanone
0.67 Not Detected 5.1 Not Detected1,2-Dibromoethane (EDB)0.67 Not Detected 3.1 Not DetectedChlorobenzene0.67 Not Detected 2.9 Not DetectedEthyl Benzene0.67 Not Detected 2.9 Not Detectedm,p-Xylene0.67 Not Detected 2.9 Not Detectedo-Xylene0.67 Not Detected 2.8 Not DetectedStyrene0.67 Not Detected 4.6 Not Detected1,1,2,2-Tetrachloroethane0.67 Not Detected 3.3 Not Detected1,2,4-Trimethylbenzene0.67 Not Detected 4.0 Not Detected1,3-Dichlorobenzene0.67 Not Detected 4.0 Not Detected1,4-Dichlorobenzene0.67 Not Detected 3.5 Not Detectedalpha-Chlorotoluene0.67 Not Detected 4.0 Not Detected1,2-Dichlorobenzene
Page 9 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCODR02
Lab ID#: 0411433-03A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112316File Name:Dil. Factor: 1.34
Date of Collection: 11/18/04Date of Analysis: 11/23/04 11:22 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.7 Not Detected 20 Not Detected1,2,4-Trichlorobenzene2.7 Not Detected 11 Not DetectedDichlorofluoromethane
0.67 Not Detected 3.3 Not Detected1,3,5-Trimethylbenzene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d8104 70-1301,2-Dichloroethane-d4103 70-1304-Bromofluorobenzene
Page 10 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCODL02
Lab ID#: 0411433-04A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112317File Name:Dil. Factor: 1.34
Date of Collection: 11/18/04Date of Analysis: 11/24/04 01:15 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.67 Not Detected 4.7 Not DetectedFreon 1142.7 Not Detected 5.5 Not DetectedChloromethane
0.67 Not Detected 1.7 Not DetectedVinyl Chloride0.67 Not Detected 2.6 Not DetectedBromomethane0.67 Not Detected 1.8 Not DetectedChloroethane0.67 Not Detected 3.8 Not DetectedFreon 110.67 Not Detected 5.1 Not DetectedFreon 1130.67 Not Detected 2.6 Not Detected1,1-Dichloroethene2.7 3.0 6.4 7.0Acetone
0.67 Not Detected 2.3 Not DetectedMethylene Chloride0.67 Not Detected 2.6 Not Detectedtrans-1,2-Dichloroethene0.67 Not Detected 2.7 Not Detected1,1-Dichloroethane0.67 0.98 2.0 2.92-Butanone (Methyl Ethyl Ketone)0.67 Not Detected 2.6 Not Detectedcis-1,2-Dichloroethene0.67 Not Detected 3.3 Not DetectedChloroform0.67 Not Detected 3.6 Not Detected1,1,1-Trichloroethane0.67 Not Detected 4.2 Not DetectedCarbon Tetrachloride0.67 Not Detected 2.1 Not DetectedBenzene0.67 Not Detected 2.7 Not Detected1,2-Dichloroethane0.67 Not Detected 3.6 Not DetectedTrichloroethene0.67 Not Detected 3.1 Not Detected1,2-Dichloropropane0.67 Not Detected 3.0 Not Detectedcis-1,3-Dichloropropene0.67 Not Detected 2.7 Not Detected4-Methyl-2-pentanone0.67 0.97 2.5 3.7Toluene0.67 Not Detected 3.0 Not Detectedtrans-1,3-Dichloropropene0.67 Not Detected 3.6 Not Detected1,1,2-Trichloroethane0.67 Not Detected 4.5 Not DetectedTetrachloroethene2.7 Not Detected 11 Not Detected2-Hexanone
0.67 Not Detected 5.1 Not Detected1,2-Dibromoethane (EDB)0.67 Not Detected 3.1 Not DetectedChlorobenzene0.67 Not Detected 2.9 Not DetectedEthyl Benzene0.67 1.2 2.9 5.2m,p-Xylene0.67 Not Detected 2.9 Not Detectedo-Xylene0.67 Not Detected 2.8 Not DetectedStyrene0.67 Not Detected 4.6 Not Detected1,1,2,2-Tetrachloroethane0.67 Not Detected 3.3 Not Detected1,2,4-Trimethylbenzene0.67 Not Detected 4.0 Not Detected1,3-Dichlorobenzene0.67 Not Detected 4.0 Not Detected1,4-Dichlorobenzene0.67 Not Detected 3.5 Not Detectedalpha-Chlorotoluene0.67 Not Detected 4.0 Not Detected1,2-Dichlorobenzene
Page 11 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCODL02
Lab ID#: 0411433-04A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112317File Name:Dil. Factor: 1.34
Date of Collection: 11/18/04Date of Analysis: 11/24/04 01:15 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.7 Not Detected 20 Not Detected1,2,4-Trichlorobenzene2.7 Not Detected 11 Not DetectedDichlorofluoromethane
0.67 Not Detected 3.3 Not Detected1,3,5-Trimethylbenzene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
101 70-130Toluene-d8105 70-1301,2-Dichloroethane-d499 70-1304-Bromofluorobenzene
Page 12 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab ID#: 0411433-05A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112307File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 11/23/04 03:53 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.50 Not Detected 3.5 Not DetectedFreon 1142.0 Not Detected 4.1 Not DetectedChloromethane
0.50 Not Detected 1.3 Not DetectedVinyl Chloride0.50 Not Detected 1.9 Not DetectedBromomethane0.50 Not Detected 1.3 Not DetectedChloroethane0.50 Not Detected 2.8 Not DetectedFreon 110.50 Not Detected 3.8 Not DetectedFreon 1130.50 Not Detected 2.0 Not Detected1,1-Dichloroethene2.0 Not Detected 4.8 Not DetectedAcetone
0.50 Not Detected 1.7 Not DetectedMethylene Chloride0.50 Not Detected 2.0 Not Detectedtrans-1,2-Dichloroethene0.50 Not Detected 2.0 Not Detected1,1-Dichloroethane0.50 Not Detected 1.5 Not Detected2-Butanone (Methyl Ethyl Ketone)0.50 Not Detected 2.0 Not Detectedcis-1,2-Dichloroethene0.50 Not Detected 2.4 Not DetectedChloroform0.50 Not Detected 2.7 Not Detected1,1,1-Trichloroethane0.50 Not Detected 3.1 Not DetectedCarbon Tetrachloride0.50 Not Detected 1.6 Not DetectedBenzene0.50 Not Detected 2.0 Not Detected1,2-Dichloroethane0.50 Not Detected 2.7 Not DetectedTrichloroethene0.50 Not Detected 2.3 Not Detected1,2-Dichloropropane0.50 Not Detected 2.3 Not Detectedcis-1,3-Dichloropropene0.50 Not Detected 2.0 Not Detected4-Methyl-2-pentanone0.50 Not Detected 1.9 Not DetectedToluene0.50 Not Detected 2.3 Not Detectedtrans-1,3-Dichloropropene0.50 Not Detected 2.7 Not Detected1,1,2-Trichloroethane0.50 Not Detected 3.4 Not DetectedTetrachloroethene2.0 Not Detected 8.2 Not Detected2-Hexanone
0.50 Not Detected 3.8 Not Detected1,2-Dibromoethane (EDB)0.50 Not Detected 2.3 Not DetectedChlorobenzene0.50 Not Detected 2.2 Not DetectedEthyl Benzene0.50 Not Detected 2.2 Not Detectedm,p-Xylene0.50 Not Detected 2.2 Not Detectedo-Xylene0.50 Not Detected 2.1 Not DetectedStyrene0.50 Not Detected 3.4 Not Detected1,1,2,2-Tetrachloroethane0.50 Not Detected 2.4 Not Detected1,2,4-Trimethylbenzene0.50 Not Detected 3.0 Not Detected1,3-Dichlorobenzene0.50 Not Detected 3.0 Not Detected1,4-Dichlorobenzene0.50 Not Detected 2.6 Not Detectedalpha-Chlorotoluene0.50 Not Detected 3.0 Not Detected1,2-Dichlorobenzene
Page 13 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab ID#: 0411433-05A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112307File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 11/23/04 03:53 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.0 Not Detected 15 Not Detected1,2,4-Trichlorobenzene2.0 Not Detected 8.4 Not DetectedDichlorofluoromethane
0.50 Not Detected 2.4 Not Detected1,3,5-Trimethylbenzene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d8100 70-1301,2-Dichloroethane-d499 70-1304-Bromofluorobenzene
Page 14 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCV
Lab ID#: 0411433-06A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112302File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 11/23/04 08:57 AM
%RecoveryCompound
123Freon 114101Chloromethane84Vinyl Chloride86Bromomethane89Chloroethane87Freon 1182Freon 113791,1-Dichloroethene84Acetone90Methylene Chloride76trans-1,2-Dichloroethene811,1-Dichloroethane872-Butanone (Methyl Ethyl Ketone)84cis-1,2-Dichloroethene86Chloroform961,1,1-Trichloroethane111Carbon Tetrachloride76Benzene841,2-Dichloroethane83Trichloroethene831,2-Dichloropropane89cis-1,3-Dichloropropene924-Methyl-2-pentanone86Toluene94trans-1,3-Dichloropropene861,1,2-Trichloroethane95Tetrachloroethene982-Hexanone911,2-Dibromoethane (EDB)87Chlorobenzene88Ethyl Benzene84m,p-Xylene83o-Xylene86Styrene801,1,2,2-Tetrachloroethane751,2,4-Trimethylbenzene781,3-Dichlorobenzene771,4-Dichlorobenzene75alpha-Chlorotoluene731,2-Dichlorobenzene
Page 15 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCV
Lab ID#: 0411433-06A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112302File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 11/23/04 08:57 AM
%RecoveryCompound
761,2,4-Trichlorobenzene134Dichlorofluoromethane761,3,5-Trimethylbenzene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d8104 70-1301,2-Dichloroethane-d497 70-1304-Bromofluorobenzene
Page 16 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
Lab ID#: 0411433-07A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112306File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 11/23/04 02:57 PM
%RecoveryCompound
124Freon 114109Chloromethane90Vinyl Chloride88Bromomethane94Chloroethane83Freon 1182Freon 113771,1-Dichloroethene91Acetone85Methylene Chloride79trans-1,2-Dichloroethene821,1-Dichloroethane912-Butanone (Methyl Ethyl Ketone)88cis-1,2-Dichloroethene87Chloroform971,1,1-Trichloroethane108Carbon Tetrachloride82Benzene871,2-Dichloroethane88Trichloroethene941,2-Dichloropropane88cis-1,3-Dichloropropene974-Methyl-2-pentanone91Toluene91trans-1,3-Dichloropropene881,1,2-Trichloroethane96Tetrachloroethene992-Hexanone931,2-Dibromoethane (EDB)88Chlorobenzene89Ethyl Benzene86m,p-Xylene83o-Xylene80Styrene801,1,2,2-Tetrachloroethane701,2,4-Trimethylbenzene751,3-Dichlorobenzene731,4-Dichlorobenzene73alpha-Chlorotoluene701,2-Dichlorobenzene
Page 17 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
Lab ID#: 0411433-07A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112306File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 11/23/04 02:57 PM
%RecoveryCompound
911,2,4-TrichlorobenzeneNot SpikedDichlorofluoromethane
721,3,5-Trimethylbenzene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d898 70-1301,2-Dichloroethane-d497 70-1304-Bromofluorobenzene
Page 18 of 18
AIR TOXICS LTD.@AN ENVIRONMENTAL ANALYTICAL LABORATORY
Air Toxics Ltd. Introduces the Electronic Report
Thank you for choosing Air Toxics Ltd. To better serve our customers, we are providing your report by e-mail. This document is provided in Portable Document Format which can be viewed with Acrobat Reader by Adobe.
This electronic report includes the following:• Work order Summary;• Laboratory Narrative;• Results; and• Chain of Custody (copy).
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630
(916) 985-1000 .FAX (916) 985-1020Hours 8:00 A.M to 6:00 P.M. Pacific
AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
@
Mr. Bruce KenningtonEnviron International123 North Wacker Dr. Suite 250Chicago, IL 60606
WORK ORDER #: 0411319
CLIENT: BILL TO:
PHONE:
Mr. Felix MoranEnviron International740 Waukegan RoadSuite 401Deerfield, IL 60015
312-853-9430
312-853-9025
11/17/2004DATE COMPLETED: 11/28/2004
P.O. #
PROJECT #
Work Order Summary
FAX:
DATE RECEIVED: CONTACT: Susan Alaniz
NAMEFRACTION # TEST VAC./PRES.RECEIPT
01A 2AMCOU01 Modified TO-15 0.2psi02A 2AMCODO1 Modified TO-15 0.2psi03A 2AMCODR01 Modified TO-15 0.0 "Hg04A 2AMCODL01 Modified TO-15 0.0 "Hg05A 2AMCOU01D Modified TO-15 0.0 "Hg05AA 2AMCOU01D Duplicate Modified TO-15 0.0 "Hg06A Lab Blank Modified TO-15 NA07A CCV Modified TO-15 NA08A LCS Modified TO-15 NA
CERTIFIED BY:
Laboratory Director
DATE:
Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, Expiration date: 06/30/06
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020
12/01/04
Page 1 of 23
This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards
Certfication numbers: CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004NY NELAP - 11291, UT NELAP - 9166389892
LABORATORY NARRATIVEModified TO-15
Environ InternationalWorkorder# 0411319
@AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Five 6 Liter Summa Canister samples were received on November 17, 2004. The laboratory performedanalysis via modified EPA Method TO-15 using GC/MS in the full scan mode. The method involvesconcentrating up to 0.2 liters of air. The concentrated aliquot is then flash vaporized and swept through awater management system to remove water vapor. Following dehumidification, the sample passes directlyinto the GC/MS for analysis. See the data sheets for the reporting limits for each compound.
Method modifications taken to run these samples include:
Requirement ATL ModificationsTO-15BFB acceptance criteria CLP protocol (TO-15) SW-846 protocol
Concentration of IS spike 10 ppbv (TO-15) 25 ppbv
Dilutions for initial calibration Dynamic dilutions or static using canisters
Syringe dilutions
Daily CCV +- 30% Difference </= 30% Difference with two allowed out up to </=40%.; flag and narrate outliers
Primary ions for Quantification Freon 114: 85, Carbon Tetrachloride: 117, Trichloroethene: 130, Ethyl Benzene, m,p- and o-Xylene: 91, Vinyl Acetate: 43, 2-Butanone: 43, 4-Methyl-2-Pentanone: 43.
Freon 114: 135, Carbon Tetrachloride: 119, Trichloroethene: 95, Ethyl Benzene, m,p- and o-Xylene: 106, Vinyl Acetate: 86, 2-Butanone: 72, 4-Methyl-2-Pentanone: 58.
Sample collection media Summa canister ATL recommends use of summa canisters to insure data defensibility, but will report results from Tedlar bags at client request
Sample Drying System Nafion Dryer (TO-14A) Multisorbent
Sample Load Volume 400 mL (TO-14A) Varied to 0.2 L.
Blank Acceptance Criteria. < 0.20 ppbv (TO-14A) < RL
BFB Absolute Abundance Criteria (TO-14A)
Within 10% of that from the previous day.
CCV internal standard area counts are compared to ICAL, corrective action for > 40 % D.
Initial Calibration +- 30 %RSD (TO-14A) </= 30 % RSD with 2 compounds allowed out to </= 40 % RSD.
IS Recoveries Within 40% of mean over ICAL for blanks, and within 40 % of daily CCV for samples. (TO-15)
Within 40% of CCV recoveries for blank and samples.
Page 2 of 23
AN ENVIRONMENTAL ANALYTICAL LABORATORY
AIR TOXICS LTD.@Method Detection Limit Follow 40CFR Pt.136
App. BThe MDL met all relevant requirements in Method TO-15 (statistical MDL less than the LOQ). The concentration of the spiked replicate may have exceeded 10X the calculated MDL in some cases. A list of these compounds is available.
Receiving Notes
There were no receiving discrepancies.
The reported CCV for each daily batch may be derived from more than one individual analytical file due tothe client's request for non-standard compounds.
Non-standard compounds may have different acceptance criteria than the standard TO-14A/TO-15compound list as per contract or verbal agreement.
Analytical Notes
Eight qualifiers may have been used on the data analysis sheets and indicates as follows: B - Compound present in laboratory blank greater than reporting limit (background subtraction notperformed). J - Estimated value. E - Exceeds instrument calibration range. S - Saturated Peak. Q - Exceeds quality control limits. U - Compound analyzed for but not detected above the reporting limit. UJ- Non-detected compound associated with low bias in the CCV N - The identification is based on presumptive evidence.
File extensions may have been used on the data analysis sheets and indicates as follows: a-File was requantified b-File was quantified by a second column and detector r1-File was requantified for the purpose of reissue
Definition of Data Qualifying Flags
Page 3 of 23
MODIFIED EPA METHOD TO-15 GC/MS FULL SCANSummary of Detected Compounds
AIR TOXICS LTD.@ AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCOU01
Lab ID#: 0411319-01ANo Detections Were Found.
Client Sample ID: 2AMCODO1
Lab ID#: 0411319-02A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.6 4.0 6.3 9.6Acetone0.66 0.97 1.9 2.92-Butanone (Methyl Ethyl Ketone)
Client Sample ID: 2AMCODR01
Lab ID#: 0411319-03A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.67 0.83 2.0 2.42-Butanone (Methyl Ethyl Ketone)0.67 1.5 2.5 5.5Toluene0.67 0.84 2.9 3.6m,p-Xylene
Client Sample ID: 2AMCODL01
Lab ID#: 0411319-04A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.7 4.1 6.4 9.6Acetone0.67 3.6 2.0 112-Butanone (Methyl Ethyl Ketone)0.67 1.7 2.5 6.3Toluene0.67 1.1 2.9 4.6m,p-Xylene
Client Sample ID: 2AMCOU01D
Lab ID#: 0411319-05A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.7 3.0 6.4 7.1Acetone0.67 0.74 2.0 2.22-Butanone (Methyl Ethyl Ketone)0.67 1.6 2.5 6.2Toluene0.67 0.91 2.9 3.9m,p-Xylene
Page 4 of 23
MODIFIED EPA METHOD TO-15 GC/MS FULL SCANSummary of Detected Compounds
AIR TOXICS LTD.@ AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCOU01D Duplicate
Lab ID#: 0411319-05AA
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.7 3.1 6.4 7.5Acetone0.67 0.86 2.0 2.52-Butanone (Methyl Ethyl Ketone)0.67 1.6 2.5 6.2Toluene0.67 0.98 2.9 4.3m,p-Xylene
Page 5 of 23
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCOU01
Lab ID#: 0411319-01A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112308File Name:Dil. Factor: 1.32
Date of Collection: 11/16/04Date of Analysis: 11/23/04 05:19 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.66 Not Detected 4.6 Not DetectedFreon 1142.6 Not Detected 5.4 Not DetectedChloromethane
0.66 Not Detected 1.7 Not DetectedVinyl Chloride0.66 Not Detected 2.6 Not DetectedBromomethane0.66 Not Detected 1.7 Not DetectedChloroethane0.66 Not Detected 3.7 Not DetectedFreon 110.66 Not Detected 5.0 Not DetectedFreon 1130.66 Not Detected 2.6 Not Detected1,1-Dichloroethene2.6 Not Detected 6.3 Not DetectedAcetone
0.66 Not Detected 2.3 Not DetectedMethylene Chloride0.66 Not Detected 2.6 Not Detectedtrans-1,2-Dichloroethene0.66 Not Detected 2.7 Not Detected1,1-Dichloroethane0.66 Not Detected 1.9 Not Detected2-Butanone (Methyl Ethyl Ketone)0.66 Not Detected 2.6 Not Detectedcis-1,2-Dichloroethene0.66 Not Detected 3.2 Not DetectedChloroform0.66 Not Detected 3.6 Not Detected1,1,1-Trichloroethane0.66 Not Detected 4.2 Not DetectedCarbon Tetrachloride0.66 Not Detected 2.1 Not DetectedBenzene0.66 Not Detected 2.7 Not Detected1,2-Dichloroethane0.66 Not Detected 3.5 Not DetectedTrichloroethene0.66 Not Detected 3.0 Not Detected1,2-Dichloropropane0.66 Not Detected 3.0 Not Detectedcis-1,3-Dichloropropene0.66 Not Detected 2.7 Not Detected4-Methyl-2-pentanone0.66 Not Detected 2.5 Not DetectedToluene0.66 Not Detected 3.0 Not Detectedtrans-1,3-Dichloropropene0.66 Not Detected 3.6 Not Detected1,1,2-Trichloroethane0.66 Not Detected 4.5 Not DetectedTetrachloroethene2.6 Not Detected 11 Not Detected2-Hexanone
0.66 Not Detected 5.1 Not Detected1,2-Dibromoethane (EDB)0.66 Not Detected 3.0 Not DetectedChlorobenzene0.66 Not Detected 2.9 Not DetectedEthyl Benzene0.66 Not Detected 2.9 Not Detectedm,p-Xylene0.66 Not Detected 2.9 Not Detectedo-Xylene0.66 Not Detected 2.8 Not DetectedStyrene0.66 Not Detected 4.5 Not Detected1,1,2,2-Tetrachloroethane0.66 Not Detected 3.2 Not Detected1,2,4-Trimethylbenzene0.66 Not Detected 4.0 Not Detected1,3-Dichlorobenzene0.66 Not Detected 4.0 Not Detected1,4-Dichlorobenzene0.66 Not Detected 3.4 Not Detectedalpha-Chlorotoluene0.66 Not Detected 4.0 Not Detected1,2-Dichlorobenzene
Page 6 of 23
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCOU01
Lab ID#: 0411319-01A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112308File Name:Dil. Factor: 1.32
Date of Collection: 11/16/04Date of Analysis: 11/23/04 05:19 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.6 Not Detected 20 Not Detected1,2,4-Trichlorobenzene2.6 Not Detected 11 Not DetectedDichlorofluoromethane
0.66 Not Detected 3.2 Not Detected1,3,5-Trimethylbenzene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
101 70-130Toluene-d8100 70-1301,2-Dichloroethane-d499 70-1304-Bromofluorobenzene
Page 7 of 23
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCODO1
Lab ID#: 0411319-02A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112309File Name:Dil. Factor: 1.32
Date of Collection: 11/16/04Date of Analysis: 11/23/04 06:01 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.66 Not Detected 4.6 Not DetectedFreon 1142.6 Not Detected 5.4 Not DetectedChloromethane
0.66 Not Detected 1.7 Not DetectedVinyl Chloride0.66 Not Detected 2.6 Not DetectedBromomethane0.66 Not Detected 1.7 Not DetectedChloroethane0.66 Not Detected 3.7 Not DetectedFreon 110.66 Not Detected 5.0 Not DetectedFreon 1130.66 Not Detected 2.6 Not Detected1,1-Dichloroethene2.6 4.0 6.3 9.6Acetone
0.66 Not Detected 2.3 Not DetectedMethylene Chloride0.66 Not Detected 2.6 Not Detectedtrans-1,2-Dichloroethene0.66 Not Detected 2.7 Not Detected1,1-Dichloroethane0.66 0.97 1.9 2.92-Butanone (Methyl Ethyl Ketone)0.66 Not Detected 2.6 Not Detectedcis-1,2-Dichloroethene0.66 Not Detected 3.2 Not DetectedChloroform0.66 Not Detected 3.6 Not Detected1,1,1-Trichloroethane0.66 Not Detected 4.2 Not DetectedCarbon Tetrachloride0.66 Not Detected 2.1 Not DetectedBenzene0.66 Not Detected 2.7 Not Detected1,2-Dichloroethane0.66 Not Detected 3.5 Not DetectedTrichloroethene0.66 Not Detected 3.0 Not Detected1,2-Dichloropropane0.66 Not Detected 3.0 Not Detectedcis-1,3-Dichloropropene0.66 Not Detected 2.7 Not Detected4-Methyl-2-pentanone0.66 Not Detected 2.5 Not DetectedToluene0.66 Not Detected 3.0 Not Detectedtrans-1,3-Dichloropropene0.66 Not Detected 3.6 Not Detected1,1,2-Trichloroethane0.66 Not Detected 4.5 Not DetectedTetrachloroethene2.6 Not Detected 11 Not Detected2-Hexanone
0.66 Not Detected 5.1 Not Detected1,2-Dibromoethane (EDB)0.66 Not Detected 3.0 Not DetectedChlorobenzene0.66 Not Detected 2.9 Not DetectedEthyl Benzene0.66 Not Detected 2.9 Not Detectedm,p-Xylene0.66 Not Detected 2.9 Not Detectedo-Xylene0.66 Not Detected 2.8 Not DetectedStyrene0.66 Not Detected 4.5 Not Detected1,1,2,2-Tetrachloroethane0.66 Not Detected 3.2 Not Detected1,2,4-Trimethylbenzene0.66 Not Detected 4.0 Not Detected1,3-Dichlorobenzene0.66 Not Detected 4.0 Not Detected1,4-Dichlorobenzene0.66 Not Detected 3.4 Not Detectedalpha-Chlorotoluene0.66 Not Detected 4.0 Not Detected1,2-Dichlorobenzene
Page 8 of 23
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCODO1
Lab ID#: 0411319-02A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112309File Name:Dil. Factor: 1.32
Date of Collection: 11/16/04Date of Analysis: 11/23/04 06:01 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.6 Not Detected 20 Not Detected1,2,4-Trichlorobenzene2.6 Not Detected 11 Not DetectedDichlorofluoromethane
0.66 Not Detected 3.2 Not Detected1,3,5-Trimethylbenzene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d8102 70-1301,2-Dichloroethane-d4101 70-1304-Bromofluorobenzene
Page 9 of 23
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCODR01
Lab ID#: 0411319-03A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112310File Name:Dil. Factor: 1.34
Date of Collection: 11/16/04Date of Analysis: 11/23/04 06:42 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.67 Not Detected 4.7 Not DetectedFreon 1142.7 Not Detected 5.5 Not DetectedChloromethane
0.67 Not Detected 1.7 Not DetectedVinyl Chloride0.67 Not Detected 2.6 Not DetectedBromomethane0.67 Not Detected 1.8 Not DetectedChloroethane0.67 Not Detected 3.8 Not DetectedFreon 110.67 Not Detected 5.1 Not DetectedFreon 1130.67 Not Detected 2.6 Not Detected1,1-Dichloroethene2.7 Not Detected 6.4 Not DetectedAcetone
0.67 Not Detected 2.3 Not DetectedMethylene Chloride0.67 Not Detected 2.6 Not Detectedtrans-1,2-Dichloroethene0.67 Not Detected 2.7 Not Detected1,1-Dichloroethane0.67 0.83 2.0 2.42-Butanone (Methyl Ethyl Ketone)0.67 Not Detected 2.6 Not Detectedcis-1,2-Dichloroethene0.67 Not Detected 3.3 Not DetectedChloroform0.67 Not Detected 3.6 Not Detected1,1,1-Trichloroethane0.67 Not Detected 4.2 Not DetectedCarbon Tetrachloride0.67 Not Detected 2.1 Not DetectedBenzene0.67 Not Detected 2.7 Not Detected1,2-Dichloroethane0.67 Not Detected 3.6 Not DetectedTrichloroethene0.67 Not Detected 3.1 Not Detected1,2-Dichloropropane0.67 Not Detected 3.0 Not Detectedcis-1,3-Dichloropropene0.67 Not Detected 2.7 Not Detected4-Methyl-2-pentanone0.67 1.5 2.5 5.5Toluene0.67 Not Detected 3.0 Not Detectedtrans-1,3-Dichloropropene0.67 Not Detected 3.6 Not Detected1,1,2-Trichloroethane0.67 Not Detected 4.5 Not DetectedTetrachloroethene2.7 Not Detected 11 Not Detected2-Hexanone
0.67 Not Detected 5.1 Not Detected1,2-Dibromoethane (EDB)0.67 Not Detected 3.1 Not DetectedChlorobenzene0.67 Not Detected 2.9 Not DetectedEthyl Benzene0.67 0.84 2.9 3.6m,p-Xylene0.67 Not Detected 2.9 Not Detectedo-Xylene0.67 Not Detected 2.8 Not DetectedStyrene0.67 Not Detected 4.6 Not Detected1,1,2,2-Tetrachloroethane0.67 Not Detected 3.3 Not Detected1,2,4-Trimethylbenzene0.67 Not Detected 4.0 Not Detected1,3-Dichlorobenzene0.67 Not Detected 4.0 Not Detected1,4-Dichlorobenzene0.67 Not Detected 3.5 Not Detectedalpha-Chlorotoluene0.67 Not Detected 4.0 Not Detected1,2-Dichlorobenzene
Page 10 of 23
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCODR01
Lab ID#: 0411319-03A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112310File Name:Dil. Factor: 1.34
Date of Collection: 11/16/04Date of Analysis: 11/23/04 06:42 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.7 Not Detected 20 Not Detected1,2,4-Trichlorobenzene2.7 Not Detected 11 Not DetectedDichlorofluoromethane
0.67 Not Detected 3.3 Not Detected1,3,5-Trimethylbenzene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
104 70-130Toluene-d8104 70-1301,2-Dichloroethane-d4101 70-1304-Bromofluorobenzene
Page 11 of 23
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCODL01
Lab ID#: 0411319-04A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112311File Name:Dil. Factor: 1.34
Date of Collection: 11/16/04Date of Analysis: 11/23/04 07:23 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.67 Not Detected 4.7 Not DetectedFreon 1142.7 Not Detected 5.5 Not DetectedChloromethane
0.67 Not Detected 1.7 Not DetectedVinyl Chloride0.67 Not Detected 2.6 Not DetectedBromomethane0.67 Not Detected 1.8 Not DetectedChloroethane0.67 Not Detected 3.8 Not DetectedFreon 110.67 Not Detected 5.1 Not DetectedFreon 1130.67 Not Detected 2.6 Not Detected1,1-Dichloroethene2.7 4.1 6.4 9.6Acetone
0.67 Not Detected 2.3 Not DetectedMethylene Chloride0.67 Not Detected 2.6 Not Detectedtrans-1,2-Dichloroethene0.67 Not Detected 2.7 Not Detected1,1-Dichloroethane0.67 3.6 2.0 112-Butanone (Methyl Ethyl Ketone)0.67 Not Detected 2.6 Not Detectedcis-1,2-Dichloroethene0.67 Not Detected 3.3 Not DetectedChloroform0.67 Not Detected 3.6 Not Detected1,1,1-Trichloroethane0.67 Not Detected 4.2 Not DetectedCarbon Tetrachloride0.67 Not Detected 2.1 Not DetectedBenzene0.67 Not Detected 2.7 Not Detected1,2-Dichloroethane0.67 Not Detected 3.6 Not DetectedTrichloroethene0.67 Not Detected 3.1 Not Detected1,2-Dichloropropane0.67 Not Detected 3.0 Not Detectedcis-1,3-Dichloropropene0.67 Not Detected 2.7 Not Detected4-Methyl-2-pentanone0.67 1.7 2.5 6.3Toluene0.67 Not Detected 3.0 Not Detectedtrans-1,3-Dichloropropene0.67 Not Detected 3.6 Not Detected1,1,2-Trichloroethane0.67 Not Detected 4.5 Not DetectedTetrachloroethene2.7 Not Detected 11 Not Detected2-Hexanone
0.67 Not Detected 5.1 Not Detected1,2-Dibromoethane (EDB)0.67 Not Detected 3.1 Not DetectedChlorobenzene0.67 Not Detected 2.9 Not DetectedEthyl Benzene0.67 1.1 2.9 4.6m,p-Xylene0.67 Not Detected 2.9 Not Detectedo-Xylene0.67 Not Detected 2.8 Not DetectedStyrene0.67 Not Detected 4.6 Not Detected1,1,2,2-Tetrachloroethane0.67 Not Detected 3.3 Not Detected1,2,4-Trimethylbenzene0.67 Not Detected 4.0 Not Detected1,3-Dichlorobenzene0.67 Not Detected 4.0 Not Detected1,4-Dichlorobenzene0.67 Not Detected 3.5 Not Detectedalpha-Chlorotoluene0.67 Not Detected 4.0 Not Detected1,2-Dichlorobenzene
Page 12 of 23
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCODL01
Lab ID#: 0411319-04A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112311File Name:Dil. Factor: 1.34
Date of Collection: 11/16/04Date of Analysis: 11/23/04 07:23 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.7 Not Detected 20 Not Detected1,2,4-Trichlorobenzene2.7 Not Detected 11 Not DetectedDichlorofluoromethane
0.67 Not Detected 3.3 Not Detected1,3,5-Trimethylbenzene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
104 70-130Toluene-d8102 70-1301,2-Dichloroethane-d4100 70-1304-Bromofluorobenzene
Page 13 of 23
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCOU01D
Lab ID#: 0411319-05A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112312File Name:Dil. Factor: 1.34
Date of Collection: 11/16/04Date of Analysis: 11/23/04 08:04 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.67 Not Detected 4.7 Not DetectedFreon 1142.7 Not Detected 5.5 Not DetectedChloromethane
0.67 Not Detected 1.7 Not DetectedVinyl Chloride0.67 Not Detected 2.6 Not DetectedBromomethane0.67 Not Detected 1.8 Not DetectedChloroethane0.67 Not Detected 3.8 Not DetectedFreon 110.67 Not Detected 5.1 Not DetectedFreon 1130.67 Not Detected 2.6 Not Detected1,1-Dichloroethene2.7 3.0 6.4 7.1Acetone
0.67 Not Detected 2.3 Not DetectedMethylene Chloride0.67 Not Detected 2.6 Not Detectedtrans-1,2-Dichloroethene0.67 Not Detected 2.7 Not Detected1,1-Dichloroethane0.67 0.74 2.0 2.22-Butanone (Methyl Ethyl Ketone)0.67 Not Detected 2.6 Not Detectedcis-1,2-Dichloroethene0.67 Not Detected 3.3 Not DetectedChloroform0.67 Not Detected 3.6 Not Detected1,1,1-Trichloroethane0.67 Not Detected 4.2 Not DetectedCarbon Tetrachloride0.67 Not Detected 2.1 Not DetectedBenzene0.67 Not Detected 2.7 Not Detected1,2-Dichloroethane0.67 Not Detected 3.6 Not DetectedTrichloroethene0.67 Not Detected 3.1 Not Detected1,2-Dichloropropane0.67 Not Detected 3.0 Not Detectedcis-1,3-Dichloropropene0.67 Not Detected 2.7 Not Detected4-Methyl-2-pentanone0.67 1.6 2.5 6.2Toluene0.67 Not Detected 3.0 Not Detectedtrans-1,3-Dichloropropene0.67 Not Detected 3.6 Not Detected1,1,2-Trichloroethane0.67 Not Detected 4.5 Not DetectedTetrachloroethene2.7 Not Detected 11 Not Detected2-Hexanone
0.67 Not Detected 5.1 Not Detected1,2-Dibromoethane (EDB)0.67 Not Detected 3.1 Not DetectedChlorobenzene0.67 Not Detected 2.9 Not DetectedEthyl Benzene0.67 0.91 2.9 3.9m,p-Xylene0.67 Not Detected 2.9 Not Detectedo-Xylene0.67 Not Detected 2.8 Not DetectedStyrene0.67 Not Detected 4.6 Not Detected1,1,2,2-Tetrachloroethane0.67 Not Detected 3.3 Not Detected1,2,4-Trimethylbenzene0.67 Not Detected 4.0 Not Detected1,3-Dichlorobenzene0.67 Not Detected 4.0 Not Detected1,4-Dichlorobenzene0.67 Not Detected 3.5 Not Detectedalpha-Chlorotoluene0.67 Not Detected 4.0 Not Detected1,2-Dichlorobenzene
Page 14 of 23
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCOU01D
Lab ID#: 0411319-05A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112312File Name:Dil. Factor: 1.34
Date of Collection: 11/16/04Date of Analysis: 11/23/04 08:04 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.7 Not Detected 20 Not Detected1,2,4-Trichlorobenzene2.7 Not Detected 11 Not DetectedDichlorofluoromethane
0.67 Not Detected 3.3 Not Detected1,3,5-Trimethylbenzene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d8102 70-1301,2-Dichloroethane-d499 70-1304-Bromofluorobenzene
Page 15 of 23
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCOU01D Duplicate
Lab ID#: 0411319-05AA
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112313File Name:Dil. Factor: 1.34
Date of Collection: 11/16/04Date of Analysis: 11/23/04 09:18 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.67 Not Detected 4.7 Not DetectedFreon 1142.7 Not Detected 5.5 Not DetectedChloromethane
0.67 Not Detected 1.7 Not DetectedVinyl Chloride0.67 Not Detected 2.6 Not DetectedBromomethane0.67 Not Detected 1.8 Not DetectedChloroethane0.67 Not Detected 3.8 Not DetectedFreon 110.67 Not Detected 5.1 Not DetectedFreon 1130.67 Not Detected 2.6 Not Detected1,1-Dichloroethene2.7 3.1 6.4 7.5Acetone
0.67 Not Detected 2.3 Not DetectedMethylene Chloride0.67 Not Detected 2.6 Not Detectedtrans-1,2-Dichloroethene0.67 Not Detected 2.7 Not Detected1,1-Dichloroethane0.67 0.86 2.0 2.52-Butanone (Methyl Ethyl Ketone)0.67 Not Detected 2.6 Not Detectedcis-1,2-Dichloroethene0.67 Not Detected 3.3 Not DetectedChloroform0.67 Not Detected 3.6 Not Detected1,1,1-Trichloroethane0.67 Not Detected 4.2 Not DetectedCarbon Tetrachloride0.67 Not Detected 2.1 Not DetectedBenzene0.67 Not Detected 2.7 Not Detected1,2-Dichloroethane0.67 Not Detected 3.6 Not DetectedTrichloroethene0.67 Not Detected 3.1 Not Detected1,2-Dichloropropane0.67 Not Detected 3.0 Not Detectedcis-1,3-Dichloropropene0.67 Not Detected 2.7 Not Detected4-Methyl-2-pentanone0.67 1.6 2.5 6.2Toluene0.67 Not Detected 3.0 Not Detectedtrans-1,3-Dichloropropene0.67 Not Detected 3.6 Not Detected1,1,2-Trichloroethane0.67 Not Detected 4.5 Not DetectedTetrachloroethene2.7 Not Detected 11 Not Detected2-Hexanone
0.67 Not Detected 5.1 Not Detected1,2-Dibromoethane (EDB)0.67 Not Detected 3.1 Not DetectedChlorobenzene0.67 Not Detected 2.9 Not DetectedEthyl Benzene0.67 0.98 2.9 4.3m,p-Xylene0.67 Not Detected 2.9 Not Detectedo-Xylene0.67 Not Detected 2.8 Not DetectedStyrene0.67 Not Detected 4.6 Not Detected1,1,2,2-Tetrachloroethane0.67 Not Detected 3.3 Not Detected1,2,4-Trimethylbenzene0.67 Not Detected 4.0 Not Detected1,3-Dichlorobenzene0.67 Not Detected 4.0 Not Detected1,4-Dichlorobenzene0.67 Not Detected 3.5 Not Detectedalpha-Chlorotoluene0.67 Not Detected 4.0 Not Detected1,2-Dichlorobenzene
Page 16 of 23
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMCOU01D Duplicate
Lab ID#: 0411319-05AA
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112313File Name:Dil. Factor: 1.34
Date of Collection: 11/16/04Date of Analysis: 11/23/04 09:18 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.7 Not Detected 20 Not Detected1,2,4-Trichlorobenzene2.7 Not Detected 11 Not DetectedDichlorofluoromethane
0.67 Not Detected 3.3 Not Detected1,3,5-Trimethylbenzene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d8102 70-1301,2-Dichloroethane-d4102 70-1304-Bromofluorobenzene
Page 17 of 23
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab ID#: 0411319-06A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112307File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 11/23/04 03:53 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.50 Not Detected 3.5 Not DetectedFreon 1142.0 Not Detected 4.1 Not DetectedChloromethane
0.50 Not Detected 1.3 Not DetectedVinyl Chloride0.50 Not Detected 1.9 Not DetectedBromomethane0.50 Not Detected 1.3 Not DetectedChloroethane0.50 Not Detected 2.8 Not DetectedFreon 110.50 Not Detected 3.8 Not DetectedFreon 1130.50 Not Detected 2.0 Not Detected1,1-Dichloroethene2.0 Not Detected 4.8 Not DetectedAcetone
0.50 Not Detected 1.7 Not DetectedMethylene Chloride0.50 Not Detected 2.0 Not Detectedtrans-1,2-Dichloroethene0.50 Not Detected 2.0 Not Detected1,1-Dichloroethane0.50 Not Detected 1.5 Not Detected2-Butanone (Methyl Ethyl Ketone)0.50 Not Detected 2.0 Not Detectedcis-1,2-Dichloroethene0.50 Not Detected 2.4 Not DetectedChloroform0.50 Not Detected 2.7 Not Detected1,1,1-Trichloroethane0.50 Not Detected 3.1 Not DetectedCarbon Tetrachloride0.50 Not Detected 1.6 Not DetectedBenzene0.50 Not Detected 2.0 Not Detected1,2-Dichloroethane0.50 Not Detected 2.7 Not DetectedTrichloroethene0.50 Not Detected 2.3 Not Detected1,2-Dichloropropane0.50 Not Detected 2.3 Not Detectedcis-1,3-Dichloropropene0.50 Not Detected 2.0 Not Detected4-Methyl-2-pentanone0.50 Not Detected 1.9 Not DetectedToluene0.50 Not Detected 2.3 Not Detectedtrans-1,3-Dichloropropene0.50 Not Detected 2.7 Not Detected1,1,2-Trichloroethane0.50 Not Detected 3.4 Not DetectedTetrachloroethene2.0 Not Detected 8.2 Not Detected2-Hexanone
0.50 Not Detected 3.8 Not Detected1,2-Dibromoethane (EDB)0.50 Not Detected 2.3 Not DetectedChlorobenzene0.50 Not Detected 2.2 Not DetectedEthyl Benzene0.50 Not Detected 2.2 Not Detectedm,p-Xylene0.50 Not Detected 2.2 Not Detectedo-Xylene0.50 Not Detected 2.1 Not DetectedStyrene0.50 Not Detected 3.4 Not Detected1,1,2,2-Tetrachloroethane0.50 Not Detected 2.4 Not Detected1,2,4-Trimethylbenzene0.50 Not Detected 3.0 Not Detected1,3-Dichlorobenzene0.50 Not Detected 3.0 Not Detected1,4-Dichlorobenzene0.50 Not Detected 2.6 Not Detectedalpha-Chlorotoluene0.50 Not Detected 3.0 Not Detected1,2-Dichlorobenzene
Page 18 of 23
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab ID#: 0411319-06A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112307File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 11/23/04 03:53 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.0 Not Detected 15 Not Detected1,2,4-Trichlorobenzene2.0 Not Detected 8.4 Not DetectedDichlorofluoromethane
0.50 Not Detected 2.4 Not Detected1,3,5-Trimethylbenzene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d8100 70-1301,2-Dichloroethane-d499 70-1304-Bromofluorobenzene
Page 19 of 23
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCV
Lab ID#: 0411319-07A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112302File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 11/23/04 08:57 AM
%RecoveryCompound
123Freon 114101Chloromethane84Vinyl Chloride86Bromomethane89Chloroethane87Freon 1182Freon 113791,1-Dichloroethene84Acetone90Methylene Chloride76trans-1,2-Dichloroethene811,1-Dichloroethane872-Butanone (Methyl Ethyl Ketone)84cis-1,2-Dichloroethene86Chloroform961,1,1-Trichloroethane111Carbon Tetrachloride76Benzene841,2-Dichloroethane83Trichloroethene831,2-Dichloropropane89cis-1,3-Dichloropropene924-Methyl-2-pentanone86Toluene94trans-1,3-Dichloropropene861,1,2-Trichloroethane95Tetrachloroethene982-Hexanone911,2-Dibromoethane (EDB)87Chlorobenzene88Ethyl Benzene84m,p-Xylene83o-Xylene86Styrene801,1,2,2-Tetrachloroethane751,2,4-Trimethylbenzene781,3-Dichlorobenzene771,4-Dichlorobenzene75alpha-Chlorotoluene731,2-Dichlorobenzene
Page 20 of 23
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCV
Lab ID#: 0411319-07A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112302File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 11/23/04 08:57 AM
%RecoveryCompound
761,2,4-Trichlorobenzene134Dichlorofluoromethane761,3,5-Trimethylbenzene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d8104 70-1301,2-Dichloroethane-d497 70-1304-Bromofluorobenzene
Page 21 of 23
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
Lab ID#: 0411319-08A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112306File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 11/23/04 02:57 PM
%RecoveryCompound
124Freon 114109Chloromethane90Vinyl Chloride88Bromomethane94Chloroethane83Freon 1182Freon 113771,1-Dichloroethene91Acetone85Methylene Chloride79trans-1,2-Dichloroethene821,1-Dichloroethane912-Butanone (Methyl Ethyl Ketone)88cis-1,2-Dichloroethene87Chloroform971,1,1-Trichloroethane108Carbon Tetrachloride82Benzene871,2-Dichloroethane88Trichloroethene941,2-Dichloropropane88cis-1,3-Dichloropropene974-Methyl-2-pentanone91Toluene91trans-1,3-Dichloropropene881,1,2-Trichloroethane96Tetrachloroethene992-Hexanone931,2-Dibromoethane (EDB)88Chlorobenzene89Ethyl Benzene86m,p-Xylene83o-Xylene80Styrene801,1,2,2-Tetrachloroethane701,2,4-Trimethylbenzene751,3-Dichlorobenzene731,4-Dichlorobenzene73alpha-Chlorotoluene701,2-Dichlorobenzene
Page 22 of 23
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
Lab ID#: 0411319-08A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
s112306File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 11/23/04 02:57 PM
%RecoveryCompound
911,2,4-TrichlorobenzeneNot SpikedDichlorofluoromethane
721,3,5-Trimethylbenzene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d898 70-1301,2-Dichloroethane-d497 70-1304-Bromofluorobenzene
Page 23 of 23
AIR TOXICS LTD.@AN ENVIRONMENTAL ANALYTICAL LABORATORY
Air Toxics Ltd. Introduces the Electronic Report
Thank you for choosing Air Toxics Ltd. To better serve our customers, we are providing your report by e-mail. This document is provided in Portable Document Format which can be viewed with Acrobat Reader by Adobe.
