^ l-^ '- chain of custody record · 2019-12-12 · (dionex model 16 and model 2110i),...
TRANSCRIPT
ENV ONMENTAL PROTECTION AGENCY "TVPi j Office of Enforcement \ ^ L-^ '- if \^J
CHAIN OF CUSTODY RECORD
001506
PROTECTION AGENCY HWI
INORGANICS TRAFFIC REPO(7) Case Number-
Sample Site Name/Code:0 SAMPLE CONCENTRATION
(Check One)———— Low Concentration————— Madium Concentration0 SAMPLE MATRIX
(Check One)———— Water—— *— Soil/Sediment
("$) Sampling Office: j_-Sampling Personnel:
(T\Jam<=>)fPhone* . , •Sampling Date:(Begin) fEndl
0 Shipping Information:NimeOf Carrier.
DatiaShirtpi'sf*' _.,„ . .
fiirhif] IMtimher- , , .-
@ Sample Description:(Check One!
——— Surface Water———— Ground Water——— Leachate——— Mixed Media-- ,-^- Solidsr*K-r
(specify)MATCHES ORGANIC SAMPLE NO •
(3) Mark Volume LevelOn Sample BottleCheck Analysts required
. .: Total Metals. * Cyanide
0 Ship To:"*' '* 'f ' „- : :' '
Atte: , t . . ; - . .- -'IVaiwstoar * • * * * ' '*Ship To:
0 ANALYSIS U«J- k
B^ v r3Jj)Ufl 'l(iMh<Jr\rw.^.ty \» i ^-3@Saznpld Coa6^oxt _ -On Receipt; • -
{eg broken, leakage^ chaiii$i custfxiy, etc)nin(j( :
. . . . . . .
LABHLECOPY
001508
TO Jl POI/**Inrtxrlw(T) CaaeNumher:
Sample Site Name/Code:0 SAMPLECONCENTRATION
(Check Ona)——— |l — Low Concentration————— Medium Concentration© SAMPLE MATRIX
(Check One)———— Water—— t^L- Soil/Sediment
g) Samplino Office: t y.Sampling Personnel-
(N^m^^ ' .• / -(Phone) - . _ ' ' •-'Sajnpling Date; _ ,(Beam! (Endl
(e) Shipping Information:Name Of Carrier-
/. ,
DflFA Shipped: -
fl irKil lNt.mhftr- ' t , '
© Sample Description.:(Check One)
——— . Surface Water———— Ground Water- ——— Leachate
. .Mixed Media-i..i A;'' Solids
r>Ke>r(specify)
MATTHFRORGflNTr SAMPT R NO . „,'„'.,.,.
(t\ Mark Volume LevelOn Sample BottleCheck Analysis required
„ ' Total Metals^rOyunlde
, „. —— , — „. , «, T,-W,.__, — _. ———0 B l ; "
• ' ,1 i> 7 -f **, f . r . - . ^ , ;„,-/.' . /• . f • S f / - 7 C V
_ * ( ; , • 1 , , ' , f-
Atto: '.' • ^-. - -t A- p
Trajas&HT • .Sh l! -
(?) ANALYSES LAB:*^^C]^&ftAHk\H^AR^^I. *-M * ' '"
Sample ConditionOnReoe% : i
{eg broken, Ieak»ge, c in of custody, eta.);\^' it•l• '. . •
LABFILECOPY
001509
A TU: PROTECTION AGENCY' HWT Scruple M
INORGANICS TRAFFIC(7) Case Number: , .... . , ' J 'l
Sample Site Name/Code:0 SAMPLE CONCENTRATION
(Check Ono)———— Low Concentration0 SAMPLE MATRIX
(Check One)———— Water———— Soil/Sediment
r— — ——————————————————— ——————————————————————fc$y Sampling Office:
Sampling Personnel
fMAmnl
(Phone 1Sampling Date(Beam) (End)
(s) Shipping Information:Name Of Car net.
r>»ff> .^Mpp^rf _A'rhiP NFT^V^r- n i i , p , ,. ,
© Sample Description:(Check One)
——— Surface Water——— T tarounu Water——— Leachate
Mt«-aH Media___ Solidsothfir • - • .6,'.-'- > '
(specify)MATCHES ORGANIC SAMPLE NO. —————
f$\ Mark Volume LevelOn Sample BottleCheck Analysis required
. Total Metals_ Cyanide
, „ . . . . , . . ,,,..,,,,_^ . ^ , . . , „ . . . .(«) Sb^»lG»; |1-• : ^--. »*;
AfefaxTransferSls^tTo:
© ANAI..YSIP.TO:p^Kr <'w#&Au\1 "" . •"" ^Da*«H«ririt- ' . 1 * - t'''4'
®Sample Cond^teonir*\BB *^ * ••IIMMI'I^B L ' -Un necca^t: ^
Eeg broken. Ieafeage!, ?h«iEic^ custody, ate.)M • 1 If
"." T
LABFILECOPY
001510
U.S. ENVIRONMENTAL PROTECTION AGENCY HY ~ Scrapio
INORGANICS TRAFFICT Case Number:
Sample Site Name/Code:SAMPLE CONCENTRATION
' (Check One)—— Low Concentration—— Medium ConcentrationSAMPLE MATRIX
(Check One)—— Waterii Soil/Sediment
) Sampling Office:Sampling Personnel:
(Name) .^U_TJ____:{Phone; 'Sampling Date.(Begin)_____ (End)
(e) Shipping Information:Name Of Carrier-
Date Shipped: ______j. __ _!_"_!Airbill Number: 'l
© Sample Description:(Check One)
——— Surface Water——— Ground Water——— Leachate——— Mixed Media_ _-—_ Solids___ Other __________{specify}MATCHES ORGANIC SAMPLE NO.
