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Table 1Solubility Constants and pzc and iep Values of Natural and S)'nthetic Salt-Type ~fi,.er~
Solubility Electrochemical propenies
Salt-type compound pKso Method"pzc or icp, pH Conditions'
pzc4.~.Oiep 6.2iep 2.3-10.7iep 2.3iep3.4iep 10.2iep 10.8iep 8-8.5pzc 8.2lep S.S-6pIC <5iep~.5iep <7.0pzc 4.0pzc 2.8iep3.4iepS.6iep-4iep -6pzc6.9~0.2iep7.0plc8.S~0.2iep8.Siep 3.8-1.9
A~AglAuorite. CaF,Gypsym. CaS04"2H2OCele$tite. srS04Barite. B&50.Scheelite. Caw04Calcite. Caco)Calcite. CaCO)Calcite. Caco)Calcite. CaCO, "
Araeonite. CaCO)Magne$ite. M,.cO)Dolomite. (Ca. MgI CO)Eggonite. AlPO4"2H.OStrenaite. FePO4o2H;0Monmte. (Ce. La. Th) PO4Auroapatite. Ca'I)(PO.)~(F. OHhAuorapatite. Ca1n(PO.)..(F. OH);:Auorapatite. Ca\n(PO4)~(F. OH),F1uorapatite. Ca\o(PO4)&F,Auorapatite. Ca,n(P04).F2Hydroxyapatite. Ca\o(PO.)~(OH).Hydroxyapatite. Ca,.,(PO4)..IOH);frana>lite. Ca\oIC. PO.I..IF. OH):
SPSPSPSPMEMESPTDSP
SPSPDRDRMESPSPSPTIMETIMESP
10.0 pA,4.1-4.616.0 pA,5.1-6.210.3 pc:a2.6-7.74.66.29.7 pS.3.9-7.09.0 pC. 4.0-4.88.4
pCa 3.5. pCO) 3.0
8.24.9
16.721.023.0
Syn.Syn.Nat.Nat.Nat.Nat.Nat.. aged 2 hr. NaONat.. aged hoursNat.. aged daysNat.. aged daysAged 30 min.Nat.Nat.. aged 30 min. KONat.. aged 30 min. KOSyn.Syn.Nat.Nat.. aged hours. KNO,Nat.. a&ed hours. KNO,Nat.. aged days. KNO,S)'D.. a~ed S04 hr. KNO,Syn.S)'D.. aged S04 hr. KNO,S~.Nat. microcn'St..ae~.J ;\11 min. KCI
119.1
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pCB 4.38. pHPO. 4.19
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