This electronic report includes the following:• Work order Summary;• Laboratory Narrative;• Results; and• Chain of Custody (copy).
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630
(916) 985-1000 .FAX (916) 985-1020Hours 8:00 A.M to 6:00 P.M. Pacific
AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
@
Mr. Felix MoranEnviron International740 Waukegan RoadSuite 401Deerfield, IL 60015
WORK ORDER #: 0601125
CLIENT: BILL TO:
PHONE:
Mr. Michael WieczorekEnviron International123 North Wacker Dr. Suite 250Chicago, IL 60606
847-444-9200
847-444-9420
01/09/2006DATE COMPLETED: 01/20/2006
P.O. #
PROJECT # 21-8601 AJ Midco II
Work Order Summary
FAX:
DATE RECEIVED: CONTACT: Susan Alaniz
NAMEFRACTION # TEST VAC./PRES.RECEIPT
01A 2AMU007 Modified TO-15 6.0 "Hg02A 2AMDR007 Modified TO-15 3.0 "Hg03A 2AMDL007 Modified TO-15 0.0 "Hg04A 2AMDC007 Modified TO-15 0.0 "Hg04AA 2AMDC007 Duplicate Modified TO-15 0.0 "Hg05A Lab Blank Modified TO-15 NA06A CCV Modified TO-15 NA07A LCS Modified TO-15 NA
CERTIFIED BY:
Laboratory Director
DATE:
Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, Expiration date: 06/30/06
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020
01/20/06
Page 1 of 20
This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards
Certfication numbers: AR DEQ - 03-084-0, CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004NY NELAP - 11291, UT NELAP - 9166389892
LABORATORY NARRATIVEModified TO-15
Environ InternationalWorkorder# 0601125
Four 6 Liter Summa Canister samples were received on January 09, 2006. The laboratory performedanalysis via modified EPA Method TO-15 using GC/MS in the full scan mode. The method involvesconcentrating up to 0.2 liters of air. The concentrated aliquot is then flash vaporized and swept through awater management system to remove water vapor. Following dehumidification, the sample passes directlyinto the GC/MS for analysis.
Method modifications taken to run these samples are summarized in the below table. Specific projectrequirements may over-ride the ATL modifications.
Requirement ATL ModificationsTO-15Daily CCV +- 30% Difference </= 30% Difference with two allowed out up to </=40%.;
flag and narrate outliers
Sample collection media Summa canister ATL recommends use of summa canisters to insure data defensibility, but will report results from Tedlar bags at client request
Method Detection Limit Follow 40CFR Pt.136 App. B
The MDL met all relevant requirements in Method TO-15 (statistical MDL less than the LOQ). The concentration of the spiked replicate may have exceeded 10X the calculated MDL in some cases
Receiving Notes
There were no receiving discrepancies.
The reported LCS for each daily batch has been derived from more than one analytical file.
Analytical Notes
Eight qualifiers may have been used on the data analysis sheets and indicates as follows: B - Compound present in laboratory blank greater than reporting limit (background subtraction notperformed). J - Estimated value. E - Exceeds instrument calibration range. S - Saturated peak. Q - Exceeds quality control limits. U - Compound analyzed for but not detected above the reporting limit. UJ- Non-detected compound associated with low bias in the CCV N - The identification is based on presumptive evidence.
File extensions may have been used on the data analysis sheets and indicates as follows: a-File was requantified
Definition of Data Qualifying Flags
Page 2 of 20
b-File was quantified by a second column and detector r1-File was requantified for the purpose of reissue
Page 3 of 20
AIR TOXICS LTD.
MODIFIED EPA METHOD TO-15 GC/MS FULL SCANSummary of Detected Compounds
Client Sample ID: 2AMU007
Lab ID#: 0601125-01ANo Detections Were Found.
Client Sample ID: 2AMDR007
Lab ID#: 0601125-02A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.74 1.0 2.8 4.0Toluene
Client Sample ID: 2AMDL007
Lab ID#: 0601125-03A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.7 3.2 5.0 6.0Ethanol
Client Sample ID: 2AMDC007
Lab ID#: 0601125-04A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.67 0.69 2.0 2.02-Butanone (Methyl Ethyl Ketone)0.67 0.72 2.7 2.9Heptane0.67 2.2 2.5 8.2Toluene0.67 0.77 2.9 3.4Ethyl Benzene0.67 1.7 2.9 7.5m,p-Xylene
Client Sample ID: 2AMDC007 Duplicate
Lab ID#: 0601125-04AA
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.67 0.88 2.0 2.62-Butanone (Methyl Ethyl Ketone)0.67 2.2 2.5 8.5Toluene0.67 0.79 2.9 3.4Ethyl Benzene0.67 1.8 2.9 7.8m,p-Xylene
Page 4 of 20
Client Sample ID: 2AMU007
Lab ID#: 0601125-01AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1011523File Name:
AIR TOXICS LTD.
Dil. Factor: 1.68Date of Collection: 1/5/06Date of Analysis: 1/16/06 01:57 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.84 Not Detected 4.2 Not DetectedFreon 120.84 Not Detected 5.9 Not DetectedFreon 1143.4 Not Detected 6.9 Not DetectedChloromethane
0.84 Not Detected 2.1 Not DetectedVinyl Chloride0.84 Not Detected 1.8 Not Detected1,3-Butadiene0.84 Not Detected 3.3 Not DetectedBromomethane0.84 Not Detected 2.2 Not DetectedChloroethane0.84 Not Detected 4.7 Not DetectedFreon 113.4 Not Detected 6.3 Not DetectedEthanol
0.84 Not Detected 6.4 Not DetectedFreon 1130.84 Not Detected 3.3 Not Detected1,1-Dichloroethene3.4 Not Detected 8.0 Not DetectedAcetone3.4 Not Detected 8.2 Not Detected2-Propanol
0.84 Not Detected 2.6 Not DetectedCarbon Disulfide3.4 Not Detected 10 Not Detected3-Chloropropene
0.84 Not Detected 2.9 Not DetectedMethylene Chloride0.84 Not Detected 3.0 Not DetectedMethyl tert-butyl ether0.84 Not Detected 3.3 Not Detectedtrans-1,2-Dichloroethene0.84 Not Detected 3.0 Not DetectedHexane0.84 Not Detected 3.4 Not Detected1,1-Dichloroethane0.84 Not Detected 2.5 Not Detected2-Butanone (Methyl Ethyl Ketone)0.84 Not Detected 3.3 Not Detectedcis-1,2-Dichloroethene0.84 Not Detected 2.5 Not DetectedTetrahydrofuran0.84 Not Detected 4.1 Not DetectedChloroform0.84 Not Detected 4.6 Not Detected1,1,1-Trichloroethane0.84 Not Detected 2.9 Not DetectedCyclohexane0.84 Not Detected 5.3 Not DetectedCarbon Tetrachloride0.84 Not Detected 3.9 Not Detected2,2,4-Trimethylpentane0.84 Not Detected 2.7 Not DetectedBenzene0.84 Not Detected 3.4 Not Detected1,2-Dichloroethane0.84 Not Detected 3.4 Not DetectedHeptane0.84 Not Detected 4.5 Not DetectedTrichloroethene0.84 Not Detected 3.9 Not Detected1,2-Dichloropropane3.4 Not Detected 12 Not Detected1,4-Dioxane
0.84 Not Detected 5.6 Not DetectedBromodichloromethane0.84 Not Detected 3.8 Not Detectedcis-1,3-Dichloropropene0.84 Not Detected 3.4 Not Detected4-Methyl-2-pentanone0.84 Not Detected 3.2 Not DetectedToluene0.84 Not Detected 3.8 Not Detectedtrans-1,3-Dichloropropene0.84 Not Detected 4.6 Not Detected1,1,2-Trichloroethane0.84 Not Detected 5.7 Not DetectedTetrachloroethene3.4 Not Detected 14 Not Detected2-Hexanone
Page 5 of 20
Client Sample ID: 2AMU007
Lab ID#: 0601125-01AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1011523File Name:
AIR TOXICS LTD.
Dil. Factor: 1.68Date of Collection: 1/5/06Date of Analysis: 1/16/06 01:57 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.84 Not Detected 7.2 Not DetectedDibromochloromethane0.84 Not Detected 6.4 Not Detected1,2-Dibromoethane (EDB)0.84 Not Detected 3.9 Not DetectedChlorobenzene0.84 Not Detected 3.6 Not DetectedEthyl Benzene0.84 Not Detected 3.6 Not Detectedm,p-Xylene0.84 Not Detected 3.6 Not Detectedo-Xylene0.84 Not Detected 3.6 Not DetectedStyrene0.84 Not Detected 8.7 Not DetectedBromoform0.84 Not Detected 4.1 Not DetectedCumene0.84 Not Detected 5.8 Not Detected1,1,2,2-Tetrachloroethane0.84 Not Detected 4.1 Not DetectedPropylbenzene0.84 Not Detected 4.1 Not Detected4-Ethyltoluene0.84 Not Detected 4.1 Not Detected1,3,5-Trimethylbenzene0.84 Not Detected 4.1 Not Detected1,2,4-Trimethylbenzene0.84 Not Detected 5.0 Not Detected1,3-Dichlorobenzene0.84 Not Detected 5.0 Not Detected1,4-Dichlorobenzene0.84 Not Detected 4.3 Not Detectedalpha-Chlorotoluene0.84 Not Detected 5.0 Not Detected1,2-Dichlorobenzene3.4 Not Detected 25 Not Detected1,2,4-Trichlorobenzene3.4 Not Detected 36 Not DetectedHexachlorobutadiene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d899 70-1301,2-Dichloroethane-d4105 70-1304-Bromofluorobenzene
Page 6 of 20
Client Sample ID: 2AMDR007
Lab ID#: 0601125-02AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1011524File Name:
AIR TOXICS LTD.
Dil. Factor: 1.49Date of Collection: 1/5/06Date of Analysis: 1/16/06 02:35 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.74 Not Detected 3.7 Not DetectedFreon 120.74 Not Detected 5.2 Not DetectedFreon 1143.0 Not Detected 6.2 Not DetectedChloromethane
0.74 Not Detected 1.9 Not DetectedVinyl Chloride0.74 Not Detected 1.6 Not Detected1,3-Butadiene0.74 Not Detected 2.9 Not DetectedBromomethane0.74 Not Detected 2.0 Not DetectedChloroethane0.74 Not Detected 4.2 Not DetectedFreon 113.0 Not Detected 5.6 Not DetectedEthanol
0.74 Not Detected 5.7 Not DetectedFreon 1130.74 Not Detected 3.0 Not Detected1,1-Dichloroethene3.0 Not Detected 7.1 Not DetectedAcetone3.0 Not Detected 7.3 Not Detected2-Propanol
0.74 Not Detected 2.3 Not DetectedCarbon Disulfide3.0 Not Detected 9.3 Not Detected3-Chloropropene
0.74 Not Detected 2.6 Not DetectedMethylene Chloride0.74 Not Detected 2.7 Not DetectedMethyl tert-butyl ether0.74 Not Detected 3.0 Not Detectedtrans-1,2-Dichloroethene0.74 Not Detected 2.6 Not DetectedHexane0.74 Not Detected 3.0 Not Detected1,1-Dichloroethane0.74 Not Detected 2.2 Not Detected2-Butanone (Methyl Ethyl Ketone)0.74 Not Detected 3.0 Not Detectedcis-1,2-Dichloroethene0.74 Not Detected 2.2 Not DetectedTetrahydrofuran0.74 Not Detected 3.6 Not DetectedChloroform0.74 Not Detected 4.1 Not Detected1,1,1-Trichloroethane0.74 Not Detected 2.6 Not DetectedCyclohexane0.74 Not Detected 4.7 Not DetectedCarbon Tetrachloride0.74 Not Detected 3.5 Not Detected2,2,4-Trimethylpentane0.74 Not Detected 2.4 Not DetectedBenzene0.74 Not Detected 3.0 Not Detected1,2-Dichloroethane0.74 Not Detected 3.0 Not DetectedHeptane0.74 Not Detected 4.0 Not DetectedTrichloroethene0.74 Not Detected 3.4 Not Detected1,2-Dichloropropane3.0 Not Detected 11 Not Detected1,4-Dioxane
0.74 Not Detected 5.0 Not DetectedBromodichloromethane0.74 Not Detected 3.4 Not Detectedcis-1,3-Dichloropropene0.74 Not Detected 3.0 Not Detected4-Methyl-2-pentanone0.74 1.0 2.8 4.0Toluene0.74 Not Detected 3.4 Not Detectedtrans-1,3-Dichloropropene0.74 Not Detected 4.1 Not Detected1,1,2-Trichloroethane0.74 Not Detected 5.0 Not DetectedTetrachloroethene3.0 Not Detected 12 Not Detected2-Hexanone
Page 7 of 20
Client Sample ID: 2AMDR007
Lab ID#: 0601125-02AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1011524File Name:
AIR TOXICS LTD.
Dil. Factor: 1.49Date of Collection: 1/5/06Date of Analysis: 1/16/06 02:35 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.74 Not Detected 6.3 Not DetectedDibromochloromethane0.74 Not Detected 5.7 Not Detected1,2-Dibromoethane (EDB)0.74 Not Detected 3.4 Not DetectedChlorobenzene0.74 Not Detected 3.2 Not DetectedEthyl Benzene0.74 Not Detected 3.2 Not Detectedm,p-Xylene0.74 Not Detected 3.2 Not Detectedo-Xylene0.74 Not Detected 3.2 Not DetectedStyrene0.74 Not Detected 7.7 Not DetectedBromoform0.74 Not Detected 3.7 Not DetectedCumene0.74 Not Detected 5.1 Not Detected1,1,2,2-Tetrachloroethane0.74 Not Detected 3.7 Not DetectedPropylbenzene0.74 Not Detected 3.7 Not Detected4-Ethyltoluene0.74 Not Detected 3.7 Not Detected1,3,5-Trimethylbenzene0.74 Not Detected 3.7 Not Detected1,2,4-Trimethylbenzene0.74 Not Detected 4.5 Not Detected1,3-Dichlorobenzene0.74 Not Detected 4.5 Not Detected1,4-Dichlorobenzene0.74 Not Detected 3.8 Not Detectedalpha-Chlorotoluene0.74 Not Detected 4.5 Not Detected1,2-Dichlorobenzene3.0 Not Detected 22 Not Detected1,2,4-Trichlorobenzene3.0 Not Detected 32 Not DetectedHexachlorobutadiene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d898 70-1301,2-Dichloroethane-d4108 70-1304-Bromofluorobenzene
Page 8 of 20
Client Sample ID: 2AMDL007
Lab ID#: 0601125-03AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1011525File Name:
AIR TOXICS LTD.
Dil. Factor: 1.34Date of Collection: 1/5/06Date of Analysis: 1/16/06 03:17 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.67 Not Detected 3.3 Not DetectedFreon 120.67 Not Detected 4.7 Not DetectedFreon 1142.7 Not Detected 5.5 Not DetectedChloromethane
0.67 Not Detected 1.7 Not DetectedVinyl Chloride0.67 Not Detected 1.5 Not Detected1,3-Butadiene0.67 Not Detected 2.6 Not DetectedBromomethane0.67 Not Detected 1.8 Not DetectedChloroethane0.67 Not Detected 3.8 Not DetectedFreon 112.7 3.2 5.0 6.0Ethanol
0.67 Not Detected 5.1 Not DetectedFreon 1130.67 Not Detected 2.6 Not Detected1,1-Dichloroethene2.7 Not Detected 6.4 Not DetectedAcetone2.7 Not Detected 6.6 Not Detected2-Propanol
0.67 Not Detected 2.1 Not DetectedCarbon Disulfide2.7 Not Detected 8.4 Not Detected3-Chloropropene
0.67 Not Detected 2.3 Not DetectedMethylene Chloride0.67 Not Detected 2.4 Not DetectedMethyl tert-butyl ether0.67 Not Detected 2.6 Not Detectedtrans-1,2-Dichloroethene0.67 Not Detected 2.4 Not DetectedHexane0.67 Not Detected 2.7 Not Detected1,1-Dichloroethane0.67 Not Detected 2.0 Not Detected2-Butanone (Methyl Ethyl Ketone)0.67 Not Detected 2.6 Not Detectedcis-1,2-Dichloroethene0.67 Not Detected 2.0 Not DetectedTetrahydrofuran0.67 Not Detected 3.3 Not DetectedChloroform0.67 Not Detected 3.6 Not Detected1,1,1-Trichloroethane0.67 Not Detected 2.3 Not DetectedCyclohexane0.67 Not Detected 4.2 Not DetectedCarbon Tetrachloride0.67 Not Detected 3.1 Not Detected2,2,4-Trimethylpentane0.67 Not Detected 2.1 Not DetectedBenzene0.67 Not Detected 2.7 Not Detected1,2-Dichloroethane0.67 Not Detected 2.7 Not DetectedHeptane0.67 Not Detected 3.6 Not DetectedTrichloroethene0.67 Not Detected 3.1 Not Detected1,2-Dichloropropane2.7 Not Detected 9.6 Not Detected1,4-Dioxane
0.67 Not Detected 4.5 Not DetectedBromodichloromethane0.67 Not Detected 3.0 Not Detectedcis-1,3-Dichloropropene0.67 Not Detected 2.7 Not Detected4-Methyl-2-pentanone0.67 Not Detected 2.5 Not DetectedToluene0.67 Not Detected 3.0 Not Detectedtrans-1,3-Dichloropropene0.67 Not Detected 3.6 Not Detected1,1,2-Trichloroethane0.67 Not Detected 4.5 Not DetectedTetrachloroethene2.7 Not Detected 11 Not Detected2-Hexanone
Page 9 of 20
Client Sample ID: 2AMDL007
Lab ID#: 0601125-03AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1011525File Name:
AIR TOXICS LTD.
Dil. Factor: 1.34Date of Collection: 1/5/06Date of Analysis: 1/16/06 03:17 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.67 Not Detected 5.7 Not DetectedDibromochloromethane0.67 Not Detected 5.1 Not Detected1,2-Dibromoethane (EDB)0.67 Not Detected 3.1 Not DetectedChlorobenzene0.67 Not Detected 2.9 Not DetectedEthyl Benzene0.67 Not Detected 2.9 Not Detectedm,p-Xylene0.67 Not Detected 2.9 Not Detectedo-Xylene0.67 Not Detected 2.8 Not DetectedStyrene0.67 Not Detected 6.9 Not DetectedBromoform0.67 Not Detected 3.3 Not DetectedCumene0.67 Not Detected 4.6 Not Detected1,1,2,2-Tetrachloroethane0.67 Not Detected 3.3 Not DetectedPropylbenzene0.67 Not Detected 3.3 Not Detected4-Ethyltoluene0.67 Not Detected 3.3 Not Detected1,3,5-Trimethylbenzene0.67 Not Detected 3.3 Not Detected1,2,4-Trimethylbenzene0.67 Not Detected 4.0 Not Detected1,3-Dichlorobenzene0.67 Not Detected 4.0 Not Detected1,4-Dichlorobenzene0.67 Not Detected 3.5 Not Detectedalpha-Chlorotoluene0.67 Not Detected 4.0 Not Detected1,2-Dichlorobenzene2.7 Not Detected 20 Not Detected1,2,4-Trichlorobenzene2.7 Not Detected 28 Not DetectedHexachlorobutadiene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
99 70-130Toluene-d899 70-1301,2-Dichloroethane-d4106 70-1304-Bromofluorobenzene
Page 10 of 20
Client Sample ID: 2AMDC007
Lab ID#: 0601125-04AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1011526File Name:
AIR TOXICS LTD.
Dil. Factor: 1.34Date of Collection: 1/5/06Date of Analysis: 1/16/06 03:54 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.67 Not Detected 3.3 Not DetectedFreon 120.67 Not Detected 4.7 Not DetectedFreon 1142.7 Not Detected 5.5 Not DetectedChloromethane
0.67 Not Detected 1.7 Not DetectedVinyl Chloride0.67 Not Detected 1.5 Not Detected1,3-Butadiene0.67 Not Detected 2.6 Not DetectedBromomethane0.67 Not Detected 1.8 Not DetectedChloroethane0.67 Not Detected 3.8 Not DetectedFreon 112.7 Not Detected 5.0 Not DetectedEthanol
0.67 Not Detected 5.1 Not DetectedFreon 1130.67 Not Detected 2.6 Not Detected1,1-Dichloroethene2.7 Not Detected 6.4 Not DetectedAcetone2.7 Not Detected 6.6 Not Detected2-Propanol
0.67 Not Detected 2.1 Not DetectedCarbon Disulfide2.7 Not Detected 8.4 Not Detected3-Chloropropene
0.67 Not Detected 2.3 Not DetectedMethylene Chloride0.67 Not Detected 2.4 Not DetectedMethyl tert-butyl ether0.67 Not Detected 2.6 Not Detectedtrans-1,2-Dichloroethene0.67 Not Detected 2.4 Not DetectedHexane0.67 Not Detected 2.7 Not Detected1,1-Dichloroethane0.67 0.69 2.0 2.02-Butanone (Methyl Ethyl Ketone)0.67 Not Detected 2.6 Not Detectedcis-1,2-Dichloroethene0.67 Not Detected 2.0 Not DetectedTetrahydrofuran0.67 Not Detected 3.3 Not DetectedChloroform0.67 Not Detected 3.6 Not Detected1,1,1-Trichloroethane0.67 Not Detected 2.3 Not DetectedCyclohexane0.67 Not Detected 4.2 Not DetectedCarbon Tetrachloride0.67 Not Detected 3.1 Not Detected2,2,4-Trimethylpentane0.67 Not Detected 2.1 Not DetectedBenzene0.67 Not Detected 2.7 Not Detected1,2-Dichloroethane0.67 0.72 2.7 2.9Heptane0.67 Not Detected 3.6 Not DetectedTrichloroethene0.67 Not Detected 3.1 Not Detected1,2-Dichloropropane2.7 Not Detected 9.6 Not Detected1,4-Dioxane
0.67 Not Detected 4.5 Not DetectedBromodichloromethane0.67 Not Detected 3.0 Not Detectedcis-1,3-Dichloropropene0.67 Not Detected 2.7 Not Detected4-Methyl-2-pentanone0.67 2.2 2.5 8.2Toluene0.67 Not Detected 3.0 Not Detectedtrans-1,3-Dichloropropene0.67 Not Detected 3.6 Not Detected1,1,2-Trichloroethane0.67 Not Detected 4.5 Not DetectedTetrachloroethene2.7 Not Detected 11 Not Detected2-Hexanone
Page 11 of 20
Client Sample ID: 2AMDC007
Lab ID#: 0601125-04AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1011526File Name:
AIR TOXICS LTD.
Dil. Factor: 1.34Date of Collection: 1/5/06Date of Analysis: 1/16/06 03:54 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.67 Not Detected 5.7 Not DetectedDibromochloromethane0.67 Not Detected 5.1 Not Detected1,2-Dibromoethane (EDB)0.67 Not Detected 3.1 Not DetectedChlorobenzene0.67 0.77 2.9 3.4Ethyl Benzene0.67 1.7 2.9 7.5m,p-Xylene0.67 Not Detected 2.9 Not Detectedo-Xylene0.67 Not Detected 2.8 Not DetectedStyrene0.67 Not Detected 6.9 Not DetectedBromoform0.67 Not Detected 3.3 Not DetectedCumene0.67 Not Detected 4.6 Not Detected1,1,2,2-Tetrachloroethane0.67 Not Detected 3.3 Not DetectedPropylbenzene0.67 Not Detected 3.3 Not Detected4-Ethyltoluene0.67 Not Detected 3.3 Not Detected1,3,5-Trimethylbenzene0.67 Not Detected 3.3 Not Detected1,2,4-Trimethylbenzene0.67 Not Detected 4.0 Not Detected1,3-Dichlorobenzene0.67 Not Detected 4.0 Not Detected1,4-Dichlorobenzene0.67 Not Detected 3.5 Not Detectedalpha-Chlorotoluene0.67 Not Detected 4.0 Not Detected1,2-Dichlorobenzene2.7 Not Detected 20 Not Detected1,2,4-Trichlorobenzene2.7 Not Detected 28 Not DetectedHexachlorobutadiene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
101 70-130Toluene-d8101 70-1301,2-Dichloroethane-d4108 70-1304-Bromofluorobenzene
Page 12 of 20
Client Sample ID: 2AMDC007 Duplicate
Lab ID#: 0601125-04AAMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1011527File Name:
AIR TOXICS LTD.
Dil. Factor: 1.34Date of Collection: 1/5/06Date of Analysis: 1/16/06 04:41 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.67 Not Detected 3.3 Not DetectedFreon 120.67 Not Detected 4.7 Not DetectedFreon 1142.7 Not Detected 5.5 Not DetectedChloromethane
0.67 Not Detected 1.7 Not DetectedVinyl Chloride0.67 Not Detected 1.5 Not Detected1,3-Butadiene0.67 Not Detected 2.6 Not DetectedBromomethane0.67 Not Detected 1.8 Not DetectedChloroethane0.67 Not Detected 3.8 Not DetectedFreon 112.7 Not Detected 5.0 Not DetectedEthanol
0.67 Not Detected 5.1 Not DetectedFreon 1130.67 Not Detected 2.6 Not Detected1,1-Dichloroethene2.7 Not Detected 6.4 Not DetectedAcetone2.7 Not Detected 6.6 Not Detected2-Propanol
0.67 Not Detected 2.1 Not DetectedCarbon Disulfide2.7 Not Detected 8.4 Not Detected3-Chloropropene
0.67 Not Detected 2.3 Not DetectedMethylene Chloride0.67 Not Detected 2.4 Not DetectedMethyl tert-butyl ether0.67 Not Detected 2.6 Not Detectedtrans-1,2-Dichloroethene0.67 Not Detected 2.4 Not DetectedHexane0.67 Not Detected 2.7 Not Detected1,1-Dichloroethane0.67 0.88 2.0 2.62-Butanone (Methyl Ethyl Ketone)0.67 Not Detected 2.6 Not Detectedcis-1,2-Dichloroethene0.67 Not Detected 2.0 Not DetectedTetrahydrofuran0.67 Not Detected 3.3 Not DetectedChloroform0.67 Not Detected 3.6 Not Detected1,1,1-Trichloroethane0.67 Not Detected 2.3 Not DetectedCyclohexane0.67 Not Detected 4.2 Not DetectedCarbon Tetrachloride0.67 Not Detected 3.1 Not Detected2,2,4-Trimethylpentane0.67 Not Detected 2.1 Not DetectedBenzene0.67 Not Detected 2.7 Not Detected1,2-Dichloroethane0.67 Not Detected 2.7 Not DetectedHeptane0.67 Not Detected 3.6 Not DetectedTrichloroethene0.67 Not Detected 3.1 Not Detected1,2-Dichloropropane2.7 Not Detected 9.6 Not Detected1,4-Dioxane
0.67 Not Detected 4.5 Not DetectedBromodichloromethane0.67 Not Detected 3.0 Not Detectedcis-1,3-Dichloropropene0.67 Not Detected 2.7 Not Detected4-Methyl-2-pentanone0.67 2.2 2.5 8.5Toluene0.67 Not Detected 3.0 Not Detectedtrans-1,3-Dichloropropene0.67 Not Detected 3.6 Not Detected1,1,2-Trichloroethane0.67 Not Detected 4.5 Not DetectedTetrachloroethene2.7 Not Detected 11 Not Detected2-Hexanone
Page 13 of 20
Client Sample ID: 2AMDC007 Duplicate
Lab ID#: 0601125-04AAMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1011527File Name:
AIR TOXICS LTD.