'a) Mark Volume LevelOn Sample BottleCheck Analysis required
__ Total Metals
LAB FILE COPY
TransferShip To:
® ANALYSIS LAB:Reed by: OqSJ
Date Reed:
On Receipt:(eg broken, teakftga, c^Kiin erf custody, «tc.)
001511
f AL PROTECTION AGENCY HWI Samle
INORGANICS TRAFFIC REPORT(?) Case Number: . ' M
Sample Site Name/Code:@ SAMPLE CONCENTRATION
(Check Ons}——— '• — Low Concentration————— Medium Concentration® SAMPLE MATRIX
(Check One)————— Water—— ,. — Soil/Sediment
j (J) Sampliztq Office: "- 7/T"Sampling Personnel:
fName! ' - -' • 1 - ,(Phono) / , • , *Sampling Date: - - - ' •/ » . ' /
' x <•<Beoin} (End*
(«) Shipping Information:Name Of Carrier:
r r c^DateShmped: ' •' '' '
Airbill Number: - - ' '" / -"
© Sample Description:(Check One)
———— Surface Water———— Ground Water
X'fiTCM^ ^A^r^t^*
——— SolidsOfhor 1
(specify)MATCHES ORGANIC SAMPLE NO —— t ——— i
(s) Mark Volume LevelOn Sample BottlsCheck Analysis required'Total Metals
„ -^fy&nitlB
\ V
0 SBup1)K:i:: 1:' / . J I A M "' • : . * . . • ' ; ! .
'' ' ' . • X. ' . . - - > t tl . ™ • t r ', , _ ., ? - -_Attn: - -r- ,ilfc--^^' • —— ——TransferShip To:
(?) ANALYSES UP:y u :: . , \n.t.B^.' HSV ' t r -J
Sample CondStiooOn Receipt:
(eg broken, leakage, chain of custody, etc )/ UO lU
LABFUECDPY
001512
11 January 1986
USEPANEIC Contract Audit Team12600 W. Colfax, Suite C310Lakewood, Colorado 80215Re: Contract No. 68-01-06880; Case No. 5421
CC Report No. 542 1 , SOW No. 784
Enclosed are the analytical data and quality assurance for case No, 5421received from Region VI on January 13, 1986.Please note the following:
1. Enclosed is the resume for Kathryn D. Whitwortb, a chemical technicianwho will be performing cyanide analyses for this contract.
2. One ml of LOGO ppm Barium (Spex lot # 0485RS) was added to EPA concentratewp .:84 before dilution. EPA WP 882 , which does not contain barium, is usedbecause Ca, Mg, X and N'a are at appropriate concentrations for ICPES analysis.
If you have any questions or comments about this case, please call me at thenumber listed below.
Sir.~erely,
Re> ca H. BurrisDocument Control Off i cer
RHB/clEnclosure
8501 Mo-Pac Blvd. / P.O. Box 9948 / Aust i n . Texas 78766; (5 12 )454-4797
001513
RADIAN
KATHimi D, WHITtfORTH
EBUCATIQK:Del MarBig Spring,TX, September
Corpus Chrisei, TX, January - May 1978; Howard College,September 1974 - Hay 1975; Bee County College, Beeville,
1972 - May 1973.
EXPERIENCE:
Chemical Technician, Radian Corporation, Austin, TX, February 1985-Present.Claims Clerk, Prudential Group Health Claims, Austin, TX, January1984-January 1985.Laboratory Technician, Lower Colorado River Authority, Austin, TX, May1982-December 1982 .Senior Laboratory Technician, Conquista Project, Falls City, TX, March1979-May 1982 .Laboratory Technician, Panna Maria Project , Nobsou, TX, October1978-February 1 9 7 9 .