Dil. Factor: 1.34Date of Collection: 1/5/06Date of Analysis: 1/16/06 04:41 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.67 Not Detected 5.7 Not DetectedDibromochloromethane0.67 Not Detected 5.1 Not Detected1,2-Dibromoethane (EDB)0.67 Not Detected 3.1 Not DetectedChlorobenzene0.67 0.79 2.9 3.4Ethyl Benzene0.67 1.8 2.9 7.8m,p-Xylene0.67 Not Detected 2.9 Not Detectedo-Xylene0.67 Not Detected 2.8 Not DetectedStyrene0.67 Not Detected 6.9 Not DetectedBromoform0.67 Not Detected 3.3 Not DetectedCumene0.67 Not Detected 4.6 Not Detected1,1,2,2-Tetrachloroethane0.67 Not Detected 3.3 Not DetectedPropylbenzene0.67 Not Detected 3.3 Not Detected4-Ethyltoluene0.67 Not Detected 3.3 Not Detected1,3,5-Trimethylbenzene0.67 Not Detected 3.3 Not Detected1,2,4-Trimethylbenzene0.67 Not Detected 4.0 Not Detected1,3-Dichlorobenzene0.67 Not Detected 4.0 Not Detected1,4-Dichlorobenzene0.67 Not Detected 3.5 Not Detectedalpha-Chlorotoluene0.67 Not Detected 4.0 Not Detected1,2-Dichlorobenzene2.7 Not Detected 20 Not Detected1,2,4-Trichlorobenzene2.7 Not Detected 28 Not DetectedHexachlorobutadiene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
101 70-130Toluene-d899 70-1301,2-Dichloroethane-d4109 70-1304-Bromofluorobenzene
Page 14 of 20
Client Sample ID: Lab Blank
Lab ID#: 0601125-05AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1011505File Name:
AIR TOXICS LTD.
Dil. Factor: 1.00Date of Collection: NA Date of Analysis: 1/15/06 12:14 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.50 Not Detected 2.5 Not DetectedFreon 120.50 Not Detected 3.5 Not DetectedFreon 1142.0 Not Detected 4.1 Not DetectedChloromethane
0.50 Not Detected 1.3 Not DetectedVinyl Chloride0.50 Not Detected 1.1 Not Detected1,3-Butadiene0.50 Not Detected 1.9 Not DetectedBromomethane0.50 Not Detected 1.3 Not DetectedChloroethane0.50 Not Detected 2.8 Not DetectedFreon 112.0 Not Detected 3.8 Not DetectedEthanol
0.50 Not Detected 3.8 Not DetectedFreon 1130.50 Not Detected 2.0 Not Detected1,1-Dichloroethene2.0 Not Detected 4.8 Not DetectedAcetone2.0 Not Detected 4.9 Not Detected2-Propanol
0.50 Not Detected 1.6 Not DetectedCarbon Disulfide2.0 Not Detected 6.3 Not Detected3-Chloropropene
0.50 Not Detected 1.7 Not DetectedMethylene Chloride0.50 Not Detected 1.8 Not DetectedMethyl tert-butyl ether0.50 Not Detected 2.0 Not Detectedtrans-1,2-Dichloroethene0.50 Not Detected 1.8 Not DetectedHexane0.50 Not Detected 2.0 Not Detected1,1-Dichloroethane0.50 Not Detected 1.5 Not Detected2-Butanone (Methyl Ethyl Ketone)0.50 Not Detected 2.0 Not Detectedcis-1,2-Dichloroethene0.50 Not Detected 1.5 Not DetectedTetrahydrofuran0.50 Not Detected 2.4 Not DetectedChloroform0.50 Not Detected 2.7 Not Detected1,1,1-Trichloroethane0.50 Not Detected 1.7 Not DetectedCyclohexane0.50 Not Detected 3.1 Not DetectedCarbon Tetrachloride0.50 Not Detected 2.3 Not Detected2,2,4-Trimethylpentane0.50 Not Detected 1.6 Not DetectedBenzene0.50 Not Detected 2.0 Not Detected1,2-Dichloroethane0.50 Not Detected 2.0 Not DetectedHeptane0.50 Not Detected 2.7 Not DetectedTrichloroethene0.50 Not Detected 2.3 Not Detected1,2-Dichloropropane2.0 Not Detected 7.2 Not Detected1,4-Dioxane
0.50 Not Detected 3.4 Not DetectedBromodichloromethane0.50 Not Detected 2.3 Not Detectedcis-1,3-Dichloropropene0.50 Not Detected 2.0 Not Detected4-Methyl-2-pentanone0.50 Not Detected 1.9 Not DetectedToluene0.50 Not Detected 2.3 Not Detectedtrans-1,3-Dichloropropene0.50 Not Detected 2.7 Not Detected1,1,2-Trichloroethane0.50 Not Detected 3.4 Not DetectedTetrachloroethene2.0 Not Detected 8.2 Not Detected2-Hexanone
Page 15 of 20
Client Sample ID: Lab Blank
Lab ID#: 0601125-05AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1011505File Name:
AIR TOXICS LTD.
Dil. Factor: 1.00Date of Collection: NA Date of Analysis: 1/15/06 12:14 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.50 Not Detected 4.2 Not DetectedDibromochloromethane0.50 Not Detected 3.8 Not Detected1,2-Dibromoethane (EDB)0.50 Not Detected 2.3 Not DetectedChlorobenzene0.50 Not Detected 2.2 Not DetectedEthyl Benzene0.50 Not Detected 2.2 Not Detectedm,p-Xylene0.50 Not Detected 2.2 Not Detectedo-Xylene0.50 Not Detected 2.1 Not DetectedStyrene0.50 Not Detected 5.2 Not DetectedBromoform0.50 Not Detected 2.4 Not DetectedCumene0.50 Not Detected 3.4 Not Detected1,1,2,2-Tetrachloroethane0.50 Not Detected 2.4 Not DetectedPropylbenzene0.50 Not Detected 2.4 Not Detected4-Ethyltoluene0.50 Not Detected 2.4 Not Detected1,3,5-Trimethylbenzene0.50 Not Detected 2.4 Not Detected1,2,4-Trimethylbenzene0.50 Not Detected 3.0 Not Detected1,3-Dichlorobenzene0.50 Not Detected 3.0 Not Detected1,4-Dichlorobenzene0.50 Not Detected 2.6 Not Detectedalpha-Chlorotoluene0.50 Not Detected 3.0 Not Detected1,2-Dichlorobenzene2.0 Not Detected 15 Not Detected1,2,4-Trichlorobenzene2.0 Not Detected 21 Not DetectedHexachlorobutadiene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
101 70-130Toluene-d8100 70-1301,2-Dichloroethane-d4106 70-1304-Bromofluorobenzene
Page 16 of 20
Client Sample ID: CCV
Lab ID#: 0601125-06AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1011502File Name:
AIR TOXICS LTD.
Dil. Factor: 1.00Date of Collection: NA Date of Analysis: 1/15/06 09:55 AM
%RecoveryCompound
116Freon 12111Freon 114107Chloromethane101Vinyl Chloride931,3-Butadiene108Bromomethane120Chloroethane118Freon 1191Ethanol103Freon 1131021,1-Dichloroethene85Acetone992-Propanol90Carbon Disulfide923-Chloropropene104Methylene Chloride110Methyl tert-butyl ether90trans-1,2-Dichloroethene88Hexane1011,1-Dichloroethane992-Butanone (Methyl Ethyl Ketone)104cis-1,2-Dichloroethene103Tetrahydrofuran102Chloroform1061,1,1-Trichloroethane95Cyclohexane110Carbon Tetrachloride922,2,4-Trimethylpentane94Benzene1191,2-Dichloroethane96Heptane104Trichloroethene981,2-Dichloropropane921,4-Dioxane102Bromodichloromethane90cis-1,3-Dichloropropene1004-Methyl-2-pentanone95Toluene108trans-1,3-Dichloropropene961,1,2-Trichloroethane103Tetrachloroethene912-Hexanone
Page 17 of 20
Client Sample ID: CCV
Lab ID#: 0601125-06AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1011502File Name:
AIR TOXICS LTD.
Dil. Factor: 1.00Date of Collection: NA Date of Analysis: 1/15/06 09:55 AM
%RecoveryCompound
100Dibromochloromethane921,2-Dibromoethane (EDB)95Chlorobenzene94Ethyl Benzene92m,p-Xylene89o-Xylene109Styrene104Bromoform86Cumene821,1,2,2-Tetrachloroethane83Propylbenzene914-Ethyltoluene791,3,5-Trimethylbenzene781,2,4-Trimethylbenzene841,3-Dichlorobenzene791,4-Dichlorobenzene72alpha-Chlorotoluene771,2-Dichlorobenzene801,2,4-Trichlorobenzene91Hexachlorobutadiene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d8106 70-1301,2-Dichloroethane-d4110 70-1304-Bromofluorobenzene
Page 18 of 20
Client Sample ID: LCS
Lab ID#: 0601125-07AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1011503File Name:
AIR TOXICS LTD.
Dil. Factor: 1.00Date of Collection: NA Date of Analysis: 1/15/06 10:37 AM
%RecoveryCompound
109Freon 12103Freon 114108Chloromethane94Vinyl Chloride1021,3-Butadiene107Bromomethane111Chloroethane108Freon 1188Ethanol103Freon 113991,1-Dichloroethene105Acetone1032-Propanol106Carbon Disulfide1083-Chloropropene102Methylene Chloride131Methyl tert-butyl ether106trans-1,2-Dichloroethene97Hexane1011,1-Dichloroethane1212-Butanone (Methyl Ethyl Ketone)
131 Qcis-1,2-Dichloroethene113Tetrahydrofuran100Chloroform961,1,1-Trichloroethane103Cyclohexane101Carbon Tetrachloride1012,2,4-Trimethylpentane92Benzene1121,2-Dichloroethane108Heptane100Trichloroethene981,2-Dichloropropane1031,4-Dioxane112Bromodichloromethane102cis-1,3-Dichloropropene1124-Methyl-2-pentanone100Toluene112trans-1,3-Dichloropropene981,1,2-Trichloroethane107Tetrachloroethene932-Hexanone
Page 19 of 20
Client Sample ID: LCS
Lab ID#: 0601125-07AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1011503File Name:
AIR TOXICS LTD.
Dil. Factor: 1.00Date of Collection: NA Date of Analysis: 1/15/06 10:37 AM
%RecoveryCompound
108Dibromochloromethane1031,2-Dibromoethane (EDB)95Chlorobenzene96Ethyl Benzene98m,p-Xylene92o-Xylene116Styrene103Bromoform79Cumene831,1,2,2-Tetrachloroethane86Propylbenzene904-Ethyltoluene761,3,5-Trimethylbenzene801,2,4-Trimethylbenzene781,3-Dichlorobenzene781,4-Dichlorobenzene72alpha-Chlorotoluene711,2-Dichlorobenzene
60 Q1,2,4-Trichlorobenzene69 QHexachlorobutadiene
Q = Exceeds Quality Control limits.Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
101 70-130Toluene-d8104 70-1301,2-Dichloroethane-d4108 70-1304-Bromofluorobenzene
Page 20 of 20
AIR TOXICS LTD.@AN ENVIRONMENTAL ANALYTICAL LABORATORY
Air Toxics Ltd. Introduces the Electronic Report
Thank you for choosing Air Toxics Ltd. To better serve our customers, we are providing your report by e-mail. This document is provided in Portable Document Format which can be viewed with Acrobat Reader by Adobe.
This electronic report includes the following:• Work order Summary;• Laboratory Narrative;• Results; and• Chain of Custody (copy).
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630
(916) 985-1000 .FAX (916) 985-1020Hours 8:00 A.M to 6:00 P.M. Pacific
AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
@
Mr. Felix MoranEnviron International740 Waukegan RoadSuite 401Deerfield, IL 60015
WORK ORDER #: 0603308
CLIENT: BILL TO:
PHONE:
Mr. Felix MoranEnviron International740 Waukegan RoadSuite 401Deerfield, IL 60015
847-444-9200
847-444-9420
03/15/2006DATE COMPLETED: 03/22/2006
P.O. #
PROJECT # 21-8601AL MIDCO I
Work Order Summary
FAX:
DATE RECEIVED: CONTACT: Susan Alaniz
NAMEFRACTION # TEST VAC./PRES.RECEIPT
01A 1AMDL007 Modified TO-15/TICs 9.0 "Hg02A 1AMU007 Modified TO-15/TICs 9.0 "Hg03A 1AMDC007 Modified TO-15/TICs 5.5 "Hg04A 1AMDR007 Modified TO-15/TICs 9.0 "Hg05A Lab Blank Modified TO-15/TICs NA06A CCV Modified TO-15/TICs NA07A LCS Modified TO-15/TICs NA
CERTIFIED BY:
Laboratory Director
DATE:
Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, Expiration date: 06/30/06
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020
03/22/06
Page 1 of 18
This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards
Certfication numbers: CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004NY NELAP - 11291, UT NELAP - 9166389892
LABORATORY NARRATIVEModified TO-15
Environ InternationalWorkorder# 0603308
@AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Four 6 Liter Summa Canister samples were received on March 15, 2006. The laboratory performed analysisvia modified EPA Method TO-15 using GC/MS in the full scan mode. The method involves concentrating up to 0.2 liters of air. The concentrated aliquot is then flash vaporized and swept through a water managementsystem to remove water vapor. Following dehumidification, the sample passes directly into the GC/MS foranalysis.
Method modifications taken to run these samples are summarized in the below table. Specific projectrequirements may over-ride the ATL modifications.
Requirement ATL ModificationsTO-15Daily CCV +- 30% Difference </= 30% Difference with two allowed out up to </=40%.;
flag and narrate outliers
Sample collection media Summa canister ATL recommends use of summa canisters to insure data defensibility, but will report results from Tedlar bags at client request
Method Detection Limit Follow 40CFR Pt.136 App. B
The MDL met all relevant requirements in Method TO-15 (statistical MDL less than the LOQ). The concentration of the spiked replicate may have exceeded 10X the calculated MDL in some cases
Receiving Notes
There were no receiving discrepancies.
The reported LCS for each daily batch has been derived from more than one analytical file.
Analytical Notes
Eight qualifiers may have been used on the data analysis sheets and indicates as follows: B - Compound present in laboratory blank greater than reporting limit (background subtraction notperformed). J - Estimated value. E - Exceeds instrument calibration range. S - Saturated peak. Q - Exceeds quality control limits. U - Compound analyzed for but not detected above the reporting limit. UJ- Non-detected compound associated with low bias in the CCV N - The identification is based on presumptive evidence.
File extensions may have been used on the data analysis sheets and indicates as follows: a-File was requantified
Definition of Data Qualifying Flags
Page 2 of 18
AN ENVIRONMENTAL ANALYTICAL LABORATORY
AIR TOXICS LTD.@ b-File was quantified by a second column and detector r1-File was requantified for the purpose of reissue
Page 3 of 18
MODIFIED EPA METHOD TO-15 GC/MS FULL SCANSummary of Detected Compounds
AIR TOXICS LTD.@ AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDL007
Lab ID#: 0603308-01ANo Detections Were Found.
Client Sample ID: 1AMU007
Lab ID#: 0603308-02ANo Detections Were Found.
Client Sample ID: 1AMDC007
Lab ID#: 0603308-03ANo Detections Were Found.
Client Sample ID: 1AMDR007
Lab ID#: 0603308-04ANo Detections Were Found.
Page 4 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDL007
Lab ID#: 0603308-01A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031721File Name:Dil. Factor: 1.91
Date of Collection: 3/13/06Date of Analysis: 3/18/06 02:14 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.96 Not Detected 4.7 Not DetectedFreon 120.96 Not Detected 6.7 Not DetectedFreon 1140.96 Not Detected 2.4 Not DetectedVinyl Chloride0.96 Not Detected 3.7 Not DetectedBromomethane0.96 Not Detected 2.5 Not DetectedChloroethane0.96 Not Detected 5.4 Not DetectedFreon 110.96 Not Detected 3.8 Not Detected1,1-Dichloroethene0.96 Not Detected 7.3 Not DetectedFreon 1130.96 Not Detected 3.3 Not DetectedMethylene Chloride0.96 Not Detected 3.9 Not Detected1,1-Dichloroethane0.96 Not Detected 3.8 Not Detectedcis-1,2-Dichloroethene0.96 Not Detected 4.7 Not DetectedChloroform0.96 Not Detected 5.2 Not Detected1,1,1-Trichloroethane0.96 Not Detected 6.0 Not DetectedCarbon Tetrachloride0.96 Not Detected 3.0 Not DetectedBenzene0.96 Not Detected 3.9 Not Detected1,2-Dichloroethane0.96 Not Detected 5.1 Not DetectedTrichloroethene0.96 Not Detected 4.4 Not Detected1,2-Dichloropropane0.96 Not Detected 4.3 Not Detectedcis-1,3-Dichloropropene0.96 Not Detected 3.6 Not DetectedToluene0.96 Not Detected 4.3 Not Detectedtrans-1,3-Dichloropropene0.96 Not Detected 5.2 Not Detected1,1,2-Trichloroethane0.96 Not Detected 6.5 Not DetectedTetrachloroethene0.96 Not Detected 7.3 Not Detected1,2-Dibromoethane (EDB)0.96 Not Detected 4.4 Not DetectedChlorobenzene0.96 Not Detected 4.1 Not DetectedEthyl Benzene0.96 Not Detected 4.1 Not Detectedm,p-Xylene0.96 Not Detected 4.1 Not Detectedo-Xylene0.96 Not Detected 4.1 Not DetectedStyrene0.96 Not Detected 6.6 Not Detected1,1,2,2-Tetrachloroethane0.96 Not Detected 4.7 Not Detected1,3,5-Trimethylbenzene0.96 Not Detected 4.7 Not Detected1,2,4-Trimethylbenzene0.96 Not Detected 5.7 Not Detected1,3-Dichlorobenzene0.96 Not Detected 5.7 Not Detected1,4-Dichlorobenzene0.96 Not Detected 4.9 Not Detectedalpha-Chlorotoluene0.96 Not Detected 5.7 Not Detected1,2-Dichlorobenzene0.96 Not Detected 2.1 Not Detected1,3-Butadiene0.96 Not Detected 3.4 Not DetectedHexane0.96 Not Detected 3.3 Not DetectedCyclohexane0.96 Not Detected 6.4 Not DetectedBromodichloromethane
Page 5 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDL007
Lab ID#: 0603308-01A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031721File Name:Dil. Factor: 1.91
Date of Collection: 3/13/06Date of Analysis: 3/18/06 02:14 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.96 Not Detected 8.1 Not DetectedDibromochloromethane0.96 Not Detected 3.9 Not DetectedHeptane0.96 Not Detected 4.7 Not DetectedCumene0.96 Not Detected 4.7 Not DetectedPropylbenzene3.8 Not Detected 7.9 Not DetectedChloromethane3.8 Not Detected 28 Not Detected1,2,4-Trichlorobenzene3.8 Not Detected 41 Not DetectedHexachlorobutadiene3.8 Not Detected 9.1 Not DetectedAcetone
0.96 Not Detected 3.0 Not DetectedCarbon Disulfide3.8 Not Detected 9.4 Not Detected2-Propanol
0.96 Not Detected 3.8 Not Detectedtrans-1,2-Dichloroethene0.96 Not Detected 2.8 Not Detected2-Butanone (Methyl Ethyl Ketone)0.96 Not Detected 2.8 Not DetectedTetrahydrofuran3.8 Not Detected 14 Not Detected1,4-Dioxane
0.96 Not Detected 3.9 Not Detected4-Methyl-2-pentanone3.8 Not Detected 16 Not Detected2-Hexanone
0.96 Not Detected 9.9 Not DetectedBromoform0.96 Not Detected 4.7 Not Detected4-Ethyltoluene3.8 Not Detected 7.2 Not DetectedEthanol
0.96 Not Detected 3.4 Not DetectedMethyl tert-butyl ether0.96 Not Detected 4.5 Not Detected2,2,4-Trimethylpentane3.8 Not Detected 12 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
None Identified
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d8102 70-1301,2-Dichloroethane-d4104 70-1304-Bromofluorobenzene
Page 6 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMU007
Lab ID#: 0603308-02A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031723File Name:Dil. Factor: 1.91
Date of Collection: 3/13/06Date of Analysis: 3/18/06 03:48 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.96 Not Detected 4.7 Not DetectedFreon 120.96 Not Detected 6.7 Not DetectedFreon 1140.96 Not Detected 2.4 Not DetectedVinyl Chloride0.96 Not Detected 3.7 Not DetectedBromomethane0.96 Not Detected 2.5 Not DetectedChloroethane0.96 Not Detected 5.4 Not DetectedFreon 110.96 Not Detected 3.8 Not Detected1,1-Dichloroethene0.96 Not Detected 7.3 Not DetectedFreon 1130.96 Not Detected 3.3 Not DetectedMethylene Chloride0.96 Not Detected 3.9 Not Detected1,1-Dichloroethane0.96 Not Detected 3.8 Not Detectedcis-1,2-Dichloroethene0.96 Not Detected 4.7 Not DetectedChloroform0.96 Not Detected 5.2 Not Detected1,1,1-Trichloroethane0.96 Not Detected 6.0 Not DetectedCarbon Tetrachloride0.96 Not Detected 3.0 Not DetectedBenzene0.96 Not Detected 3.9 Not Detected1,2-Dichloroethane0.96 Not Detected 5.1 Not DetectedTrichloroethene0.96 Not Detected 4.4 Not Detected1,2-Dichloropropane0.96 Not Detected 4.3 Not Detectedcis-1,3-Dichloropropene0.96 Not Detected 3.6 Not DetectedToluene0.96 Not Detected 4.3 Not Detectedtrans-1,3-Dichloropropene0.96 Not Detected 5.2 Not Detected1,1,2-Trichloroethane0.96 Not Detected 6.5 Not DetectedTetrachloroethene0.96 Not Detected 7.3 Not Detected1,2-Dibromoethane (EDB)0.96 Not Detected 4.4 Not DetectedChlorobenzene0.96 Not Detected 4.1 Not DetectedEthyl Benzene0.96 Not Detected 4.1 Not Detectedm,p-Xylene0.96 Not Detected 4.1 Not Detectedo-Xylene0.96 Not Detected 4.1 Not DetectedStyrene0.96 Not Detected 6.6 Not Detected1,1,2,2-Tetrachloroethane0.96 Not Detected 4.7 Not Detected1,3,5-Trimethylbenzene0.96 Not Detected 4.7 Not Detected1,2,4-Trimethylbenzene0.96 Not Detected 5.7 Not Detected1,3-Dichlorobenzene0.96 Not Detected 5.7 Not Detected1,4-Dichlorobenzene0.96 Not Detected 4.9 Not Detectedalpha-Chlorotoluene0.96 Not Detected 5.7 Not Detected1,2-Dichlorobenzene0.96 Not Detected 2.1 Not Detected1,3-Butadiene0.96 Not Detected 3.4 Not DetectedHexane0.96 Not Detected 3.3 Not DetectedCyclohexane0.96 Not Detected 6.4 Not DetectedBromodichloromethane
Page 7 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMU007
Lab ID#: 0603308-02A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031723File Name:Dil. Factor: 1.91
Date of Collection: 3/13/06Date of Analysis: 3/18/06 03:48 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.96 Not Detected 8.1 Not DetectedDibromochloromethane0.96 Not Detected 3.9 Not DetectedHeptane0.96 Not Detected 4.7 Not DetectedCumene0.96 Not Detected 4.7 Not DetectedPropylbenzene3.8 Not Detected 7.9 Not DetectedChloromethane3.8 Not Detected 28 Not Detected1,2,4-Trichlorobenzene3.8 Not Detected 41 Not DetectedHexachlorobutadiene3.8 Not Detected 9.1 Not DetectedAcetone
0.96 Not Detected 3.0 Not DetectedCarbon Disulfide3.8 Not Detected 9.4 Not Detected2-Propanol
0.96 Not Detected 3.8 Not Detectedtrans-1,2-Dichloroethene0.96 Not Detected 2.8 Not Detected2-Butanone (Methyl Ethyl Ketone)0.96 Not Detected 2.8 Not DetectedTetrahydrofuran3.8 Not Detected 14 Not Detected1,4-Dioxane
0.96 Not Detected 3.9 Not Detected4-Methyl-2-pentanone3.8 Not Detected 16 Not Detected2-Hexanone
0.96 Not Detected 9.9 Not DetectedBromoform0.96 Not Detected 4.7 Not Detected4-Ethyltoluene3.8 Not Detected 7.2 Not DetectedEthanol
0.96 Not Detected 3.4 Not DetectedMethyl tert-butyl ether0.96 Not Detected 4.5 Not Detected2,2,4-Trimethylpentane3.8 Not Detected 12 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
None Identified
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
98 70-130Toluene-d8109 70-1301,2-Dichloroethane-d4100 70-1304-Bromofluorobenzene
Page 8 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDC007
Lab ID#: 0603308-03A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031722File Name:Dil. Factor: 1.64
Date of Collection: 3/13/06Date of Analysis: 3/18/06 03:09 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.82 Not Detected 4.0 Not DetectedFreon 120.82 Not Detected 5.7 Not DetectedFreon 1140.82 Not Detected 2.1 Not DetectedVinyl Chloride0.82 Not Detected 3.2 Not DetectedBromomethane0.82 Not Detected 2.2 Not DetectedChloroethane0.82 Not Detected 4.6 Not DetectedFreon 110.82 Not Detected 3.2 Not Detected1,1-Dichloroethene0.82 Not Detected 6.3 Not DetectedFreon 1130.82 Not Detected 2.8 Not DetectedMethylene Chloride0.82 Not Detected 3.3 Not Detected1,1-Dichloroethane0.82 Not Detected 3.2 Not Detectedcis-1,2-Dichloroethene0.82 Not Detected 4.0 Not DetectedChloroform0.82 Not Detected 4.5 Not Detected1,1,1-Trichloroethane0.82 Not Detected 5.2 Not DetectedCarbon Tetrachloride0.82 Not Detected 2.6 Not DetectedBenzene0.82 Not Detected 3.3 Not Detected1,2-Dichloroethane0.82 Not Detected 4.4 Not DetectedTrichloroethene0.82 Not Detected 3.8 Not Detected1,2-Dichloropropane0.82 Not Detected 3.7 Not Detectedcis-1,3-Dichloropropene0.82 Not Detected 3.1 Not DetectedToluene0.82 Not Detected 3.7 Not Detectedtrans-1,3-Dichloropropene0.82 Not Detected 4.5 Not Detected1,1,2-Trichloroethane0.82 Not Detected 5.6 Not DetectedTetrachloroethene0.82 Not Detected 6.3 Not Detected1,2-Dibromoethane (EDB)0.82 Not Detected 3.8 Not DetectedChlorobenzene0.82 Not Detected 3.6 Not DetectedEthyl Benzene0.82 Not Detected 3.6 Not Detectedm,p-Xylene0.82 Not Detected 3.6 Not Detectedo-Xylene0.82 Not Detected 3.5 Not DetectedStyrene0.82 Not Detected 5.6 Not Detected1,1,2,2-Tetrachloroethane0.82 Not Detected 4.0 Not Detected1,3,5-Trimethylbenzene0.82 Not Detected 4.0 Not Detected1,2,4-Trimethylbenzene0.82 Not Detected 4.9 Not Detected1,3-Dichlorobenzene0.82 Not Detected 4.9 Not Detected1,4-Dichlorobenzene0.82 Not Detected 4.2 Not Detectedalpha-Chlorotoluene0.82 Not Detected 4.9 Not Detected1,2-Dichlorobenzene0.82 Not Detected 1.8 Not Detected1,3-Butadiene0.82 Not Detected 2.9 Not DetectedHexane0.82 Not Detected 2.8 Not DetectedCyclohexane0.82 Not Detected 5.5 Not DetectedBromodichloromethane
Page 9 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDC007
Lab ID#: 0603308-03A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031722File Name:Dil. Factor: 1.64
Date of Collection: 3/13/06Date of Analysis: 3/18/06 03:09 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.82 Not Detected 7.0 Not DetectedDibromochloromethane0.82 Not Detected 3.4 Not DetectedHeptane0.82 Not Detected 4.0 Not DetectedCumene0.82 Not Detected 4.0 Not DetectedPropylbenzene3.3 Not Detected 6.8 Not DetectedChloromethane3.3 Not Detected 24 Not Detected1,2,4-Trichlorobenzene3.3 Not Detected 35 Not DetectedHexachlorobutadiene3.3 Not Detected 7.8 Not DetectedAcetone
0.82 Not Detected 2.6 Not DetectedCarbon Disulfide3.3 Not Detected 8.1 Not Detected2-Propanol
0.82 Not Detected 3.2 Not Detectedtrans-1,2-Dichloroethene0.82 Not Detected 2.4 Not Detected2-Butanone (Methyl Ethyl Ketone)0.82 Not Detected 2.4 Not DetectedTetrahydrofuran3.3 Not Detected 12 Not Detected1,4-Dioxane
0.82 Not Detected 3.4 Not Detected4-Methyl-2-pentanone3.3 Not Detected 13 Not Detected2-Hexanone
0.82 Not Detected 8.5 Not DetectedBromoform0.82 Not Detected 4.0 Not Detected4-Ethyltoluene3.3 Not Detected 6.2 Not DetectedEthanol
0.82 Not Detected 3.0 Not DetectedMethyl tert-butyl ether0.82 Not Detected 3.8 Not Detected2,2,4-Trimethylpentane3.3 Not Detected 10 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
None Identified
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d8104 70-1301,2-Dichloroethane-d4104 70-1304-Bromofluorobenzene
Page 10 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDR007
Lab ID#: 0603308-04A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031724File Name:Dil. Factor: 1.91
Date of Collection: 3/13/06Date of Analysis: 3/18/06 04:28 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.96 Not Detected 4.7 Not DetectedFreon 120.96 Not Detected 6.7 Not DetectedFreon 1140.96 Not Detected 2.4 Not DetectedVinyl Chloride0.96 Not Detected 3.7 Not DetectedBromomethane0.96 Not Detected 2.5 Not DetectedChloroethane0.96 Not Detected 5.4 Not DetectedFreon 110.96 Not Detected 3.8 Not Detected1,1-Dichloroethene0.96 Not Detected 7.3 Not DetectedFreon 1130.96 Not Detected 3.3 Not DetectedMethylene Chloride0.96 Not Detected 3.9 Not Detected1,1-Dichloroethane0.96 Not Detected 3.8 Not Detectedcis-1,2-Dichloroethene0.96 Not Detected 4.7 Not DetectedChloroform0.96 Not Detected 5.2 Not Detected1,1,1-Trichloroethane0.96 Not Detected 6.0 Not DetectedCarbon Tetrachloride0.96 Not Detected 3.0 Not DetectedBenzene0.96 Not Detected 3.9 Not Detected1,2-Dichloroethane0.96 Not Detected 5.1 Not DetectedTrichloroethene0.96 Not Detected 4.4 Not Detected1,2-Dichloropropane0.96 Not Detected 4.3 Not Detectedcis-1,3-Dichloropropene0.96 Not Detected 3.6 Not DetectedToluene0.96 Not Detected 4.3 Not Detectedtrans-1,3-Dichloropropene0.96 Not Detected 5.2 Not Detected1,1,2-Trichloroethane0.96 Not Detected 6.5 Not DetectedTetrachloroethene0.96 Not Detected 7.3 Not Detected1,2-Dibromoethane (EDB)0.96 Not Detected 4.4 Not DetectedChlorobenzene0.96 Not Detected 4.1 Not DetectedEthyl Benzene0.96 Not Detected 4.1 Not Detectedm,p-Xylene0.96 Not Detected 4.1 Not Detectedo-Xylene0.96 Not Detected 4.1 Not DetectedStyrene0.96 Not Detected 6.6 Not Detected1,1,2,2-Tetrachloroethane0.96 Not Detected 4.7 Not Detected1,3,5-Trimethylbenzene0.96 Not Detected 4.7 Not Detected1,2,4-Trimethylbenzene0.96 Not Detected 5.7 Not Detected1,3-Dichlorobenzene0.96 Not Detected 5.7 Not Detected1,4-Dichlorobenzene0.96 Not Detected 4.9 Not Detectedalpha-Chlorotoluene0.96 Not Detected 5.7 Not Detected1,2-Dichlorobenzene0.96 Not Detected 2.1 Not Detected1,3-Butadiene0.96 Not Detected 3.4 Not DetectedHexane0.96 Not Detected 3.3 Not DetectedCyclohexane0.96 Not Detected 6.4 Not DetectedBromodichloromethane
Page 11 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDR007
Lab ID#: 0603308-04A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031724File Name:Dil. Factor: 1.91
Date of Collection: 3/13/06Date of Analysis: 3/18/06 04:28 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.96 Not Detected 8.1 Not DetectedDibromochloromethane0.96 Not Detected 3.9 Not DetectedHeptane0.96 Not Detected 4.7 Not DetectedCumene0.96 Not Detected 4.7 Not DetectedPropylbenzene3.8 Not Detected 7.9 Not DetectedChloromethane3.8 Not Detected 28 Not Detected1,2,4-Trichlorobenzene3.8 Not Detected 41 Not DetectedHexachlorobutadiene3.8 Not Detected 9.1 Not DetectedAcetone
0.96 Not Detected 3.0 Not DetectedCarbon Disulfide3.8 Not Detected 9.4 Not Detected2-Propanol
0.96 Not Detected 3.8 Not Detectedtrans-1,2-Dichloroethene0.96 Not Detected 2.8 Not Detected2-Butanone (Methyl Ethyl Ketone)0.96 Not Detected 2.8 Not DetectedTetrahydrofuran3.8 Not Detected 14 Not Detected1,4-Dioxane
0.96 Not Detected 3.9 Not Detected4-Methyl-2-pentanone3.8 Not Detected 16 Not Detected2-Hexanone
0.96 Not Detected 9.9 Not DetectedBromoform0.96 Not Detected 4.7 Not Detected4-Ethyltoluene3.8 Not Detected 7.2 Not DetectedEthanol
0.96 Not Detected 3.4 Not DetectedMethyl tert-butyl ether0.96 Not Detected 4.5 Not Detected2,2,4-Trimethylpentane3.8 Not Detected 12 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
None Identified
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
99 70-130Toluene-d8108 70-1301,2-Dichloroethane-d4103 70-1304-Bromofluorobenzene
Page 12 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab ID#: 0603308-05A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031706File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 3/17/06 12:04 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.50 Not Detected 2.5 Not DetectedFreon 120.50 Not Detected 3.5 Not DetectedFreon 1140.50 Not Detected 1.3 Not DetectedVinyl Chloride0.50 Not Detected 1.9 Not DetectedBromomethane0.50 Not Detected 1.3 Not DetectedChloroethane0.50 Not Detected 2.8 Not DetectedFreon 110.50 Not Detected 2.0 Not Detected1,1-Dichloroethene0.50 Not Detected 3.8 Not DetectedFreon 1130.50 Not Detected 1.7 Not DetectedMethylene Chloride0.50 Not Detected 2.0 Not Detected1,1-Dichloroethane0.50 Not Detected 2.0 Not Detectedcis-1,2-Dichloroethene0.50 Not Detected 2.4 Not DetectedChloroform0.50 Not Detected 2.7 Not Detected1,1,1-Trichloroethane0.50 Not Detected 3.1 Not DetectedCarbon Tetrachloride0.50 Not Detected 1.6 Not DetectedBenzene0.50 Not Detected 2.0 Not Detected1,2-Dichloroethane0.50 Not Detected 2.7 Not DetectedTrichloroethene0.50 Not Detected 2.3 Not Detected1,2-Dichloropropane0.50 Not Detected 2.3 Not Detectedcis-1,3-Dichloropropene0.50 Not Detected 1.9 Not DetectedToluene0.50 Not Detected 2.3 Not Detectedtrans-1,3-Dichloropropene0.50 Not Detected 2.7 Not Detected1,1,2-Trichloroethane0.50 Not Detected 3.4 Not DetectedTetrachloroethene0.50 Not Detected 3.8 Not Detected1,2-Dibromoethane (EDB)0.50 Not Detected 2.3 Not DetectedChlorobenzene0.50 Not Detected 2.2 Not DetectedEthyl Benzene0.50 Not Detected 2.2 Not Detectedm,p-Xylene0.50 Not Detected 2.2 Not Detectedo-Xylene0.50 Not Detected 2.1 Not DetectedStyrene0.50 Not Detected 3.4 Not Detected1,1,2,2-Tetrachloroethane0.50 Not Detected 2.4 Not Detected1,3,5-Trimethylbenzene0.50 Not Detected 2.4 Not Detected1,2,4-Trimethylbenzene0.50 Not Detected 3.0 Not Detected1,3-Dichlorobenzene0.50 Not Detected 3.0 Not Detected1,4-Dichlorobenzene0.50 Not Detected 2.6 Not Detectedalpha-Chlorotoluene0.50 Not Detected 3.0 Not Detected1,2-Dichlorobenzene0.50 Not Detected 1.1 Not Detected1,3-Butadiene0.50 Not Detected 1.8 Not DetectedHexane0.50 Not Detected 1.7 Not DetectedCyclohexane0.50 Not Detected 3.4 Not DetectedBromodichloromethane
Page 13 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab ID#: 0603308-05A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031706File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 3/17/06 12:04 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.50 Not Detected 4.2 Not DetectedDibromochloromethane0.50 Not Detected 2.0 Not DetectedHeptane0.50 Not Detected 2.4 Not DetectedCumene0.50 Not Detected 2.4 Not DetectedPropylbenzene2.0 Not Detected 4.1 Not DetectedChloromethane2.0 Not Detected 15 Not Detected1,2,4-Trichlorobenzene2.0 Not Detected 21 Not DetectedHexachlorobutadiene2.0 Not Detected 4.8 Not DetectedAcetone
0.50 Not Detected 1.6 Not DetectedCarbon Disulfide2.0 Not Detected 4.9 Not Detected2-Propanol
0.50 Not Detected 2.0 Not Detectedtrans-1,2-Dichloroethene0.50 Not Detected 1.5 Not Detected2-Butanone (Methyl Ethyl Ketone)0.50 Not Detected 1.5 Not DetectedTetrahydrofuran2.0 Not Detected 7.2 Not Detected1,4-Dioxane
0.50 Not Detected 2.0 Not Detected4-Methyl-2-pentanone2.0 Not Detected 8.2 Not Detected2-Hexanone
0.50 Not Detected 5.2 Not DetectedBromoform0.50 Not Detected 2.4 Not Detected4-Ethyltoluene2.0 Not Detected 3.8 Not DetectedEthanol
0.50 Not Detected 1.8 Not DetectedMethyl tert-butyl ether0.50 Not Detected 2.3 Not Detected2,2,4-Trimethylpentane2.0 Not Detected 6.3 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
None Identified
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
99 70-130Toluene-d897 70-1301,2-Dichloroethane-d499 70-1304-Bromofluorobenzene
Page 14 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCV
Lab ID#: 0603308-06A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031702File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 3/17/06 09:09 AM
%RecoveryCompound
96Freon 1295Freon 11494Vinyl Chloride98Bromomethane99Chloroethane100Freon 111001,1-Dichloroethene97Freon 11394Methylene Chloride991,1-Dichloroethane101cis-1,2-Dichloroethene100Chloroform1051,1,1-Trichloroethane105Carbon Tetrachloride97Benzene1061,2-Dichloroethane105Trichloroethene1021,2-Dichloropropane108cis-1,3-Dichloropropene101Toluene104trans-1,3-Dichloropropene1021,1,2-Trichloroethane103Tetrachloroethene1051,2-Dibromoethane (EDB)99Chlorobenzene102Ethyl Benzene93m,p-Xylene101o-Xylene98Styrene931,1,2,2-Tetrachloroethane961,3,5-Trimethylbenzene971,2,4-Trimethylbenzene901,3-Dichlorobenzene911,4-Dichlorobenzene100alpha-Chlorotoluene901,2-Dichlorobenzene971,3-Butadiene99Hexane102Cyclohexane110Bromodichloromethane
Page 15 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCV
Lab ID#: 0603308-06A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031702File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 3/17/06 09:09 AM
%RecoveryCompound
111Dibromochloromethane108Heptane89Cumene98Propylbenzene96Chloromethane921,2,4-Trichlorobenzene101Hexachlorobutadiene95Acetone97Carbon Disulfide972-Propanol96trans-1,2-Dichloroethene1072-Butanone (Methyl Ethyl Ketone)103Tetrahydrofuran1011,4-Dioxane1094-Methyl-2-pentanone992-Hexanone108Bromoform1004-Ethyltoluene98Ethanol107Methyl tert-butyl ether1012,2,4-Trimethylpentane963-Chloropropene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d8105 70-1301,2-Dichloroethane-d4101 70-1304-Bromofluorobenzene
Page 16 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
Lab ID#: 0603308-07A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031703File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 3/17/06 09:50 AM
%RecoveryCompound
97Freon 1297Freon 11497Vinyl Chloride103Bromomethane104Chloroethane103Freon 111021,1-Dichloroethene100Freon 11398Methylene Chloride1021,1-Dichloroethane104cis-1,2-Dichloroethene101Chloroform1061,1,1-Trichloroethane107Carbon Tetrachloride99Benzene1041,2-Dichloroethane106Trichloroethene1051,2-Dichloropropane98cis-1,3-Dichloropropene102Toluene73trans-1,3-Dichloropropene1031,1,2-Trichloroethane103Tetrachloroethene1021,2-Dibromoethane (EDB)99Chlorobenzene105Ethyl Benzene90m,p-Xylene91o-Xylene100Styrene951,1,2,2-Tetrachloroethane921,3,5-Trimethylbenzene751,2,4-Trimethylbenzene961,3-Dichlorobenzene971,4-Dichlorobenzene100alpha-Chlorotoluene951,2-Dichlorobenzene1121,3-Butadiene108Hexane105Cyclohexane104Bromodichloromethane
Page 17 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
Lab ID#: 0603308-07A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031703File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 3/17/06 09:50 AM
%RecoveryCompound
100Dibromochloromethane106Heptane95Cumene104Propylbenzene99Chloromethane1101,2,4-Trichlorobenzene109Hexachlorobutadiene103Acetone110Carbon Disulfide1012-Propanol104trans-1,2-Dichloroethene1162-Butanone (Methyl Ethyl Ketone)108Tetrahydrofuran1041,4-Dioxane1084-Methyl-2-pentanone932-Hexanone83Bromoform1064-Ethyltoluene98Ethanol113Methyl tert-butyl ether1132,2,4-Trimethylpentane1123-Chloropropene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d8104 70-1301,2-Dichloroethane-d499 70-1304-Bromofluorobenzene
Page 18 of 18
AIR TOXICS LTD.@AN ENVIRONMENTAL ANALYTICAL LABORATORY
Air Toxics Ltd. Introduces the Electronic Report
Thank you for choosing Air Toxics Ltd. To better serve our customers, we are providing your report by e-mail. This document is provided in Portable Document Format which can be viewed with Acrobat Reader by Adobe.
This electronic report includes the following:• Work order Summary;• Laboratory Narrative;• Results; and• Chain of Custody (copy).
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630
(916) 985-1000 .FAX (916) 985-1020Hours 8:00 A.M to 6:00 P.M. Pacific
AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
@
Mr. Felix MoranEnviron International740 Waukegan RoadSuite 401Deerfield, IL 60015
WORK ORDER #: 0603207
CLIENT: BILL TO:
PHONE:
Mr. Felix MoranEnviron International740 Waukegan RoadSuite 401Deerfield, IL 60015
847-444-9200
847-444-942003/09/2006
DATE COMPLETED: 03/15/2006
P.O. #
PROJECT # 21-8601AJ Midco II
Work Order Summary
FAX:
DATE RECEIVED:CONTACT: Susan Alaniz
NAMEFRACTION # TEST VAC./PRES.RECEIPT
01A 2AMDC10 Modified TO-15/TICs 4.0 "Hg02A 2AMDL10 Modified TO-15/TICs 3.5 "Hg03A 2AMDR10 Modified TO-15/TICs 4.5 "Hg04A 2AMU10 Modified TO-15/TICs 3.0 "Hg05A Lab Blank Modified TO-15/TICs NA06A CCV Modified TO-15/TICs NA07A LCS Modified TO-15/TICs NA
CERTIFIED BY:
Laboratory Director
DATE:
Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, Expiration date: 06/30/06
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020
03/16/06
Page 1 of 18
This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards
Certfication numbers: CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004NY NELAP - 11291, UT NELAP - 9166389892
LABORATORY NARRATIVEModified TO-15
Environ InternationalWorkorder# 0603207
@AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Four 6 Liter Summa Canister samples were received on March 09, 2006. The laboratory performed analysis via modified EPA Method TO-15 using GC/MS in the full scan mode. The method involves concentrating up to 0.2 liters of air. The concentrated aliquot is then flash vaporized and swept through a water management system to remove water vapor. Following dehumidification, the sample passes directly into the GC/MS for analysis.
Method modifications taken to run these samples are summarized in the below table. Specific project requirements may over-ride the ATL modifications.
Requirement ATL ModificationsTO-15Daily CCV +- 30% Difference </= 30% Difference with two allowed out up to </=40%.;
flag and narrate outliers
Sample collection media Summa canister ATL recommends use of summa canisters to insure data defensibility, but will report results from Tedlar bags at client request
Method Detection Limit Follow 40CFR Pt.136 App. B
The MDL met all relevant requirements in Method TO-15 (statistical MDL less than the LOQ). The concentration of the spiked replicate may have exceeded 10X the calculated MDL in some cases
Receiving Notes
There were no receiving discrepancies.
The reported LCS for each daily batch has been derived from more than one analytical file.
Analytical Notes
Eight qualifiers may have been used on the data analysis sheets and indicates as follows: B - Compound present in laboratory blank greater than reporting limit (background subtraction not performed). J - Estimated value. E - Exceeds instrument calibration range. S - Saturated peak. Q - Exceeds quality control limits. U - Compound analyzed for but not detected above the reporting limit. UJ- Non-detected compound associated with low bias in the CCV N - The identification is based on presumptive evidence.
File extensions may have been used on the data analysis sheets and indicates as follows: a-File was requantified b-File was quantified by a second column and detector
Definition of Data Qualifying Flags
Page 2 of 18
AN ENVIRONMENTAL ANALYTICAL LABORATORY
AIR TOXICS LTD.@ r1-File was requantified for the purpose of reissue
Page 3 of 18
MODIFIED EPA METHOD TO-15 GC/MS FULL SCANSummary of Detected Compounds
AIR TOXICS LTD.@ AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMDC10
Lab ID#: 0603207-01A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
3.1 5.2 7.4 12Acetone
Client Sample ID: 2AMDL10
Lab ID#: 0603207-02ANo Detections Were Found.
Client Sample ID: 2AMDR10
Lab ID#: 0603207-03A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
3.2 3.5 7.5 8.4Acetone
TENTATIVELY IDENTIFIED COMPOUNDS
ppbvMatch QualityCAS NumberCompoundAmount
624-92-0 97% 7.8 N JDisulfide, dimethyl
Client Sample ID: 2AMU10
Lab ID#: 0603207-04ANo Detections Were Found.
Page 4 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMDC10Lab ID#: 0603207-01A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031213File Name:Dil. Factor: 1.55
Date of Collection: 3/7/06Date of Analysis: 3/12/06 08:00 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.78 Not Detected 3.8 Not DetectedFreon 120.78 Not Detected 5.4 Not DetectedFreon 1140.78 Not Detected 2.0 Not DetectedVinyl Chloride0.78 Not Detected 3.0 Not DetectedBromomethane0.78 Not Detected 2.0 Not DetectedChloroethane0.78 Not Detected 4.4 Not DetectedFreon 110.78 Not Detected 3.1 Not Detected1,1-Dichloroethene0.78 Not Detected 5.9 Not DetectedFreon 1130.78 Not Detected 2.7 Not DetectedMethylene Chloride0.78 Not Detected 3.1 Not Detected1,1-Dichloroethane0.78 Not Detected 3.1 Not Detectedcis-1,2-Dichloroethene0.78 Not Detected 3.8 Not DetectedChloroform0.78 Not Detected 4.2 Not Detected1,1,1-Trichloroethane0.78 Not Detected 4.9 Not DetectedCarbon Tetrachloride0.78 Not Detected 2.5 Not DetectedBenzene0.78 Not Detected 3.1 Not Detected1,2-Dichloroethane0.78 Not Detected 4.2 Not DetectedTrichloroethene0.78 Not Detected 3.6 Not Detected1,2-Dichloropropane0.78 Not Detected 3.5 Not Detectedcis-1,3-Dichloropropene0.78 Not Detected 2.9 Not DetectedToluene0.78 Not Detected 3.5 Not Detectedtrans-1,3-Dichloropropene0.78 Not Detected 4.2 Not Detected1,1,2-Trichloroethane0.78 Not Detected 5.2 Not DetectedTetrachloroethene0.78 Not Detected 6.0 Not Detected1,2-Dibromoethane (EDB)0.78 Not Detected 3.6 Not DetectedChlorobenzene0.78 Not Detected 3.4 Not DetectedEthyl Benzene0.78 Not Detected 3.4 Not Detectedm,p-Xylene0.78 Not Detected 3.4 Not Detectedo-Xylene0.78 Not Detected 3.3 Not DetectedStyrene0.78 Not Detected 5.3 Not Detected1,1,2,2-Tetrachloroethane0.78 Not Detected 3.8 Not Detected1,3,5-Trimethylbenzene0.78 Not Detected 3.8 Not Detected1,2,4-Trimethylbenzene0.78 Not Detected 4.6 Not Detected1,3-Dichlorobenzene0.78 Not Detected 4.6 Not Detected1,4-Dichlorobenzene0.78 Not Detected 4.0 Not Detectedalpha-Chlorotoluene0.78 Not Detected 4.6 Not Detected1,2-Dichlorobenzene0.78 Not Detected 1.7 Not Detected1,3-Butadiene0.78 Not Detected 2.7 Not DetectedHexane0.78 Not Detected 2.7 Not DetectedCyclohexane0.78 Not Detected 5.2 Not DetectedBromodichloromethane
Page 5 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMDC10Lab ID#: 0603207-01A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031213File Name:Dil. Factor: 1.55
Date of Collection: 3/7/06Date of Analysis: 3/12/06 08:00 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.78 Not Detected 6.6 Not DetectedDibromochloromethane0.78 Not Detected 3.2 Not DetectedHeptane0.78 Not Detected 3.8 Not DetectedCumene0.78 Not Detected 3.8 Not DetectedPropylbenzene3.1 Not Detected 6.4 Not DetectedChloromethane3.1 Not Detected 23 Not Detected1,2,4-Trichlorobenzene3.1 Not Detected 33 Not DetectedHexachlorobutadiene3.1 5.2 7.4 12Acetone
0.78 Not Detected 2.4 Not DetectedCarbon Disulfide3.1 Not Detected 7.6 Not Detected2-Propanol
0.78 Not Detected 3.1 Not Detectedtrans-1,2-Dichloroethene0.78 Not Detected 2.3 Not Detected2-Butanone (Methyl Ethyl Ketone)0.78 Not Detected 2.3 Not DetectedTetrahydrofuran3.1 Not Detected 11 Not Detected1,4-Dioxane
0.78 Not Detected 3.2 Not Detected4-Methyl-2-pentanone3.1 Not Detected 13 Not Detected2-Hexanone
0.78 Not Detected 8.0 Not DetectedBromoform0.78 Not Detected 3.8 Not Detected4-Ethyltoluene3.1 Not Detected 5.8 Not DetectedEthanol
0.78 Not Detected 2.8 Not DetectedMethyl tert-butyl ether0.78 Not Detected 3.6 Not Detected2,2,4-Trimethylpentane3.1 Not Detected 9.7 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
None Identified
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d891 70-1301,2-Dichloroethane-d4
101 70-1304-Bromofluorobenzene
Page 6 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMDL10Lab ID#: 0603207-02A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031214File Name:Dil. Factor: 1.52
Date of Collection: 3/7/06Date of Analysis: 3/12/06 09:40 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.76 Not Detected 3.8 Not DetectedFreon 120.76 Not Detected 5.3 Not DetectedFreon 1140.76 Not Detected 1.9 Not DetectedVinyl Chloride0.76 Not Detected 3.0 Not DetectedBromomethane0.76 Not Detected 2.0 Not DetectedChloroethane0.76 Not Detected 4.3 Not DetectedFreon 110.76 Not Detected 3.0 Not Detected1,1-Dichloroethene0.76 Not Detected 5.8 Not DetectedFreon 1130.76 Not Detected 2.6 Not DetectedMethylene Chloride0.76 Not Detected 3.1 Not Detected1,1-Dichloroethane0.76 Not Detected 3.0 Not Detectedcis-1,2-Dichloroethene0.76 Not Detected 3.7 Not DetectedChloroform0.76 Not Detected 4.1 Not Detected1,1,1-Trichloroethane0.76 Not Detected 4.8 Not DetectedCarbon Tetrachloride0.76 Not Detected 2.4 Not DetectedBenzene0.76 Not Detected 3.1 Not Detected1,2-Dichloroethane0.76 Not Detected 4.1 Not DetectedTrichloroethene0.76 Not Detected 3.5 Not Detected1,2-Dichloropropane0.76 Not Detected 3.4 Not Detectedcis-1,3-Dichloropropene0.76 Not Detected 2.9 Not DetectedToluene0.76 Not Detected 3.4 Not Detectedtrans-1,3-Dichloropropene0.76 Not Detected 4.1 Not Detected1,1,2-Trichloroethane0.76 Not Detected 5.2 Not DetectedTetrachloroethene0.76 Not Detected 5.8 Not Detected1,2-Dibromoethane (EDB)0.76 Not Detected 3.5 Not DetectedChlorobenzene0.76 Not Detected 3.3 Not DetectedEthyl Benzene0.76 Not Detected 3.3 Not Detectedm,p-Xylene0.76 Not Detected 3.3 Not Detectedo-Xylene0.76 Not Detected 3.2 Not DetectedStyrene0.76 Not Detected 5.2 Not Detected1,1,2,2-Tetrachloroethane0.76 Not Detected 3.7 Not Detected1,3,5-Trimethylbenzene0.76 Not Detected 3.7 Not Detected1,2,4-Trimethylbenzene0.76 Not Detected 4.6 Not Detected1,3-Dichlorobenzene0.76 Not Detected 4.6 Not Detected1,4-Dichlorobenzene0.76 Not Detected 3.9 Not Detectedalpha-Chlorotoluene0.76 Not Detected 4.6 Not Detected1,2-Dichlorobenzene0.76 Not Detected 1.7 Not Detected1,3-Butadiene0.76 Not Detected 2.7 Not DetectedHexane0.76 Not Detected 2.6 Not DetectedCyclohexane0.76 Not Detected 5.1 Not DetectedBromodichloromethane
Page 7 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMDL10Lab ID#: 0603207-02A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031214File Name:Dil. Factor: 1.52
Date of Collection: 3/7/06Date of Analysis: 3/12/06 09:40 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.76 Not Detected 6.5 Not DetectedDibromochloromethane0.76 Not Detected 3.1 Not DetectedHeptane0.76 Not Detected 3.7 Not DetectedCumene0.76 Not Detected 3.7 Not DetectedPropylbenzene3.0 Not Detected 6.3 Not DetectedChloromethane3.0 Not Detected 22 Not Detected1,2,4-Trichlorobenzene3.0 Not Detected 32 Not DetectedHexachlorobutadiene3.0 Not Detected 7.2 Not DetectedAcetone
0.76 Not Detected 2.4 Not DetectedCarbon Disulfide3.0 Not Detected 7.5 Not Detected2-Propanol
0.76 Not Detected 3.0 Not Detectedtrans-1,2-Dichloroethene0.76 Not Detected 2.2 Not Detected2-Butanone (Methyl Ethyl Ketone)0.76 Not Detected 2.2 Not DetectedTetrahydrofuran3.0 Not Detected 11 Not Detected1,4-Dioxane
0.76 Not Detected 3.1 Not Detected4-Methyl-2-pentanone3.0 Not Detected 12 Not Detected2-Hexanone
0.76 Not Detected 7.8 Not DetectedBromoform0.76 Not Detected 3.7 Not Detected4-Ethyltoluene3.0 Not Detected 5.7 Not DetectedEthanol
0.76 Not Detected 2.7 Not DetectedMethyl tert-butyl ether0.76 Not Detected 3.6 Not Detected2,2,4-Trimethylpentane3.0 Not Detected 9.5 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
None Identified
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
103 70-130Toluene-d892 70-1301,2-Dichloroethane-d4
104 70-1304-Bromofluorobenzene
Page 8 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMDR10Lab ID#: 0603207-03A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031215File Name:Dil. Factor: 1.58
Date of Collection: 3/7/06Date of Analysis: 3/12/06 10:34 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.79 Not Detected 3.9 Not DetectedFreon 120.79 Not Detected 5.5 Not DetectedFreon 1140.79 Not Detected 2.0 Not DetectedVinyl Chloride0.79 Not Detected 3.1 Not DetectedBromomethane0.79 Not Detected 2.1 Not DetectedChloroethane0.79 Not Detected 4.4 Not DetectedFreon 110.79 Not Detected 3.1 Not Detected1,1-Dichloroethene0.79 Not Detected 6.0 Not DetectedFreon 1130.79 Not Detected 2.7 Not DetectedMethylene Chloride0.79 Not Detected 3.2 Not Detected1,1-Dichloroethane0.79 Not Detected 3.1 Not Detectedcis-1,2-Dichloroethene0.79 Not Detected 3.8 Not DetectedChloroform0.79 Not Detected 4.3 Not Detected1,1,1-Trichloroethane0.79 Not Detected 5.0 Not DetectedCarbon Tetrachloride0.79 Not Detected 2.5 Not DetectedBenzene0.79 Not Detected 3.2 Not Detected1,2-Dichloroethane0.79 Not Detected 4.2 Not DetectedTrichloroethene0.79 Not Detected 3.6 Not Detected1,2-Dichloropropane0.79 Not Detected 3.6 Not Detectedcis-1,3-Dichloropropene0.79 Not Detected 3.0 Not DetectedToluene0.79 Not Detected 3.6 Not Detectedtrans-1,3-Dichloropropene0.79 Not Detected 4.3 Not Detected1,1,2-Trichloroethane0.79 Not Detected 5.4 Not DetectedTetrachloroethene0.79 Not Detected 6.1 Not Detected1,2-Dibromoethane (EDB)0.79 Not Detected 3.6 Not DetectedChlorobenzene0.79 Not Detected 3.4 Not DetectedEthyl Benzene0.79 Not Detected 3.4 Not Detectedm,p-Xylene0.79 Not Detected 3.4 Not Detectedo-Xylene0.79 Not Detected 3.4 Not DetectedStyrene0.79 Not Detected 5.4 Not Detected1,1,2,2-Tetrachloroethane0.79 Not Detected 3.9 Not Detected1,3,5-Trimethylbenzene0.79 Not Detected 3.9 Not Detected1,2,4-Trimethylbenzene0.79 Not Detected 4.8 Not Detected1,3-Dichlorobenzene0.79 Not Detected 4.8 Not Detected1,4-Dichlorobenzene0.79 Not Detected 4.1 Not Detectedalpha-Chlorotoluene0.79 Not Detected 4.7 Not Detected1,2-Dichlorobenzene0.79 Not Detected 1.7 Not Detected1,3-Butadiene0.79 Not Detected 2.8 Not DetectedHexane0.79 Not Detected 2.7 Not DetectedCyclohexane0.79 Not Detected 5.3 Not DetectedBromodichloromethane
Page 9 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMDR10Lab ID#: 0603207-03A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031215File Name:Dil. Factor: 1.58
Date of Collection: 3/7/06Date of Analysis: 3/12/06 10:34 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.79 Not Detected 6.7 Not DetectedDibromochloromethane0.79 Not Detected 3.2 Not DetectedHeptane0.79 Not Detected 3.9 Not DetectedCumene0.79 Not Detected 3.9 Not DetectedPropylbenzene3.2 Not Detected 6.5 Not DetectedChloromethane3.2 Not Detected 23 Not Detected1,2,4-Trichlorobenzene3.2 Not Detected 34 Not DetectedHexachlorobutadiene3.2 3.5 7.5 8.4Acetone
0.79 Not Detected 2.5 Not DetectedCarbon Disulfide3.2 Not Detected 7.8 Not Detected2-Propanol
0.79 Not Detected 3.1 Not Detectedtrans-1,2-Dichloroethene0.79 Not Detected 2.3 Not Detected2-Butanone (Methyl Ethyl Ketone)0.79 Not Detected 2.3 Not DetectedTetrahydrofuran3.2 Not Detected 11 Not Detected1,4-Dioxane
0.79 Not Detected 3.2 Not Detected4-Methyl-2-pentanone3.2 Not Detected 13 Not Detected2-Hexanone
0.79 Not Detected 8.2 Not DetectedBromoform0.79 Not Detected 3.9 Not Detected4-Ethyltoluene3.2 Not Detected 6.0 Not DetectedEthanol
0.79 Not Detected 2.8 Not DetectedMethyl tert-butyl ether0.79 Not Detected 3.7 Not Detected2,2,4-Trimethylpentane3.2 Not Detected 9.9 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
624-92-0 97% 7.8 N JDisulfide, dimethyl
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
101 70-130Toluene-d892 70-1301,2-Dichloroethane-d4
102 70-1304-Bromofluorobenzene
Page 10 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMU10Lab ID#: 0603207-04A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031216File Name:Dil. Factor: 1.49
Date of Collection: 3/7/06Date of Analysis: 3/12/06 11:44 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.74 Not Detected 3.7 Not DetectedFreon 120.74 Not Detected 5.2 Not DetectedFreon 1140.74 Not Detected 1.9 Not DetectedVinyl Chloride0.74 Not Detected 2.9 Not DetectedBromomethane0.74 Not Detected 2.0 Not DetectedChloroethane0.74 Not Detected 4.2 Not DetectedFreon 110.74 Not Detected 3.0 Not Detected1,1-Dichloroethene0.74 Not Detected 5.7 Not DetectedFreon 1130.74 Not Detected 2.6 Not DetectedMethylene Chloride0.74 Not Detected 3.0 Not Detected1,1-Dichloroethane0.74 Not Detected 3.0 Not Detectedcis-1,2-Dichloroethene0.74 Not Detected 3.6 Not DetectedChloroform0.74 Not Detected 4.1 Not Detected1,1,1-Trichloroethane0.74 Not Detected 4.7 Not DetectedCarbon Tetrachloride0.74 Not Detected 2.4 Not DetectedBenzene0.74 Not Detected 3.0 Not Detected1,2-Dichloroethane0.74 Not Detected 4.0 Not DetectedTrichloroethene0.74 Not Detected 3.4 Not Detected1,2-Dichloropropane0.74 Not Detected 3.4 Not Detectedcis-1,3-Dichloropropene0.74 Not Detected 2.8 Not DetectedToluene0.74 Not Detected 3.4 Not Detectedtrans-1,3-Dichloropropene0.74 Not Detected 4.1 Not Detected1,1,2-Trichloroethane0.74 Not Detected 5.0 Not DetectedTetrachloroethene0.74 Not Detected 5.7 Not Detected1,2-Dibromoethane (EDB)0.74 Not Detected 3.4 Not DetectedChlorobenzene0.74 Not Detected 3.2 Not DetectedEthyl Benzene0.74 Not Detected 3.2 Not Detectedm,p-Xylene0.74 Not Detected 3.2 Not Detectedo-Xylene0.74 Not Detected 3.2 Not DetectedStyrene0.74 Not Detected 5.1 Not Detected1,1,2,2-Tetrachloroethane0.74 Not Detected 3.7 Not Detected1,3,5-Trimethylbenzene0.74 Not Detected 3.7 Not Detected1,2,4-Trimethylbenzene0.74 Not Detected 4.5 Not Detected1,3-Dichlorobenzene0.74 Not Detected 4.5 Not Detected1,4-Dichlorobenzene0.74 Not Detected 3.8 Not Detectedalpha-Chlorotoluene0.74 Not Detected 4.5 Not Detected1,2-Dichlorobenzene0.74 Not Detected 1.6 Not Detected1,3-Butadiene0.74 Not Detected 2.6 Not DetectedHexane0.74 Not Detected 2.6 Not DetectedCyclohexane0.74 Not Detected 5.0 Not DetectedBromodichloromethane
Page 11 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 2AMU10Lab ID#: 0603207-04A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031216File Name:Dil. Factor: 1.49
Date of Collection: 3/7/06Date of Analysis: 3/12/06 11:44 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.74 Not Detected 6.3 Not DetectedDibromochloromethane0.74 Not Detected 3.0 Not DetectedHeptane0.74 Not Detected 3.7 Not DetectedCumene0.74 Not Detected 3.7 Not DetectedPropylbenzene3.0 Not Detected 6.2 Not DetectedChloromethane3.0 Not Detected 22 Not Detected1,2,4-Trichlorobenzene3.0 Not Detected 32 Not DetectedHexachlorobutadiene3.0 Not Detected 7.1 Not DetectedAcetone
0.74 Not Detected 2.3 Not DetectedCarbon Disulfide3.0 Not Detected 7.3 Not Detected2-Propanol
0.74 Not Detected 3.0 Not Detectedtrans-1,2-Dichloroethene0.74 Not Detected 2.2 Not Detected2-Butanone (Methyl Ethyl Ketone)0.74 Not Detected 2.2 Not DetectedTetrahydrofuran3.0 Not Detected 11 Not Detected1,4-Dioxane
0.74 Not Detected 3.0 Not Detected4-Methyl-2-pentanone3.0 Not Detected 12 Not Detected2-Hexanone
0.74 Not Detected 7.7 Not DetectedBromoform0.74 Not Detected 3.7 Not Detected4-Ethyltoluene3.0 Not Detected 5.6 Not DetectedEthanol
0.74 Not Detected 2.7 Not DetectedMethyl tert-butyl ether0.74 Not Detected 3.5 Not Detected2,2,4-Trimethylpentane3.0 Not Detected 9.3 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
None Identified
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
101 70-130Toluene-d893 70-1301,2-Dichloroethane-d4
101 70-1304-Bromofluorobenzene
Page 12 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab BlankLab ID#: 0603207-05A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031207File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 3/12/06 02:32 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.50 Not Detected 2.5 Not DetectedFreon 120.50 Not Detected 3.5 Not DetectedFreon 1140.50 Not Detected 1.3 Not DetectedVinyl Chloride0.50 Not Detected 1.9 Not DetectedBromomethane0.50 Not Detected 1.3 Not DetectedChloroethane0.50 Not Detected 2.8 Not DetectedFreon 110.50 Not Detected 2.0 Not Detected1,1-Dichloroethene0.50 Not Detected 3.8 Not DetectedFreon 1130.50 Not Detected 1.7 Not DetectedMethylene Chloride0.50 Not Detected 2.0 Not Detected1,1-Dichloroethane0.50 Not Detected 2.0 Not Detectedcis-1,2-Dichloroethene0.50 Not Detected 2.4 Not DetectedChloroform0.50 Not Detected 2.7 Not Detected1,1,1-Trichloroethane0.50 Not Detected 3.1 Not DetectedCarbon Tetrachloride0.50 Not Detected 1.6 Not DetectedBenzene0.50 Not Detected 2.0 Not Detected1,2-Dichloroethane0.50 Not Detected 2.7 Not DetectedTrichloroethene0.50 Not Detected 2.3 Not Detected1,2-Dichloropropane0.50 Not Detected 2.3 Not Detectedcis-1,3-Dichloropropene0.50 Not Detected 1.9 Not DetectedToluene0.50 Not Detected 2.3 Not Detectedtrans-1,3-Dichloropropene0.50 Not Detected 2.7 Not Detected1,1,2-Trichloroethane0.50 Not Detected 3.4 Not DetectedTetrachloroethene0.50 Not Detected 3.8 Not Detected1,2-Dibromoethane (EDB)0.50 Not Detected 2.3 Not DetectedChlorobenzene0.50 Not Detected 2.2 Not DetectedEthyl Benzene0.50 Not Detected 2.2 Not Detectedm,p-Xylene0.50 Not Detected 2.2 Not Detectedo-Xylene0.50 Not Detected 2.1 Not DetectedStyrene0.50 Not Detected 3.4 Not Detected1,1,2,2-Tetrachloroethane0.50 Not Detected 2.4 Not Detected1,3,5-Trimethylbenzene0.50 Not Detected 2.4 Not Detected1,2,4-Trimethylbenzene0.50 Not Detected 3.0 Not Detected1,3-Dichlorobenzene0.50 Not Detected 3.0 Not Detected1,4-Dichlorobenzene0.50 Not Detected 2.6 Not Detectedalpha-Chlorotoluene0.50 Not Detected 3.0 Not Detected1,2-Dichlorobenzene0.50 Not Detected 1.1 Not Detected1,3-Butadiene0.50 Not Detected 1.8 Not DetectedHexane0.50 Not Detected 1.7 Not DetectedCyclohexane0.50 Not Detected 3.4 Not DetectedBromodichloromethane
Page 13 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab BlankLab ID#: 0603207-05A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031207File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 3/12/06 02:32 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.50 Not Detected 4.2 Not DetectedDibromochloromethane0.50 Not Detected 2.0 Not DetectedHeptane0.50 Not Detected 2.4 Not DetectedCumene0.50 Not Detected 2.4 Not DetectedPropylbenzene2.0 Not Detected 4.1 Not DetectedChloromethane2.0 Not Detected 15 Not Detected1,2,4-Trichlorobenzene2.0 Not Detected 21 Not DetectedHexachlorobutadiene2.0 Not Detected 4.8 Not DetectedAcetone
0.50 Not Detected 1.6 Not DetectedCarbon Disulfide2.0 Not Detected 4.9 Not Detected2-Propanol
0.50 Not Detected 2.0 Not Detectedtrans-1,2-Dichloroethene0.50 Not Detected 1.5 Not Detected2-Butanone (Methyl Ethyl Ketone)0.50 Not Detected 1.5 Not DetectedTetrahydrofuran2.0 Not Detected 7.2 Not Detected1,4-Dioxane
0.50 Not Detected 2.0 Not Detected4-Methyl-2-pentanone2.0 Not Detected 8.2 Not Detected2-Hexanone
0.50 Not Detected 5.2 Not DetectedBromoform0.50 Not Detected 2.4 Not Detected4-Ethyltoluene2.0 Not Detected 3.8 Not DetectedEthanol
0.50 Not Detected 1.8 Not DetectedMethyl tert-butyl ether0.50 Not Detected 2.3 Not Detected2,2,4-Trimethylpentane2.0 Not Detected 6.3 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
None Identified
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
101 70-130Toluene-d892 70-1301,2-Dichloroethane-d4
100 70-1304-Bromofluorobenzene
Page 14 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCVLab ID#: 0603207-06A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031202File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 3/12/06 10:16 AM
%RecoveryCompound
100Freon 12100Freon 114103Vinyl Chloride105Bromomethane108Chloroethane102Freon 111041,1-Dichloroethene103Freon 11399Methylene Chloride
1031,1-Dichloroethane105cis-1,2-Dichloroethene100Chloroform1061,1,1-Trichloroethane107Carbon Tetrachloride100Benzene1051,2-Dichloroethane106Trichloroethene1051,2-Dichloropropane111cis-1,3-Dichloropropene103Toluene108trans-1,3-Dichloropropene1051,1,2-Trichloroethane106Tetrachloroethene1071,2-Dibromoethane (EDB)101Chlorobenzene104Ethyl Benzene95m,p-Xylene
102o-Xylene101Styrene941,1,2,2-Tetrachloroethane981,3,5-Trimethylbenzene981,2,4-Trimethylbenzene931,3-Dichlorobenzene941,4-Dichlorobenzene
102alpha-Chlorotoluene941,2-Dichlorobenzene
1041,3-Butadiene106Hexane107Cyclohexane111Bromodichloromethane
Page 15 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCVLab ID#: 0603207-06A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031202File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 3/12/06 10:16 AM
%RecoveryCompound
113Dibromochloromethane111Heptane93Cumene99Propylbenzene96Chloromethane
1011,2,4-Trichlorobenzene109Hexachlorobutadiene100Acetone104Carbon Disulfide1042-Propanol102trans-1,2-Dichloroethene1142-Butanone (Methyl Ethyl Ketone)108Tetrahydrofuran1041,4-Dioxane1124-Methyl-2-pentanone1022-Hexanone111Bromoform1034-Ethyltoluene100Ethanol113Methyl tert-butyl ether1072,2,4-Trimethylpentane1023-Chloropropene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d8104 70-1301,2-Dichloroethane-d499 70-1304-Bromofluorobenzene
Page 16 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCSLab ID#: 0603207-07A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031203File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 3/12/06 11:01 AM
%RecoveryCompound
98Freon 12100Freon 114103Vinyl Chloride106Bromomethane112Chloroethane101Freon 111041,1-Dichloroethene102Freon 113101Methylene Chloride1041,1-Dichloroethane105cis-1,2-Dichloroethene99Chloroform
1031,1,1-Trichloroethane104Carbon Tetrachloride100Benzene1051,2-Dichloroethane106Trichloroethene1051,2-Dichloropropane97cis-1,3-Dichloropropene
103Toluene64 Qtrans-1,3-Dichloropropene1061,1,2-Trichloroethane106Tetrachloroethene1071,2-Dibromoethane (EDB)103Chlorobenzene109Ethyl Benzene93m,p-Xylene94o-Xylene
105Styrene981,1,2,2-Tetrachloroethane921,3,5-Trimethylbenzene761,2,4-Trimethylbenzene
1001,3-Dichlorobenzene1001,4-Dichlorobenzene89alpha-Chlorotoluene
1001,2-Dichlorobenzene1191,3-Butadiene111Hexane106Cyclohexane103Bromodichloromethane
Page 17 of 18
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCSLab ID#: 0603207-07A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f031203File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 3/12/06 11:01 AM
%RecoveryCompound
102Dibromochloromethane107Heptane86Cumene92Propylbenzene95Chloromethane
1121,2,4-Trichlorobenzene111Hexachlorobutadiene106Acetone114Carbon Disulfide1072-Propanol107trans-1,2-Dichloroethene1162-Butanone (Methyl Ethyl Ketone)109Tetrahydrofuran1031,4-Dioxane1114-Methyl-2-pentanone982-Hexanone86Bromoform964-Ethyltoluene
105Ethanol114Methyl tert-butyl ether1012,2,4-Trimethylpentane1053-Chloropropene
Q = Exceeds Quality Control limits.Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d8101 70-1301,2-Dichloroethane-d4100 70-1304-Bromofluorobenzene
Page 18 of 18
AIR TOXICS LTD.@AN ENVIRONMENTAL ANALYTICAL LABORATORY
Air Toxics Ltd. Introduces the Electronic Report
Thank you for choosing Air Toxics Ltd. To better serve our customers, we are providing your report by e-mail. This document is provided in Portable Document Format which can be viewed with Acrobat Reader by Adobe.
This electronic report includes the following:• Work order Summary;• Laboratory Narrative;• Results; and• Chain of Custody (copy).