FIELDS OR EXPERIENCE:
Ms. Whitworth has worked in Radian Analytical Services' Water QualityLaboratory since February 1984 as a Chemical Technician. Her job dutiesinclude analysis of water and wastewater by EPA and SM techniques. Sheperforms classical wet chemistry analyses by colorimetric and titrime-tric methods. Physical parameters of dissolved solids and oil and greaseare done gravimetrically. In addition, Ms. Whitworth has gainedproficiency in the following instrumental analyses: Technicon Auto-analyzer II, Beckman 915-B Carbon Analyzer , and Oil and Grease Analysesby IR. Also, secondary area of proficiency include ion chromatography(Dionex Model 16 and Model 2 1 10 i ) , automatic t itrat ion (Metrohm Auto-t itrator) , and TOX (Dohrmann Model 2 0 ) .In addition to her analytical dut ies , Ms. Whitworth performs extensivepreventative maintenance on the equipment:. She is also responsible forthe preparation of chemical standards, analysis reagents, and general labwork.Since beginning work at RAS, Ma. Whitworth has gained experience in theanalysis of cyanides in water and sediments. Due to her expertise incyanide analyses, she is a participant in Radian Analytical Services 'Contract Laboratory Program as a Classical Inorganic Techniques Analyst.Ms. Whitworth'a laboratory experience prior to Radian include environmen-tal analyses for the Lower Colorado River Authority, quantitativeanalysis for uranium mining and milling, and quality control*
001514
DOCUMEKT
H3H£s Serial * *> €ag$ # - Region - Ifcea&gsd Document
DQCUt-lBffiS
REPORTSTAGS (NEIC only)
(L^CHAIN OF CUSTODY ( "(IKAIRBILL { "f^Y RADIAN SATtPLE RECEIPT ("(t-T^ADIAN IORKORDER ( "( } TELEPHOME LOG
REPOPT PKG
ICP DM*A(-^Benchsheet?(i^lnstr Log J '( *TStd Sources - /
Data
GRAPHITE FURfJACE DATA<T CALCULATION SHEETS
AS
nstr LogPaw Data
SEBI&L # OP PM5RS
0102030405
j- 06-- 07
.- 10
— Tfl
25
30
CASE I - REGIO!ORIGIHM.
001515
M» *•»« •!• . • •:C O R R O Wl»T ION
PA6E 1CLIENT:PROJ:COMPANY
FACILREP
PHONE
TAKEN^TRANS^P TYPE
REPORTTO
AfTENINVOICE
TO
ATTENP 0 #
Jt PREV
Analytical 5e?v WORK ORDERCLP 1NORS CON: WJFORD GAT:6RQUP 10 01/13/86 13 : 17 :59USEPA .. . . . . . . . . . . . . . . . . . __„.. . . . . . . . . . INVOICE BY R DEPTS/ DASHinof oanic ...... XFB..^...Linda Haas . . . . .7Q3-557-34TO .case 5421. rfc&J&n 6CDM£e^ Ex . . . . . . . . . . . : . . . , .
USEPAContract Labor.atoru ProaramBox 818 . . . _ . . . .^^tJt»TWir4fl-» 1VftJ22J|^3SMOAccounting .Qf.£lc« <PH5'-32)Financial fla&a&aaieftt DivisionResearch Trian*ale ParkNC S7711Accountina Of $!c«r_contract &S—Oiii^fo^©0TRf^^OIlT Re^O^TED INVOICED
X SURCHARGE TESTS% DISC: AU-
TEST/JOS 02 A# REP/INV 3 3 03 144
SAMPLES &KEEP FOR 6OKEEP TIL O4/13/8&
DISP SQUOTED *SAHPLE * 2352. OO 11 5
MISC *TOTAL * 2332, OO
INV #CREATED Ol/ 13/36WRITTEN 01/13/86
TRANSMIT Ql/13/86COMPLETEREPORTEDINVOICEDTOTAL *
Q1AO1B02AO2BO3AO3BO4A04BO5A05B06AG68
——— -
LAB 1 86-01-04?RCVD: 01/13/86 DUE: 02/12/86STAT: TRANSMITTED 01/13/86
SAMPLE IDENTIFICATION JQSMFC O2O Iw -fie lds blank 1AND2MFCMFCMFCMFCMFCMFCMFCMFCMFCMFCMFC
O2O Itii field blank038 Is038 IsO39 Is039O4O l-s040041 Is041042 IsO42
1 2 31 2 31 2 31 2 31 2 3
WORK ORDER COMMENTS
001516
U.S. ££A Contract Laboratory ProgramSaaplfi Managatoant OfficeP.O. Box 8Ib - Alexandria, VA 22313703/557-2490 TO: 8-557-2*90 Date
COVER PAGEANALYSES DATA PACKAGE
SOW Q.C. Report No
Ub ID No. EPA No. Lab ID No
Cotmienes:<^
ICP Interelement and background corrections applied? Yes No ___.If yes, corrections applied before v or after ____ generation of raw data,Footnotes:NR - not required by contract at this timeForta I:Value - If the resulc is a value greater than or equal to the instrument
detection limit but lass than the contract required detection limit,report che value in brackets ( i .e . , [ I O J ) . Indicate the analyticalawthod used with P (fot ICF/Flamc AA) or F (for furnace).
- Indicates element was analyzed for but not detected. Report with thedetection limit value ( e .g . , 10U) .
- Indicates a value estimated or not reported due to the preaanca ofinterference. Explanatory note included on cover page.
" Indicates value determined by Method of Standard Addition.- Indicates spike sample recovery is not withia control limits.- Indicates duplicate analysis is not within control limits.- Indicates the correlation coefficient for method of standard addition isless than 0.995
0
- 6
001517
Fora IU.S. £?A Concracc Laboratory ProgramSae?i& Manageseae OfficeP.O. Bex 81* - Alexandria. VA 22313703/517-2490 ft!:. 8-557*2490
SAMEsou so.LAS SAMPLE ID. NO.
|EPA saapla No
DaceINORGANIC ANALYSIS DATA SHEET
CASE MO.