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630
(916) 985-1000 .FAX (916) 985-1020Hours 8:00 A.M to 6:00 P.M. Pacific
AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
@
Mr. Felix MoranEnviron International740 Waukegan RoadSuite 401Deerfield, IL 60015
WORK ORDER #: 0602429
CLIENT: BILL TO:
PHONE:
Mr. Felix MoranEnviron International740 Waukegan RoadSuite 401Deerfield, IL 60015
847-444-9200
847-444-9420
02/21/2006DATE COMPLETED: 02/27/2006
P.O. #
PROJECT # 21-8601AJ Midco II
Work Order Summary
FAX:
DATE RECEIVED: CONTACT: Susan Alaniz
NAMEFRACTION # TEST VAC./PRES.RECEIPT
01A 2AMDWR09 Modified TO-15 6.0 "Hg02A 2AMU09 Modified TO-15 6.0 "Hg03A 2AMDWC09 Modified TO-15 5.5 "Hg04A 2AMDWL09 Modified TO-15 5.5 "Hg05A Lab Blank Modified TO-15 NA06A CCV Modified TO-15 NA07A LCS Modified TO-15 NA
CERTIFIED BY:
Laboratory Director
DATE:
Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, Expiration date: 06/30/06
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020
02/28/06
Page 1 of 18
This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards
Certfication numbers: AR DEQ - 03-084-0, CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004NY NELAP - 11291, UT NELAP - 9166389892
LABORATORY NARRATIVEModified TO-15
Environ InternationalWorkorder# 0602429
Four 6 Liter Summa Canister samples were received on February 21, 2006. The laboratory performed analysis via modified EPA Method TO-15 using GC/MS in the full scan mode. The method involvesconcentrating up to 0.2 liters of air. The concentrated aliquot is then flash vaporized and swept through awater management system to remove water vapor. Following dehumidification, the sample passes directlyinto the GC/MS for analysis.
Method modifications taken to run these samples are summarized in the below table. Specific projectrequirements may over-ride the ATL modifications.
Requirement ATL ModificationsTO-15Daily CCV +- 30% Difference </= 30% Difference with two allowed out up to </=40%.;
flag and narrate outliers
Sample collection media Summa canister ATL recommends use of summa canisters to insure data defensibility, but will report results from Tedlar bags at client request
Method Detection Limit Follow 40CFR Pt.136 App. B
The MDL met all relevant requirements in Method TO-15 (statistical MDL less than the LOQ). The concentration of the spiked replicate may have exceeded 10X the calculated MDL in some cases
Receiving Notes
There were no receiving discrepancies.
All Quality Control Limit failures and affected sample results are noted by flags. Each flag is defined at thebottom of this Case Narrative and on each Sample Result Summary page. Target compound non-detects inthe samples that are associated with high bias in QC analyses have not been flagged.
The reported LCS for each daily batch has been derived from more than one analytical file.
Analytical Notes
Eight qualifiers may have been used on the data analysis sheets and indicates as follows: B - Compound present in laboratory blank greater than reporting limit (background subtraction notperformed). J - Estimated value. E - Exceeds instrument calibration range. S - Saturated peak. Q - Exceeds quality control limits. U - Compound analyzed for but not detected above the reporting limit. UJ- Non-detected compound associated with low bias in the CCV N - The identification is based on presumptive evidence.
Definition of Data Qualifying Flags
Page 2 of 18
File extensions may have been used on the data analysis sheets and indicates as follows: a-File was requantified b-File was quantified by a second column and detector r1-File was requantified for the purpose of reissue
Page 3 of 18
AIR TOXICS LTD.
MODIFIED EPA METHOD TO-15 GC/MS FULL SCANSummary of Detected Compounds
Client Sample ID: 2AMDWR09
Lab ID#: 0602429-01ANo Detections Were Found.
Client Sample ID: 2AMU09
Lab ID#: 0602429-02ANo Detections Were Found.
Client Sample ID: 2AMDWC09
Lab ID#: 0602429-03A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
3.3 3.6 7.8 8.6Acetone
Client Sample ID: 2AMDWL09
Lab ID#: 0602429-04ANo Detections Were Found.
Page 4 of 18
Client Sample ID: 2AMDWR09
Lab ID#: 0602429-01AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1022614File Name:
AIR TOXICS LTD.
Dil. Factor: 1.68Date of Collection: 2/17/06Date of Analysis: 2/26/06 10:08 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.84 Not Detected 4.2 Not DetectedFreon 120.84 Not Detected 5.9 Not DetectedFreon 1143.4 Not Detected 6.9 Not DetectedChloromethane
0.84 Not Detected 2.1 Not DetectedVinyl Chloride0.84 Not Detected 1.8 Not Detected1,3-Butadiene0.84 Not Detected 3.3 Not DetectedBromomethane0.84 Not Detected 2.2 Not DetectedChloroethane0.84 Not Detected 4.7 Not DetectedFreon 113.4 Not Detected 6.3 Not DetectedEthanol
0.84 Not Detected 6.4 Not DetectedFreon 1130.84 Not Detected 3.3 Not Detected1,1-Dichloroethene3.4 Not Detected 8.0 Not DetectedAcetone3.4 Not Detected 8.2 Not Detected2-Propanol
0.84 Not Detected 2.6 Not DetectedCarbon Disulfide3.4 Not Detected 10 Not Detected3-Chloropropene
0.84 Not Detected 2.9 Not DetectedMethylene Chloride0.84 Not Detected 3.0 Not DetectedMethyl tert-butyl ether0.84 Not Detected 3.3 Not Detectedtrans-1,2-Dichloroethene0.84 Not Detected 3.0 Not DetectedHexane0.84 Not Detected 3.4 Not Detected1,1-Dichloroethane0.84 Not Detected 2.5 Not Detected2-Butanone (Methyl Ethyl Ketone)0.84 Not Detected 3.3 Not Detectedcis-1,2-Dichloroethene0.84 Not Detected 2.5 Not DetectedTetrahydrofuran0.84 Not Detected 4.1 Not DetectedChloroform0.84 Not Detected 4.6 Not Detected1,1,1-Trichloroethane0.84 Not Detected 2.9 Not DetectedCyclohexane0.84 Not Detected 5.3 Not DetectedCarbon Tetrachloride0.84 Not Detected 3.9 Not Detected2,2,4-Trimethylpentane0.84 Not Detected 2.7 Not DetectedBenzene0.84 Not Detected 3.4 Not Detected1,2-Dichloroethane0.84 Not Detected 3.4 Not DetectedHeptane0.84 Not Detected 4.5 Not DetectedTrichloroethene0.84 Not Detected 3.9 Not Detected1,2-Dichloropropane3.4 Not Detected 12 Not Detected1,4-Dioxane
0.84 Not Detected 5.6 Not DetectedBromodichloromethane0.84 Not Detected 3.8 Not Detectedcis-1,3-Dichloropropene0.84 Not Detected 3.4 Not Detected4-Methyl-2-pentanone0.84 Not Detected 3.2 Not DetectedToluene0.84 Not Detected 3.8 Not Detectedtrans-1,3-Dichloropropene0.84 Not Detected 4.6 Not Detected1,1,2-Trichloroethane0.84 Not Detected 5.7 Not DetectedTetrachloroethene3.4 Not Detected 14 Not Detected2-Hexanone
Page 5 of 18
Client Sample ID: 2AMDWR09
Lab ID#: 0602429-01AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1022614File Name:
AIR TOXICS LTD.
Dil. Factor: 1.68Date of Collection: 2/17/06Date of Analysis: 2/26/06 10:08 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.84 Not Detected 7.2 Not DetectedDibromochloromethane0.84 Not Detected 6.4 Not Detected1,2-Dibromoethane (EDB)0.84 Not Detected 3.9 Not DetectedChlorobenzene0.84 Not Detected 3.6 Not DetectedEthyl Benzene0.84 Not Detected 3.6 Not Detectedm,p-Xylene0.84 Not Detected 3.6 Not Detectedo-Xylene0.84 Not Detected 3.6 Not DetectedStyrene0.84 Not Detected 8.7 Not DetectedBromoform0.84 Not Detected 4.1 Not DetectedCumene0.84 Not Detected 5.8 Not Detected1,1,2,2-Tetrachloroethane0.84 Not Detected 4.1 Not DetectedPropylbenzene0.84 Not Detected 4.1 Not Detected4-Ethyltoluene0.84 Not Detected 4.1 Not Detected1,3,5-Trimethylbenzene0.84 Not Detected 4.1 Not Detected1,2,4-Trimethylbenzene0.84 Not Detected 5.0 Not Detected1,3-Dichlorobenzene0.84 Not Detected 5.0 Not Detected1,4-Dichlorobenzene0.84 Not Detected 4.3 Not Detectedalpha-Chlorotoluene0.84 Not Detected 5.0 Not Detected1,2-Dichlorobenzene3.4 Not Detected 25 Not Detected1,2,4-Trichlorobenzene3.4 Not Detected 36 Not DetectedHexachlorobutadiene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d8104 70-1301,2-Dichloroethane-d498 70-1304-Bromofluorobenzene
Page 6 of 18
Client Sample ID: 2AMU09
Lab ID#: 0602429-02AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1022615File Name:
AIR TOXICS LTD.
Dil. Factor: 1.68Date of Collection: 2/17/06Date of Analysis: 2/26/06 10:51 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.84 Not Detected 4.2 Not DetectedFreon 120.84 Not Detected 5.9 Not DetectedFreon 1143.4 Not Detected 6.9 Not DetectedChloromethane
0.84 Not Detected 2.1 Not DetectedVinyl Chloride0.84 Not Detected 1.8 Not Detected1,3-Butadiene0.84 Not Detected 3.3 Not DetectedBromomethane0.84 Not Detected 2.2 Not DetectedChloroethane0.84 Not Detected 4.7 Not DetectedFreon 113.4 Not Detected 6.3 Not DetectedEthanol
0.84 Not Detected 6.4 Not DetectedFreon 1130.84 Not Detected 3.3 Not Detected1,1-Dichloroethene3.4 Not Detected 8.0 Not DetectedAcetone3.4 Not Detected 8.2 Not Detected2-Propanol
0.84 Not Detected 2.6 Not DetectedCarbon Disulfide3.4 Not Detected 10 Not Detected3-Chloropropene
0.84 Not Detected 2.9 Not DetectedMethylene Chloride0.84 Not Detected 3.0 Not DetectedMethyl tert-butyl ether0.84 Not Detected 3.3 Not Detectedtrans-1,2-Dichloroethene0.84 Not Detected 3.0 Not DetectedHexane0.84 Not Detected 3.4 Not Detected1,1-Dichloroethane0.84 Not Detected 2.5 Not Detected2-Butanone (Methyl Ethyl Ketone)0.84 Not Detected 3.3 Not Detectedcis-1,2-Dichloroethene0.84 Not Detected 2.5 Not DetectedTetrahydrofuran0.84 Not Detected 4.1 Not DetectedChloroform0.84 Not Detected 4.6 Not Detected1,1,1-Trichloroethane0.84 Not Detected 2.9 Not DetectedCyclohexane0.84 Not Detected 5.3 Not DetectedCarbon Tetrachloride0.84 Not Detected 3.9 Not Detected2,2,4-Trimethylpentane0.84 Not Detected 2.7 Not DetectedBenzene0.84 Not Detected 3.4 Not Detected1,2-Dichloroethane0.84 Not Detected 3.4 Not DetectedHeptane0.84 Not Detected 4.5 Not DetectedTrichloroethene0.84 Not Detected 3.9 Not Detected1,2-Dichloropropane3.4 Not Detected 12 Not Detected1,4-Dioxane
0.84 Not Detected 5.6 Not DetectedBromodichloromethane0.84 Not Detected 3.8 Not Detectedcis-1,3-Dichloropropene0.84 Not Detected 3.4 Not Detected4-Methyl-2-pentanone0.84 Not Detected 3.2 Not DetectedToluene0.84 Not Detected 3.8 Not Detectedtrans-1,3-Dichloropropene0.84 Not Detected 4.6 Not Detected1,1,2-Trichloroethane0.84 Not Detected 5.7 Not DetectedTetrachloroethene3.4 Not Detected 14 Not Detected2-Hexanone
Page 7 of 18
Client Sample ID: 2AMU09
Lab ID#: 0602429-02AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1022615File Name:
AIR TOXICS LTD.
Dil. Factor: 1.68Date of Collection: 2/17/06Date of Analysis: 2/26/06 10:51 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.84 Not Detected 7.2 Not DetectedDibromochloromethane0.84 Not Detected 6.4 Not Detected1,2-Dibromoethane (EDB)0.84 Not Detected 3.9 Not DetectedChlorobenzene0.84 Not Detected 3.6 Not DetectedEthyl Benzene0.84 Not Detected 3.6 Not Detectedm,p-Xylene0.84 Not Detected 3.6 Not Detectedo-Xylene0.84 Not Detected 3.6 Not DetectedStyrene0.84 Not Detected 8.7 Not DetectedBromoform0.84 Not Detected 4.1 Not DetectedCumene0.84 Not Detected 5.8 Not Detected1,1,2,2-Tetrachloroethane0.84 Not Detected 4.1 Not DetectedPropylbenzene0.84 Not Detected 4.1 Not Detected4-Ethyltoluene0.84 Not Detected 4.1 Not Detected1,3,5-Trimethylbenzene0.84 Not Detected 4.1 Not Detected1,2,4-Trimethylbenzene0.84 Not Detected 5.0 Not Detected1,3-Dichlorobenzene0.84 Not Detected 5.0 Not Detected1,4-Dichlorobenzene0.84 Not Detected 4.3 Not Detectedalpha-Chlorotoluene0.84 Not Detected 5.0 Not Detected1,2-Dichlorobenzene3.4 Not Detected 25 Not Detected1,2,4-Trichlorobenzene3.4 Not Detected 36 Not DetectedHexachlorobutadiene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
101 70-130Toluene-d8104 70-1301,2-Dichloroethane-d499 70-1304-Bromofluorobenzene
Page 8 of 18
Client Sample ID: 2AMDWC09
Lab ID#: 0602429-03AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1022616File Name:
AIR TOXICS LTD.
Dil. Factor: 1.64Date of Collection: 2/17/06Date of Analysis: 2/26/06 11:28 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.82 Not Detected 4.0 Not DetectedFreon 120.82 Not Detected 5.7 Not DetectedFreon 1143.3 Not Detected 6.8 Not DetectedChloromethane
0.82 Not Detected 2.1 Not DetectedVinyl Chloride0.82 Not Detected 1.8 Not Detected1,3-Butadiene0.82 Not Detected 3.2 Not DetectedBromomethane0.82 Not Detected 2.2 Not DetectedChloroethane0.82 Not Detected 4.6 Not DetectedFreon 113.3 Not Detected 6.2 Not DetectedEthanol
0.82 Not Detected 6.3 Not DetectedFreon 1130.82 Not Detected 3.2 Not Detected1,1-Dichloroethene3.3 3.6 7.8 8.6Acetone3.3 Not Detected 8.1 Not Detected2-Propanol
0.82 Not Detected 2.6 Not DetectedCarbon Disulfide3.3 Not Detected 10 Not Detected3-Chloropropene
0.82 Not Detected 2.8 Not DetectedMethylene Chloride0.82 Not Detected 3.0 Not DetectedMethyl tert-butyl ether0.82 Not Detected 3.2 Not Detectedtrans-1,2-Dichloroethene0.82 Not Detected 2.9 Not DetectedHexane0.82 Not Detected 3.3 Not Detected1,1-Dichloroethane0.82 Not Detected 2.4 Not Detected2-Butanone (Methyl Ethyl Ketone)0.82 Not Detected 3.2 Not Detectedcis-1,2-Dichloroethene0.82 Not Detected 2.4 Not DetectedTetrahydrofuran0.82 Not Detected 4.0 Not DetectedChloroform0.82 Not Detected 4.5 Not Detected1,1,1-Trichloroethane0.82 Not Detected 2.8 Not DetectedCyclohexane0.82 Not Detected 5.2 Not DetectedCarbon Tetrachloride0.82 Not Detected 3.8 Not Detected2,2,4-Trimethylpentane0.82 Not Detected 2.6 Not DetectedBenzene0.82 Not Detected 3.3 Not Detected1,2-Dichloroethane0.82 Not Detected 3.4 Not DetectedHeptane0.82 Not Detected 4.4 Not DetectedTrichloroethene0.82 Not Detected 3.8 Not Detected1,2-Dichloropropane3.3 Not Detected 12 Not Detected1,4-Dioxane
0.82 Not Detected 5.5 Not DetectedBromodichloromethane0.82 Not Detected 3.7 Not Detectedcis-1,3-Dichloropropene0.82 Not Detected 3.4 Not Detected4-Methyl-2-pentanone0.82 Not Detected 3.1 Not DetectedToluene0.82 Not Detected 3.7 Not Detectedtrans-1,3-Dichloropropene0.82 Not Detected 4.5 Not Detected1,1,2-Trichloroethane0.82 Not Detected 5.6 Not DetectedTetrachloroethene3.3 Not Detected 13 Not Detected2-Hexanone
Page 9 of 18
Client Sample ID: 2AMDWC09
Lab ID#: 0602429-03AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1022616File Name:
AIR TOXICS LTD.
Dil. Factor: 1.64Date of Collection: 2/17/06Date of Analysis: 2/26/06 11:28 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.82 Not Detected 7.0 Not DetectedDibromochloromethane0.82 Not Detected 6.3 Not Detected1,2-Dibromoethane (EDB)0.82 Not Detected 3.8 Not DetectedChlorobenzene0.82 Not Detected 3.6 Not DetectedEthyl Benzene0.82 Not Detected 3.6 Not Detectedm,p-Xylene0.82 Not Detected 3.6 Not Detectedo-Xylene0.82 Not Detected 3.5 Not DetectedStyrene0.82 Not Detected 8.5 Not DetectedBromoform0.82 Not Detected 4.0 Not DetectedCumene0.82 Not Detected 5.6 Not Detected1,1,2,2-Tetrachloroethane0.82 Not Detected 4.0 Not DetectedPropylbenzene0.82 Not Detected 4.0 Not Detected4-Ethyltoluene0.82 Not Detected 4.0 Not Detected1,3,5-Trimethylbenzene0.82 Not Detected 4.0 Not Detected1,2,4-Trimethylbenzene0.82 Not Detected 4.9 Not Detected1,3-Dichlorobenzene0.82 Not Detected 4.9 Not Detected1,4-Dichlorobenzene0.82 Not Detected 4.2 Not Detectedalpha-Chlorotoluene0.82 Not Detected 4.9 Not Detected1,2-Dichlorobenzene3.3 Not Detected 24 Not Detected1,2,4-Trichlorobenzene3.3 Not Detected 35 Not DetectedHexachlorobutadiene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
102 70-130Toluene-d8104 70-1301,2-Dichloroethane-d499 70-1304-Bromofluorobenzene
Page 10 of 18
Client Sample ID: 2AMDWL09
Lab ID#: 0602429-04AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1022617File Name:
AIR TOXICS LTD.
Dil. Factor: 1.64Date of Collection: 2/17/06Date of Analysis: 2/27/06 12:18 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.82 Not Detected 4.0 Not DetectedFreon 120.82 Not Detected 5.7 Not DetectedFreon 1143.3 Not Detected 6.8 Not DetectedChloromethane
0.82 Not Detected 2.1 Not DetectedVinyl Chloride0.82 Not Detected 1.8 Not Detected1,3-Butadiene0.82 Not Detected 3.2 Not DetectedBromomethane0.82 Not Detected 2.2 Not DetectedChloroethane0.82 Not Detected 4.6 Not DetectedFreon 113.3 Not Detected 6.2 Not DetectedEthanol
0.82 Not Detected 6.3 Not DetectedFreon 1130.82 Not Detected 3.2 Not Detected1,1-Dichloroethene3.3 Not Detected 7.8 Not DetectedAcetone3.3 Not Detected 8.1 Not Detected2-Propanol
0.82 Not Detected 2.6 Not DetectedCarbon Disulfide3.3 Not Detected 10 Not Detected3-Chloropropene
0.82 Not Detected 2.8 Not DetectedMethylene Chloride0.82 Not Detected 3.0 Not DetectedMethyl tert-butyl ether0.82 Not Detected 3.2 Not Detectedtrans-1,2-Dichloroethene0.82 Not Detected 2.9 Not DetectedHexane0.82 Not Detected 3.3 Not Detected1,1-Dichloroethane0.82 Not Detected 2.4 Not Detected2-Butanone (Methyl Ethyl Ketone)0.82 Not Detected 3.2 Not Detectedcis-1,2-Dichloroethene0.82 Not Detected 2.4 Not DetectedTetrahydrofuran0.82 Not Detected 4.0 Not DetectedChloroform0.82 Not Detected 4.5 Not Detected1,1,1-Trichloroethane0.82 Not Detected 2.8 Not DetectedCyclohexane0.82 Not Detected 5.2 Not DetectedCarbon Tetrachloride0.82 Not Detected 3.8 Not Detected2,2,4-Trimethylpentane0.82 Not Detected 2.6 Not DetectedBenzene0.82 Not Detected 3.3 Not Detected1,2-Dichloroethane0.82 Not Detected 3.4 Not DetectedHeptane0.82 Not Detected 4.4 Not DetectedTrichloroethene0.82 Not Detected 3.8 Not Detected1,2-Dichloropropane3.3 Not Detected 12 Not Detected1,4-Dioxane
0.82 Not Detected 5.5 Not DetectedBromodichloromethane0.82 Not Detected 3.7 Not Detectedcis-1,3-Dichloropropene0.82 Not Detected 3.4 Not Detected4-Methyl-2-pentanone0.82 Not Detected 3.1 Not DetectedToluene0.82 Not Detected 3.7 Not Detectedtrans-1,3-Dichloropropene0.82 Not Detected 4.5 Not Detected1,1,2-Trichloroethane0.82 Not Detected 5.6 Not DetectedTetrachloroethene3.3 Not Detected 13 Not Detected2-Hexanone
Page 11 of 18
Client Sample ID: 2AMDWL09
Lab ID#: 0602429-04AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1022617File Name:
AIR TOXICS LTD.
Dil. Factor: 1.64Date of Collection: 2/17/06Date of Analysis: 2/27/06 12:18 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.82 Not Detected 7.0 Not DetectedDibromochloromethane0.82 Not Detected 6.3 Not Detected1,2-Dibromoethane (EDB)0.82 Not Detected 3.8 Not DetectedChlorobenzene0.82 Not Detected 3.6 Not DetectedEthyl Benzene0.82 Not Detected 3.6 Not Detectedm,p-Xylene0.82 Not Detected 3.6 Not Detectedo-Xylene0.82 Not Detected 3.5 Not DetectedStyrene0.82 Not Detected 8.5 Not DetectedBromoform0.82 Not Detected 4.0 Not DetectedCumene0.82 Not Detected 5.6 Not Detected1,1,2,2-Tetrachloroethane0.82 Not Detected 4.0 Not DetectedPropylbenzene0.82 Not Detected 4.0 Not Detected4-Ethyltoluene0.82 Not Detected 4.0 Not Detected1,3,5-Trimethylbenzene0.82 Not Detected 4.0 Not Detected1,2,4-Trimethylbenzene0.82 Not Detected 4.9 Not Detected1,3-Dichlorobenzene0.82 Not Detected 4.9 Not Detected1,4-Dichlorobenzene0.82 Not Detected 4.2 Not Detectedalpha-Chlorotoluene0.82 Not Detected 4.9 Not Detected1,2-Dichlorobenzene3.3 Not Detected 24 Not Detected1,2,4-Trichlorobenzene3.3 Not Detected 35 Not DetectedHexachlorobutadiene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d8105 70-1301,2-Dichloroethane-d499 70-1304-Bromofluorobenzene
Page 12 of 18
Client Sample ID: Lab Blank
Lab ID#: 0602429-05AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1022605File Name:
AIR TOXICS LTD.
Dil. Factor: 1.00Date of Collection: NA Date of Analysis: 2/26/06 03:19 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.50 Not Detected 2.5 Not DetectedFreon 120.50 Not Detected 3.5 Not DetectedFreon 1142.0 Not Detected 4.1 Not DetectedChloromethane
0.50 Not Detected 1.3 Not DetectedVinyl Chloride0.50 Not Detected 1.1 Not Detected1,3-Butadiene0.50 Not Detected 1.9 Not DetectedBromomethane0.50 Not Detected 1.3 Not DetectedChloroethane0.50 Not Detected 2.8 Not DetectedFreon 112.0 Not Detected 3.8 Not DetectedEthanol
0.50 Not Detected 3.8 Not DetectedFreon 1130.50 Not Detected 2.0 Not Detected1,1-Dichloroethene2.0 Not Detected 4.8 Not DetectedAcetone2.0 Not Detected 4.9 Not Detected2-Propanol
0.50 Not Detected 1.6 Not DetectedCarbon Disulfide2.0 Not Detected 6.3 Not Detected3-Chloropropene
0.50 Not Detected 1.7 Not DetectedMethylene Chloride0.50 Not Detected 1.8 Not DetectedMethyl tert-butyl ether0.50 Not Detected 2.0 Not Detectedtrans-1,2-Dichloroethene0.50 Not Detected 1.8 Not DetectedHexane0.50 Not Detected 2.0 Not Detected1,1-Dichloroethane0.50 Not Detected 1.5 Not Detected2-Butanone (Methyl Ethyl Ketone)0.50 Not Detected 2.0 Not Detectedcis-1,2-Dichloroethene0.50 Not Detected 1.5 Not DetectedTetrahydrofuran0.50 Not Detected 2.4 Not DetectedChloroform0.50 Not Detected 2.7 Not Detected1,1,1-Trichloroethane0.50 Not Detected 1.7 Not DetectedCyclohexane0.50 Not Detected 3.1 Not DetectedCarbon Tetrachloride0.50 Not Detected 2.3 Not Detected2,2,4-Trimethylpentane0.50 Not Detected 1.6 Not DetectedBenzene0.50 Not Detected 2.0 Not Detected1,2-Dichloroethane0.50 Not Detected 2.0 Not DetectedHeptane0.50 Not Detected 2.7 Not DetectedTrichloroethene0.50 Not Detected 2.3 Not Detected1,2-Dichloropropane2.0 Not Detected 7.2 Not Detected1,4-Dioxane
0.50 Not Detected 3.4 Not DetectedBromodichloromethane0.50 Not Detected 2.3 Not Detectedcis-1,3-Dichloropropene0.50 Not Detected 2.0 Not Detected4-Methyl-2-pentanone0.50 Not Detected 1.9 Not DetectedToluene0.50 Not Detected 2.3 Not Detectedtrans-1,3-Dichloropropene0.50 Not Detected 2.7 Not Detected1,1,2-Trichloroethane0.50 Not Detected 3.4 Not DetectedTetrachloroethene2.0 Not Detected 8.2 Not Detected2-Hexanone
Page 13 of 18
Client Sample ID: Lab Blank
Lab ID#: 0602429-05AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1022605File Name:
AIR TOXICS LTD.
Dil. Factor: 1.00Date of Collection: NA Date of Analysis: 2/26/06 03:19 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.50 Not Detected 4.2 Not DetectedDibromochloromethane0.50 Not Detected 3.8 Not Detected1,2-Dibromoethane (EDB)0.50 Not Detected 2.3 Not DetectedChlorobenzene0.50 Not Detected 2.2 Not DetectedEthyl Benzene0.50 Not Detected 2.2 Not Detectedm,p-Xylene0.50 Not Detected 2.2 Not Detectedo-Xylene0.50 Not Detected 2.1 Not DetectedStyrene0.50 Not Detected 5.2 Not DetectedBromoform0.50 Not Detected 2.4 Not DetectedCumene0.50 Not Detected 3.4 Not Detected1,1,2,2-Tetrachloroethane0.50 Not Detected 2.4 Not DetectedPropylbenzene0.50 Not Detected 2.4 Not Detected4-Ethyltoluene0.50 Not Detected 2.4 Not Detected1,3,5-Trimethylbenzene0.50 Not Detected 2.4 Not Detected1,2,4-Trimethylbenzene0.50 Not Detected 3.0 Not Detected1,3-Dichlorobenzene0.50 Not Detected 3.0 Not Detected1,4-Dichlorobenzene0.50 Not Detected 2.6 Not Detectedalpha-Chlorotoluene0.50 Not Detected 3.0 Not Detected1,2-Dichlorobenzene2.0 Not Detected 15 Not Detected1,2,4-Trichlorobenzene2.0 Not Detected 21 Not DetectedHexachlorobutadiene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d8101 70-1301,2-Dichloroethane-d4100 70-1304-Bromofluorobenzene
Page 14 of 18
Client Sample ID: CCV
Lab ID#: 0602429-06AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1022602File Name:
AIR TOXICS LTD.
Dil. Factor: 1.00Date of Collection: NA Date of Analysis: 2/26/06 01:14 PM
%RecoveryCompound
114Freon 12113Freon 114110Chloromethane106Vinyl Chloride1121,3-Butadiene112Bromomethane103Chloroethane117Freon 11105Ethanol116Freon 1131111,1-Dichloroethene105Acetone1072-Propanol109Carbon Disulfide1063-Chloropropene110Methylene Chloride93Methyl tert-butyl ether100trans-1,2-Dichloroethene106Hexane1091,1-Dichloroethane1122-Butanone (Methyl Ethyl Ketone)111cis-1,2-Dichloroethene103Tetrahydrofuran112Chloroform1161,1,1-Trichloroethane114Cyclohexane130Carbon Tetrachloride1092,2,4-Trimethylpentane97Benzene1191,2-Dichloroethane109Heptane111Trichloroethene1121,2-Dichloropropane1091,4-Dioxane120Bromodichloromethane120cis-1,3-Dichloropropene1224-Methyl-2-pentanone110Toluene122trans-1,3-Dichloropropene1141,1,2-Trichloroethane116Tetrachloroethene1162-Hexanone
Page 15 of 18
Client Sample ID: CCV
Lab ID#: 0602429-06AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1022602File Name:
AIR TOXICS LTD.
Dil. Factor: 1.00Date of Collection: NA Date of Analysis: 2/26/06 01:14 PM
%RecoveryCompound
130Dibromochloromethane1201,2-Dibromoethane (EDB)116Chlorobenzene113Ethyl Benzene112m,p-Xylene112o-Xylene121Styrene
133 QBromoform113Cumene1161,1,2,2-Tetrachloroethane112Propylbenzene1124-Ethyltoluene1111,3,5-Trimethylbenzene1101,2,4-Trimethylbenzene1111,3-Dichlorobenzene1121,4-Dichlorobenzene117alpha-Chlorotoluene1101,2-Dichlorobenzene981,2,4-Trichlorobenzene109Hexachlorobutadiene
Q = Exceeds Quality Control limits.Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
99 70-130Toluene-d8103 70-1301,2-Dichloroethane-d4103 70-1304-Bromofluorobenzene
Page 16 of 18
Client Sample ID: LCS
Lab ID#: 0602429-07AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1022603File Name:
AIR TOXICS LTD.
Dil. Factor: 1.00Date of Collection: NA Date of Analysis: 2/26/06 02:00 PM
%RecoveryCompound
113Freon 12112Freon 114111Chloromethane107Vinyl Chloride1271,3-Butadiene115Bromomethane107Chloroethane118Freon 11116Ethanol116Freon 1131131,1-Dichloroethene112Acetone1142-Propanol121Carbon Disulfide1113-Chloropropene113Methylene Chloride94Methyl tert-butyl ether108trans-1,2-Dichloroethene114Hexane1121,1-Dichloroethane1212-Butanone (Methyl Ethyl Ketone)114cis-1,2-Dichloroethene108Tetrahydrofuran114Chloroform1161,1,1-Trichloroethane116Cyclohexane
131 QCarbon Tetrachloride1102,2,4-Trimethylpentane99Benzene1231,2-Dichloroethane110Heptane115Trichloroethene1161,2-Dichloropropane1181,4-Dioxane116Bromodichloromethane113cis-1,3-Dichloropropene1264-Methyl-2-pentanone112Toluene87trans-1,3-Dichloropropene1141,1,2-Trichloroethane116Tetrachloroethene1192-Hexanone
Page 17 of 18
Client Sample ID: LCS
Lab ID#: 0602429-07AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1022603File Name:
AIR TOXICS LTD.
Dil. Factor: 1.00Date of Collection: NA Date of Analysis: 2/26/06 02:00 PM
%RecoveryCompound
119Dibromochloromethane1211,2-Dibromoethane (EDB)117Chlorobenzene116Ethyl Benzene110m,p-Xylene104o-Xylene
134 QStyrene108Bromoform114Cumene1181,1,2,2-Tetrachloroethane114Propylbenzene1154-Ethyltoluene1051,3,5-Trimethylbenzene851,2,4-Trimethylbenzene1141,3-Dichlorobenzene1151,4-Dichlorobenzene121alpha-Chlorotoluene1121,2-Dichlorobenzene1251,2,4-Trichlorobenzene
141 QHexachlorobutadiene
Q = Exceeds Quality Control limits.Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d8104 70-1301,2-Dichloroethane-d4101 70-1304-Bromofluorobenzene
Page 18 of 18
AIR TOXICS LTD.@AN ENVIRONMENTAL ANALYTICAL LABORATORY
Air Toxics Ltd. Introduces the Electronic Report
Thank you for choosing Air Toxics Ltd. To better serve our customers, we are providing your report by e-mail. This document is provided in Portable Document Format which can be viewed with Acrobat Reader by Adobe.
This electronic report includes the following:• Work order Summary;• Laboratory Narrative;• Results; and• Chain of Custody (copy).
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630
(916) 985-1000 .FAX (916) 985-1020Hours 8:00 A.M to 6:00 P.M. Pacific
AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
@
Mr. Felix MoranEnviron International740 Waukegan RoadSuite 401Deerfield, IL 60015
WORK ORDER #: 0602295
CLIENT: BILL TO:
PHONE:
Mr. Felix MoranEnviron International740 Waukegan RoadSuite 401Deerfield, IL 60015
847-444-9200
847-444-9420
02/13/2006DATE COMPLETED: 02/22/2006
P.O. #
PROJECT # 21-8601AJ Midco II
Work Order Summary
FAX:
DATE RECEIVED: CONTACT: Susan Alaniz
NAMEFRACTION # TEST VAC./PRES.RECEIPT
01A 2AMDR08 Modified TO-15 10.0 "Hg02A 2AMDL08 Modified TO-15 4.0 "Hg03A 2AMDC08 Modified TO-15 9.0 "Hg04A 2AMU08 Modified TO-15 10.0 "Hg05A Lab Blank Modified TO-15 NA06A CCV Modified TO-15 NA07A LCS Modified TO-15 NA
CERTIFIED BY:
Laboratory Director
DATE:
Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, Expiration date: 06/30/06
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020
02/22/06
Page 1 of 18
This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards
Certfication numbers: AR DEQ - 03-084-0, CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004NY NELAP - 11291, UT NELAP - 9166389892
LABORATORY NARRATIVEModified TO-15
Environ InternationalWorkorder# 0602295
Four 6 Liter Summa Canister samples were received on February 13, 2006. The laboratory performed analysis via modified EPA Method TO-15 using GC/MS in the full scan mode. The method involvesconcentrating up to 0.2 liters of air. The concentrated aliquot is then flash vaporized and swept through awater management system to remove water vapor. Following dehumidification, the sample passes directlyinto the GC/MS for analysis.
Method modifications taken to run these samples are summarized in the below table. Specific projectrequirements may over-ride the ATL modifications.
Requirement ATL ModificationsTO-15Daily CCV +- 30% Difference </= 30% Difference with two allowed out up to </=40%.;
flag and narrate outliers
Sample collection media Summa canister ATL recommends use of summa canisters to insure data defensibility, but will report results from Tedlar bags at client request
Method Detection Limit Follow 40CFR Pt.136 App. B
The MDL met all relevant requirements in Method TO-15 (statistical MDL less than the LOQ). The concentration of the spiked replicate may have exceeded 10X the calculated MDL in some cases
Receiving Notes
There were no receiving discrepancies.
The reported LCS for each daily batch has been derived from more than one analytical file.
Analytical Notes
Eight qualifiers may have been used on the data analysis sheets and indicates as follows: B - Compound present in laboratory blank greater than reporting limit (background subtraction notperformed). J - Estimated value. E - Exceeds instrument calibration range. S - Saturated peak. Q - Exceeds quality control limits. U - Compound analyzed for but not detected above the reporting limit. UJ- Non-detected compound associated with low bias in the CCV N - The identification is based on presumptive evidence.
File extensions may have been used on the data analysis sheets and indicates as follows: a-File was requantified b-File was quantified by a second column and detector
Definition of Data Qualifying Flags
Page 2 of 18
r1-File was requantified for the purpose of reissue
Page 3 of 18
AIR TOXICS LTD.
MODIFIED EPA METHOD TO-15 GC/MS FULL SCANSummary of Detected Compounds
Client Sample ID: 2AMDR08
Lab ID#: 0602295-01ANo Detections Were Found.
Client Sample ID: 2AMDL08
Lab ID#: 0602295-02A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
3.1 6.2 7.4 15Acetone0.78 0.98 2.3 2.92-Butanone (Methyl Ethyl Ketone)
Client Sample ID: 2AMDC08
Lab ID#: 0602295-03A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.96 1.6 3.6 6.0Toluene
Client Sample ID: 2AMU08
Lab ID#: 0602295-04ANo Detections Were Found.