QC REPORT MO.
Elements Idencified and MeasuredjConcentrat ion: Low *•
Mac
I.2 .3 .4.5.6 .7 .8 *9.10.1 1 .12 .
nx: Water Soil
,— *— 7 //Aj-uainua O / {/(Ancisonv 1 ty Ll $\Arsenic /. ^?^/,> ^Sariua 1 1 L{ServLliuo ,V7WCadaiua /, ^,/Caicma C_5~7 \Chrataiura -3-^lLCabals j~T. / /Coooer ^2. 8Utron I3.ULLead /./^- /t
^^*-~~*~' ~*X
rfg/!cg/r£f*PPpp9P9P
f-Cyanide ri4Ld£~ fcnn H A
1 4
15161 718192021222324
MediuaSludge Ocher
weight (Circle One)Matmesium f? / IA~Manganese . ~7 (AMercur'' 0.&3&H
. Nickel & {&UPoe^ss iua /(JolsLSelenxaa /• £ tjSilver c^?- 3LLSodium t- / 3tf )
. Thallium $ . $7u
. Tin 4-. ^7^4 f
. Vanadiua I^Hi
. Zinc 3' 3 H
/? &v*pp#. ffc ppff}p
Percent Solids (*) \;f€&'C(ft?1/W&lfe>Footnotes: For reporting results to EPA, standard result qualifiers ara used
as defined on Cover Page. Additional flags or foocnotas explainingresults Are encouraged. Definition of such flags muse be explicitand contained on Cover Page, however.
_!xAn_aau.eQu$ $g] L blank ' -fn ft,
Lab .'Unager
001518
Fora IU.S- SPA Concrace Laboratory PrograaSacpie Management OfficeF,0. Box 818 - Alexandria. VA 22313703./S57-249Q FTS;. * *557-2t90
IE? A aaapia No,
SOU NO. ____LAS SAMPLE ID. ;
BacssANALTStS DATA SH££t
CASE NO.
QC REPORT NO.
Elements IdetiCifitsd and MeasuredConcentrat ion:Matrix: Water
1. Aiuainua2. ABCiaonv3. Arsenic
Low 2</</-^^ MediuaSoil ->* Sludge Ocrter
/ug/L 'or sag/kg dry weight (Circle One )
1 ^ . Manzanese15 . Hercurv
4, Sanuai 16. Nickel5. Bervlliua6. Cadalun7. Calciuo8. Chrasaiua9. Cobalt10. Coooer1 1 . Iron12. LeadCyanide __ /Of
17 . Potass ium18. Seler-iuta19 . Silver20. Sodiua21 . thallium22. Tin23. Vanadium24. Zinc
I/ SL- Percent Solids (*)Footnotes : Foe reporting results to EPA, standard result qualifiers aca used
as defined on Cover Page. Additional flags or footnoeas explainingrasulta are encouraged. Definit ion of such flags oust be explicitand contained on Cover Page, however.
Consents:
Ub Manager
001519
Fora IU.S. E?A Contract Laboratory Program
ii Manageaeat Office, Sox 816 - &l*x«ndri*, VA 22313
E? A No.
DaceANALYSIS DATA SHEET
CASE »0.sow so. ?^^LAB SAMPLE ID. NO, I^DIDLf?"t
ElementsConcentrat ion: Lotf vMatr ix : Water Soil
ug/L or aV.
1 . AJ. as! sum fa (0CO_ i r - -. O / /V O
3. Arsen ic ^i j?, b 1 & /t
03. QC REPORT NO, 5^?/
Identified and Measured
s42—-""
P
f
MediuaSludge Ocner
)dry weight (Circle One)13. Magnesium / Qff^-) J P14. Manzanese 13 - l\ P15. Mercur*' f 0 . £-4-~~] cvrftf
ft. Sanum /. 3_ O 73 /^ 16. Nickel h> &LL. p5. 8«rvi:iua . fyQLL6. Cadoiua /. $ UL7, Caici.ua / /£r'/'£)_^8. Chrcaiua / ^,$ _j9 . Co bal t ^, *5 (jL10. Cotsner -*},OLL-U. Iron _337<012. Lea^d _ ^/ ^Cyanide ^ ^. -^//y, x^FoocnoGcs : Foe reportir .tr results
PPPPPPP/r
to F
17. Potassium ^^^^ _> p18 . Selenium / * & ? £ - * • $ £ X=19. Silver o>- 5 IL R p20. Sodium ^5!O"7"3 /°21. Tha.Uium ^. ,?/^< A22. Tin .^, 0 M ^23. Vanadium I^LL f>24. 2inc /T^-7~3 /*Percent Solids f") <7^
:PA, standard result aualif iers are ustas defin«d on Covar Page. Additional flags oc foocnocas explainingresults ar« encouraged. Definition of such flags muse be axpiici:and contained on Covee Page, however.
Co cm eat s :
Lab Managar
001520
uOQc
133
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340coT3Oc--4*du?•TJC*
001521
Fora IU.S . £PA Coneraee Laboratory ProgramSacple Manageaeat OfficeP.O. Box SIS - Alexandria, VA 22313703/557*2490 ?T$J
|E? A Saapie No
INORGANIC ASALmS DATA SHEET___. . . CASE NO. _.g>MjM
sow sc.LAB SAMPLE ID. MO. Tl0QlO{47'03 QC REPORT MO.
Elements Identified and MeasuredConcencracion:Macr ix : Uacar
1. Aluminum2. Anciscnv3. Arsen ic4, Bariua5. Berviiiuta6. Cadaiua7. Calciua8. Chrataiuta9. Cobai:10 , Coocer1 1 . Iron12. LeadCyanide
Low vSoil i/^
ug/L °r/^AgJlir7JWDO 1> u^53 /? ^ u
Q.& ^ /L ? 15^"^<? 3 ^ 1 6^"o2, "1 /^ i7
t.5U P is3^5/9 ^ 19£7 p 20^O ^ 21^4 ^ 22i-l <55£Q P 23^.^ A. .5- X 24
HediuGSludge
weight: (CircleHasnesiufflManaanese
. Kercurv ,. Nicxel
PoeassiuTa iSeleniua
. Si lverSodiumThallium
. TinVanadium
. Zinc
Oc.ner
One).3 /CO _.. P*-li£ft R P
<?.0f& u Cv##4-0 Pr^uo] P/.3u$ ^_ ^
o?, k>« /? /^fi030~l Pf. 9-^u ^.#I/.^_- ... . . . . . ^703 ^f-fO P
O.ljtu % Percenc Solids (t) ^/5_Foocnocas : For capocclng results to SPA, standard rasulc qualiftars are used
as dafined on Covar Page. Additional flags or foocnoces «xplaiair.geaaulcs are encouraged. Definit ion of such flags muse be explicitand contained on Covar Page, hou«v«r.
Cotamants
Lab Manager
001522
Fora IU.S . E?A Contract Laboratory PrograaSadpla Managesent OfficeP.O. Box 818 - Alexandria, VA 22313703/557-2490 fTSi 8»5S7*2490
Saapit .No
Date
ussou so.
ANALYSIS DATA SHUTCASE MO.
LAB SAMPLE ID. NO. <5(&Q\ 0^47 QC R£?ORT MO.
Concentrat ion:Matrix: Water
Elements Identified and MeasuredLow
SoilMedina
Sludge ___ Ocner
1 .2.3.4.5.6.7 .8 .9.10 .1 1 .12 .
Alusunum
Arsenic3ariua
CaiciuaChrsaiuaCobaltCoonerIronLead
Cyanide
ug/L or jfig/tcgjlry weight (Circle One)P 13. Maenesiura
.5114
&J.
Cctoaencs:
R
£P
Percent Solids
P14 .
15 .16 .1 7 .1 8 .19 .20.2 1 .22 .23 .26.
Manganese o?*-/Her cur*' & •# 3*7 Nickel __ /^ / UPocass iua £*d2. / *? 7^Selenma / y'^-/,^ ^Silver o?. 6? i^Sodium ^_\ "5>(-?/ ^3Thallium ^ , *7/^/Tin ^- / u tfVanadium /^ ^,(2inc /LA S^^ 5
/? p0p
£ fp/=•fp
Foocnocaa: For reporting resales to EPA, standard rasulc (tuali*i*rs are usedas defined on Cover Page. Additional flags or faacnocas explainingresults are encouraged. Oefinic ion of such flags BJUS: be axplici:and concainad on Cover Page , however.
Lab :una««:
001523
Fora IU*S. £?A Concraec Laboratory ProgramSac?la Managasenc Off icef.O* Box 818 - AlaxandrtA, VA 22313
sow N°-LA3 SAMPLE ID. NO. Qjj [7~
[EfA baa? la So.
DaceXH0RGANIG AWALTSIS 0AtA SHE&T
CASE NO.
R£?ORT MO.
Identified and MeasuredConcencrac ion :Macr i . t : ' »Jacer
1 .2 .3 .4.5 .6 .i8 .9 .10 .1 1 .12 .
AluainuasAncizonvArsenicBariua8er''lliuaCadaiuaCalciuaChrataiasCobal:CoolerIronLead
Low ySoil v^
/- —— Nug/t or^jag/k-gyd
^-5 /? /c?/4 J £. £
/Oh P.f53Lt P/, ts?U P%3ffOD P
- ./.9, ^_/"77"7 . . .. ^./"//T" /^-g- —— UL~_j ————————————— ™,
"7 / "vWn /9<V--/ oL.-'LJ r6". <=> J- ^
Cyanide & . iJ / ,, tf"Illar i .if in B _- '. ' . L \. __ . /!_ - . _ . _ . . . .. . . . . ..
ry ^13 .
15 .16 .1 7 .18 .19 .20.2 1 .22 .23 .