Page 4 of 18
Client Sample ID: 2AMDR08
Lab ID#: 0602295-01AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f022116File Name:
AIR TOXICS LTD.
Dil. Factor: 2.01Date of Collection: 2/10/06Date of Analysis: 2/21/06 09:46 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
1.0 Not Detected 5.0 Not DetectedFreon 121.0 Not Detected 7.0 Not DetectedFreon 1144.0 Not Detected 8.3 Not DetectedChloromethane1.0 Not Detected 2.6 Not DetectedVinyl Chloride1.0 Not Detected 2.2 Not Detected1,3-Butadiene1.0 Not Detected 3.9 Not DetectedBromomethane1.0 Not Detected 2.6 Not DetectedChloroethane1.0 Not Detected 5.6 Not DetectedFreon 114.0 Not Detected 7.6 Not DetectedEthanol1.0 Not Detected 7.7 Not DetectedFreon 1131.0 Not Detected 4.0 Not Detected1,1-Dichloroethene4.0 Not Detected 9.5 Not DetectedAcetone4.0 Not Detected 9.9 Not Detected2-Propanol1.0 Not Detected 3.1 Not DetectedCarbon Disulfide4.0 Not Detected 12 Not Detected3-Chloropropene1.0 Not Detected 3.5 Not DetectedMethylene Chloride1.0 Not Detected 3.6 Not DetectedMethyl tert-butyl ether1.0 Not Detected 4.0 Not Detectedtrans-1,2-Dichloroethene1.0 Not Detected 3.5 Not DetectedHexane1.0 Not Detected 4.1 Not Detected1,1-Dichloroethane1.0 Not Detected 3.0 Not Detected2-Butanone (Methyl Ethyl Ketone)1.0 Not Detected 4.0 Not Detectedcis-1,2-Dichloroethene1.0 Not Detected 3.0 Not DetectedTetrahydrofuran1.0 Not Detected 4.9 Not DetectedChloroform1.0 Not Detected 5.5 Not Detected1,1,1-Trichloroethane1.0 Not Detected 3.4 Not DetectedCyclohexane1.0 Not Detected 6.3 Not DetectedCarbon Tetrachloride1.0 Not Detected 4.7 Not Detected2,2,4-Trimethylpentane1.0 Not Detected 3.2 Not DetectedBenzene1.0 Not Detected 4.1 Not Detected1,2-Dichloroethane1.0 Not Detected 4.1 Not DetectedHeptane1.0 Not Detected 5.4 Not DetectedTrichloroethene1.0 Not Detected 4.6 Not Detected1,2-Dichloropropane4.0 Not Detected 14 Not Detected1,4-Dioxane1.0 Not Detected 6.7 Not DetectedBromodichloromethane1.0 Not Detected 4.6 Not Detectedcis-1,3-Dichloropropene1.0 Not Detected 4.1 Not Detected4-Methyl-2-pentanone1.0 Not Detected 3.8 Not DetectedToluene1.0 Not Detected 4.6 Not Detectedtrans-1,3-Dichloropropene1.0 Not Detected 5.5 Not Detected1,1,2-Trichloroethane1.0 Not Detected 6.8 Not DetectedTetrachloroethene4.0 Not Detected 16 Not Detected2-Hexanone
Page 5 of 18
Client Sample ID: 2AMDR08
Lab ID#: 0602295-01AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f022116File Name:
AIR TOXICS LTD.
Dil. Factor: 2.01Date of Collection: 2/10/06Date of Analysis: 2/21/06 09:46 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
1.0 Not Detected 8.6 Not DetectedDibromochloromethane1.0 Not Detected 7.7 Not Detected1,2-Dibromoethane (EDB)1.0 Not Detected 4.6 Not DetectedChlorobenzene1.0 Not Detected 4.4 Not DetectedEthyl Benzene1.0 Not Detected 4.4 Not Detectedm,p-Xylene1.0 Not Detected 4.4 Not Detectedo-Xylene1.0 Not Detected 4.3 Not DetectedStyrene1.0 Not Detected 10 Not DetectedBromoform1.0 Not Detected 4.9 Not DetectedCumene1.0 Not Detected 6.9 Not Detected1,1,2,2-Tetrachloroethane1.0 Not Detected 4.9 Not DetectedPropylbenzene1.0 Not Detected 4.9 Not Detected4-Ethyltoluene1.0 Not Detected 4.9 Not Detected1,3,5-Trimethylbenzene1.0 Not Detected 4.9 Not Detected1,2,4-Trimethylbenzene1.0 Not Detected 6.0 Not Detected1,3-Dichlorobenzene1.0 Not Detected 6.0 Not Detected1,4-Dichlorobenzene1.0 Not Detected 5.2 Not Detectedalpha-Chlorotoluene1.0 Not Detected 6.0 Not Detected1,2-Dichlorobenzene4.0 Not Detected 30 Not Detected1,2,4-Trichlorobenzene4.0 Not Detected 43 Not DetectedHexachlorobutadiene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d890 70-1301,2-Dichloroethane-d4104 70-1304-Bromofluorobenzene
Page 6 of 18
Client Sample ID: 2AMDL08
Lab ID#: 0602295-02AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f022117File Name:
AIR TOXICS LTD.
Dil. Factor: 1.55Date of Collection: 2/10/06Date of Analysis: 2/21/06 10:26 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.78 Not Detected 3.8 Not DetectedFreon 120.78 Not Detected 5.4 Not DetectedFreon 1143.1 Not Detected 6.4 Not DetectedChloromethane
0.78 Not Detected 2.0 Not DetectedVinyl Chloride0.78 Not Detected 1.7 Not Detected1,3-Butadiene0.78 Not Detected 3.0 Not DetectedBromomethane0.78 Not Detected 2.0 Not DetectedChloroethane0.78 Not Detected 4.4 Not DetectedFreon 113.1 Not Detected 5.8 Not DetectedEthanol
0.78 Not Detected 5.9 Not DetectedFreon 1130.78 Not Detected 3.1 Not Detected1,1-Dichloroethene3.1 6.2 7.4 15Acetone3.1 Not Detected 7.6 Not Detected2-Propanol
0.78 Not Detected 2.4 Not DetectedCarbon Disulfide3.1 Not Detected 9.7 Not Detected3-Chloropropene
0.78 Not Detected 2.7 Not DetectedMethylene Chloride0.78 Not Detected 2.8 Not DetectedMethyl tert-butyl ether0.78 Not Detected 3.1 Not Detectedtrans-1,2-Dichloroethene0.78 Not Detected 2.7 Not DetectedHexane0.78 Not Detected 3.1 Not Detected1,1-Dichloroethane0.78 0.98 2.3 2.92-Butanone (Methyl Ethyl Ketone)0.78 Not Detected 3.1 Not Detectedcis-1,2-Dichloroethene0.78 Not Detected 2.3 Not DetectedTetrahydrofuran0.78 Not Detected 3.8 Not DetectedChloroform0.78 Not Detected 4.2 Not Detected1,1,1-Trichloroethane0.78 Not Detected 2.7 Not DetectedCyclohexane0.78 Not Detected 4.9 Not DetectedCarbon Tetrachloride0.78 Not Detected 3.6 Not Detected2,2,4-Trimethylpentane0.78 Not Detected 2.5 Not DetectedBenzene0.78 Not Detected 3.1 Not Detected1,2-Dichloroethane0.78 Not Detected 3.2 Not DetectedHeptane0.78 Not Detected 4.2 Not DetectedTrichloroethene0.78 Not Detected 3.6 Not Detected1,2-Dichloropropane3.1 Not Detected 11 Not Detected1,4-Dioxane
0.78 Not Detected 5.2 Not DetectedBromodichloromethane0.78 Not Detected 3.5 Not Detectedcis-1,3-Dichloropropene0.78 Not Detected 3.2 Not Detected4-Methyl-2-pentanone0.78 Not Detected 2.9 Not DetectedToluene0.78 Not Detected 3.5 Not Detectedtrans-1,3-Dichloropropene0.78 Not Detected 4.2 Not Detected1,1,2-Trichloroethane0.78 Not Detected 5.2 Not DetectedTetrachloroethene3.1 Not Detected 13 Not Detected2-Hexanone
Page 7 of 18
Client Sample ID: 2AMDL08
Lab ID#: 0602295-02AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f022117File Name:
AIR TOXICS LTD.
Dil. Factor: 1.55Date of Collection: 2/10/06Date of Analysis: 2/21/06 10:26 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.78 Not Detected 6.6 Not DetectedDibromochloromethane0.78 Not Detected 6.0 Not Detected1,2-Dibromoethane (EDB)0.78 Not Detected 3.6 Not DetectedChlorobenzene0.78 Not Detected 3.4 Not DetectedEthyl Benzene0.78 Not Detected 3.4 Not Detectedm,p-Xylene0.78 Not Detected 3.4 Not Detectedo-Xylene0.78 Not Detected 3.3 Not DetectedStyrene0.78 Not Detected 8.0 Not DetectedBromoform0.78 Not Detected 3.8 Not DetectedCumene0.78 Not Detected 5.3 Not Detected1,1,2,2-Tetrachloroethane0.78 Not Detected 3.8 Not DetectedPropylbenzene0.78 Not Detected 3.8 Not Detected4-Ethyltoluene0.78 Not Detected 3.8 Not Detected1,3,5-Trimethylbenzene0.78 Not Detected 3.8 Not Detected1,2,4-Trimethylbenzene0.78 Not Detected 4.6 Not Detected1,3-Dichlorobenzene0.78 Not Detected 4.6 Not Detected1,4-Dichlorobenzene0.78 Not Detected 4.0 Not Detectedalpha-Chlorotoluene0.78 Not Detected 4.6 Not Detected1,2-Dichlorobenzene3.1 Not Detected 23 Not Detected1,2,4-Trichlorobenzene3.1 Not Detected 33 Not DetectedHexachlorobutadiene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
101 70-130Toluene-d892 70-1301,2-Dichloroethane-d4102 70-1304-Bromofluorobenzene
Page 8 of 18
Client Sample ID: 2AMDC08
Lab ID#: 0602295-03AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f022118File Name:
AIR TOXICS LTD.
Dil. Factor: 1.91Date of Collection: 2/10/06Date of Analysis: 2/21/06 11:08 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.96 Not Detected 4.7 Not DetectedFreon 120.96 Not Detected 6.7 Not DetectedFreon 1143.8 Not Detected 7.9 Not DetectedChloromethane
0.96 Not Detected 2.4 Not DetectedVinyl Chloride0.96 Not Detected 2.1 Not Detected1,3-Butadiene0.96 Not Detected 3.7 Not DetectedBromomethane0.96 Not Detected 2.5 Not DetectedChloroethane0.96 Not Detected 5.4 Not DetectedFreon 113.8 Not Detected 7.2 Not DetectedEthanol
0.96 Not Detected 7.3 Not DetectedFreon 1130.96 Not Detected 3.8 Not Detected1,1-Dichloroethene3.8 Not Detected 9.1 Not DetectedAcetone3.8 Not Detected 9.4 Not Detected2-Propanol
0.96 Not Detected 3.0 Not DetectedCarbon Disulfide3.8 Not Detected 12 Not Detected3-Chloropropene
0.96 Not Detected 3.3 Not DetectedMethylene Chloride0.96 Not Detected 3.4 Not DetectedMethyl tert-butyl ether0.96 Not Detected 3.8 Not Detectedtrans-1,2-Dichloroethene0.96 Not Detected 3.4 Not DetectedHexane0.96 Not Detected 3.9 Not Detected1,1-Dichloroethane0.96 Not Detected 2.8 Not Detected2-Butanone (Methyl Ethyl Ketone)0.96 Not Detected 3.8 Not Detectedcis-1,2-Dichloroethene0.96 Not Detected 2.8 Not DetectedTetrahydrofuran0.96 Not Detected 4.7 Not DetectedChloroform0.96 Not Detected 5.2 Not Detected1,1,1-Trichloroethane0.96 Not Detected 3.3 Not DetectedCyclohexane0.96 Not Detected 6.0 Not DetectedCarbon Tetrachloride0.96 Not Detected 4.5 Not Detected2,2,4-Trimethylpentane0.96 Not Detected 3.0 Not DetectedBenzene0.96 Not Detected 3.9 Not Detected1,2-Dichloroethane0.96 Not Detected 3.9 Not DetectedHeptane0.96 Not Detected 5.1 Not DetectedTrichloroethene0.96 Not Detected 4.4 Not Detected1,2-Dichloropropane3.8 Not Detected 14 Not Detected1,4-Dioxane
0.96 Not Detected 6.4 Not DetectedBromodichloromethane0.96 Not Detected 4.3 Not Detectedcis-1,3-Dichloropropene0.96 Not Detected 3.9 Not Detected4-Methyl-2-pentanone0.96 1.6 3.6 6.0Toluene0.96 Not Detected 4.3 Not Detectedtrans-1,3-Dichloropropene0.96 Not Detected 5.2 Not Detected1,1,2-Trichloroethane0.96 Not Detected 6.5 Not DetectedTetrachloroethene3.8 Not Detected 16 Not Detected2-Hexanone
Page 9 of 18
Client Sample ID: 2AMDC08
Lab ID#: 0602295-03AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f022118File Name:
AIR TOXICS LTD.
Dil. Factor: 1.91Date of Collection: 2/10/06Date of Analysis: 2/21/06 11:08 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.96 Not Detected 8.1 Not DetectedDibromochloromethane0.96 Not Detected 7.3 Not Detected1,2-Dibromoethane (EDB)0.96 Not Detected 4.4 Not DetectedChlorobenzene0.96 Not Detected 4.1 Not DetectedEthyl Benzene0.96 Not Detected 4.1 Not Detectedm,p-Xylene0.96 Not Detected 4.1 Not Detectedo-Xylene0.96 Not Detected 4.1 Not DetectedStyrene0.96 Not Detected 9.9 Not DetectedBromoform0.96 Not Detected 4.7 Not DetectedCumene0.96 Not Detected 6.6 Not Detected1,1,2,2-Tetrachloroethane0.96 Not Detected 4.7 Not DetectedPropylbenzene0.96 Not Detected 4.7 Not Detected4-Ethyltoluene0.96 Not Detected 4.7 Not Detected1,3,5-Trimethylbenzene0.96 Not Detected 4.7 Not Detected1,2,4-Trimethylbenzene0.96 Not Detected 5.7 Not Detected1,3-Dichlorobenzene0.96 Not Detected 5.7 Not Detected1,4-Dichlorobenzene0.96 Not Detected 4.9 Not Detectedalpha-Chlorotoluene0.96 Not Detected 5.7 Not Detected1,2-Dichlorobenzene3.8 Not Detected 28 Not Detected1,2,4-Trichlorobenzene3.8 Not Detected 41 Not DetectedHexachlorobutadiene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
101 70-130Toluene-d893 70-1301,2-Dichloroethane-d4102 70-1304-Bromofluorobenzene
Page 10 of 18
Client Sample ID: 2AMU08
Lab ID#: 0602295-04AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f022119File Name:
AIR TOXICS LTD.
Dil. Factor: 2.01Date of Collection: 2/10/06Date of Analysis: 2/21/06 11:48 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
1.0 Not Detected 5.0 Not DetectedFreon 121.0 Not Detected 7.0 Not DetectedFreon 1144.0 Not Detected 8.3 Not DetectedChloromethane1.0 Not Detected 2.6 Not DetectedVinyl Chloride1.0 Not Detected 2.2 Not Detected1,3-Butadiene1.0 Not Detected 3.9 Not DetectedBromomethane1.0 Not Detected 2.6 Not DetectedChloroethane1.0 Not Detected 5.6 Not DetectedFreon 114.0 Not Detected 7.6 Not DetectedEthanol1.0 Not Detected 7.7 Not DetectedFreon 1131.0 Not Detected 4.0 Not Detected1,1-Dichloroethene4.0 Not Detected 9.5 Not DetectedAcetone4.0 Not Detected 9.9 Not Detected2-Propanol1.0 Not Detected 3.1 Not DetectedCarbon Disulfide4.0 Not Detected 12 Not Detected3-Chloropropene1.0 Not Detected 3.5 Not DetectedMethylene Chloride1.0 Not Detected 3.6 Not DetectedMethyl tert-butyl ether1.0 Not Detected 4.0 Not Detectedtrans-1,2-Dichloroethene1.0 Not Detected 3.5 Not DetectedHexane1.0 Not Detected 4.1 Not Detected1,1-Dichloroethane1.0 Not Detected 3.0 Not Detected2-Butanone (Methyl Ethyl Ketone)1.0 Not Detected 4.0 Not Detectedcis-1,2-Dichloroethene1.0 Not Detected 3.0 Not DetectedTetrahydrofuran1.0 Not Detected 4.9 Not DetectedChloroform1.0 Not Detected 5.5 Not Detected1,1,1-Trichloroethane1.0 Not Detected 3.4 Not DetectedCyclohexane1.0 Not Detected 6.3 Not DetectedCarbon Tetrachloride1.0 Not Detected 4.7 Not Detected2,2,4-Trimethylpentane1.0 Not Detected 3.2 Not DetectedBenzene1.0 Not Detected 4.1 Not Detected1,2-Dichloroethane1.0 Not Detected 4.1 Not DetectedHeptane1.0 Not Detected 5.4 Not DetectedTrichloroethene1.0 Not Detected 4.6 Not Detected1,2-Dichloropropane4.0 Not Detected 14 Not Detected1,4-Dioxane1.0 Not Detected 6.7 Not DetectedBromodichloromethane1.0 Not Detected 4.6 Not Detectedcis-1,3-Dichloropropene1.0 Not Detected 4.1 Not Detected4-Methyl-2-pentanone1.0 Not Detected 3.8 Not DetectedToluene1.0 Not Detected 4.6 Not Detectedtrans-1,3-Dichloropropene1.0 Not Detected 5.5 Not Detected1,1,2-Trichloroethane1.0 Not Detected 6.8 Not DetectedTetrachloroethene4.0 Not Detected 16 Not Detected2-Hexanone
Page 11 of 18
Client Sample ID: 2AMU08
Lab ID#: 0602295-04AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f022119File Name:
AIR TOXICS LTD.
Dil. Factor: 2.01Date of Collection: 2/10/06Date of Analysis: 2/21/06 11:48 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
1.0 Not Detected 8.6 Not DetectedDibromochloromethane1.0 Not Detected 7.7 Not Detected1,2-Dibromoethane (EDB)1.0 Not Detected 4.6 Not DetectedChlorobenzene1.0 Not Detected 4.4 Not DetectedEthyl Benzene1.0 Not Detected 4.4 Not Detectedm,p-Xylene1.0 Not Detected 4.4 Not Detectedo-Xylene1.0 Not Detected 4.3 Not DetectedStyrene1.0 Not Detected 10 Not DetectedBromoform1.0 Not Detected 4.9 Not DetectedCumene1.0 Not Detected 6.9 Not Detected1,1,2,2-Tetrachloroethane1.0 Not Detected 4.9 Not DetectedPropylbenzene1.0 Not Detected 4.9 Not Detected4-Ethyltoluene1.0 Not Detected 4.9 Not Detected1,3,5-Trimethylbenzene1.0 Not Detected 4.9 Not Detected1,2,4-Trimethylbenzene1.0 Not Detected 6.0 Not Detected1,3-Dichlorobenzene1.0 Not Detected 6.0 Not Detected1,4-Dichlorobenzene1.0 Not Detected 5.2 Not Detectedalpha-Chlorotoluene1.0 Not Detected 6.0 Not Detected1,2-Dichlorobenzene4.0 Not Detected 30 Not Detected1,2,4-Trichlorobenzene4.0 Not Detected 43 Not DetectedHexachlorobutadiene
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d895 70-1301,2-Dichloroethane-d4104 70-1304-Bromofluorobenzene
Page 12 of 18
Client Sample ID: Lab Blank
Lab ID#: 0602295-05AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f022113File Name:
AIR TOXICS LTD.
Dil. Factor: 1.00Date of Collection: NA Date of Analysis: 2/21/06 06:44 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.50 Not Detected 2.5 Not DetectedFreon 120.50 Not Detected 3.5 Not DetectedFreon 1142.0 Not Detected 4.1 Not DetectedChloromethane
0.50 Not Detected 1.3 Not DetectedVinyl Chloride0.50 Not Detected 1.1 Not Detected1,3-Butadiene0.50 Not Detected 1.9 Not DetectedBromomethane0.50 Not Detected 1.3 Not DetectedChloroethane0.50 Not Detected 2.8 Not DetectedFreon 112.0 Not Detected 3.8 Not DetectedEthanol
0.50 Not Detected 3.8 Not DetectedFreon 1130.50 Not Detected 2.0 Not Detected1,1-Dichloroethene2.0 Not Detected 4.8 Not DetectedAcetone2.0 Not Detected 4.9 Not Detected2-Propanol
0.50 Not Detected 1.6 Not DetectedCarbon Disulfide2.0 Not Detected 6.3 Not Detected3-Chloropropene
0.50 Not Detected 1.7 Not DetectedMethylene Chloride0.50 Not Detected 1.8 Not DetectedMethyl tert-butyl ether0.50 Not Detected 2.0 Not Detectedtrans-1,2-Dichloroethene0.50 Not Detected 1.8 Not DetectedHexane0.50 Not Detected 2.0 Not Detected1,1-Dichloroethane0.50 Not Detected 1.5 Not Detected2-Butanone (Methyl Ethyl Ketone)0.50 Not Detected 2.0 Not Detectedcis-1,2-Dichloroethene0.50 Not Detected 1.5 Not DetectedTetrahydrofuran0.50 Not Detected 2.4 Not DetectedChloroform0.50 Not Detected 2.7 Not Detected1,1,1-Trichloroethane0.50 Not Detected 1.7 Not DetectedCyclohexane0.50 Not Detected 3.1 Not DetectedCarbon Tetrachloride0.50 Not Detected 2.3 Not Detected2,2,4-Trimethylpentane0.50 Not Detected 1.6 Not DetectedBenzene0.50 Not Detected 2.0 Not Detected1,2-Dichloroethane0.50 Not Detected 2.0 Not DetectedHeptane0.50 Not Detected 2.7 Not DetectedTrichloroethene0.50 Not Detected 2.3 Not Detected1,2-Dichloropropane2.0 Not Detected 7.2 Not Detected1,4-Dioxane
0.50 Not Detected 3.4 Not DetectedBromodichloromethane0.50 Not Detected 2.3 Not Detectedcis-1,3-Dichloropropene0.50 Not Detected 2.0 Not Detected4-Methyl-2-pentanone0.50 Not Detected 1.9 Not DetectedToluene0.50 Not Detected 2.3 Not Detectedtrans-1,3-Dichloropropene0.50 Not Detected 2.7 Not Detected1,1,2-Trichloroethane0.50 Not Detected 3.4 Not DetectedTetrachloroethene2.0 Not Detected 8.2 Not Detected2-Hexanone
Page 13 of 18
Client Sample ID: Lab Blank
Lab ID#: 0602295-05AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f022113File Name:
AIR TOXICS LTD.
Dil. Factor: 1.00Date of Collection: NA Date of Analysis: 2/21/06 06:44 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.50 Not Detected 4.2 Not DetectedDibromochloromethane0.50 Not Detected 3.8 Not Detected1,2-Dibromoethane (EDB)0.50 Not Detected 2.3 Not DetectedChlorobenzene0.50 Not Detected 2.2 Not DetectedEthyl Benzene0.50 Not Detected 2.2 Not Detectedm,p-Xylene0.50 Not Detected 2.2 Not Detectedo-Xylene0.50 Not Detected 2.1 Not DetectedStyrene0.50 Not Detected 5.2 Not DetectedBromoform0.50 Not Detected 2.4 Not DetectedCumene0.50 Not Detected 3.4 Not Detected1,1,2,2-Tetrachloroethane0.50 Not Detected 2.4 Not DetectedPropylbenzene0.50 Not Detected 2.4 Not Detected4-Ethyltoluene0.50 Not Detected 2.4 Not Detected1,3,5-Trimethylbenzene0.50 Not Detected 2.4 Not Detected1,2,4-Trimethylbenzene0.50 Not Detected 3.0 Not Detected1,3-Dichlorobenzene0.50 Not Detected 3.0 Not Detected1,4-Dichlorobenzene0.50 Not Detected 2.6 Not Detectedalpha-Chlorotoluene0.50 Not Detected 3.0 Not Detected1,2-Dichlorobenzene2.0 Not Detected 15 Not Detected1,2,4-Trichlorobenzene2.0 Not Detected 21 Not DetectedHexachlorobutadiene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d889 70-1301,2-Dichloroethane-d4101 70-1304-Bromofluorobenzene
Page 14 of 18
Client Sample ID: CCV
Lab ID#: 0602295-06AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f022102File Name:
AIR TOXICS LTD.
Dil. Factor: 1.00Date of Collection: NA Date of Analysis: 2/21/06 09:12 AM
%RecoveryCompound
96Freon 1296Freon 11499Chloromethane92Vinyl Chloride921,3-Butadiene95Bromomethane93Chloroethane98Freon 1186Ethanol95Freon 113961,1-Dichloroethene89Acetone912-Propanol92Carbon Disulfide893-Chloropropene90Methylene Chloride102Methyl tert-butyl ether91trans-1,2-Dichloroethene94Hexane951,1-Dichloroethane1032-Butanone (Methyl Ethyl Ketone)97cis-1,2-Dichloroethene96Tetrahydrofuran96Chloroform1031,1,1-Trichloroethane101Cyclohexane104Carbon Tetrachloride982,2,4-Trimethylpentane93Benzene1011,2-Dichloroethane105Heptane103Trichloroethene991,2-Dichloropropane971,4-Dioxane103Bromodichloromethane105cis-1,3-Dichloropropene1024-Methyl-2-pentanone98Toluene103trans-1,3-Dichloropropene991,1,2-Trichloroethane101Tetrachloroethene942-Hexanone
Page 15 of 18
Client Sample ID: CCV
Lab ID#: 0602295-06AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f022102File Name:
AIR TOXICS LTD.
Dil. Factor: 1.00Date of Collection: NA Date of Analysis: 2/21/06 09:12 AM
%RecoveryCompound
105Dibromochloromethane1021,2-Dibromoethane (EDB)97Chlorobenzene99Ethyl Benzene91m,p-Xylene98o-Xylene98Styrene104Bromoform88Cumene931,1,2,2-Tetrachloroethane95Propylbenzene984-Ethyltoluene951,3,5-Trimethylbenzene961,2,4-Trimethylbenzene931,3-Dichlorobenzene951,4-Dichlorobenzene97alpha-Chlorotoluene921,2-Dichlorobenzene881,2,4-Trichlorobenzene84Hexachlorobutadiene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
99 70-130Toluene-d8102 70-1301,2-Dichloroethane-d4100 70-1304-Bromofluorobenzene
Page 16 of 18
Client Sample ID: LCS
Lab ID#: 0602295-07AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f022103File Name:
AIR TOXICS LTD.
Dil. Factor: 1.00Date of Collection: NA Date of Analysis: 2/21/06 09:59 AM
%RecoveryCompound
92Freon 1295Freon 11498Chloromethane90Vinyl Chloride1041,3-Butadiene88Bromomethane86Chloroethane95Freon 1186Ethanol93Freon 113921,1-Dichloroethene93Acetone872-Propanol100Carbon Disulfide1003-Chloropropene89Methylene Chloride99Methyl tert-butyl ether94trans-1,2-Dichloroethene96Hexane911,1-Dichloroethane1002-Butanone (Methyl Ethyl Ketone)92cis-1,2-Dichloroethene92Tetrahydrofuran91Chloroform981,1,1-Trichloroethane95Cyclohexane97Carbon Tetrachloride1012,2,4-Trimethylpentane87Benzene961,2-Dichloroethane96Heptane94Trichloroethene921,2-Dichloropropane901,4-Dioxane88Bromodichloromethane85cis-1,3-Dichloropropene964-Methyl-2-pentanone90Toluene
62 Qtrans-1,3-Dichloropropene881,1,2-Trichloroethane92Tetrachloroethene782-Hexanone
Page 17 of 18
Client Sample ID: LCS
Lab ID#: 0602295-07AMODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f022103File Name:
AIR TOXICS LTD.
Dil. Factor: 1.00Date of Collection: NA Date of Analysis: 2/21/06 09:59 AM
%RecoveryCompound
84Dibromochloromethane871,2-Dibromoethane (EDB)87Chlorobenzene93Ethyl Benzene81m,p-Xylene81o-Xylene101Styrene71Bromoform86Cumene811,1,2,2-Tetrachloroethane92Propylbenzene934-Ethyltoluene811,3,5-Trimethylbenzene
66 Q1,2,4-Trimethylbenzene831,3-Dichlorobenzene831,4-Dichlorobenzene84alpha-Chlorotoluene831,2-Dichlorobenzene951,2,4-Trichlorobenzene95Hexachlorobutadiene
Q = Exceeds Quality Control limits.Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d896 70-1301,2-Dichloroethane-d4105 70-1304-Bromofluorobenzene
Page 18 of 18
AIR TOXICS LTD.@AN ENVIRONMENTAL ANALYTICAL LABORATORY
Air Toxics Ltd. Introduces the Electronic Report
Thank you for choosing Air Toxics Ltd. To better serve our customers, we are providing your report by e-mail. This document is provided in Portable Document Format which can be viewed with Acrobat Reader by Adobe.
This electronic report includes the following:• Work order Summary;• Laboratory Narrative;• Results; and• Chain of Custody (copy).
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630
(916) 985-1000 .FAX (916) 985-1020Hours 8:00 A.M to 6:00 P.M. Pacific
AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
@
Mr. Felix MoranEnviron International740 Waukegan RoadSuite 401Deerfield, IL 60015
WORK ORDER #: 0604149
CLIENT: BILL TO:
PHONE:
Mr. Felix MoranEnviron International740 Waukegan RoadSuite 401Deerfield, IL 60015
847-444-9200
847-444-9420
04/07/2006DATE COMPLETED: 04/14/2006
P.O. #
PROJECT # 218601AL Midco I SVE
Work Order Summary
FAX:
DATE RECEIVED: CONTACT: Susan Alaniz
NAMEFRACTION # TEST VAC./PRES.RECEIPT
01A 1OXD06 Modified TO-15/TICs 5.5 "Hg02A 1OXI06 Modified TO-15/TICs 5.5 "Hg03A 1AMDL09 Modified TO-15/TICs 8.5 "Hg04A 1AMDC09 Modified TO-15/TICs 0.2 psi05A 1AMDR09 Modified TO-15/TICs 8.0 "Hg06A 1AMU09 Modified TO-15/TICs 7.5 "Hg07A Lab Blank Modified TO-15/TICs NA08A CCV Modified TO-15/TICs NA09A LCS Modified TO-15/TICs NA
CERTIFIED BY:
Laboratory Director
DATE:
Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, Expiration date: 06/30/06
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020
04/14/06
Page 1 of 25
This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards
Certfication numbers: CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004NY NELAP - 11291, UT NELAP - 9166389892
LABORATORY NARRATIVEModified TO-15
Environ InternationalWorkorder# 0604149
@AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Two 1 Liter Summa Canister and four 6 Liter Summa Canister samples were received on April 07, 2006.The laboratory performed analysis via modified EPA Method TO-15 using GC/MS in the full scan mode.The method involves concentrating up to 0.2 liters of air. The concentrated aliquot is then flash vaporized and swept through a water management system to remove water vapor. Following dehumidification, the samplepasses directly into the GC/MS for analysis.
Method modifications taken to run these samples are summarized in the below table. Specific projectrequirements may over-ride the ATL modifications.
Requirement ATL ModificationsTO-15Daily CCV +- 30% Difference </= 30% Difference with two allowed out up to </=40%.;
flag and narrate outliers
Sample collection media Summa canister ATL recommends use of summa canisters to insure data defensibility, but will report results from Tedlar bags at client request
Method Detection Limit Follow 40CFR Pt.136 App. B
The MDL met all relevant requirements in Method TO-15 (statistical MDL less than the LOQ). The concentration of the spiked replicate may have exceeded 10X the calculated MDL in some cases
Receiving Notes
There were no receiving discrepancies.
The reported LCS for each daily batch has been derived from more than one analytical file.
Analytical Notes
Eight qualifiers may have been used on the data analysis sheets and indicates as follows: B - Compound present in laboratory blank greater than reporting limit (background subtraction notperformed). J - Estimated value. E - Exceeds instrument calibration range. S - Saturated peak. Q - Exceeds quality control limits. U - Compound analyzed for but not detected above the reporting limit. UJ- Non-detected compound associated with low bias in the CCV N - The identification is based on presumptive evidence.
File extensions may have been used on the data analysis sheets and indicates as follows: a-File was requantified
Definition of Data Qualifying Flags
Page 2 of 25
AN ENVIRONMENTAL ANALYTICAL LABORATORY
AIR TOXICS LTD.@ b-File was quantified by a second column and detector r1-File was requantified for the purpose of reissue
Page 3 of 25
MODIFIED EPA METHOD TO-15 GC/MS FULL SCANSummary of Detected Compounds
AIR TOXICS LTD.@ AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1OXD06
Lab ID#: 0604149-01A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
1.2 3.4 4.6 13Toluene1.2 1.3 5.4 5.6Ethyl Benzene1.2 4.2 5.4 18m,p-Xylene4.9 7.7 12 18Acetone1.2 1.3 3.6 3.82-Butanone (Methyl Ethyl Ketone)
TENTATIVELY IDENTIFIED COMPOUNDS
ppbvMatch QualityCAS NumberCompoundAmount
NA NA 8.9 JUnknown75-07-0 74% 7.0 N JAcetaldehyde75-52-5 86% 15 N JMethane, nitro-
Client Sample ID: 1OXI06
Lab ID#: 0604149-02A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
1200 6400 3200 16000Vinyl Chloride1200 2400 4900 94001,1-Dichloroethene1200 60000 9500 460000Freon 1131200 100000 4300 370000Methylene Chloride1200 8500 5000 340001,1-Dichloroethane1200 38000 4900 150000cis-1,2-Dichloroethene1200 5000 6700 280001,1,1-Trichloroethane1200 3700 3900 12000Benzene1200 18000 6600 99000Trichloroethene1200 240000 4600 910000Toluene1200 9600 8400 65000Tetrachloroethene1200 15000 5400 65000Ethyl Benzene1200 62000 5400 270000m,p-Xylene1200 14000 5400 59000o-Xylene1200 43000 4400 150000Hexane1200 3200 4200 11000Cyclohexane1200 18000 5100 73000Heptane1200 2100 3600 62002-Butanone (Methyl Ethyl Ketone)1200 1800 5000 72004-Methyl-2-pentanone1200 1400 6100 70004-Ethyltoluene
Page 4 of 25
MODIFIED EPA METHOD TO-15 GC/MS FULL SCANSummary of Detected Compounds
AIR TOXICS LTD.@ AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1OXI06
Lab ID#: 0604149-02ATENTATIVELY IDENTIFIED COMPOUNDS
ppbvMatch QualityCAS NumberCompoundAmount
106-97-8 40% 9200 N JButane78-78-4 86% 18000 N JButane, 2-methyl-
109-66-0 86% 9500 N JPentane107-83-5 91% 46000 N JPentane, 2-methyl-
16747-25-4 56% 46000 N JHexane, 2,2,3-trimethyl-96-37-7 90% 28000 N JCyclopentane, methyl-
591-76-4 93% 19000 N JHexane, 2-methyl-617-78-7 80% 32000 N JPentane, 3-ethyl-108-87-2 74% 20000 N JCyclohexane, methyl-592-27-8 86% 9800 N JHeptane, 2-methyl-
Client Sample ID: 1AMDL09
Lab ID#: 0604149-03ATENTATIVELY IDENTIFIED COMPOUNDS
ppbvMatch QualityCAS NumberCompoundAmount
109-66-0 86% 5.1 N JPentane
Client Sample ID: 1AMDC09
Lab ID#: 0604149-04A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
2.6 7.4 6.3 18Acetone0.66 1.1 1.9 3.22-Butanone (Methyl Ethyl Ketone)
Client Sample ID: 1AMDR09
Lab ID#: 0604149-05ANo Detections Were Found.