MedianSludge Other
/eight (Circle One)Matrnesiua £>$*JOMansanese 7/ 9Mercur*' ^. ^?Mickel o{ 7Pocaas iusn o2(^o?fy
Si lver <3.~7USodiuta / o "3/>2 >Thallium & . tf$nTin 5T 4 uVanadium r*5 /Zinc 3^
Pereanc So Lids ( *) ( ,P
pf{ p(f t/tftf
pp£d Pj)prPP
Fooenoce s : For reporting results to EPA, standard rasulc qualifiers are usedas daflned on Co^er Page . Additional flags or footnotes *x?lainir.gresults are sncouraged. Definition at" such flags ausc be axpiici:and concainsd on Cover Page, however.
Coomenes:
Lab Manager
a -
001524
Fora IU.S . £?A Cone race Laboratory ProgranSacale Manageaanc Ofiicef .0 . 3ox 818 * AlAxandria. VA 22313703/537-2450 fT3: 8-557-2490
E? A Saapii No
INORGANIC ANALYSIS DATA SKtETLAB »AM£ JSQJWrsow so, "7^LAB SAMPLE ia. .vo.
wJl^Oum-l-O^CASE SO. ,3*-fc*ZI
QC REPORT N'O. ^Mj '
Element s Identified and MeasuresConcentrat ion:Matrix: Wacar
1. Al^2Linuoi2. Ancisonv3. Arsan i c4. 3arlua5. aer-'ii iua6. Cadaiu=7. Caiciua8. Chrooiuo9. Cobalt10. Coooer1 1 . Iron12. LeadCyaniie ^.Footnote s : For rap
Low \/Soil v/
/*—ug/L argg/fcj
^/ ^ ^/4 j JL f
135 P5*4 IL ^l.bU P
G3CD P-}^ P&< / r
1*4 P<338PO P/1 £ ?$#u SLorcing results to
MediuaSludge Otner
pdry weight (Circ le One )13. Maenesiuta L33&O1 < * . Manzaneaa <=»-?c2 /15. Mercur 1 ' /• &16. Nickel £/ <717 . Potasa iua ^/^r^t^?18. Seleniua /,3u$ &19. Si lver c?*7U20. Sodium ZT^TfO ~^>21. Thailiua <T . ^//22. tin *?.$&&23. Vanadium ^(J24. 2tnc ^>J2_Percanc Solids (*) QO
£PA. standard result qualifiers
pR PfiP^
/? PpfI*PP
are usias defined on Cover Page. Additional flags or footnotes explain!?.;results are encouraged. Definit ion of such flags muse be explicl:and contained on Cover ?aga,
Cooaenes:
Lab anagert>CQ
001525
UA HAttf
II-Q. C. (Upoe-t Ho.
IHZTUL AWD eOKtlHUlHft CALIBRATIONass HO.SOW 80.
Co^rol
.X./5" r/_7.Calihracion Source /-CQnciauing caabraci« Source
* a I , " "CUr7 "d TlnIndicac* Analyeical Machod Ug«d: P - AA; F - ruraace
B " 8
001526
FeraII -AQ. C. Report No*
LAS NAME
OATS //* /*&
INITIAL AND CONTINUING CALIBRATION VERIFICATION3
_____ CASE NO.SOU NO.
___ QUIZSConpound Initial Continuingit1 . Aluminum2. Ancioony
JL3. Arsenic*. Barium5. 8«ryllius6. Cadoium7. Calcium8. Chromium9. Cobalt
10. Coooer11. Iron12. Lead13. Magnesiua14. Manganese15. Mercur^— — • —— '— - —16. Nickel17. PotassiumIS. Selaniua19. Silver20. Sodium21. Thallium22. Tin23. Vanadium26. ZiacOther:
Cvanidc
Tru* Valu*ii_ _ i<J3 |
1it1
Found '
S3
2K
^/
„. 1
1
trua Value
4-3
1
Found
¥^
MR
/0$
Found
4-5-
Xft
/£F
\
Method4
/*
'
iiI
i Initial Calibration Source ffii^Jt/f/, 2 Continuing Calibracicsa Source3 Control Limits: Mercury and Tin 80-120; All Other Compounds '90 - 1 104 Indicate Analytical Mechod Used: P - ICP/Flama AA; F - Furnace
- 8
001528
fit PC
Q. C, Report No.
tAB HAHE
CATS
INITIAL AND CONTINUING CALIBRATION VERIFICATION3
CASE KG.
WHOCoHpautid Initial Calib. * Concinuin? Calibration^Metals :i. Aluminum2. Aneinsony3. Arsenic4, Barium5. B«rylliua6. Cadmium7. Calcium8. Chromium9. Cobalt
10. Copper
True Value £2u£i
11, Iron12. Lead13. Magnesium14. Manganese
ZR True Value Found
11
15. Mercurv <$.£> ^ •%16. Nickeli". Potass ium18. Selenium19. Silver20- Sodium21. Thallium22. Tin23, Vanadium24. Zinc^^ iOeher:
Cvanide
**
t
j.f 3.3
*H found
1
ZR
iii
Method*
1ii1
j i!fff \ -» " s*
\111
C,V&?
* Initial Calibration Source Mfi&rfz #& 2 Continuing Calibration Source3 Control Limits: Mercury and Tin- 80-120; All Other Compounds ' 90 - 1 104 Indicate Analytical Method Used: P - ICP/Flame AA; F - Furnace
Si #3
B - 8
001529
03'&
Fora ll-CIQ. C. Report No.
NAMEINITIAL AND CONTINUING CALIBRATION VERIFICATION3
________ CASE MO.SOW NO.UNITS
Coapound Initial Calib.1
Hetals :1. Aluminum2-. Ancitaony3. Arsenic4, Barium5. Serytlius6 . Cadmiutn7. Calcium8. Chroaiuo9. Cobalt
10. CoooerII. Iron12. Lead13. Magnesium14. ManganeseIS. Mercurv16. Nickel17. Potass ium18. Seleniua19. Silver20. Sodium21. Thalliuts22 . Tin23. Vanadium26. ZincOther:
Cvanide
True Value
&.$
Found
. _
£.*j
XR
|1
I
^1
True Value
i
1s.s
Found
<?• 4-
a
^
Found aIMethod6
1
ev#/?
(
Continuing Calibration SourceInitial Calibration SourceConcrol Limits: Mercury and Tin- 80-120; All Other Compounds '90-1 10Tndicaca Analytical Mechod Used: P - ICP/Flame AA; F - Furnace
B - 8
001530
ForaQ. C. Report No.
LAB HAMS CASEONUS
Preparation CalibrationBlank Value
Blank Value Preoaracion Blanlc1 2
1 . Aluminum U.2* Antimony Wit3 * Arsenic
Barium5, BtryUUua6. Cadmium7 . Calcium8 • Chromium9. Cobalt1011
ItuCooer ,C u 6. OnIron £/
12. Laad13. Maonesiura14. Manganese /.0U.
15. Mercury16. Nickel I [llSl1?. PotassiumIS. Selaniuta19. Silver20. Sodium L2 £Z^*- L-UL"~~JL:-LI
21. Thallium /.I LL22. Tin__23 * Vanadium24. ZincOther:
Cvanida /OILfire-p
001531
FormQ. C. Report Ho.
BUNKSLAB CASE HO,
ONUSM-acris
rCCattbrate 3,
PreparationCotaoound
SUtals:1 . Alualnum2. Aseiaony3. Ara«n±c4, Baritua5 . B«rr Ilium6. Cadmium7 . CdXclum3 . Chromium9 . Cobalc10. Cooa«r11, Iron
j^^eiaj^CalibracioaBlank Valu«
<^-^^c
T1
C00£j
I
^-^^
11
suiSKnCj!Blank V
2
f — "" " '
libfaticFalu«
3
_____
a
4Praearae
Iion Blank
2
... -iii
U. UadVrf » *13stn€3 1, tlQl
14, Manganese13. Mercury16. Hickal17. PocasaiumIS. S«l«aium19, Silver20. Sodium21. Thallium2*. Tin23. Vaoadiua24. ZincOther:
Cwanide
I
i•
I
| ______ ,|_
—————
I11
11
. , ! , ._ • i ii
B - 9
001532
fora III -Q. C. Report No.
BLANKSCASE MO.OHITS
CalibraclonPreparationCemoaund Praearacioe Blank
PocaastumSelanium
SodiumThalliumTia
001533
FoemQ* C. Raport Mo.
BLANKSus CASE MO.
owns
fropafaeidaCoooouod
Metals :1 . Aluainua2. Aatiaony3 . Ara sale4. Bariua5. Barvtlium6. Cadmiua7. Calcium3 . Chromium9. Cabal £10. Coot»«r11. Iron12. Uad13. Magnesium
JH4S&&CalibtacionBlaak ?alu«
1
C<5tUi
I
nui flft CjBlank ^
2
i i HE tt £«L-£alu*
3
-
rg
4
1
?r*parae.1
i
Ion Blank ,2
1
1
I
14. Manganese15. H«rcury16. Nickel17. Pocaaaiuai13. Selenium19. Silver20* Sodiua21. thallium^22. Tin .___23. Vanadium24. 2iacOchsr:
C. /£ u.
•
idie*
\\
.
<=?' /-P w.!
i
i ii-iCvanida
B - 9
001534
Q. C. Report Mo.BLANKS
PreparacionCotaoound
|jj&Ct*$CalibracidflBlank Valua
Calibf aciQQBlank Valua Preparation Blank(
1 2 IMctali:1. Aluminum2.3.
Barium5. Beryllium6. Cadmium7, Calcium3.9. Co bait10. Cooe r11* tr_an12.13. Maeneslua14.15. Mercury £0. '3716. Miekei17. Poeasaluta IIB* S«leaius19. Silver20. Sodium21* Thallium22- Yin TF23* Vanadium24, ZincOcher:
Cvanide
w g
001535
JVQ. C. Report No*
ICP INTfiRFEKNCi CHECK SAMPLECASE NO.