Client Sample ID: 1AMU09
Lab ID#: 0604149-06A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
Page 5 of 25
MODIFIED EPA METHOD TO-15 GC/MS FULL SCANSummary of Detected Compounds
AIR TOXICS LTD.@ AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMU09
Lab ID#: 0604149-06A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
3.6 3.5 J 8.5 8.4 JAcetone
Page 6 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1OXD06
Lab ID#: 0604149-01A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041217File Name:Dil. Factor: 2.47
Date of Collection: 4/5/06Date of Analysis: 4/12/06 10:54 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
1.2 Not Detected 6.1 Not DetectedFreon 121.2 Not Detected 8.6 Not DetectedFreon 1141.2 Not Detected 3.2 Not DetectedVinyl Chloride1.2 Not Detected 4.8 Not DetectedBromomethane1.2 Not Detected 3.2 Not DetectedChloroethane1.2 Not Detected 6.9 Not DetectedFreon 111.2 Not Detected 4.9 Not Detected1,1-Dichloroethene1.2 Not Detected 9.5 Not DetectedFreon 1131.2 Not Detected 4.3 Not DetectedMethylene Chloride1.2 Not Detected 5.0 Not Detected1,1-Dichloroethane1.2 Not Detected 4.9 Not Detectedcis-1,2-Dichloroethene1.2 Not Detected 6.0 Not DetectedChloroform1.2 Not Detected 6.7 Not Detected1,1,1-Trichloroethane1.2 Not Detected 7.8 Not DetectedCarbon Tetrachloride1.2 Not Detected 3.9 Not DetectedBenzene1.2 Not Detected 5.0 Not Detected1,2-Dichloroethane1.2 Not Detected 6.6 Not DetectedTrichloroethene1.2 Not Detected 5.7 Not Detected1,2-Dichloropropane1.2 Not Detected 5.6 Not Detectedcis-1,3-Dichloropropene1.2 3.4 4.6 13Toluene1.2 Not Detected 5.6 Not Detectedtrans-1,3-Dichloropropene1.2 Not Detected 6.7 Not Detected1,1,2-Trichloroethane1.2 Not Detected 8.4 Not DetectedTetrachloroethene1.2 Not Detected 9.5 Not Detected1,2-Dibromoethane (EDB)1.2 Not Detected 5.7 Not DetectedChlorobenzene1.2 1.3 5.4 5.6Ethyl Benzene1.2 4.2 5.4 18m,p-Xylene1.2 Not Detected 5.4 Not Detectedo-Xylene1.2 Not Detected 5.3 Not DetectedStyrene1.2 Not Detected 8.5 Not Detected1,1,2,2-Tetrachloroethane1.2 Not Detected 6.1 Not Detected1,3,5-Trimethylbenzene1.2 Not Detected 6.1 Not Detected1,2,4-Trimethylbenzene1.2 Not Detected 7.4 Not Detected1,3-Dichlorobenzene1.2 Not Detected 7.4 Not Detected1,4-Dichlorobenzene1.2 Not Detected 6.4 Not Detectedalpha-Chlorotoluene1.2 Not Detected 7.4 Not Detected1,2-Dichlorobenzene1.2 Not Detected 2.7 Not Detected1,3-Butadiene1.2 Not Detected 4.4 Not DetectedHexane1.2 Not Detected 4.2 Not DetectedCyclohexane1.2 Not Detected 8.3 Not DetectedBromodichloromethane
Page 7 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1OXD06
Lab ID#: 0604149-01A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041217File Name:Dil. Factor: 2.47
Date of Collection: 4/5/06Date of Analysis: 4/12/06 10:54 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
1.2 Not Detected 10 Not DetectedDibromochloromethane1.2 Not Detected 5.1 Not DetectedHeptane1.2 Not Detected 6.1 Not DetectedCumene1.2 Not Detected 6.1 Not DetectedPropylbenzene4.9 Not Detected 10 Not DetectedChloromethane4.9 Not Detected 37 Not Detected1,2,4-Trichlorobenzene4.9 Not Detected 53 Not DetectedHexachlorobutadiene4.9 7.7 12 18Acetone1.2 Not Detected 3.8 Not DetectedCarbon Disulfide4.9 Not Detected 12 Not Detected2-Propanol1.2 Not Detected 4.9 Not Detectedtrans-1,2-Dichloroethene1.2 1.3 3.6 3.82-Butanone (Methyl Ethyl Ketone)1.2 Not Detected 3.6 Not DetectedTetrahydrofuran4.9 Not Detected 18 Not Detected1,4-Dioxane1.2 Not Detected 5.0 Not Detected4-Methyl-2-pentanone4.9 Not Detected 20 Not Detected2-Hexanone1.2 Not Detected 13 Not DetectedBromoform1.2 Not Detected 6.1 Not Detected4-Ethyltoluene4.9 Not Detected 9.3 Not DetectedEthanol1.2 Not Detected 4.4 Not DetectedMethyl tert-butyl ether1.2 Not Detected 5.8 Not Detected2,2,4-Trimethylpentane4.9 Not Detected 15 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
NA NA 8.9 JUnknown75-07-0 74% 7.0 N JAcetaldehyde75-52-5 86% 15 N JMethane, nitro-
Container Type: 1 Liter Summa Canister
Limits%RecoverySurrogatesMethod
98 70-130Toluene-d894 70-1301,2-Dichloroethane-d493 70-1304-Bromofluorobenzene
Page 8 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1OXI06
Lab ID#: 0604149-02A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041218File Name:Dil. Factor: 2470
Date of Collection: 4/5/06Date of Analysis: 4/13/06 12:00 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
1200 Not Detected 6100 Not DetectedFreon 121200 Not Detected 8600 Not DetectedFreon 1141200 6400 3200 16000Vinyl Chloride1200 Not Detected 4800 Not DetectedBromomethane1200 Not Detected 3200 Not DetectedChloroethane1200 Not Detected 6900 Not DetectedFreon 111200 2400 4900 94001,1-Dichloroethene1200 60000 9500 460000Freon 1131200 100000 4300 370000Methylene Chloride1200 8500 5000 340001,1-Dichloroethane1200 38000 4900 150000cis-1,2-Dichloroethene1200 Not Detected 6000 Not DetectedChloroform1200 5000 6700 280001,1,1-Trichloroethane1200 Not Detected 7800 Not DetectedCarbon Tetrachloride1200 3700 3900 12000Benzene1200 Not Detected 5000 Not Detected1,2-Dichloroethane1200 18000 6600 99000Trichloroethene1200 Not Detected 5700 Not Detected1,2-Dichloropropane1200 Not Detected 5600 Not Detectedcis-1,3-Dichloropropene1200 240000 4600 910000Toluene1200 Not Detected 5600 Not Detectedtrans-1,3-Dichloropropene1200 Not Detected 6700 Not Detected1,1,2-Trichloroethane1200 9600 8400 65000Tetrachloroethene1200 Not Detected 9500 Not Detected1,2-Dibromoethane (EDB)1200 Not Detected 5700 Not DetectedChlorobenzene1200 15000 5400 65000Ethyl Benzene1200 62000 5400 270000m,p-Xylene1200 14000 5400 59000o-Xylene1200 Not Detected 5300 Not DetectedStyrene1200 Not Detected 8500 Not Detected1,1,2,2-Tetrachloroethane1200 Not Detected 6100 Not Detected1,3,5-Trimethylbenzene1200 Not Detected 6100 Not Detected1,2,4-Trimethylbenzene1200 Not Detected 7400 Not Detected1,3-Dichlorobenzene1200 Not Detected 7400 Not Detected1,4-Dichlorobenzene1200 Not Detected 6400 Not Detectedalpha-Chlorotoluene1200 Not Detected 7400 Not Detected1,2-Dichlorobenzene1200 Not Detected 2700 Not Detected1,3-Butadiene1200 43000 4400 150000Hexane1200 3200 4200 11000Cyclohexane1200 Not Detected 8300 Not DetectedBromodichloromethane
Page 9 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1OXI06
Lab ID#: 0604149-02A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041218File Name:Dil. Factor: 2470
Date of Collection: 4/5/06Date of Analysis: 4/13/06 12:00 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
1200 Not Detected 10000 Not DetectedDibromochloromethane1200 18000 5100 73000Heptane1200 Not Detected 6100 Not DetectedCumene1200 Not Detected 6100 Not DetectedPropylbenzene4900 Not Detected 10000 Not DetectedChloromethane4900 Not Detected 37000 Not Detected1,2,4-Trichlorobenzene4900 Not Detected 53000 Not DetectedHexachlorobutadiene4900 Not Detected 12000 Not DetectedAcetone1200 Not Detected 3800 Not DetectedCarbon Disulfide4900 Not Detected 12000 Not Detected2-Propanol1200 Not Detected 4900 Not Detectedtrans-1,2-Dichloroethene1200 2100 3600 62002-Butanone (Methyl Ethyl Ketone)1200 Not Detected 3600 Not DetectedTetrahydrofuran4900 Not Detected 18000 Not Detected1,4-Dioxane1200 1800 5000 72004-Methyl-2-pentanone4900 Not Detected 20000 Not Detected2-Hexanone1200 Not Detected 13000 Not DetectedBromoform1200 1400 6100 70004-Ethyltoluene4900 Not Detected 9300 Not DetectedEthanol1200 Not Detected 4400 Not DetectedMethyl tert-butyl ether1200 Not Detected 5800 Not Detected2,2,4-Trimethylpentane4900 Not Detected 15000 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
106-97-8 40% 9200 N JButane78-78-4 86% 18000 N JButane, 2-methyl-
109-66-0 86% 9500 N JPentane107-83-5 91% 46000 N JPentane, 2-methyl-
16747-25-4 56% 46000 N JHexane, 2,2,3-trimethyl-96-37-7 90% 28000 N JCyclopentane, methyl-
591-76-4 93% 19000 N JHexane, 2-methyl-617-78-7 80% 32000 N JPentane, 3-ethyl-108-87-2 74% 20000 N JCyclohexane, methyl-592-27-8 86% 9800 N JHeptane, 2-methyl-
Container Type: 1 Liter Summa Canister
Limits%RecoverySurrogatesMethod
Page 10 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1OXI06
Lab ID#: 0604149-02A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041218File Name:Dil. Factor: 2470
Date of Collection: 4/5/06Date of Analysis: 4/13/06 12:00 AM
Limits%RecoverySurrogatesMethod
96 70-130Toluene-d898 70-1301,2-Dichloroethane-d4101 70-1304-Bromofluorobenzene
Page 11 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDL09
Lab ID#: 0604149-03A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041219File Name:Dil. Factor: 1.87
Date of Collection: 4/5/06Date of Analysis: 4/13/06 12:55 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.94 Not Detected 4.6 Not DetectedFreon 120.94 Not Detected 6.5 Not DetectedFreon 1140.94 Not Detected 2.4 Not DetectedVinyl Chloride0.94 Not Detected 3.6 Not DetectedBromomethane0.94 Not Detected 2.5 Not DetectedChloroethane0.94 Not Detected 5.2 Not DetectedFreon 110.94 Not Detected 3.7 Not Detected1,1-Dichloroethene0.94 Not Detected 7.2 Not DetectedFreon 1130.94 Not Detected 3.2 Not DetectedMethylene Chloride0.94 Not Detected 3.8 Not Detected1,1-Dichloroethane0.94 Not Detected 3.7 Not Detectedcis-1,2-Dichloroethene0.94 Not Detected 4.6 Not DetectedChloroform0.94 Not Detected 5.1 Not Detected1,1,1-Trichloroethane0.94 Not Detected 5.9 Not DetectedCarbon Tetrachloride0.94 Not Detected 3.0 Not DetectedBenzene0.94 Not Detected 3.8 Not Detected1,2-Dichloroethane0.94 Not Detected 5.0 Not DetectedTrichloroethene0.94 Not Detected 4.3 Not Detected1,2-Dichloropropane0.94 Not Detected 4.2 Not Detectedcis-1,3-Dichloropropene0.94 Not Detected 3.5 Not DetectedToluene0.94 Not Detected 4.2 Not Detectedtrans-1,3-Dichloropropene0.94 Not Detected 5.1 Not Detected1,1,2-Trichloroethane0.94 Not Detected 6.3 Not DetectedTetrachloroethene0.94 Not Detected 7.2 Not Detected1,2-Dibromoethane (EDB)0.94 Not Detected 4.3 Not DetectedChlorobenzene0.94 Not Detected 4.0 Not DetectedEthyl Benzene0.94 Not Detected 4.1 Not Detectedm,p-Xylene0.94 Not Detected 4.1 Not Detectedo-Xylene0.94 Not Detected 4.0 Not DetectedStyrene0.94 Not Detected 6.4 Not Detected1,1,2,2-Tetrachloroethane0.94 Not Detected 4.6 Not Detected1,3,5-Trimethylbenzene0.94 Not Detected 4.6 Not Detected1,2,4-Trimethylbenzene0.94 Not Detected 5.6 Not Detected1,3-Dichlorobenzene0.94 Not Detected 5.6 Not Detected1,4-Dichlorobenzene0.94 Not Detected 4.8 Not Detectedalpha-Chlorotoluene0.94 Not Detected 5.6 Not Detected1,2-Dichlorobenzene0.94 Not Detected 2.1 Not Detected1,3-Butadiene0.94 Not Detected 3.3 Not DetectedHexane0.94 Not Detected 3.2 Not DetectedCyclohexane0.94 Not Detected 6.3 Not DetectedBromodichloromethane
Page 12 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDL09
Lab ID#: 0604149-03A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041219File Name:Dil. Factor: 1.87
Date of Collection: 4/5/06Date of Analysis: 4/13/06 12:55 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.94 Not Detected 8.0 Not DetectedDibromochloromethane0.94 Not Detected 3.8 Not DetectedHeptane0.94 Not Detected 4.6 Not DetectedCumene0.94 Not Detected 4.6 Not DetectedPropylbenzene3.7 Not Detected 7.7 Not DetectedChloromethane3.7 Not Detected 28 Not Detected1,2,4-Trichlorobenzene3.7 Not Detected 40 Not DetectedHexachlorobutadiene3.7 Not Detected 8.9 Not DetectedAcetone
0.94 Not Detected 2.9 Not DetectedCarbon Disulfide3.7 Not Detected 9.2 Not Detected2-Propanol
0.94 Not Detected 3.7 Not Detectedtrans-1,2-Dichloroethene0.94 Not Detected 2.8 Not Detected2-Butanone (Methyl Ethyl Ketone)0.94 Not Detected 2.8 Not DetectedTetrahydrofuran3.7 Not Detected 13 Not Detected1,4-Dioxane
0.94 Not Detected 3.8 Not Detected4-Methyl-2-pentanone3.7 Not Detected 15 Not Detected2-Hexanone
0.94 Not Detected 9.7 Not DetectedBromoform0.94 Not Detected 4.6 Not Detected4-Ethyltoluene3.7 Not Detected 7.0 Not DetectedEthanol
0.94 Not Detected 3.4 Not DetectedMethyl tert-butyl ether0.94 Not Detected 4.4 Not Detected2,2,4-Trimethylpentane3.7 Not Detected 12 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
109-66-0 86% 5.1 N JPentane
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
98 70-130Toluene-d895 70-1301,2-Dichloroethane-d4100 70-1304-Bromofluorobenzene
Page 13 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDC09
Lab ID#: 0604149-04A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041220File Name:Dil. Factor: 1.32
Date of Collection: 4/5/06Date of Analysis: 4/13/06 01:45 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.66 Not Detected 3.3 Not DetectedFreon 120.66 Not Detected 4.6 Not DetectedFreon 1140.66 Not Detected 1.7 Not DetectedVinyl Chloride0.66 Not Detected 2.6 Not DetectedBromomethane0.66 Not Detected 1.7 Not DetectedChloroethane0.66 Not Detected 3.7 Not DetectedFreon 110.66 Not Detected 2.6 Not Detected1,1-Dichloroethene0.66 Not Detected 5.0 Not DetectedFreon 1130.66 Not Detected 2.3 Not DetectedMethylene Chloride0.66 Not Detected 2.7 Not Detected1,1-Dichloroethane0.66 Not Detected 2.6 Not Detectedcis-1,2-Dichloroethene0.66 Not Detected 3.2 Not DetectedChloroform0.66 Not Detected 3.6 Not Detected1,1,1-Trichloroethane0.66 Not Detected 4.2 Not DetectedCarbon Tetrachloride0.66 Not Detected 2.1 Not DetectedBenzene0.66 Not Detected 2.7 Not Detected1,2-Dichloroethane0.66 Not Detected 3.5 Not DetectedTrichloroethene0.66 Not Detected 3.0 Not Detected1,2-Dichloropropane0.66 Not Detected 3.0 Not Detectedcis-1,3-Dichloropropene0.66 Not Detected 2.5 Not DetectedToluene0.66 Not Detected 3.0 Not Detectedtrans-1,3-Dichloropropene0.66 Not Detected 3.6 Not Detected1,1,2-Trichloroethane0.66 Not Detected 4.5 Not DetectedTetrachloroethene0.66 Not Detected 5.1 Not Detected1,2-Dibromoethane (EDB)0.66 Not Detected 3.0 Not DetectedChlorobenzene0.66 Not Detected 2.9 Not DetectedEthyl Benzene0.66 Not Detected 2.9 Not Detectedm,p-Xylene0.66 Not Detected 2.9 Not Detectedo-Xylene0.66 Not Detected 2.8 Not DetectedStyrene0.66 Not Detected 4.5 Not Detected1,1,2,2-Tetrachloroethane0.66 Not Detected 3.2 Not Detected1,3,5-Trimethylbenzene0.66 Not Detected 3.2 Not Detected1,2,4-Trimethylbenzene0.66 Not Detected 4.0 Not Detected1,3-Dichlorobenzene0.66 Not Detected 4.0 Not Detected1,4-Dichlorobenzene0.66 Not Detected 3.4 Not Detectedalpha-Chlorotoluene0.66 Not Detected 4.0 Not Detected1,2-Dichlorobenzene0.66 Not Detected 1.5 Not Detected1,3-Butadiene0.66 Not Detected 2.3 Not DetectedHexane0.66 Not Detected 2.3 Not DetectedCyclohexane0.66 Not Detected 4.4 Not DetectedBromodichloromethane
Page 14 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDC09
Lab ID#: 0604149-04A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041220File Name:Dil. Factor: 1.32
Date of Collection: 4/5/06Date of Analysis: 4/13/06 01:45 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.66 Not Detected 5.6 Not DetectedDibromochloromethane0.66 Not Detected 2.7 Not DetectedHeptane0.66 Not Detected 3.2 Not DetectedCumene0.66 Not Detected 3.2 Not DetectedPropylbenzene2.6 Not Detected 5.4 Not DetectedChloromethane2.6 Not Detected 20 Not Detected1,2,4-Trichlorobenzene2.6 Not Detected 28 Not DetectedHexachlorobutadiene2.6 7.4 6.3 18Acetone
0.66 Not Detected 2.0 Not DetectedCarbon Disulfide2.6 Not Detected 6.5 Not Detected2-Propanol
0.66 Not Detected 2.6 Not Detectedtrans-1,2-Dichloroethene0.66 1.1 1.9 3.22-Butanone (Methyl Ethyl Ketone)0.66 Not Detected 1.9 Not DetectedTetrahydrofuran2.6 Not Detected 9.5 Not Detected1,4-Dioxane
0.66 Not Detected 2.7 Not Detected4-Methyl-2-pentanone2.6 Not Detected 11 Not Detected2-Hexanone
0.66 Not Detected 6.8 Not DetectedBromoform0.66 Not Detected 3.2 Not Detected4-Ethyltoluene2.6 Not Detected 5.0 Not DetectedEthanol
0.66 Not Detected 2.4 Not DetectedMethyl tert-butyl ether0.66 Not Detected 3.1 Not Detected2,2,4-Trimethylpentane2.6 Not Detected 8.3 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
None Identified
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
98 70-130Toluene-d896 70-1301,2-Dichloroethane-d498 70-1304-Bromofluorobenzene
Page 15 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDR09
Lab ID#: 0604149-05A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041221File Name:Dil. Factor: 1.83
Date of Collection: 4/5/06Date of Analysis: 4/13/06 02:27 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.92 Not Detected 4.5 Not DetectedFreon 120.92 Not Detected 6.4 Not DetectedFreon 1140.92 Not Detected 2.3 Not DetectedVinyl Chloride0.92 Not Detected 3.6 Not DetectedBromomethane0.92 Not Detected 2.4 Not DetectedChloroethane0.92 Not Detected 5.1 Not DetectedFreon 110.92 Not Detected 3.6 Not Detected1,1-Dichloroethene0.92 Not Detected 7.0 Not DetectedFreon 1130.92 Not Detected 3.2 Not DetectedMethylene Chloride0.92 Not Detected 3.7 Not Detected1,1-Dichloroethane0.92 Not Detected 3.6 Not Detectedcis-1,2-Dichloroethene0.92 Not Detected 4.5 Not DetectedChloroform0.92 Not Detected 5.0 Not Detected1,1,1-Trichloroethane0.92 Not Detected 5.8 Not DetectedCarbon Tetrachloride0.92 Not Detected 2.9 Not DetectedBenzene0.92 Not Detected 3.7 Not Detected1,2-Dichloroethane0.92 Not Detected 4.9 Not DetectedTrichloroethene0.92 Not Detected 4.2 Not Detected1,2-Dichloropropane0.92 Not Detected 4.2 Not Detectedcis-1,3-Dichloropropene0.92 Not Detected 3.4 Not DetectedToluene0.92 Not Detected 4.2 Not Detectedtrans-1,3-Dichloropropene0.92 Not Detected 5.0 Not Detected1,1,2-Trichloroethane0.92 Not Detected 6.2 Not DetectedTetrachloroethene0.92 Not Detected 7.0 Not Detected1,2-Dibromoethane (EDB)0.92 Not Detected 4.2 Not DetectedChlorobenzene0.92 Not Detected 4.0 Not DetectedEthyl Benzene0.92 Not Detected 4.0 Not Detectedm,p-Xylene0.92 Not Detected 4.0 Not Detectedo-Xylene0.92 Not Detected 3.9 Not DetectedStyrene0.92 Not Detected 6.3 Not Detected1,1,2,2-Tetrachloroethane0.92 Not Detected 4.5 Not Detected1,3,5-Trimethylbenzene0.92 Not Detected 4.5 Not Detected1,2,4-Trimethylbenzene0.92 Not Detected 5.5 Not Detected1,3-Dichlorobenzene0.92 Not Detected 5.5 Not Detected1,4-Dichlorobenzene0.92 Not Detected 4.7 Not Detectedalpha-Chlorotoluene0.92 Not Detected 5.5 Not Detected1,2-Dichlorobenzene0.92 Not Detected 2.0 Not Detected1,3-Butadiene0.92 Not Detected 3.2 Not DetectedHexane0.92 Not Detected 3.1 Not DetectedCyclohexane0.92 Not Detected 6.1 Not DetectedBromodichloromethane
Page 16 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDR09
Lab ID#: 0604149-05A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041221File Name:Dil. Factor: 1.83
Date of Collection: 4/5/06Date of Analysis: 4/13/06 02:27 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.92 Not Detected 7.8 Not DetectedDibromochloromethane0.92 Not Detected 3.7 Not DetectedHeptane0.92 Not Detected 4.5 Not DetectedCumene0.92 Not Detected 4.5 Not DetectedPropylbenzene3.7 Not Detected 7.6 Not DetectedChloromethane3.7 Not Detected 27 Not Detected1,2,4-Trichlorobenzene3.7 Not Detected 39 Not DetectedHexachlorobutadiene3.7 Not Detected 8.7 Not DetectedAcetone
0.92 Not Detected 2.8 Not DetectedCarbon Disulfide3.7 Not Detected 9.0 Not Detected2-Propanol
0.92 Not Detected 3.6 Not Detectedtrans-1,2-Dichloroethene0.92 Not Detected 2.7 Not Detected2-Butanone (Methyl Ethyl Ketone)0.92 Not Detected 2.7 Not DetectedTetrahydrofuran3.7 Not Detected 13 Not Detected1,4-Dioxane
0.92 Not Detected 3.7 Not Detected4-Methyl-2-pentanone3.7 Not Detected 15 Not Detected2-Hexanone
0.92 Not Detected 9.4 Not DetectedBromoform0.92 Not Detected 4.5 Not Detected4-Ethyltoluene3.7 Not Detected 6.9 Not DetectedEthanol
0.92 Not Detected 3.3 Not DetectedMethyl tert-butyl ether0.92 Not Detected 4.3 Not Detected2,2,4-Trimethylpentane3.7 Not Detected 11 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
None Identified
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
97 70-130Toluene-d897 70-1301,2-Dichloroethane-d4101 70-1304-Bromofluorobenzene
Page 17 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMU09
Lab ID#: 0604149-06A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041222File Name:Dil. Factor: 1.79
Date of Collection: 4/5/06Date of Analysis: 4/13/06 04:09 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.90 Not Detected 4.4 Not DetectedFreon 120.90 Not Detected 6.2 Not DetectedFreon 1140.90 Not Detected 2.3 Not DetectedVinyl Chloride0.90 Not Detected 3.5 Not DetectedBromomethane0.90 Not Detected 2.4 Not DetectedChloroethane0.90 Not Detected 5.0 Not DetectedFreon 110.90 Not Detected 3.5 Not Detected1,1-Dichloroethene0.90 Not Detected 6.8 Not DetectedFreon 1130.90 Not Detected 3.1 Not DetectedMethylene Chloride0.90 Not Detected 3.6 Not Detected1,1-Dichloroethane0.90 Not Detected 3.5 Not Detectedcis-1,2-Dichloroethene0.90 Not Detected 4.4 Not DetectedChloroform0.90 Not Detected 4.9 Not Detected1,1,1-Trichloroethane0.90 Not Detected 5.6 Not DetectedCarbon Tetrachloride0.90 Not Detected 2.8 Not DetectedBenzene0.90 Not Detected 3.6 Not Detected1,2-Dichloroethane0.90 Not Detected 4.8 Not DetectedTrichloroethene0.90 Not Detected 4.1 Not Detected1,2-Dichloropropane0.90 Not Detected 4.1 Not Detectedcis-1,3-Dichloropropene0.90 Not Detected 3.4 Not DetectedToluene0.90 Not Detected 4.1 Not Detectedtrans-1,3-Dichloropropene0.90 Not Detected 4.9 Not Detected1,1,2-Trichloroethane0.90 Not Detected 6.1 Not DetectedTetrachloroethene0.90 Not Detected 6.9 Not Detected1,2-Dibromoethane (EDB)0.90 Not Detected 4.1 Not DetectedChlorobenzene0.90 Not Detected 3.9 Not DetectedEthyl Benzene0.90 Not Detected 3.9 Not Detectedm,p-Xylene0.90 Not Detected 3.9 Not Detectedo-Xylene0.90 Not Detected 3.8 Not DetectedStyrene0.90 Not Detected 6.1 Not Detected1,1,2,2-Tetrachloroethane0.90 Not Detected 4.4 Not Detected1,3,5-Trimethylbenzene0.90 Not Detected 4.4 Not Detected1,2,4-Trimethylbenzene0.90 Not Detected 5.4 Not Detected1,3-Dichlorobenzene0.90 Not Detected 5.4 Not Detected1,4-Dichlorobenzene0.90 Not Detected 4.6 Not Detectedalpha-Chlorotoluene0.90 Not Detected 5.4 Not Detected1,2-Dichlorobenzene0.90 Not Detected 2.0 Not Detected1,3-Butadiene0.90 Not Detected 3.2 Not DetectedHexane0.90 Not Detected 3.1 Not DetectedCyclohexane0.90 Not Detected 6.0 Not DetectedBromodichloromethane
Page 18 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMU09
Lab ID#: 0604149-06A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041222File Name:Dil. Factor: 1.79
Date of Collection: 4/5/06Date of Analysis: 4/13/06 04:09 AM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.90 Not Detected 7.6 Not DetectedDibromochloromethane0.90 Not Detected 3.7 Not DetectedHeptane0.90 Not Detected 4.4 Not DetectedCumene0.90 Not Detected 4.4 Not DetectedPropylbenzene3.6 Not Detected 7.4 Not DetectedChloromethane3.6 Not Detected 26 Not Detected1,2,4-Trichlorobenzene3.6 Not Detected 38 Not DetectedHexachlorobutadiene3.6 3.5 J 8.5 8.4 JAcetone
0.90 Not Detected 2.8 Not DetectedCarbon Disulfide3.6 Not Detected 8.8 Not Detected2-Propanol
0.90 Not Detected 3.5 Not Detectedtrans-1,2-Dichloroethene0.90 Not Detected 2.6 Not Detected2-Butanone (Methyl Ethyl Ketone)0.90 Not Detected 2.6 Not DetectedTetrahydrofuran3.6 Not Detected 13 Not Detected1,4-Dioxane
0.90 Not Detected 3.7 Not Detected4-Methyl-2-pentanone3.6 Not Detected 15 Not Detected2-Hexanone
0.90 Not Detected 9.2 Not DetectedBromoform0.90 Not Detected 4.4 Not Detected4-Ethyltoluene3.6 Not Detected 6.7 Not DetectedEthanol
0.90 Not Detected 3.2 Not DetectedMethyl tert-butyl ether0.90 Not Detected 4.2 Not Detected2,2,4-Trimethylpentane3.6 Not Detected 11 Not Detected3-Chloropropene
J = Estimated value.
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
None Identified
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
99 70-130Toluene-d899 70-1301,2-Dichloroethane-d491 70-1304-Bromofluorobenzene
Page 19 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab ID#: 0604149-07A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041211File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 4/12/06 05:19 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.50 Not Detected 2.5 Not DetectedFreon 120.50 Not Detected 3.5 Not DetectedFreon 1140.50 Not Detected 1.3 Not DetectedVinyl Chloride0.50 Not Detected 1.9 Not DetectedBromomethane0.50 Not Detected 1.3 Not DetectedChloroethane0.50 Not Detected 2.8 Not DetectedFreon 110.50 Not Detected 2.0 Not Detected1,1-Dichloroethene0.50 Not Detected 3.8 Not DetectedFreon 1130.50 Not Detected 1.7 Not DetectedMethylene Chloride0.50 Not Detected 2.0 Not Detected1,1-Dichloroethane0.50 Not Detected 2.0 Not Detectedcis-1,2-Dichloroethene0.50 Not Detected 2.4 Not DetectedChloroform0.50 Not Detected 2.7 Not Detected1,1,1-Trichloroethane0.50 Not Detected 3.1 Not DetectedCarbon Tetrachloride0.50 Not Detected 1.6 Not DetectedBenzene0.50 Not Detected 2.0 Not Detected1,2-Dichloroethane0.50 Not Detected 2.7 Not DetectedTrichloroethene0.50 Not Detected 2.3 Not Detected1,2-Dichloropropane0.50 Not Detected 2.3 Not Detectedcis-1,3-Dichloropropene0.50 Not Detected 1.9 Not DetectedToluene0.50 Not Detected 2.3 Not Detectedtrans-1,3-Dichloropropene0.50 Not Detected 2.7 Not Detected1,1,2-Trichloroethane0.50 Not Detected 3.4 Not DetectedTetrachloroethene0.50 Not Detected 3.8 Not Detected1,2-Dibromoethane (EDB)0.50 Not Detected 2.3 Not DetectedChlorobenzene0.50 Not Detected 2.2 Not DetectedEthyl Benzene0.50 Not Detected 2.2 Not Detectedm,p-Xylene0.50 Not Detected 2.2 Not Detectedo-Xylene0.50 Not Detected 2.1 Not DetectedStyrene0.50 Not Detected 3.4 Not Detected1,1,2,2-Tetrachloroethane0.50 Not Detected 2.4 Not Detected1,3,5-Trimethylbenzene0.50 Not Detected 2.4 Not Detected1,2,4-Trimethylbenzene0.50 Not Detected 3.0 Not Detected1,3-Dichlorobenzene0.50 Not Detected 3.0 Not Detected1,4-Dichlorobenzene0.50 Not Detected 2.6 Not Detectedalpha-Chlorotoluene0.50 Not Detected 3.0 Not Detected1,2-Dichlorobenzene0.50 Not Detected 1.1 Not Detected1,3-Butadiene0.50 Not Detected 1.8 Not DetectedHexane0.50 Not Detected 1.7 Not DetectedCyclohexane0.50 Not Detected 3.4 Not DetectedBromodichloromethane
Page 20 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab ID#: 0604149-07A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041211File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 4/12/06 05:19 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.50 Not Detected 4.2 Not DetectedDibromochloromethane0.50 Not Detected 2.0 Not DetectedHeptane0.50 Not Detected 2.4 Not DetectedCumene0.50 Not Detected 2.4 Not DetectedPropylbenzene2.0 Not Detected 4.1 Not DetectedChloromethane2.0 Not Detected 15 Not Detected1,2,4-Trichlorobenzene2.0 Not Detected 21 Not DetectedHexachlorobutadiene2.0 Not Detected 4.8 Not DetectedAcetone
0.50 Not Detected 1.6 Not DetectedCarbon Disulfide2.0 Not Detected 4.9 Not Detected2-Propanol
0.50 Not Detected 2.0 Not Detectedtrans-1,2-Dichloroethene0.50 Not Detected 1.5 Not Detected2-Butanone (Methyl Ethyl Ketone)0.50 Not Detected 1.5 Not DetectedTetrahydrofuran2.0 Not Detected 7.2 Not Detected1,4-Dioxane
0.50 Not Detected 2.0 Not Detected4-Methyl-2-pentanone2.0 Not Detected 8.2 Not Detected2-Hexanone
0.50 Not Detected 5.2 Not DetectedBromoform0.50 Not Detected 2.4 Not Detected4-Ethyltoluene2.0 Not Detected 3.8 Not DetectedEthanol
0.50 Not Detected 1.8 Not DetectedMethyl tert-butyl ether0.50 Not Detected 2.3 Not Detected2,2,4-Trimethylpentane2.0 Not Detected 6.3 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
None Identified
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d897 70-1301,2-Dichloroethane-d491 70-1304-Bromofluorobenzene
Page 21 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCV
Lab ID#: 0604149-08A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041202File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 4/12/06 09:58 AM
%RecoveryCompound
89Freon 12114Freon 11486Vinyl Chloride99Bromomethane86Chloroethane98Freon 11971,1-Dichloroethene102Freon 113110Methylene Chloride1001,1-Dichloroethane101cis-1,2-Dichloroethene100Chloroform1011,1,1-Trichloroethane104Carbon Tetrachloride102Benzene1051,2-Dichloroethane104Trichloroethene1051,2-Dichloropropane107cis-1,3-Dichloropropene104Toluene105trans-1,3-Dichloropropene1021,1,2-Trichloroethane103Tetrachloroethene1061,2-Dibromoethane (EDB)99Chlorobenzene98Ethyl Benzene95m,p-Xylene95o-Xylene104Styrene931,1,2,2-Tetrachloroethane821,3,5-Trimethylbenzene821,2,4-Trimethylbenzene821,3-Dichlorobenzene821,4-Dichlorobenzene85alpha-Chlorotoluene781,2-Dichlorobenzene951,3-Butadiene101Hexane102Cyclohexane110Bromodichloromethane
Page 22 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCV
Lab ID#: 0604149-08A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041202File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 4/12/06 09:58 AM
%RecoveryCompound
111Dibromochloromethane104Heptane90Cumene90Propylbenzene99Chloromethane841,2,4-Trichlorobenzene86Hexachlorobutadiene96Acetone100Carbon Disulfide1002-Propanol94trans-1,2-Dichloroethene1062-Butanone (Methyl Ethyl Ketone)95Tetrahydrofuran1031,4-Dioxane1124-Methyl-2-pentanone1052-Hexanone108Bromoform884-Ethyltoluene97Ethanol100Methyl tert-butyl ether1002,2,4-Trimethylpentane1003-Chloropropene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d896 70-1301,2-Dichloroethane-d497 70-1304-Bromofluorobenzene
Page 23 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
Lab ID#: 0604149-09A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041204File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 4/12/06 11:44 AM
%RecoveryCompound
91Freon 12116Freon 11489Vinyl Chloride
52 QBromomethane95Chloroethane101Freon 111061,1-Dichloroethene106Freon 113112Methylene Chloride1031,1-Dichloroethane106cis-1,2-Dichloroethene104Chloroform961,1,1-Trichloroethane102Carbon Tetrachloride102Benzene1031,2-Dichloroethane105Trichloroethene1051,2-Dichloropropane86cis-1,3-Dichloropropene102Toluene82trans-1,3-Dichloropropene1031,1,2-Trichloroethane105Tetrachloroethene1051,2-Dibromoethane (EDB)101Chlorobenzene105Ethyl Benzene95m,p-Xylene91o-Xylene108Styrene1011,1,2,2-Tetrachloroethane911,3,5-Trimethylbenzene741,2,4-Trimethylbenzene971,3-Dichlorobenzene971,4-Dichlorobenzene116alpha-Chlorotoluene971,2-Dichlorobenzene1121,3-Butadiene113Hexane107Cyclohexane104Bromodichloromethane
Page 24 of 25
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
Lab ID#: 0604149-09A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
1041204File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 4/12/06 11:44 AM
%RecoveryCompound
104Dibromochloromethane105Heptane119Cumene120Propylbenzene115Chloromethane1011,2,4-Trichlorobenzene95Hexachlorobutadiene108Acetone113Carbon Disulfide1032-Propanol105trans-1,2-Dichloroethene1162-Butanone (Methyl Ethyl Ketone)99Tetrahydrofuran961,4-Dioxane1114-Methyl-2-pentanone1022-Hexanone96Bromoform1144-Ethyltoluene100Ethanol102Methyl tert-butyl ether1322,2,4-Trimethylpentane1093-Chloropropene
Q = Exceeds Quality Control limits.Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
97 70-130Toluene-d898 70-1301,2-Dichloroethane-d4103 70-1304-Bromofluorobenzene
Page 25 of 25
AIR TOXICS LTD.@AN ENVIRONMENTAL ANALYTICAL LABORATORY
Air Toxics Ltd. Introduces the Electronic Report
Thank you for choosing Air Toxics Ltd. To better serve our customers, we are providing your report by e-mail. This document is provided in Portable Document Format which can be viewed with Acrobat Reader by Adobe.
This electronic report includes the following:• Work order Summary;• Laboratory Narrative;• Results; and• Chain of Custody (copy).
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630
(916) 985-1000 .FAX (916) 985-1020Hours 8:00 A.M to 6:00 P.M. Pacific
AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
@
Mr. Felix MoranEnviron International740 Waukegan RoadSuite 401Deerfield, IL 60015
WORK ORDER #: 0604005
CLIENT: BILL TO:
PHONE:
Mr. Felix MoranEnviron International740 Waukegan RoadSuite 401Deerfield, IL 60015
847-444-9200
847-444-9420
04/03/2006DATE COMPLETED: 04/09/2006
P.O. #
PROJECT # 218601AL Midco I
Work Order Summary
FAX:
DATE RECEIVED: CONTACT: Susan Alaniz
NAMEFRACTION # TEST VAC./PRES.RECEIPT
01A 1AMU08 Modified TO-15/TICs 8.5 "Hg02A 1AMDL08 Modified TO-15/TICs 9.0 "Hg03A 1AMDC08 Modified TO-15/TICs 8.5 "Hg04A 1AMDR08 Modified TO-15/TICs 10.0 "Hg04AA 1AMDR08 Duplicate Modified TO-15/TICs 10.0 "Hg05A Lab Blank Modified TO-15/TICs NA06A CCV Modified TO-15/TICs NA07A LCS Modified TO-15/TICs NA
CERTIFIED BY:
Laboratory Director
DATE:
Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/05, Expiration date: 06/30/06
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020
04/09/06
Page 1 of 20
This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards
Certfication numbers: CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004NY NELAP - 11291, UT NELAP - 9166389892
LABORATORY NARRATIVEModified TO-15
Environ InternationalWorkorder# 0604005
@AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Four 6 Liter Summa Canister samples were received on April 03, 2006. The laboratory performed analysisvia modified EPA Method TO-15 using GC/MS in the full scan mode. The method involves concentrating up to 0.2 liters of air. The concentrated aliquot is then flash vaporized and swept through a water managementsystem to remove water vapor. Following dehumidification, the sample passes directly into the GC/MS foranalysis.
Method modifications taken to run these samples are summarized in the below table. Specific projectrequirements may over-ride the ATL modifications.
Requirement ATL ModificationsTO-15Daily CCV +- 30% Difference </= 30% Difference with two allowed out up to </=40%.;
flag and narrate outliers
Sample collection media Summa canister ATL recommends use of summa canisters to insure data defensibility, but will report results from Tedlar bags at client request
Method Detection Limit Follow 40CFR Pt.136 App. B
The MDL met all relevant requirements in Method TO-15 (statistical MDL less than the LOQ). The concentration of the spiked replicate may have exceeded 10X the calculated MDL in some cases
Receiving Notes
There were no receiving discrepancies.
The reported LCS for each daily batch has been derived from more than one analytical file.
Analytical Notes
Eight qualifiers may have been used on the data analysis sheets and indicates as follows: B - Compound present in laboratory blank greater than reporting limit (background subtraction notperformed). J - Estimated value. E - Exceeds instrument calibration range. S - Saturated peak. Q - Exceeds quality control limits. U - Compound analyzed for but not detected above the reporting limit. UJ- Non-detected compound associated with low bias in the CCV N - The identification is based on presumptive evidence.
File extensions may have been used on the data analysis sheets and indicates as follows: a-File was requantified
Definition of Data Qualifying Flags
Page 2 of 20
AN ENVIRONMENTAL ANALYTICAL LABORATORY
AIR TOXICS LTD.@ b-File was quantified by a second column and detector r1-File was requantified for the purpose of reissue
Page 3 of 20
MODIFIED EPA METHOD TO-15 GC/MS FULL SCANSummary of Detected Compounds
AIR TOXICS LTD.@ AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMU08
Lab ID#: 0604005-01ANo Detections Were Found.
Client Sample ID: 1AMDL08
Lab ID#: 0604005-02A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
3.8 3.9 9.1 9.2Acetone
Client Sample ID: 1AMDC08
Lab ID#: 0604005-03A
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
3.7 8.0 8.9 19Acetone
TENTATIVELY IDENTIFIED COMPOUNDS
ppbvMatch QualityCAS NumberCompoundAmount
115-11-7 56% 8.9 N J1-Propene, 2-methyl-75-65-0 72% 5.4 N J2-Propanol, 2-methyl-
Client Sample ID: 1AMDR08
Lab ID#: 0604005-04ANo Detections Were Found.
Client Sample ID: 1AMDR08 Duplicate
Lab ID#: 0604005-04AANo Detections Were Found.
Page 4 of 20
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMU08
Lab ID#: 0604005-01A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f040411File Name:Dil. Factor: 1.87
Date of Collection: 3/30/06Date of Analysis: 4/4/06 05:55 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.94 Not Detected 4.6 Not DetectedFreon 120.94 Not Detected 6.5 Not DetectedFreon 1140.94 Not Detected 2.4 Not DetectedVinyl Chloride0.94 Not Detected 3.6 Not DetectedBromomethane0.94 Not Detected 2.5 Not DetectedChloroethane0.94 Not Detected 5.2 Not DetectedFreon 110.94 Not Detected 3.7 Not Detected1,1-Dichloroethene0.94 Not Detected 7.2 Not DetectedFreon 1130.94 Not Detected 3.2 Not DetectedMethylene Chloride0.94 Not Detected 3.8 Not Detected1,1-Dichloroethane0.94 Not Detected 3.7 Not Detectedcis-1,2-Dichloroethene0.94 Not Detected 4.6 Not DetectedChloroform0.94 Not Detected 5.1 Not Detected1,1,1-Trichloroethane0.94 Not Detected 5.9 Not DetectedCarbon Tetrachloride0.94 Not Detected 3.0 Not DetectedBenzene0.94 Not Detected 3.8 Not Detected1,2-Dichloroethane0.94 Not Detected 5.0 Not DetectedTrichloroethene0.94 Not Detected 4.3 Not Detected1,2-Dichloropropane0.94 Not Detected 4.2 Not Detectedcis-1,3-Dichloropropene0.94 Not Detected 3.5 Not DetectedToluene0.94 Not Detected 4.2 Not Detectedtrans-1,3-Dichloropropene0.94 Not Detected 5.1 Not Detected1,1,2-Trichloroethane0.94 Not Detected 6.3 Not DetectedTetrachloroethene0.94 Not Detected 7.2 Not Detected1,2-Dibromoethane (EDB)0.94 Not Detected 4.3 Not DetectedChlorobenzene0.94 Not Detected 4.0 Not DetectedEthyl Benzene0.94 Not Detected 4.1 Not Detectedm,p-Xylene0.94 Not Detected 4.1 Not Detectedo-Xylene0.94 Not Detected 4.0 Not DetectedStyrene0.94 Not Detected 6.4 Not Detected1,1,2,2-Tetrachloroethane0.94 Not Detected 4.6 Not Detected1,3,5-Trimethylbenzene0.94 Not Detected 4.6 Not Detected1,2,4-Trimethylbenzene0.94 Not Detected 5.6 Not Detected1,3-Dichlorobenzene0.94 Not Detected 5.6 Not Detected1,4-Dichlorobenzene0.94 Not Detected 4.8 Not Detectedalpha-Chlorotoluene0.94 Not Detected 5.6 Not Detected1,2-Dichlorobenzene0.94 Not Detected 2.1 Not Detected1,3-Butadiene0.94 Not Detected 3.3 Not DetectedHexane0.94 Not Detected 3.2 Not DetectedCyclohexane0.94 Not Detected 6.3 Not DetectedBromodichloromethane
Page 5 of 20
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMU08
Lab ID#: 0604005-01A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f040411File Name:Dil. Factor: 1.87
Date of Collection: 3/30/06Date of Analysis: 4/4/06 05:55 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.94 Not Detected 8.0 Not DetectedDibromochloromethane0.94 Not Detected 3.8 Not DetectedHeptane0.94 Not Detected 4.6 Not DetectedCumene0.94 Not Detected 4.6 Not DetectedPropylbenzene3.7 Not Detected 7.7 Not DetectedChloromethane3.7 Not Detected 28 Not Detected1,2,4-Trichlorobenzene3.7 Not Detected 40 Not DetectedHexachlorobutadiene3.7 Not Detected 8.9 Not DetectedAcetone
0.94 Not Detected 2.9 Not DetectedCarbon Disulfide3.7 Not Detected 9.2 Not Detected2-Propanol
0.94 Not Detected 3.7 Not Detectedtrans-1,2-Dichloroethene0.94 Not Detected 2.8 Not Detected2-Butanone (Methyl Ethyl Ketone)0.94 Not Detected 2.8 Not DetectedTetrahydrofuran3.7 Not Detected 13 Not Detected1,4-Dioxane
0.94 Not Detected 3.8 Not Detected4-Methyl-2-pentanone3.7 Not Detected 15 Not Detected2-Hexanone
0.94 Not Detected 9.7 Not DetectedBromoform0.94 Not Detected 4.6 Not Detected4-Ethyltoluene3.7 Not Detected 7.0 Not DetectedEthanol
0.94 Not Detected 3.4 Not DetectedMethyl tert-butyl ether0.94 Not Detected 4.4 Not Detected2,2,4-Trimethylpentane3.7 Not Detected 12 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
None Identified
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
104 70-130Toluene-d889 70-1301,2-Dichloroethane-d4106 70-1304-Bromofluorobenzene
Page 6 of 20
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDL08
Lab ID#: 0604005-02A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f040412File Name:Dil. Factor: 1.91
Date of Collection: 3/30/06Date of Analysis: 4/4/06 06:47 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.96 Not Detected 4.7 Not DetectedFreon 120.96 Not Detected 6.7 Not DetectedFreon 1140.96 Not Detected 2.4 Not DetectedVinyl Chloride0.96 Not Detected 3.7 Not DetectedBromomethane0.96 Not Detected 2.5 Not DetectedChloroethane0.96 Not Detected 5.4 Not DetectedFreon 110.96 Not Detected 3.8 Not Detected1,1-Dichloroethene0.96 Not Detected 7.3 Not DetectedFreon 1130.96 Not Detected 3.3 Not DetectedMethylene Chloride0.96 Not Detected 3.9 Not Detected1,1-Dichloroethane0.96 Not Detected 3.8 Not Detectedcis-1,2-Dichloroethene0.96 Not Detected 4.7 Not DetectedChloroform0.96 Not Detected 5.2 Not Detected1,1,1-Trichloroethane0.96 Not Detected 6.0 Not DetectedCarbon Tetrachloride0.96 Not Detected 3.0 Not DetectedBenzene0.96 Not Detected 3.9 Not Detected1,2-Dichloroethane0.96 Not Detected 5.1 Not DetectedTrichloroethene0.96 Not Detected 4.4 Not Detected1,2-Dichloropropane0.96 Not Detected 4.3 Not Detectedcis-1,3-Dichloropropene0.96 Not Detected 3.6 Not DetectedToluene0.96 Not Detected 4.3 Not Detectedtrans-1,3-Dichloropropene0.96 Not Detected 5.2 Not Detected1,1,2-Trichloroethane0.96 Not Detected 6.5 Not DetectedTetrachloroethene0.96 Not Detected 7.3 Not Detected1,2-Dibromoethane (EDB)0.96 Not Detected 4.4 Not DetectedChlorobenzene0.96 Not Detected 4.1 Not DetectedEthyl Benzene0.96 Not Detected 4.1 Not Detectedm,p-Xylene0.96 Not Detected 4.1 Not Detectedo-Xylene0.96 Not Detected 4.1 Not DetectedStyrene0.96 Not Detected 6.6 Not Detected1,1,2,2-Tetrachloroethane0.96 Not Detected 4.7 Not Detected1,3,5-Trimethylbenzene0.96 Not Detected 4.7 Not Detected1,2,4-Trimethylbenzene0.96 Not Detected 5.7 Not Detected1,3-Dichlorobenzene0.96 Not Detected 5.7 Not Detected1,4-Dichlorobenzene0.96 Not Detected 4.9 Not Detectedalpha-Chlorotoluene0.96 Not Detected 5.7 Not Detected1,2-Dichlorobenzene0.96 Not Detected 2.1 Not Detected1,3-Butadiene0.96 Not Detected 3.4 Not DetectedHexane0.96 Not Detected 3.3 Not DetectedCyclohexane0.96 Not Detected 6.4 Not DetectedBromodichloromethane
Page 7 of 20
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDL08
Lab ID#: 0604005-02A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f040412File Name:Dil. Factor: 1.91
Date of Collection: 3/30/06Date of Analysis: 4/4/06 06:47 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.96 Not Detected 8.1 Not DetectedDibromochloromethane0.96 Not Detected 3.9 Not DetectedHeptane0.96 Not Detected 4.7 Not DetectedCumene0.96 Not Detected 4.7 Not DetectedPropylbenzene3.8 Not Detected 7.9 Not DetectedChloromethane3.8 Not Detected 28 Not Detected1,2,4-Trichlorobenzene3.8 Not Detected 41 Not DetectedHexachlorobutadiene3.8 3.9 9.1 9.2Acetone
0.96 Not Detected 3.0 Not DetectedCarbon Disulfide3.8 Not Detected 9.4 Not Detected2-Propanol
0.96 Not Detected 3.8 Not Detectedtrans-1,2-Dichloroethene0.96 Not Detected 2.8 Not Detected2-Butanone (Methyl Ethyl Ketone)0.96 Not Detected 2.8 Not DetectedTetrahydrofuran3.8 Not Detected 14 Not Detected1,4-Dioxane
0.96 Not Detected 3.9 Not Detected4-Methyl-2-pentanone3.8 Not Detected 16 Not Detected2-Hexanone
0.96 Not Detected 9.9 Not DetectedBromoform0.96 Not Detected 4.7 Not Detected4-Ethyltoluene3.8 Not Detected 7.2 Not DetectedEthanol
0.96 Not Detected 3.4 Not DetectedMethyl tert-butyl ether0.96 Not Detected 4.5 Not Detected2,2,4-Trimethylpentane3.8 Not Detected 12 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
None Identified
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d893 70-1301,2-Dichloroethane-d4103 70-1304-Bromofluorobenzene
Page 8 of 20
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDC08
Lab ID#: 0604005-03A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f040413File Name:Dil. Factor: 1.87
Date of Collection: 3/30/06Date of Analysis: 4/4/06 07:27 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.94 Not Detected 4.6 Not DetectedFreon 120.94 Not Detected 6.5 Not DetectedFreon 1140.94 Not Detected 2.4 Not DetectedVinyl Chloride0.94 Not Detected 3.6 Not DetectedBromomethane0.94 Not Detected 2.5 Not DetectedChloroethane0.94 Not Detected 5.2 Not DetectedFreon 110.94 Not Detected 3.7 Not Detected1,1-Dichloroethene0.94 Not Detected 7.2 Not DetectedFreon 1130.94 Not Detected 3.2 Not DetectedMethylene Chloride0.94 Not Detected 3.8 Not Detected1,1-Dichloroethane0.94 Not Detected 3.7 Not Detectedcis-1,2-Dichloroethene0.94 Not Detected 4.6 Not DetectedChloroform0.94 Not Detected 5.1 Not Detected1,1,1-Trichloroethane0.94 Not Detected 5.9 Not DetectedCarbon Tetrachloride0.94 Not Detected 3.0 Not DetectedBenzene0.94 Not Detected 3.8 Not Detected1,2-Dichloroethane0.94 Not Detected 5.0 Not DetectedTrichloroethene0.94 Not Detected 4.3 Not Detected1,2-Dichloropropane0.94 Not Detected 4.2 Not Detectedcis-1,3-Dichloropropene0.94 Not Detected 3.5 Not DetectedToluene0.94 Not Detected 4.2 Not Detectedtrans-1,3-Dichloropropene0.94 Not Detected 5.1 Not Detected1,1,2-Trichloroethane0.94 Not Detected 6.3 Not DetectedTetrachloroethene0.94 Not Detected 7.2 Not Detected1,2-Dibromoethane (EDB)0.94 Not Detected 4.3 Not DetectedChlorobenzene0.94 Not Detected 4.0 Not DetectedEthyl Benzene0.94 Not Detected 4.1 Not Detectedm,p-Xylene0.94 Not Detected 4.1 Not Detectedo-Xylene0.94 Not Detected 4.0 Not DetectedStyrene0.94 Not Detected 6.4 Not Detected1,1,2,2-Tetrachloroethane0.94 Not Detected 4.6 Not Detected1,3,5-Trimethylbenzene0.94 Not Detected 4.6 Not Detected1,2,4-Trimethylbenzene0.94 Not Detected 5.6 Not Detected1,3-Dichlorobenzene0.94 Not Detected 5.6 Not Detected1,4-Dichlorobenzene0.94 Not Detected 4.8 Not Detectedalpha-Chlorotoluene0.94 Not Detected 5.6 Not Detected1,2-Dichlorobenzene0.94 Not Detected 2.1 Not Detected1,3-Butadiene0.94 Not Detected 3.3 Not DetectedHexane0.94 Not Detected 3.2 Not DetectedCyclohexane0.94 Not Detected 6.3 Not DetectedBromodichloromethane
Page 9 of 20
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDC08
Lab ID#: 0604005-03A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f040413File Name:Dil. Factor: 1.87
Date of Collection: 3/30/06Date of Analysis: 4/4/06 07:27 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.94 Not Detected 8.0 Not DetectedDibromochloromethane0.94 Not Detected 3.8 Not DetectedHeptane0.94 Not Detected 4.6 Not DetectedCumene0.94 Not Detected 4.6 Not DetectedPropylbenzene3.7 Not Detected 7.7 Not DetectedChloromethane3.7 Not Detected 28 Not Detected1,2,4-Trichlorobenzene3.7 Not Detected 40 Not DetectedHexachlorobutadiene3.7 8.0 8.9 19Acetone
0.94 Not Detected 2.9 Not DetectedCarbon Disulfide3.7 Not Detected 9.2 Not Detected2-Propanol
0.94 Not Detected 3.7 Not Detectedtrans-1,2-Dichloroethene0.94 Not Detected 2.8 Not Detected2-Butanone (Methyl Ethyl Ketone)0.94 Not Detected 2.8 Not DetectedTetrahydrofuran3.7 Not Detected 13 Not Detected1,4-Dioxane
0.94 Not Detected 3.8 Not Detected4-Methyl-2-pentanone3.7 Not Detected 15 Not Detected2-Hexanone
0.94 Not Detected 9.7 Not DetectedBromoform0.94 Not Detected 4.6 Not Detected4-Ethyltoluene3.7 Not Detected 7.0 Not DetectedEthanol
0.94 Not Detected 3.4 Not DetectedMethyl tert-butyl ether0.94 Not Detected 4.4 Not Detected2,2,4-Trimethylpentane3.7 Not Detected 12 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
115-11-7 56% 8.9 N J1-Propene, 2-methyl-75-65-0 72% 5.4 N J2-Propanol, 2-methyl-
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d895 70-1301,2-Dichloroethane-d4105 70-1304-Bromofluorobenzene
Page 10 of 20
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDR08
Lab ID#: 0604005-04A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f040414File Name:Dil. Factor: 2.01
Date of Collection: 3/30/06Date of Analysis: 4/4/06 08:07 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
1.0 Not Detected 5.0 Not DetectedFreon 121.0 Not Detected 7.0 Not DetectedFreon 1141.0 Not Detected 2.6 Not DetectedVinyl Chloride1.0 Not Detected 3.9 Not DetectedBromomethane1.0 Not Detected 2.6 Not DetectedChloroethane1.0 Not Detected 5.6 Not DetectedFreon 111.0 Not Detected 4.0 Not Detected1,1-Dichloroethene1.0 Not Detected 7.7 Not DetectedFreon 1131.0 Not Detected 3.5 Not DetectedMethylene Chloride1.0 Not Detected 4.1 Not Detected1,1-Dichloroethane1.0 Not Detected 4.0 Not Detectedcis-1,2-Dichloroethene1.0 Not Detected 4.9 Not DetectedChloroform1.0 Not Detected 5.5 Not Detected1,1,1-Trichloroethane1.0 Not Detected 6.3 Not DetectedCarbon Tetrachloride1.0 Not Detected 3.2 Not DetectedBenzene1.0 Not Detected 4.1 Not Detected1,2-Dichloroethane1.0 Not Detected 5.4 Not DetectedTrichloroethene1.0 Not Detected 4.6 Not Detected1,2-Dichloropropane1.0 Not Detected 4.6 Not Detectedcis-1,3-Dichloropropene1.0 Not Detected 3.8 Not DetectedToluene1.0 Not Detected 4.6 Not Detectedtrans-1,3-Dichloropropene1.0 Not Detected 5.5 Not Detected1,1,2-Trichloroethane1.0 Not Detected 6.8 Not DetectedTetrachloroethene1.0 Not Detected 7.7 Not Detected1,2-Dibromoethane (EDB)1.0 Not Detected 4.6 Not DetectedChlorobenzene1.0 Not Detected 4.4 Not DetectedEthyl Benzene1.0 Not Detected 4.4 Not Detectedm,p-Xylene1.0 Not Detected 4.4 Not Detectedo-Xylene1.0 Not Detected 4.3 Not DetectedStyrene1.0 Not Detected 6.9 Not Detected1,1,2,2-Tetrachloroethane1.0 Not Detected 4.9 Not Detected1,3,5-Trimethylbenzene1.0 Not Detected 4.9 Not Detected1,2,4-Trimethylbenzene1.0 Not Detected 6.0 Not Detected1,3-Dichlorobenzene1.0 Not Detected 6.0 Not Detected1,4-Dichlorobenzene1.0 Not Detected 5.2 Not Detectedalpha-Chlorotoluene1.0 Not Detected 6.0 Not Detected1,2-Dichlorobenzene1.0 Not Detected 2.2 Not Detected1,3-Butadiene1.0 Not Detected 3.5 Not DetectedHexane1.0 Not Detected 3.4 Not DetectedCyclohexane1.0 Not Detected 6.7 Not DetectedBromodichloromethane
Page 11 of 20
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDR08
Lab ID#: 0604005-04A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f040414File Name:Dil. Factor: 2.01
Date of Collection: 3/30/06Date of Analysis: 4/4/06 08:07 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
1.0 Not Detected 8.6 Not DetectedDibromochloromethane1.0 Not Detected 4.1 Not DetectedHeptane1.0 Not Detected 4.9 Not DetectedCumene1.0 Not Detected 4.9 Not DetectedPropylbenzene4.0 Not Detected 8.3 Not DetectedChloromethane4.0 Not Detected 30 Not Detected1,2,4-Trichlorobenzene4.0 Not Detected 43 Not DetectedHexachlorobutadiene4.0 Not Detected 9.5 Not DetectedAcetone1.0 Not Detected 3.1 Not DetectedCarbon Disulfide4.0 Not Detected 9.9 Not Detected2-Propanol1.0 Not Detected 4.0 Not Detectedtrans-1,2-Dichloroethene1.0 Not Detected 3.0 Not Detected2-Butanone (Methyl Ethyl Ketone)1.0 Not Detected 3.0 Not DetectedTetrahydrofuran4.0 Not Detected 14 Not Detected1,4-Dioxane1.0 Not Detected 4.1 Not Detected4-Methyl-2-pentanone4.0 Not Detected 16 Not Detected2-Hexanone1.0 Not Detected 10 Not DetectedBromoform1.0 Not Detected 4.9 Not Detected4-Ethyltoluene4.0 Not Detected 7.6 Not DetectedEthanol1.0 Not Detected 3.6 Not DetectedMethyl tert-butyl ether1.0 Not Detected 4.7 Not Detected2,2,4-Trimethylpentane4.0 Not Detected 12 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
None Identified
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
103 70-130Toluene-d893 70-1301,2-Dichloroethane-d4105 70-1304-Bromofluorobenzene
Page 12 of 20
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDR08 Duplicate
Lab ID#: 0604005-04AA
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f040415File Name:Dil. Factor: 2.01
Date of Collection: 3/30/06Date of Analysis: 4/4/06 09:00 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
1.0 Not Detected 5.0 Not DetectedFreon 121.0 Not Detected 7.0 Not DetectedFreon 1141.0 Not Detected 2.6 Not DetectedVinyl Chloride1.0 Not Detected 3.9 Not DetectedBromomethane1.0 Not Detected 2.6 Not DetectedChloroethane1.0 Not Detected 5.6 Not DetectedFreon 111.0 Not Detected 4.0 Not Detected1,1-Dichloroethene1.0 Not Detected 7.7 Not DetectedFreon 1131.0 Not Detected 3.5 Not DetectedMethylene Chloride1.0 Not Detected 4.1 Not Detected1,1-Dichloroethane1.0 Not Detected 4.0 Not Detectedcis-1,2-Dichloroethene1.0 Not Detected 4.9 Not DetectedChloroform1.0 Not Detected 5.5 Not Detected1,1,1-Trichloroethane1.0 Not Detected 6.3 Not DetectedCarbon Tetrachloride1.0 Not Detected 3.2 Not DetectedBenzene1.0 Not Detected 4.1 Not Detected1,2-Dichloroethane1.0 Not Detected 5.4 Not DetectedTrichloroethene1.0 Not Detected 4.6 Not Detected1,2-Dichloropropane1.0 Not Detected 4.6 Not Detectedcis-1,3-Dichloropropene1.0 Not Detected 3.8 Not DetectedToluene1.0 Not Detected 4.6 Not Detectedtrans-1,3-Dichloropropene1.0 Not Detected 5.5 Not Detected1,1,2-Trichloroethane1.0 Not Detected 6.8 Not DetectedTetrachloroethene1.0 Not Detected 7.7 Not Detected1,2-Dibromoethane (EDB)1.0 Not Detected 4.6 Not DetectedChlorobenzene1.0 Not Detected 4.4 Not DetectedEthyl Benzene1.0 Not Detected 4.4 Not Detectedm,p-Xylene1.0 Not Detected 4.4 Not Detectedo-Xylene1.0 Not Detected 4.3 Not DetectedStyrene1.0 Not Detected 6.9 Not Detected1,1,2,2-Tetrachloroethane1.0 Not Detected 4.9 Not Detected1,3,5-Trimethylbenzene1.0 Not Detected 4.9 Not Detected1,2,4-Trimethylbenzene1.0 Not Detected 6.0 Not Detected1,3-Dichlorobenzene1.0 Not Detected 6.0 Not Detected1,4-Dichlorobenzene1.0 Not Detected 5.2 Not Detectedalpha-Chlorotoluene1.0 Not Detected 6.0 Not Detected1,2-Dichlorobenzene1.0 Not Detected 2.2 Not Detected1,3-Butadiene1.0 Not Detected 3.5 Not DetectedHexane1.0 Not Detected 3.4 Not DetectedCyclohexane1.0 Not Detected 6.7 Not DetectedBromodichloromethane
Page 13 of 20
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 1AMDR08 Duplicate
Lab ID#: 0604005-04AA
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f040415File Name:Dil. Factor: 2.01
Date of Collection: 3/30/06Date of Analysis: 4/4/06 09:00 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
1.0 Not Detected 8.6 Not DetectedDibromochloromethane1.0 Not Detected 4.1 Not DetectedHeptane1.0 Not Detected 4.9 Not DetectedCumene1.0 Not Detected 4.9 Not DetectedPropylbenzene4.0 Not Detected 8.3 Not DetectedChloromethane4.0 Not Detected 30 Not Detected1,2,4-Trichlorobenzene4.0 Not Detected 43 Not DetectedHexachlorobutadiene4.0 Not Detected 9.5 Not DetectedAcetone1.0 Not Detected 3.1 Not DetectedCarbon Disulfide4.0 Not Detected 9.9 Not Detected2-Propanol1.0 Not Detected 4.0 Not Detectedtrans-1,2-Dichloroethene1.0 Not Detected 3.0 Not Detected2-Butanone (Methyl Ethyl Ketone)1.0 Not Detected 3.0 Not DetectedTetrahydrofuran4.0 Not Detected 14 Not Detected1,4-Dioxane1.0 Not Detected 4.1 Not Detected4-Methyl-2-pentanone4.0 Not Detected 16 Not Detected2-Hexanone1.0 Not Detected 10 Not DetectedBromoform1.0 Not Detected 4.9 Not Detected4-Ethyltoluene4.0 Not Detected 7.6 Not DetectedEthanol1.0 Not Detected 3.6 Not DetectedMethyl tert-butyl ether1.0 Not Detected 4.7 Not Detected2,2,4-Trimethylpentane4.0 Not Detected 12 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
None Identified
Container Type: 6 Liter Summa Canister
Limits%RecoverySurrogatesMethod
97 70-130Toluene-d8102 70-1301,2-Dichloroethane-d4104 70-1304-Bromofluorobenzene
Page 14 of 20
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab ID#: 0604005-05A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f040406File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 4/4/06 01:19 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.50 Not Detected 2.5 Not DetectedFreon 120.50 Not Detected 3.5 Not DetectedFreon 1140.50 Not Detected 1.3 Not DetectedVinyl Chloride0.50 Not Detected 1.9 Not DetectedBromomethane0.50 Not Detected 1.3 Not DetectedChloroethane0.50 Not Detected 2.8 Not DetectedFreon 110.50 Not Detected 2.0 Not Detected1,1-Dichloroethene0.50 Not Detected 3.8 Not DetectedFreon 1130.50 Not Detected 1.7 Not DetectedMethylene Chloride0.50 Not Detected 2.0 Not Detected1,1-Dichloroethane0.50 Not Detected 2.0 Not Detectedcis-1,2-Dichloroethene0.50 Not Detected 2.4 Not DetectedChloroform0.50 Not Detected 2.7 Not Detected1,1,1-Trichloroethane0.50 Not Detected 3.1 Not DetectedCarbon Tetrachloride0.50 Not Detected 1.6 Not DetectedBenzene0.50 Not Detected 2.0 Not Detected1,2-Dichloroethane0.50 Not Detected 2.7 Not DetectedTrichloroethene0.50 Not Detected 2.3 Not Detected1,2-Dichloropropane0.50 Not Detected 2.3 Not Detectedcis-1,3-Dichloropropene0.50 Not Detected 1.9 Not DetectedToluene0.50 Not Detected 2.3 Not Detectedtrans-1,3-Dichloropropene0.50 Not Detected 2.7 Not Detected1,1,2-Trichloroethane0.50 Not Detected 3.4 Not DetectedTetrachloroethene0.50 Not Detected 3.8 Not Detected1,2-Dibromoethane (EDB)0.50 Not Detected 2.3 Not DetectedChlorobenzene0.50 Not Detected 2.2 Not DetectedEthyl Benzene0.50 Not Detected 2.2 Not Detectedm,p-Xylene0.50 Not Detected 2.2 Not Detectedo-Xylene0.50 Not Detected 2.1 Not DetectedStyrene0.50 Not Detected 3.4 Not Detected1,1,2,2-Tetrachloroethane0.50 Not Detected 2.4 Not Detected1,3,5-Trimethylbenzene0.50 Not Detected 2.4 Not Detected1,2,4-Trimethylbenzene0.50 Not Detected 3.0 Not Detected1,3-Dichlorobenzene0.50 Not Detected 3.0 Not Detected1,4-Dichlorobenzene0.50 Not Detected 2.6 Not Detectedalpha-Chlorotoluene0.50 Not Detected 3.0 Not Detected1,2-Dichlorobenzene0.50 Not Detected 1.1 Not Detected1,3-Butadiene0.50 Not Detected 1.8 Not DetectedHexane0.50 Not Detected 1.7 Not DetectedCyclohexane0.50 Not Detected 3.4 Not DetectedBromodichloromethane
Page 15 of 20
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab ID#: 0604005-05A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f040406File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 4/4/06 01:19 PM
(uG/m3)(uG/m3)(ppbv)(ppbv)CompoundAmountRpt. LimitAmountRpt. Limit
0.50 Not Detected 4.2 Not DetectedDibromochloromethane0.50 Not Detected 2.0 Not DetectedHeptane0.50 Not Detected 2.4 Not DetectedCumene0.50 Not Detected 2.4 Not DetectedPropylbenzene2.0 Not Detected 4.1 Not DetectedChloromethane2.0 Not Detected 15 Not Detected1,2,4-Trichlorobenzene2.0 Not Detected 21 Not DetectedHexachlorobutadiene2.0 Not Detected 4.8 Not DetectedAcetone
0.50 Not Detected 1.6 Not DetectedCarbon Disulfide2.0 Not Detected 4.9 Not Detected2-Propanol
0.50 Not Detected 2.0 Not Detectedtrans-1,2-Dichloroethene0.50 Not Detected 1.5 Not Detected2-Butanone (Methyl Ethyl Ketone)0.50 Not Detected 1.5 Not DetectedTetrahydrofuran2.0 Not Detected 7.2 Not Detected1,4-Dioxane
0.50 Not Detected 2.0 Not Detected4-Methyl-2-pentanone2.0 Not Detected 8.2 Not Detected2-Hexanone
0.50 Not Detected 5.2 Not DetectedBromoform0.50 Not Detected 2.4 Not Detected4-Ethyltoluene2.0 Not Detected 3.8 Not DetectedEthanol
0.50 Not Detected 1.8 Not DetectedMethyl tert-butyl ether0.50 Not Detected 2.3 Not Detected2,2,4-Trimethylpentane2.0 Not Detected 6.3 Not Detected3-Chloropropene
TENTATIVELY IDENTIFIED COMPOUNDS
(ppbv)Match QualityCAS NumberCompoundAmount
None Identified
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
103 70-130Toluene-d888 70-1301,2-Dichloroethane-d4103 70-1304-Bromofluorobenzene
Page 16 of 20
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCV
Lab ID#: 0604005-06A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f040402File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 4/4/06 10:33 AM
%RecoveryCompound
93Freon 1294Freon 11496Vinyl Chloride97Bromomethane94Chloroethane96Freon 11991,1-Dichloroethene95Freon 11396Methylene Chloride991,1-Dichloroethane100cis-1,2-Dichloroethene96Chloroform1001,1,1-Trichloroethane101Carbon Tetrachloride98Benzene1041,2-Dichloroethane103Trichloroethene1051,2-Dichloropropane108cis-1,3-Dichloropropene102Toluene105trans-1,3-Dichloropropene1021,1,2-Trichloroethane102Tetrachloroethene1031,2-Dibromoethane (EDB)99Chlorobenzene103Ethyl Benzene94m,p-Xylene101o-Xylene98Styrene951,1,2,2-Tetrachloroethane971,3,5-Trimethylbenzene981,2,4-Trimethylbenzene921,3-Dichlorobenzene921,4-Dichlorobenzene100alpha-Chlorotoluene911,2-Dichlorobenzene1001,3-Butadiene102Hexane103Cyclohexane107Bromodichloromethane
Page 17 of 20
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCV
Lab ID#: 0604005-06A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f040402File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 4/4/06 10:33 AM
%RecoveryCompound
109Dibromochloromethane108Heptane90Cumene99Propylbenzene97Chloromethane971,2,4-Trichlorobenzene104Hexachlorobutadiene96Acetone98Carbon Disulfide1012-Propanol95trans-1,2-Dichloroethene1082-Butanone (Methyl Ethyl Ketone)107Tetrahydrofuran1021,4-Dioxane1124-Methyl-2-pentanone1022-Hexanone107Bromoform1004-Ethyltoluene94Ethanol107Methyl tert-butyl ether1032,2,4-Trimethylpentane1003-Chloropropene
Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
100 70-130Toluene-d8102 70-1301,2-Dichloroethane-d499 70-1304-Bromofluorobenzene
Page 18 of 20
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
Lab ID#: 0604005-07A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f040403File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 4/4/06 11:16 AM
%RecoveryCompound
95Freon 1295Freon 11499Vinyl Chloride105Bromomethane108Chloroethane99Freon 111021,1-Dichloroethene99Freon 113100Methylene Chloride1031,1-Dichloroethane106cis-1,2-Dichloroethene100Chloroform1041,1,1-Trichloroethane105Carbon Tetrachloride99Benzene1051,2-Dichloroethane105Trichloroethene1061,2-Dichloropropane95cis-1,3-Dichloropropene102Toluene59 Qtrans-1,3-Dichloropropene1041,1,2-Trichloroethane104Tetrachloroethene1051,2-Dibromoethane (EDB)101Chlorobenzene107Ethyl Benzene92m,p-Xylene91o-Xylene87Styrene981,1,2,2-Tetrachloroethane901,3,5-Trimethylbenzene731,2,4-Trimethylbenzene981,3-Dichlorobenzene991,4-Dichlorobenzene108alpha-Chlorotoluene971,2-Dichlorobenzene1121,3-Butadiene110Hexane105Cyclohexane102Bromodichloromethane
Page 19 of 20
@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
Lab ID#: 0604005-07A
MODIFIED EPA METHOD TO-15 GC/MS FULL SCAN
f040403File Name:Dil. Factor: 1.00
Date of Collection: NA Date of Analysis: 4/4/06 11:16 AM
%RecoveryCompound
101Dibromochloromethane104Heptane98Cumene111Propylbenzene99Chloromethane1171,2,4-Trichlorobenzene110Hexachlorobutadiene105Acetone109Carbon Disulfide1042-Propanol102trans-1,2-Dichloroethene1162-Butanone (Methyl Ethyl Ketone)111Tetrahydrofuran961,4-Dioxane1114-Methyl-2-pentanone972-Hexanone88Bromoform1104-Ethyltoluene102Ethanol112Methyl tert-butyl ether1202,2,4-Trimethylpentane1203-Chloropropene
Q = Exceeds Quality Control limits.Container Type: NA - Not Applicable
Limits%RecoverySurrogatesMethod
101 70-130Toluene-d8105 70-1301,2-Dichloroethane-d497 70-1304-Bromofluorobenzene
Page 20 of 20