19. Silver20. jjpdiua21. Thallium22. Tin23. Vanadlun
1 Mean value based on nICP Interference Check Sample or
B - 10
•rt*.. i:
001536
LA3 N'AME
DATE
Fora V). C. Eteporc No. __ _SPI:<£ SAMPLE RECOVERY
CASE NO,EPA S«a?:« N'o-Lab 5aapi« 10Units
ICentral Limit | Spik«d Sa«ol« I SaaoU• ^^ . •** * **a^""""«^^™* BIfc* I «*H* HMACompound [ It | R**uU (3SR)
M«t1.2.3.
5.6.7 .8.9 .10 .1 1 .u.1 3 .U.1 5 .1 6 .1 7 .13 .19 .20.2 1 .22 .2 3 .24 .
iAluainuffl | 75- 125Anciaony f " /3&Arsen i c 1 " f?3ariua | " /C3QSeryUitrat " | c2£?Cadaiua | " ^2^Calciua (Chroaiua I " | / / 3>£obalc - ^S^Coooer • ILL Ironlead 1 5 Magnes iumManzar.ese ' . =2 *•?Merc-jrv - ^7, ^^Nickel ' o2*?/}Pocass iua " 1Seleniaa - /. ^^Silver - /<9SodiuaThalliua * $ 0^Tin - ^-7^i i"** / j*^t
* t) * * o G J» LiCJI ^ \ **^fi v7—— » — « ————— . _JX v»— *^*r^^
Zinc - ! ^27*4Other :
Cvanidt
| Ram 1C (SB) Add*d fSA) f ?R:
ii i/S53 All ! V/' f.^ ^/ * ^^t ^T9^3 /^7 ! ^6*
r""™^5 *^ "v^ "N ^f , y t-f/ i^' » c^ _j *yt- I iiil.fjtL A1 » /?4i57 i LO^L ' 7^^D j? 7<2 ' SV^^f 7^6^ ( Jff\6-3 <?£ \ /at.
\^(^ c£7<^ \ <3<^LC . Q £&* P && ! /^^Ltr\ ^7.2 i ^) 5
i/ • j */ S • J \ &cv. (j(?\.s\ <=*• 1 t /t-'
j 1^.^c/ ^^ 1 /$<r./u, £•?-& 1 //^/jC3 ^?7c2 ' ^6^
f ^ <9 ^7O- ' ?O1
| ___ iI
- SRJ/5A , x ioo"R"- ^uc cc concrol-oeccncs:
8 - 1 1
001537
gsrg VIQ. C. Report No,
;a?r_:
r? Ko* gfaOtpyi'DZ.
C^ar.zde* Out or Control
ro be added at a later dace . ._ _ l |U
- Son calculable RPD due co valu«(s) less chan CRDLRPD D ) / : j ] x 100
B - 12
001539
VIIQ.C. Sapost Ho.
WSTWMfiHT DETECTION LIMITS AKDLABORATORY CONTROL 5AMPLE
us HAMS KOAWiiLOATS &J/6/ $bi
Compound
1 * Aluminum2. Antimony3* Arsenic4. Barium5. Beryllium6 . Cadmium7. Calcium8. Chromium9. Cobalc10. Coooer11. Iron
Reduirad Dec ace ionLimits (CRDL)-U!?/1
2CO6010
20055
30001050
CAS£ HO.LCS UHITS
;lageruaene Deeaceion |Uffllea (ICL)-y?/l |ICP/AA Furnace 1
/32 !
, , , „ , , ^& fflg/»fi(Circia One)
|Lab Control Satn&le jTru« Found t%_ . .„.„,„n%n / -7*^ /o /^^ //* /^J HT rS
j V/ ! £OOO\ M3P ID fi33
^•^ i &O0 /#& <9& \t j I^DrfY)\'i "7///OA '5<y'7[ 1 a£\J,U(JU \ j /t-fisLA 0 l
1.0 \ £35 £0^ ^13<O 3<1 33 ?S70
25/ /
£jbl 3£7 ?71 £b / £30 %% f
£>,£ j 33^ 305 qOtoo II a.b \ 7Q b 73£> 100
12. Lead 5 113. Magnesium! 500014. Manganese15. X-ireury16. Nickel17. Potassium13* Selenium19. Silver20. Sodium21- Thallium22. Tin23. Vanadium
150 .2
405000
5 ..... .
J. X 1 £$£> 1 -*/-!» ^V
/^^ \3D.OCQ ifflQQ <?/I>O .3^g 5// ^9 f
-*-f) .££> J^tj \f&/nP M~4sT\&££.
/JL£33-
103000
104050
24. Zinc 20Other:
j.4&.Oqq
/,^_
3,0 3.6 /£<?<5C* ' /^v o 7
'"vn fYY)\ i '/^/*y) 0 /O.5"<2 _5"/? /^) ^7~~)f~y^rji \ ~Jt-lf} ^ ~73 *?/) *) 3 *? f3 £/ irtjvtx t&^yZ* ' / i
* | / A
3D gift*, 741 ?Y7. 0 ///r 377 3n
i 1C/anids I 10 /C
i ix^yi // 3? ^J7/&<O 110 i a
8 - 1 3
001540